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A Sustainable Synthesis of 2-Benzoxazyl and 2-Benzothiazyl Ketones from Alkynyl Bromides and 2-Amino(thio)phenols Promoted by a Recyclable Catalytic System
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作者 崔良艳 何艳 范学森 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2012年第4期992-996,共5页
An environmentally and economically sustainable synthesis of 2-benzoxazyl ketones and 2-benzothiazyl ke- tones through FeC13·6H2O catalyzed tandem reactions of alkynyl bromides with 2-amino(thio)phenols in [bmi... An environmentally and economically sustainable synthesis of 2-benzoxazyl ketones and 2-benzothiazyl ke- tones through FeC13·6H2O catalyzed tandem reactions of alkynyl bromides with 2-amino(thio)phenols in [bmim]BF4 has been developed. Remarkable advantages of this new synthetic strategy include high efficiency, readily available starting materials, and recyclable catalyst and reaction medium. 展开更多
关键词 2-benzoxazyl ketone 2-benzothiazyl ketone alkynyl bromide FeCl3·6H2O ionic liquid
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