The value of a drawing die's cone angle has great influence on wire drawing. In order to determine the optimum value of a drawing die' s cone angle, the plastic deformation power Wi, shear deformation power Wi and f...The value of a drawing die's cone angle has great influence on wire drawing. In order to determine the optimum value of a drawing die' s cone angle, the plastic deformation power Wi, shear deformation power Wi and friction power of contact surface Wf were calculated using the upper bound theory with a reasonable and movement permitted velocity field according to the related characteristics. Then the relation between half cone angle and unit drawing force was obtained and it was compared with the result with the spherical velocity field. The relative error of the two near the optimal value is only about 0. 26% through comparing with existing calculated results. Finally, in an ABAQUS environment the finite element modal of the wire rod with 12. 5 mm diameter in first drawing pass was established and the axial drawing force in different cone angles was obtained using the ABAQUS/Explicit explicit integration method. The finite element method (FEM) results verify the results using the upper bound theory and this indicated that the velocity field and the relation between half cone angle and unit drawing force reasonable.展开更多
Flange earrings of strong anisotropic sheet metals in deep-drawing process are numerically analyzed by the elastic-plastic large deformation finite element formulation based on a discrete Kirchhoff triangle plate shel...Flange earrings of strong anisotropic sheet metals in deep-drawing process are numerically analyzed by the elastic-plastic large deformation finite element formulation based on a discrete Kirchhoff triangle plate shell element model. A Barlat-Lian anisotropic yield function and a quasi-flow corner theory are used in the present formulation. The numerical results are compared with the experimental ones of cylindrical cup drawing process. The focus of the present researches is on the numerical analysis and the constraining scheme of the flange earring of circular sheets with strong anisotropy in square cup drawing process.展开更多
This paper explores the data theory of value along the line of reasoning epochal characteristics of data-theoretical innovation-paradigmatic transformation and,through a comparison of hard and soft factors and observa...This paper explores the data theory of value along the line of reasoning epochal characteristics of data-theoretical innovation-paradigmatic transformation and,through a comparison of hard and soft factors and observation of data peculiar features,it draws the conclusion that data have the epochal characteristics of non-competitiveness and non-exclusivity,decreasing marginal cost and increasing marginal return,non-physical and intangible form,and non-finiteness and non-scarcity.It is the epochal characteristics of data that undermine the traditional theory of value and innovate the“production-exchange”theory,including data value generation,data value realization,data value rights determination and data value pricing.From the perspective of data value generation,the levels of data quality,processing,use and connectivity,data application scenarios and data openness will influence data value.From the perspective of data value realization,data,as independent factors of production,show value creation effect,create a value multiplier effect by empowering other factors of production,and substitute other factors of production to create a zero-price effect.From the perspective of data value rights determination,based on the theory of property,the tragedy of the private outweighs the comedy of the private with respect to data,and based on the theory of sharing economy,the comedy of the commons outweighs the tragedy of the commons with respect to data.From the perspective of data pricing,standardized data products can be priced according to the physical product attributes,and non-standardized data products can be priced according to the virtual product attributes.Based on the epochal characteristics of data and theoretical innovation,the“production-exchange”paradigm has undergone a transformation from“using tangible factors to produce tangible products and exchanging tangible products for tangible products”to“using intangible factors to produce tangible products and exchanging intangible products for tangible products”and ultimately to“using intangible factors to produce intangible products and exchanging intangible products for intangible products”.展开更多
The processing of measuri ng data plays an important role in reverse engineering. Based on grey system the ory, we first propose some methods to the processing of measuring data in revers e engineering. The measured d...The processing of measuri ng data plays an important role in reverse engineering. Based on grey system the ory, we first propose some methods to the processing of measuring data in revers e engineering. The measured data usually have some abnormalities. When the abnor mal data are eliminated by filtering, blanks are created. The grey generation an d GM(1,1) are used to create new data for these blanks. For the uneven data sequ en ce created by measuring error, the mean generation is used to smooth it and then the stepwise and smooth generations are used to improve the data sequence.展开更多
