This work evaluated the effects of inherent alkali and alkaline earth metals on nitrogen transformation during steam gasification of Shengli lignite at the temperature of 873-1173 K in a fluidized-bed/fixed-bed quartz...This work evaluated the effects of inherent alkali and alkaline earth metals on nitrogen transformation during steam gasification of Shengli lignite at the temperature of 873-1173 K in a fluidized-bed/fixed-bed quartz reactor. The results indicated that the alkali metal Na and alkaline earth metals Ca, Mg in coal have different effects on inherent nitrogen transformation to NH3, HCN and char-N during the lignite steam gasification. Specifically during the steam gasification of Shengli lignite, Na and Ca, Mg not only catalyze the inherent nitrogen conversions to NH3, but also promote the secondary reactions of the nascent char-N as well as the generation of NH3 from the generated HCN, meanwhile they also inhibited the inherent nitrogen conversion to HCN and char-N. The presence of Na, Ca and Mg hindered the formation of oxidized nitrogen (N-X) functional groups, but enhanced pyridinic nitrogen (N-6) and quaternary nitrogen's (N-Q) formation in char.展开更多
Soil alkali-hydrolyzable nitrogen, which is sensitive to N fertilization rate, is one of the indicators of soil nitrogen supplying capacity. Two field experiments were conducted in Dongtai(120°19″ E, 32°52...Soil alkali-hydrolyzable nitrogen, which is sensitive to N fertilization rate, is one of the indicators of soil nitrogen supplying capacity. Two field experiments were conducted in Dongtai(120°19″ E, 32°52″ N), Jiangsu, China in 2009 and Dafeng(120°28″ E, 33°12″ N), Jiangsu province, China in 2010. Six nitrogen rates(0, 150, 300, 375, 450, and 600 kg ha^(-1)) were used to study the effect of N fertilization rate on soil alkali-hydrolyzable nitrogen content(SAHNC), subtending leaf nitrogen concentration(SLNC), yield, and fiber quality. In both Dongtai and Dafeng experiment station, the highest yield(1709 kg ha^(-1)), best quality(fiber length 30.6 mm, fiber strength 31.6 c N tex^(-1), micronaire 4.82), and highest N agronomic efficiency(2.03 kg kg^(-1)) were achieved at the nitrogen fertilization rate of 375 kg ha^(-1). The dynamics of SAHNC and SLNC could be simulated with a cubic and an exponential function,respectively. The changes in SAHNC were consistent with the changes in SLNC. Optimal average rate(0.276 mg day^(-1)) and duration(51.8 days) of SAHNC rapid decline were similar to the values obtained at the nitrogen rate of 375 kg ha^(-1)at which cotton showed highest fiber yield, quality, and N agronomic efficiency. Thus, the levels and strategies of nitrogen fertilization can affect SAHNC dynamics. The N fertilization rate that optimizes soil alkali-hydrolyzable nitrogen content would optimize the subtending leaf nitrogen concentration and thereby increase the yield and quality of the cotton fiber.展开更多
Plenty of inorganic nitrogen in wastewater can cause the eutrophication in water bodies, so it is an important task to remove nitrogen. Purification role was realized by absorption, filtration, depositon, evaporation,...Plenty of inorganic nitrogen in wastewater can cause the eutrophication in water bodies, so it is an important task to remove nitrogen. Purification role was realized by absorption, filtration, depositon, evaporation, nitrification and denitrification of microbes. Although the studies of Phragmites austrilis bed in the constructed wetland are popular, the purification performances of constructed wetland filled by saline-alkali soil substrate are less reported. In the paper, the purification efficiency of nitrogen with Phragmites austrilis bed in the constructed wetland filled by saline-alkali soil substrate was discussed through a simulation study. Results to date indicated that the first order plug flow model was adequate to describe the nitrogen removal. The experiment showed that the diminishing concentration of TN, NO 2-N, NO 3-N, NH 4-N were closely related to hydrological retention time (HRT), the correlation coefficient was R 2=0.98499, R 2=0.9911, R 2=0.89407 and R 2=0.95459, respectively. According to the data, the most suitable hydrological retention time (HRT) for this kind of constructed wetland should be determined to 4 days. In addition, the experiment showed the purification efficiency of nitrogen has very broad range and drastic vibration, TN (17%-79%), NO 2-N (33%-98%), NO 3-N(13%-93%), NH 4-N (28%-64%). The study will promote wetland’s design and operation procedures in large saline-alkaline soil areas.展开更多
基金The authors gratefully acknowledge the financial support provided by the 12th Five-Year Plan of National Science and Technology Support (Grant 2012BAA04B02)the National Natural Science Foundation of China (No.21406261).
