Extraction of V（V） and Cr（III） from acidic sulfate leach liquors of ilmenite using 0.4 mol/L Aliquat 336 chloride in kerosene was carried out. Different parameters affecting the extraction process such as equilibr...Extraction of V（V） and Cr（III） from acidic sulfate leach liquors of ilmenite using 0.4 mol/L Aliquat 336 chloride in kerosene was carried out. Different parameters affecting the extraction process such as equilibrium time, sulfate concentration, Aliquat 336 concentration, equilibrium p H and the extraction temperature were investigated. Extraction of V（V） and Cr（III） by Aliquat 336 involved anion exchange mechanism, and the extracted species are [（VO2SO4）R4N]org at low equilibrium p H for V（V） and [R4N-Cr（OH）4]org at high equilibrium p H for Cr（III）. Calculated thermodynamic parameters show that the extraction process is endothermic reaction for V（V） and exothermic for Cr（III）. Also, calculated values of ？Gex and ？Sex indicate that the extraction reactions of V（V） and Cr（III） proceed as non-spontaneous reaction is more random. V（V） and Cr（III） were stripped, precipitated, separated and calcined at 500 °C for 2.0 h to produce the corresponding oxide in pure form after rinsing and drying.展开更多
p-Aminobenzenesulfonic acid was selected as a typical solute withamphoteric functional groups to be separated from dilute solution. Aquaternary ammonium chloride, Aliquat 336, was used as theextractant. The effects of...p-Aminobenzenesulfonic acid was selected as a typical solute withamphoteric functional groups to be separated from dilute solution. Aquaternary ammonium chloride, Aliquat 336, was used as theextractant. The effects of pH, extractant concentration and diluenttypes on distribution coefficient, D, were investigated. Meanwhile,the ion exchange reaction for Aliquat 336 with p-aminobenzenesulfonicacid in the extraction process Was discussed. The description of Dwas proposed according to the mass action law.展开更多
文摘Extraction of V（V） and Cr（III） from acidic sulfate leach liquors of ilmenite using 0.4 mol/L Aliquat 336 chloride in kerosene was carried out. Different parameters affecting the extraction process such as equilibrium time, sulfate concentration, Aliquat 336 concentration, equilibrium p H and the extraction temperature were investigated. Extraction of V（V） and Cr（III） by Aliquat 336 involved anion exchange mechanism, and the extracted species are [（VO2SO4）R4N]org at low equilibrium p H for V（V） and [R4N-Cr（OH）4]org at high equilibrium p H for Cr（III）. Calculated thermodynamic parameters show that the extraction process is endothermic reaction for V（V） and exothermic for Cr（III）. Also, calculated values of ？Gex and ？Sex indicate that the extraction reactions of V（V） and Cr（III） proceed as non-spontaneous reaction is more random. V（V） and Cr（III） were stripped, precipitated, separated and calcined at 500 °C for 2.0 h to produce the corresponding oxide in pure form after rinsing and drying.
基金Supported by the National Natural Science Foundation of China (No. 29836130).
文摘p-Aminobenzenesulfonic acid was selected as a typical solute withamphoteric functional groups to be separated from dilute solution. Aquaternary ammonium chloride, Aliquat 336, was used as theextractant. The effects of pH, extractant concentration and diluenttypes on distribution coefficient, D, were investigated. Meanwhile,the ion exchange reaction for Aliquat 336 with p-aminobenzenesulfonicacid in the extraction process Was discussed. The description of Dwas proposed according to the mass action law.