Following a quasi-dynamic scheme proposed by Minear and Toksoz (1970), thermal structures of subduction zonesfor different models by finite element method (FEM) were calculated. Density distribution and p-wave anomaly...Following a quasi-dynamic scheme proposed by Minear and Toksoz (1970), thermal structures of subduction zonesfor different models by finite element method (FEM) were calculated. Density distribution and p-wave anomaly ofsubduction zones were calculated at the same time. Comparing with seismological evidences and results of laboratories. it is proposed that earthquakes occurred below 400 km depth are probably controlled by anti-crackmechanism.展开更多
Limit equilibrium method (LEM) and strength reduction method (SRM) are the most widely used methods for slope stability analysis. However, it can be noted that they both have some limitations in practical applicat...Limit equilibrium method (LEM) and strength reduction method (SRM) are the most widely used methods for slope stability analysis. However, it can be noted that they both have some limitations in practical application. In the LEM, the constitutive model cannot be considered and many assumptions are needed between slices of soil/rock. The SRM requires iterative calculations and does not give the slip surface directly. A method for slope stability analysis based on the graph theory is recently developed to directly calculate the minimum safety factor and potential critical slip surface according to the stress results of numerical simulation. The method is based on current stress state and can overcome the disadvantages mentioned above in the two traditional methods. The influences of edge generation and mesh geometry on the position of slip surface and the safety factor of slope are studied, in which a new method for edge generation is proposed, and reasonable mesh size is suggested. The results of benchmark examples and a rock slope show good accuracy and efficiency of the presented method.展开更多
An unequal time interval sequence or a sequence with blanks is usually completed with average generation in grey system theory. This paper discovers that there exists obvious errors when using average generation to ge...An unequal time interval sequence or a sequence with blanks is usually completed with average generation in grey system theory. This paper discovers that there exists obvious errors when using average generation to generate internal points of non-consecutive neighbours. The average generation and the preference generation of the sequence are discussed, the concave and convex properties show the status of local sequence and propose a new idea for using the status to build up the criteria of choosing generation coefficient. Compared with the general average method of the one-dimensional data sequence, the two-dimensional data sequence is defined and its average generation is discussed, and the coefficient decision method for the preference generation is presented.展开更多
Controllable drawing roof coal mining method is applied either to rently inclined seam or to big dipping seam. This paper sums up four corresponding methods according to conditions of our country, and analyses the coa...Controllable drawing roof coal mining method is applied either to rently inclined seam or to big dipping seam. This paper sums up four corresponding methods according to conditions of our country, and analyses the coal-recovering effects and proves applicated conditions and measures for improving by "drawing coal theory of the ellipsoid". Its conclusion basically consists with practice. This work is of guiding meaning for designing drawing coal technology.展开更多
High-order harmonic generation of the cyclo[18]carbon(C_(18) ) molecule under few-cycle circularly polarized laser pulse is studied by time-dependent density functional theory. Compared with the harmonic emission of t...High-order harmonic generation of the cyclo[18]carbon(C_(18) ) molecule under few-cycle circularly polarized laser pulse is studied by time-dependent density functional theory. Compared with the harmonic emission of the ring molecule C_(6)H_(6) having similar ionization potential, the C_(18) molecule has higher efficiency and cutoff energy than C_(6)H_(6) with the same laser field parameters. Further researches indicate that the harmonic efficiency and cutoff energy of the C_(18) molecule increase gradually with the increase of the laser intensity of the driving laser or decrease of the wavelength, both are larger than those of the C_(6)H_(6) molecule. Through the analysis of the time-dependent evolution of the electronic wave packets, it is also found that the higher efficiency of harmonic generation can be attributed to the larger spatial scale of the C_(18) molecule,which leads to a greater chance for the ionized electrons from one atom to recombine with others of the parent molecule.Selecting the suitable driving laser pulse, it is demonstrated that high-order harmonic generation in the C_(18) molecule has a wide range of applications in producing circularly polarized isolated attosecond pulse.展开更多