文摘This work evaluated the effects of inherent alkali and alkaline earth metals on nitrogen transformation during steam gasification of Shengli lignite at the temperature of 873-1173 K in a fluidized-bed/fixed-bed quartz reactor. The results indicated that the alkali metal Na and alkaline earth metals Ca, Mg in coal have different effects on inherent nitrogen transformation to NH3, HCN and char-N during the lignite steam gasification. Specifically during the steam gasification of Shengli lignite, Na and Ca, Mg not only catalyze the inherent nitrogen conversions to NH3, but also promote the secondary reactions of the nascent char-N as well as the generation of NH3 from the generated HCN, meanwhile they also inhibited the inherent nitrogen conversion to HCN and char-N. The presence of Na, Ca and Mg hindered the formation of oxidized nitrogen (N-X) functional groups, but enhanced pyridinic nitrogen (N-6) and quaternary nitrogen's (N-Q) formation in char.
基金funded by the National Key Technology R&D Program of China (No. 2014BAD11B02)the Special Fund for Agro-scientific Research in the Public Interest (No. 201203096)+1 种基金the National Natural Science Foundation of China (Nos. 31401327, 30971735)the China Agriculture Research System (No. CARS-18-20)
文摘Soil alkali-hydrolyzable nitrogen, which is sensitive to N fertilization rate, is one of the indicators of soil nitrogen supplying capacity. Two field experiments were conducted in Dongtai(120°19″ E, 32°52″ N), Jiangsu, China in 2009 and Dafeng(120°28″ E, 33°12″ N), Jiangsu province, China in 2010. Six nitrogen rates(0, 150, 300, 375, 450, and 600 kg ha^(-1)) were used to study the effect of N fertilization rate on soil alkali-hydrolyzable nitrogen content(SAHNC), subtending leaf nitrogen concentration(SLNC), yield, and fiber quality. In both Dongtai and Dafeng experiment station, the highest yield(1709 kg ha^(-1)), best quality(fiber length 30.6 mm, fiber strength 31.6 c N tex^(-1), micronaire 4.82), and highest N agronomic efficiency(2.03 kg kg^(-1)) were achieved at the nitrogen fertilization rate of 375 kg ha^(-1). The dynamics of SAHNC and SLNC could be simulated with a cubic and an exponential function,respectively. The changes in SAHNC were consistent with the changes in SLNC. Optimal average rate(0.276 mg day^(-1)) and duration(51.8 days) of SAHNC rapid decline were similar to the values obtained at the nitrogen rate of 375 kg ha^(-1)at which cotton showed highest fiber yield, quality, and N agronomic efficiency. Thus, the levels and strategies of nitrogen fertilization can affect SAHNC dynamics. The N fertilization rate that optimizes soil alkali-hydrolyzable nitrogen content would optimize the subtending leaf nitrogen concentration and thereby increase the yield and quality of the cotton fiber.
基金NortheastInstituteofGeographyAgriculturalEcology,CAS .(KZCX3 SW NA 13 )
文摘Plenty of inorganic nitrogen in wastewater can cause the eutrophication in water bodies, so it is an important task to remove nitrogen. Purification role was realized by absorption, filtration, depositon, evaporation, nitrification and denitrification of microbes. Although the studies of Phragmites austrilis bed in the constructed wetland are popular, the purification performances of constructed wetland filled by saline-alkali soil substrate are less reported. In the paper, the purification efficiency of nitrogen with Phragmites austrilis bed in the constructed wetland filled by saline-alkali soil substrate was discussed through a simulation study. Results to date indicated that the first order plug flow model was adequate to describe the nitrogen removal. The experiment showed that the diminishing concentration of TN, NO 2-N, NO 3-N, NH 4-N were closely related to hydrological retention time (HRT), the correlation coefficient was R 2=0.98499, R 2=0.9911, R 2=0.89407 and R 2=0.95459, respectively. According to the data, the most suitable hydrological retention time (HRT) for this kind of constructed wetland should be determined to 4 days. In addition, the experiment showed the purification efficiency of nitrogen has very broad range and drastic vibration, TN (17%-79%), NO 2-N (33%-98%), NO 3-N(13%-93%), NH 4-N (28%-64%). The study will promote wetland’s design and operation procedures in large saline-alkaline soil areas.
