Water-soluble algal polysaccharides (APS) (alginic acid, fucoidan and laminaran) possess many pharmacological activities. The results of this study showed that the APS- Ce4+ complexes have some enzyme-like activities....Water-soluble algal polysaccharides (APS) (alginic acid, fucoidan and laminaran) possess many pharmacological activities. The results of this study showed that the APS- Ce4+ complexes have some enzyme-like activities. Fucoidan and its complex with Ce4+ have activities similar to those of SOD. The activities of laminaran, alginic acid and their complexes are not measurable. The APS do not show measurable activities in the digestion of plasmid DNA. In contrast, the APS- Ce4+ complexes show these measurable activities under the comparable condition when APS bind Ce4+ and form homogenous solu-tions. The laminaran- Ce4+ complex shows the most obvious activity in the digestion of plasmid DNA, pNPP and chloropy-rifos under neutral conditions.展开更多
Enteromorpha polysaccharide （Ep） extracted from alga a novel green coagulant aid for nanoparticles （NPs） and heavy metal ions removal and the structure of EP was intensively studied in this study. The integration ...Enteromorpha polysaccharide （Ep） extracted from alga a novel green coagulant aid for nanoparticles （NPs） and heavy metal ions removal and the structure of EP was intensively studied in this study. The integration of Ep with polyaluminum chloride （PAC-Ep） coagulants exhibited higher coagulation performance than that of the polyaluminum chloride （PAC） because of the negatively charged NPs suspension and humic aid （HA） solution. Significant high removal efficiencies of dissolved organic matter （94.1%）, turbidity （99.3%） and Zn ions （69.3%） were achieved by the PAC-Ep coagulants. The dual-coagulation properties of PAC-Ep for different pollutants was based on multiple mechanisms, including （i） AI^3＋ charge neutralization; （ii） hydroxy aluminum hydroxyl bridging formed polynuclearhydroxy complexes bridge and sweep colloidal particles; （iii） adsorption and bridging of Ep chain for the NPs and heavy metal ions. Results indicated that the destabilization of colloid was induced by the coexisting HA and higher removal was achieved as ions adsorption was enhance in the presence of HA complexation. On the basis of that, the extraction of polysaccharide is a promising candidate for its high coagulation performance in water treatment.展开更多
文摘Water-soluble algal polysaccharides (APS) (alginic acid, fucoidan and laminaran) possess many pharmacological activities. The results of this study showed that the APS- Ce4+ complexes have some enzyme-like activities. Fucoidan and its complex with Ce4+ have activities similar to those of SOD. The activities of laminaran, alginic acid and their complexes are not measurable. The APS do not show measurable activities in the digestion of plasmid DNA. In contrast, the APS- Ce4+ complexes show these measurable activities under the comparable condition when APS bind Ce4+ and form homogenous solu-tions. The laminaran- Ce4+ complex shows the most obvious activity in the digestion of plasmid DNA, pNPP and chloropy-rifos under neutral conditions.
文摘Enteromorpha polysaccharide （Ep） extracted from alga a novel green coagulant aid for nanoparticles （NPs） and heavy metal ions removal and the structure of EP was intensively studied in this study. The integration of Ep with polyaluminum chloride （PAC-Ep） coagulants exhibited higher coagulation performance than that of the polyaluminum chloride （PAC） because of the negatively charged NPs suspension and humic aid （HA） solution. Significant high removal efficiencies of dissolved organic matter （94.1%）, turbidity （99.3%） and Zn ions （69.3%） were achieved by the PAC-Ep coagulants. The dual-coagulation properties of PAC-Ep for different pollutants was based on multiple mechanisms, including （i） AI^3＋ charge neutralization; （ii） hydroxy aluminum hydroxyl bridging formed polynuclearhydroxy complexes bridge and sweep colloidal particles; （iii） adsorption and bridging of Ep chain for the NPs and heavy metal ions. Results indicated that the destabilization of colloid was induced by the coexisting HA and higher removal was achieved as ions adsorption was enhance in the presence of HA complexation. On the basis of that, the extraction of polysaccharide is a promising candidate for its high coagulation performance in water treatment.