The development of theoretical models for crystals has led to the evolution of computational methods with which much more thorough investigations than previously possible can be done, including studies of the nonlinea...The development of theoretical models for crystals has led to the evolution of computational methods with which much more thorough investigations than previously possible can be done, including studies of the nonlinear optical properties. There has recently been a rise in interest in 2-dimensional materials;unfortunately, measurements of the nonlinear susceptibility of these materials in the wavelength range of the order of hundreds of nanometers by traditional methods are difficult. Studies of second-harmonic generation (SHG) from the transition-metal dichalcogenides (TMDCs), MoS2 and MoSe2, have been reported;however, SHG from other typical van der Waals crystals such as GaSe and other transition metal monochalcogenides (TMMCs) has rarely been studied under the same conditions. In this study, the 211 (i = 2, j = 1, k = 1) elements in the susceptibility matrices of GaSe, InSe, MoS2 and WS2 were calculated and compared. A tendency for the SHG intensity to weaken as the wavelength increases from 500 nm to 1000 nm was observed for GaSe and InSe, and, apart from some periodic fluctuations, no clear increase could be seen for these two materials in the SHG response curve in the near infrared. By comparison, MoS2 and WS2 have obvious peaks in both the visible and infrared bands. Calculations of the SHG response show peaks at around 500 nm (for GaSe), 570 (for InSe), 660 nm, 980 nm (for MoS2) and 580 nm, 920 nm (for WS2). Moreover, similarities between the SHG curves for GaSe and InSe and for MoS2 and WS2 were revealed, which may be due to the similarities found for these two groups of crystals.展开更多
The article deals with the methodology of pseudorandom data analysis. As a mathematical tool for carrying out the research the extreme value theory was used that creates one of the directions in mathematical statistic...The article deals with the methodology of pseudorandom data analysis. As a mathematical tool for carrying out the research the extreme value theory was used that creates one of the directions in mathematical statistics, and is related to investigating the extreme deviations from the median values in probability distributions. Also, the methods for estimating unknown parameters and algorithm of random-number generation are discussed. The models of treatment the extreme values are constructed which are based on machine generated sample and approach is proposed for their future application for constructing forecasting models.展开更多
“Key competence”has become a hot vocabulary in educational reform in recent years.However,the essential connotation and specific generation mechanism of“competence”as its basic concept are still far from clear,and...“Key competence”has become a hot vocabulary in educational reform in recent years.However,the essential connotation and specific generation mechanism of“competence”as its basic concept are still far from clear,and often controversial due to vague expressions.The rise of the concept of“key competence”undoubtedly originated in the West,but in the context of Chinese,its meaning has changed significantly.By analyzing the origin and evolution of the concept of“competence”in the Western social context and the concept from“quality”to“competence”in the Chinese social context,we can deeply understand the essence of the concept of“competence”and further clarify the specific generation mechanism of“competence”and its relationship with education.Analyzing the formation of competence based on situational learning theory emphasizes the occurrence of competence through participation in situational activities,the development of learning courses and identity consultation,which can provide some inspiration for the formation of competence.展开更多
Currently,the operational performance assessment system in the power market primarily focuses on power generation and electricity retail companies,lacking a system tailored to the operational characteristics of power ...Currently,the operational performance assessment system in the power market primarily focuses on power generation and electricity retail companies,lacking a system tailored to the operational characteristics of power generation/selling integrated companies.Therefore,this article proposes an assessment index system for assessing the operational performance of a power generation/selling integrated company,encompassing three dimensions:basic capacity,development potential,and external environment.A dynamic proportional adjustment coefficient is designed,along with a subjective and objective weighting model for assessment indexes based on a combined weightingmethod.Subsequently,the operational performance of an integrated company is assessed using extension theory.The results in the case study demonstrate the feasibility and effectiveness of the proposed dynamic proportional adjustment coefficient.展开更多
Density‐functional theory calculations were carried out to study the strontium(Sr)‐doping effect on methane activation over a lanthanum‐oxide(La2O3)catalyst for the oxidative coupling of methane(OCM)using the clust...Density‐functional theory calculations were carried out to study the strontium(Sr)‐doping effect on methane activation over a lanthanum‐oxide(La2O3)catalyst for the oxidative coupling of methane(OCM)using the cluster model.Eight Sr‐doped La2O3cluster models were built from pure La2O3clusters that were used previously to model the La2O3catalyst.These form two distinct categories,namely,those without a radical character(LaSrO2(OH),La2SrO4,La3SrO5(OH),and La5SrO8(OH))and those with a radical character(LaSrO3,La2SrO4(OH),La3SrO6,and La5SrO9).The potential‐energy surface for CH4activation to form a CH3radical at different Sr-O and La-O pair sites on these Sr‐doped La2O3clusters was calculated to study the Sr‐doping effect on the OCM catalytic activity.CH4physisorption and chemisorption energies,and activation barriers,and CH3desorption energies were predicted.Compared with the pure La2O3clusters,in general,the Sr‐doped La2O3clusters are thermodynamically and kinetically more reactive with CH4.For the Sr‐doped La2O3clusters without the radical character,the Sr-O pair site is more reactive with CH4than the La-O pair site,although a direct release of the CH3radical is also highly endothermic as in the case of the pure La2O3clusters.In contrast,for the Sr‐doped La2O3clusters with a radical character,the activation of CH4at the oxygen radical site and the release of the CH3radical are much easier.Thus,our calculations suggest that the Sr dopant prompts the OCM catalytic activity of the La2O3catalyst by providing a highly active oxygen‐radical site and by strengthening the basicity of the M-O pair site,which leads to lower CH4activation energies and lower CH3desorption energies.展开更多
Taking the output power, thermal efficiency, and thermo-economic performance as the optimization objectives, we optimize the operation parameters of a thermodynamic system with combined endoreversible Carnot heat engi...Taking the output power, thermal efficiency, and thermo-economic performance as the optimization objectives, we optimize the operation parameters of a thermodynamic system with combined endoreversible Carnot heat engines in this paper. The applicabilities of the entropy generation minimization and entransy theory to the optimizations are discussed. For the discussed cases, only the entransy loss coefficient is always agreeable to the optimization of thermal efficiency. The applicabilities of the other discussed concepts to the optimizations are conditional. Different concepts and principles are needed for different optimization objectives, and the optimization principles have their application preconditions. When the preconditions are not satisfied, the principles may be not applicable.展开更多
Due to the development of Distributed Generation (DG), which is installed in Medium-Voltage Distribution Networks (MVDNs) such as generators based on renewable energy (e.g., wind energy or solar energy), voltage contr...Due to the development of Distributed Generation (DG), which is installed in Medium-Voltage Distribution Networks (MVDNs) such as generators based on renewable energy (e.g., wind energy or solar energy), voltage control is currently a very important issue. The voltage is now regulated at the MV busbars acting on the On-Load Tap Changer of the HV/MV transformer. This method does not guarantee the correct voltage value in the network nodes when the distributed generators deliver their power. In this paper an approach based on Sensitivity Theory is shown, in order to control the node voltages regulating the reactive power exchanged between the network and the dispersed generators. The automatic distributed voltage regulation is a particular topic of the Smart Grids.展开更多
A comprehensive study on the requirements for the highly efficient third harmonic generation(THG) and its inverse process, one-third harmonic generation(OTHG), in lossy waveguides is proposed. The field intensity rest...A comprehensive study on the requirements for the highly efficient third harmonic generation(THG) and its inverse process, one-third harmonic generation(OTHG), in lossy waveguides is proposed. The field intensity restrictions for both THG and OTHG caused by loss are demonstrated. The effective relative phase ranges, supporting the positive growth of signal fields of THG and OTHG are shrunken by the loss. Furthermore, it turns out that the effective relative phase ranges depend on the intensities of the interacting fields. At last, a modified definition of coherent length in loss situation, which evaluates the phase matching degree more precisely, is proposed by incorporating the shrunken relative phase range and the nonlinear phase mismatch. These theoretical analysis are valuable for guiding the experimental designs for highly efficient THG and OTHG.展开更多
The first-principles density functional calculations are performed to study the geometries and electronic structures of HgGa2X4(X = S,Se,Te) semiconductors with defect chalcopyrite structures,and the optical propert...The first-principles density functional calculations are performed to study the geometries and electronic structures of HgGa2X4(X = S,Se,Te) semiconductors with defect chalcopyrite structures,and the optical properties of all crystals are investigated systematically.The results indicate that these compounds have similar band structures and the band gap decreases from S to Se to Te.For the linear optical properties,three crystals show good light transmission in the IR and part visible regions,and in particular,HgGa2S4 and HgGa2Se4 crystals possess moderate birefringence.For the nonlinear optical properties,these crystals have stronger second harmonic generation(SHG),and are theoretically predicted to have larger second-order static SHG coefficients( 30 pm/V).The SHG of HgGa2X4(X = S,Se,Te) semiconductors can be attributed to the transitions from the bands near the top of valence band derived from X(X = S,Se,Te) p states to the unoccupied bands contributed by the p states of Ga atoms.Our results indicate that the HgGa2S4 and HgGa2Se4 compounds are good candidates for nonlinear optical crystals in the IR region.展开更多
It is well known that energy-momentum is the source of gravitational field. For a long time, it is generally believed that only stars with huge masses can generate strong gravitational field. Based on the unified theo...It is well known that energy-momentum is the source of gravitational field. For a long time, it is generally believed that only stars with huge masses can generate strong gravitational field. Based on the unified theory of gravitational interactions and electromagnetic interactions, a new mechanism of the generation of gravitational field is studied. According to this mechanism, in some special conditions, electromagnetic energy can be directly converted into gravitational energy, and strong gravitational field can be generated without massive stars. Gravity impulse found in experiments is generated by this mechanism.展开更多
基金supported by Foundation of Guizhou Science and Technology Department under Grant No.[2008]2210 and No.[2009]3009Foundation of Guizhou University under Grant No. [2007]25
文摘The value of a drawing die's cone angle has great influence on wire drawing. In order to determine the optimum value of a drawing die' s cone angle, the plastic deformation power Wi, shear deformation power Wi and friction power of contact surface Wf were calculated using the upper bound theory with a reasonable and movement permitted velocity field according to the related characteristics. Then the relation between half cone angle and unit drawing force was obtained and it was compared with the result with the spherical velocity field. The relative error of the two near the optimal value is only about 0. 26% through comparing with existing calculated results. Finally, in an ABAQUS environment the finite element modal of the wire rod with 12. 5 mm diameter in first drawing pass was established and the axial drawing force in different cone angles was obtained using the ABAQUS/Explicit explicit integration method. The finite element method (FEM) results verify the results using the upper bound theory and this indicated that the velocity field and the relation between half cone angle and unit drawing force reasonable.
基金The project supported by the National Natural Science Foundation of China (19832020)Provincial Natural Science Foundation of Jilin, China (200000519)
文摘Flange earrings of strong anisotropic sheet metals in deep-drawing process are numerically analyzed by the elastic-plastic large deformation finite element formulation based on a discrete Kirchhoff triangle plate shell element model. A Barlat-Lian anisotropic yield function and a quasi-flow corner theory are used in the present formulation. The numerical results are compared with the experimental ones of cylindrical cup drawing process. The focus of the present researches is on the numerical analysis and the constraining scheme of the flange earring of circular sheets with strong anisotropy in square cup drawing process.
基金funded by“Management Model Innovation of Chinese Enterprises”Research Project,Institute of Industrial Economics,CASS(Grant No.2019-gjs-06)Project under the Graduate Student Scientific and Research Innovation Support Program,University of Chinese Academy of Social Sciences(Graduate School)(Grant No.2022-KY-118).
文摘This paper explores the data theory of value along the line of reasoning epochal characteristics of data-theoretical innovation-paradigmatic transformation and,through a comparison of hard and soft factors and observation of data peculiar features,it draws the conclusion that data have the epochal characteristics of non-competitiveness and non-exclusivity,decreasing marginal cost and increasing marginal return,non-physical and intangible form,and non-finiteness and non-scarcity.It is the epochal characteristics of data that undermine the traditional theory of value and innovate the“production-exchange”theory,including data value generation,data value realization,data value rights determination and data value pricing.From the perspective of data value generation,the levels of data quality,processing,use and connectivity,data application scenarios and data openness will influence data value.From the perspective of data value realization,data,as independent factors of production,show value creation effect,create a value multiplier effect by empowering other factors of production,and substitute other factors of production to create a zero-price effect.From the perspective of data value rights determination,based on the theory of property,the tragedy of the private outweighs the comedy of the private with respect to data,and based on the theory of sharing economy,the comedy of the commons outweighs the tragedy of the commons with respect to data.From the perspective of data pricing,standardized data products can be priced according to the physical product attributes,and non-standardized data products can be priced according to the virtual product attributes.Based on the epochal characteristics of data and theoretical innovation,the“production-exchange”paradigm has undergone a transformation from“using tangible factors to produce tangible products and exchanging tangible products for tangible products”to“using intangible factors to produce tangible products and exchanging intangible products for tangible products”and ultimately to“using intangible factors to produce intangible products and exchanging intangible products for intangible products”.
文摘The processing of measuri ng data plays an important role in reverse engineering. Based on grey system the ory, we first propose some methods to the processing of measuring data in revers e engineering. The measured data usually have some abnormalities. When the abnor mal data are eliminated by filtering, blanks are created. The grey generation an d GM(1,1) are used to create new data for these blanks. For the uneven data sequ en ce created by measuring error, the mean generation is used to smooth it and then the stepwise and smooth generations are used to improve the data sequence.
文摘Following a quasi-dynamic scheme proposed by Minear and Toksoz (1970), thermal structures of subduction zonesfor different models by finite element method (FEM) were calculated. Density distribution and p-wave anomaly ofsubduction zones were calculated at the same time. Comparing with seismological evidences and results of laboratories. it is proposed that earthquakes occurred below 400 km depth are probably controlled by anti-crackmechanism.
基金support of the National Natural Science Foundation of China (Grant No. 41130751)China Scholarship Council, Research Program for Western China Communication (Grant No. 2011ZB04)China Central University Funding
文摘Limit equilibrium method (LEM) and strength reduction method (SRM) are the most widely used methods for slope stability analysis. However, it can be noted that they both have some limitations in practical application. In the LEM, the constitutive model cannot be considered and many assumptions are needed between slices of soil/rock. The SRM requires iterative calculations and does not give the slip surface directly. A method for slope stability analysis based on the graph theory is recently developed to directly calculate the minimum safety factor and potential critical slip surface according to the stress results of numerical simulation. The method is based on current stress state and can overcome the disadvantages mentioned above in the two traditional methods. The influences of edge generation and mesh geometry on the position of slip surface and the safety factor of slope are studied, in which a new method for edge generation is proposed, and reasonable mesh size is suggested. The results of benchmark examples and a rock slope show good accuracy and efficiency of the presented method.
文摘An unequal time interval sequence or a sequence with blanks is usually completed with average generation in grey system theory. This paper discovers that there exists obvious errors when using average generation to generate internal points of non-consecutive neighbours. The average generation and the preference generation of the sequence are discussed, the concave and convex properties show the status of local sequence and propose a new idea for using the status to build up the criteria of choosing generation coefficient. Compared with the general average method of the one-dimensional data sequence, the two-dimensional data sequence is defined and its average generation is discussed, and the coefficient decision method for the preference generation is presented.
文摘Controllable drawing roof coal mining method is applied either to rently inclined seam or to big dipping seam. This paper sums up four corresponding methods according to conditions of our country, and analyses the coal-recovering effects and proves applicated conditions and measures for improving by "drawing coal theory of the ellipsoid". Its conclusion basically consists with practice. This work is of guiding meaning for designing drawing coal technology.
基金Project supported by the National Key Research and Development Program of China (Grant No.2019YFA0307700)the National Natural Science Foundation of China (Grant Nos.12204214,12074145,and 11627807)。
文摘High-order harmonic generation of the cyclo[18]carbon(C_(18) ) molecule under few-cycle circularly polarized laser pulse is studied by time-dependent density functional theory. Compared with the harmonic emission of the ring molecule C_(6)H_(6) having similar ionization potential, the C_(18) molecule has higher efficiency and cutoff energy than C_(6)H_(6) with the same laser field parameters. Further researches indicate that the harmonic efficiency and cutoff energy of the C_(18) molecule increase gradually with the increase of the laser intensity of the driving laser or decrease of the wavelength, both are larger than those of the C_(6)H_(6) molecule. Through the analysis of the time-dependent evolution of the electronic wave packets, it is also found that the higher efficiency of harmonic generation can be attributed to the larger spatial scale of the C_(18) molecule,which leads to a greater chance for the ionized electrons from one atom to recombine with others of the parent molecule.Selecting the suitable driving laser pulse, it is demonstrated that high-order harmonic generation in the C_(18) molecule has a wide range of applications in producing circularly polarized isolated attosecond pulse.
文摘The development of theoretical models for crystals has led to the evolution of computational methods with which much more thorough investigations than previously possible can be done, including studies of the nonlinear optical properties. There has recently been a rise in interest in 2-dimensional materials;unfortunately, measurements of the nonlinear susceptibility of these materials in the wavelength range of the order of hundreds of nanometers by traditional methods are difficult. Studies of second-harmonic generation (SHG) from the transition-metal dichalcogenides (TMDCs), MoS2 and MoSe2, have been reported;however, SHG from other typical van der Waals crystals such as GaSe and other transition metal monochalcogenides (TMMCs) has rarely been studied under the same conditions. In this study, the 211 (i = 2, j = 1, k = 1) elements in the susceptibility matrices of GaSe, InSe, MoS2 and WS2 were calculated and compared. A tendency for the SHG intensity to weaken as the wavelength increases from 500 nm to 1000 nm was observed for GaSe and InSe, and, apart from some periodic fluctuations, no clear increase could be seen for these two materials in the SHG response curve in the near infrared. By comparison, MoS2 and WS2 have obvious peaks in both the visible and infrared bands. Calculations of the SHG response show peaks at around 500 nm (for GaSe), 570 (for InSe), 660 nm, 980 nm (for MoS2) and 580 nm, 920 nm (for WS2). Moreover, similarities between the SHG curves for GaSe and InSe and for MoS2 and WS2 were revealed, which may be due to the similarities found for these two groups of crystals.
文摘The article deals with the methodology of pseudorandom data analysis. As a mathematical tool for carrying out the research the extreme value theory was used that creates one of the directions in mathematical statistics, and is related to investigating the extreme deviations from the median values in probability distributions. Also, the methods for estimating unknown parameters and algorithm of random-number generation are discussed. The models of treatment the extreme values are constructed which are based on machine generated sample and approach is proposed for their future application for constructing forecasting models.
文摘“Key competence”has become a hot vocabulary in educational reform in recent years.However,the essential connotation and specific generation mechanism of“competence”as its basic concept are still far from clear,and often controversial due to vague expressions.The rise of the concept of“key competence”undoubtedly originated in the West,but in the context of Chinese,its meaning has changed significantly.By analyzing the origin and evolution of the concept of“competence”in the Western social context and the concept from“quality”to“competence”in the Chinese social context,we can deeply understand the essence of the concept of“competence”and further clarify the specific generation mechanism of“competence”and its relationship with education.Analyzing the formation of competence based on situational learning theory emphasizes the occurrence of competence through participation in situational activities,the development of learning courses and identity consultation,which can provide some inspiration for the formation of competence.
基金supported in part by the Science and Technology Innovation Program of Hunan Province under Grants 2023JJ40046 and 2023JJ30049.
文摘Currently,the operational performance assessment system in the power market primarily focuses on power generation and electricity retail companies,lacking a system tailored to the operational characteristics of power generation/selling integrated companies.Therefore,this article proposes an assessment index system for assessing the operational performance of a power generation/selling integrated company,encompassing three dimensions:basic capacity,development potential,and external environment.A dynamic proportional adjustment coefficient is designed,along with a subjective and objective weighting model for assessment indexes based on a combined weightingmethod.Subsequently,the operational performance of an integrated company is assessed using extension theory.The results in the case study demonstrate the feasibility and effectiveness of the proposed dynamic proportional adjustment coefficient.
基金supported by the National Natural Science Foundation of China(21473233,21403277)the Frontier Science Program of Shell Global Solutions International B.V.(PT32281)+1 种基金the Ministry of Science and Technology of China(2016YFA0202802)the Shanghai Municipal Science and Technology Commission(14ZR1444600)~~
文摘Density‐functional theory calculations were carried out to study the strontium(Sr)‐doping effect on methane activation over a lanthanum‐oxide(La2O3)catalyst for the oxidative coupling of methane(OCM)using the cluster model.Eight Sr‐doped La2O3cluster models were built from pure La2O3clusters that were used previously to model the La2O3catalyst.These form two distinct categories,namely,those without a radical character(LaSrO2(OH),La2SrO4,La3SrO5(OH),and La5SrO8(OH))and those with a radical character(LaSrO3,La2SrO4(OH),La3SrO6,and La5SrO9).The potential‐energy surface for CH4activation to form a CH3radical at different Sr-O and La-O pair sites on these Sr‐doped La2O3clusters was calculated to study the Sr‐doping effect on the OCM catalytic activity.CH4physisorption and chemisorption energies,and activation barriers,and CH3desorption energies were predicted.Compared with the pure La2O3clusters,in general,the Sr‐doped La2O3clusters are thermodynamically and kinetically more reactive with CH4.For the Sr‐doped La2O3clusters without the radical character,the Sr-O pair site is more reactive with CH4than the La-O pair site,although a direct release of the CH3radical is also highly endothermic as in the case of the pure La2O3clusters.In contrast,for the Sr‐doped La2O3clusters with a radical character,the activation of CH4at the oxygen radical site and the release of the CH3radical are much easier.Thus,our calculations suggest that the Sr dopant prompts the OCM catalytic activity of the La2O3catalyst by providing a highly active oxygen‐radical site and by strengthening the basicity of the M-O pair site,which leads to lower CH4activation energies and lower CH3desorption energies.
基金Project supported by the National Natural Science Foundation of China(Grant No.51376101)the Science Fund for Creative Research Groups,China(Grant No.51321002)
文摘Taking the output power, thermal efficiency, and thermo-economic performance as the optimization objectives, we optimize the operation parameters of a thermodynamic system with combined endoreversible Carnot heat engines in this paper. The applicabilities of the entropy generation minimization and entransy theory to the optimizations are discussed. For the discussed cases, only the entransy loss coefficient is always agreeable to the optimization of thermal efficiency. The applicabilities of the other discussed concepts to the optimizations are conditional. Different concepts and principles are needed for different optimization objectives, and the optimization principles have their application preconditions. When the preconditions are not satisfied, the principles may be not applicable.
文摘Due to the development of Distributed Generation (DG), which is installed in Medium-Voltage Distribution Networks (MVDNs) such as generators based on renewable energy (e.g., wind energy or solar energy), voltage control is currently a very important issue. The voltage is now regulated at the MV busbars acting on the On-Load Tap Changer of the HV/MV transformer. This method does not guarantee the correct voltage value in the network nodes when the distributed generators deliver their power. In this paper an approach based on Sensitivity Theory is shown, in order to control the node voltages regulating the reactive power exchanged between the network and the dispersed generators. The automatic distributed voltage regulation is a particular topic of the Smart Grids.
基金Project supported by Shenzhen Municipal Science and Technology Plan Project,China(Grant Nos.JCYJ20160427183803458 and JCYJ20150403161923546)
文摘A comprehensive study on the requirements for the highly efficient third harmonic generation(THG) and its inverse process, one-third harmonic generation(OTHG), in lossy waveguides is proposed. The field intensity restrictions for both THG and OTHG caused by loss are demonstrated. The effective relative phase ranges, supporting the positive growth of signal fields of THG and OTHG are shrunken by the loss. Furthermore, it turns out that the effective relative phase ranges depend on the intensities of the interacting fields. At last, a modified definition of coherent length in loss situation, which evaluates the phase matching degree more precisely, is proposed by incorporating the shrunken relative phase range and the nonlinear phase mismatch. These theoretical analysis are valuable for guiding the experimental designs for highly efficient THG and OTHG.
基金Supported by the National Natural Science Foundation of China(No.21171039)
文摘The first-principles density functional calculations are performed to study the geometries and electronic structures of HgGa2X4(X = S,Se,Te) semiconductors with defect chalcopyrite structures,and the optical properties of all crystals are investigated systematically.The results indicate that these compounds have similar band structures and the band gap decreases from S to Se to Te.For the linear optical properties,three crystals show good light transmission in the IR and part visible regions,and in particular,HgGa2S4 and HgGa2Se4 crystals possess moderate birefringence.For the nonlinear optical properties,these crystals have stronger second harmonic generation(SHG),and are theoretically predicted to have larger second-order static SHG coefficients( 30 pm/V).The SHG of HgGa2X4(X = S,Se,Te) semiconductors can be attributed to the transitions from the bands near the top of valence band derived from X(X = S,Se,Te) p states to the unoccupied bands contributed by the p states of Ga atoms.Our results indicate that the HgGa2S4 and HgGa2Se4 compounds are good candidates for nonlinear optical crystals in the IR region.
文摘It is well known that energy-momentum is the source of gravitational field. For a long time, it is generally believed that only stars with huge masses can generate strong gravitational field. Based on the unified theory of gravitational interactions and electromagnetic interactions, a new mechanism of the generation of gravitational field is studied. According to this mechanism, in some special conditions, electromagnetic energy can be directly converted into gravitational energy, and strong gravitational field can be generated without massive stars. Gravity impulse found in experiments is generated by this mechanism.