Hot Hydrostatic Extrusion of Mechanically Alloyed Al-4.9Fe-4.9Ni Powders

Al-4.9 Fe-4.9 Ni alloy powders have been synthesized by mechanical alloying. The rnechanically alloyed powders are consolidated by hot hydrostatic extrusion. The results show that extrusion tempereture. extrusion ratio and lubricant have great effects on the quality of extruded rods and their mechanical properties, The mixture of graphite and glass powders as lubricant can prevent the oxidization of cold compacted billet by cladding the billet with this lubricant before heating. This technique greatly simplifies the conventional densification process of powders

CHARACTERISTICS OF FATIGUE SURFACE MICROCRACK GROWTH IN VICINAL INCLUSION FOR POWDER METALLURGY ALLOYS

Inclusion flaw is one of the worst flaws of powder metallurgy.The inclusion flaw plays an important role in the failure of high temperature turbine materials in aircraft components and automotive parts,especially fatigue failure.In this paper,an experimental investigation of fatigue microcrack propagation in the vicinal inclusion were carried out by the servo-hydraulic fatigue test system with scanning electron microscope(SEM).It has been found from the SEM images that the fatigue surface microcrack occurs in the matrix and inclusion.According to the SEM images,the characteristics of fatigue crack initiation and growth in vicinal inclusion for powder metallurgy alloys are analyzed in detail.The effect of the geometrical shape and material type of surface inclusions on the cracking is also discussed with the finite element method(FEM).

Improvement of Ductility of Powder Metallurgy Titanium Alloys by Addition of Rare Earth Element

Ti-4.5Al-6.0Mo-1.5Fe, Ti-6Al-1Mo-1Fe and Ti-6Al-4V alloys were prepared by blended elemental powder metallurgy （PM） process, and the effects of Nd on the microstructures and mechanical properties were investigated by scanning electron microscopy （SEM）, transmission electron microscopy （TEM） and X-ray diffraction （XRD）. It was found out that the addition of Nd increased the density of sintered titanium alloys slightly by a maximum increment of 1% because small amount of liquid phase occurred during sintering. The addition of Nd shows little effect on the improvement of tensile strength, while the elongation is significantly improved. For example, the elongation of Ti-4.SAl-6.0Mo-1.5Fe can be increased from 1% without addition of Nd to 13% at a Nd content of 1.2 wt pct.

Characteristics and Microstructure of a Hypereutectic Al-Si Alloy Powder by Ultrasonic Gas Atomization Process

A hypereutectic Al-Si alloy powder was prepared by ultrasonic gas atomization process. The morphologies, microstructure and phase constituent of the alloy powder were studied. The results showed that powder of the alloy was very fine and its microstructure was mainly consisted of Si crystals plus intermetallic compound A19FeSi3, which were.very fine and uniformly distributed.

Processing TiAl-Based Alloy by Elemental Powder Metallurgy

TiAI-based alloys with various compositions (including Ti-48Al, Ti-47Al-2Cr-2Nb, Ti-47Al-2Cr-2Nb-0.2B and Ti-47Al-3Cr, in mole fraction) had been prepared by elemental powder metallurgy (EPM). The results have shown that the density of the prepared Ti-48AI alloy increases with increasing hot pressing temperature up to 1300℃. The Ti-48AI alloy microstructure mainly consisted of island-like Ti3Al phase and TiAl matrix at hot pressing temperature below 1300℃, however, coarse α2/γ lamellar colonies and γ grains appeared at 1400℃. It has also indicated that the additions of elemental Cr and B can refine the alloy microstructure. The main microstructural inhomogeneity in EPM TiAI-based alloys was the island-like α2 phase or the aggregate of α2/γ lamellar colony, and such island-like structure will be inherited during subsequent heat treatment in (α＋γ) field. Only after heat treatment in a field would this structure be eliminated. The mechanical properties of EPM TiAl-based alloys with various compositions were tested, and the effect of alloy elements on the mechanical properties was closely related to that of alloy elements on the alloy microstructures. Based on the above results, TiAI-based alloy exhaust valves were fabricated by elemental powder metallurgy and diffusion joining. The automobile engine test had demonstrated that the performance of the manufactured valves was very promising for engine service.

Investigation of the compressibility and sinterabilty of AZ91 powder production and particle production by gas atomisation method

This study intends to determine the pressability and sinterability of AZ91 powder production by gas atomisation method and that of the produced powder for partial production.Therefore,first,a gas atomisation unit has been designed and manufactured in the laboratories of the Karabiik University,Department of Manufacturing Engineering.Atomised powder production has been achieved at a temperature of 795℃,with nozzle diameters of 2 and 4 mm and four different gas pressures(5,15,25,35 bars).Argon gas has been used for atomisation and as a protective gas atmosphere.Scanning electron microscope(SEM)is used to determine the shape of the produced AZ91 powder,and a laser particle size analyzer is used to analyze the powder size.Additionally,a microhardness(HV0.025)measurement has been conducted to determine the hardness of the produced powders.To achieve a homogeneous distribution,the produced powders are mixed in a three-dimensional moving turbulator for 30 min.Mixed powders have been pressed at 300,400,500 and 600 MPa and have been sintered at 500℃,550℃and 600℃.Additionally,the density values have been determined before and after sintering of the materials.SEM images have been obtained from the fractured surfaces of the samples before and after sintering.XRD and EDX analyses have been performed to determine the chemical composition.Further,microhardness(HV0.5)is obtained from the pressure surfaces of the samples to determine the effects of the pressing pressure and the sintering temperature on the hardness.As a result of the experimental studies,it has been observed that the powder size decreases with the increase in gas pressure and that the powder shape generally changes from ligament and complex shape to droplet and spherical shape.From the XRD,XRF and EDX results,it has been determined that the structure comprises an a phase(Mg main matrix)and Mg17Al12 interphase,which isβphase,and very small amounts of MgO have been observed.The hardness of the produced powders increased based on the increase in gas pressure.The densities of the samples increased with both increasing pressing pressure and sintering temperature.It has been observed from the fractured surface SEM images that the number of pores formed in the samples decrease with an increase in the pressing pressure.It has been determined that the post-sintering structure exhibitsαtypical dendritic structure.In addition to theα-Mg matrix phase,β(Mg17Al12)intermetallic andα+βeutectic were formed in the structure.The microhardness values of the samples decreased depending on the sintering temperature;the highest hardness value was measured as 64,02 HV0.5 at a pressing pressure of 300 MPa and a sintering temperature of 500℃,whereas the lowest hardness value was measured as 54,86 HV0.5 at a pressing pressure of 600 MPa and a sintering temperature of 600℃.

THE PREPARATION AND APPLICATION OF ELECTROPLATEDSHEET CONTAINING RS ALUMINUM ALLOY POWDERS

Baded on the study of nickel electroplating technology at room temperature, the plated sheet containing rapidly solidified Al-Fe-Cu- V-Si-Ni-Ce-Zr aluminum alloy powders is constructed successfully. The powders and nickel matrix are combined well in the sheet. It can be used to prepare the observation specimen for TEM and determine the hardness of single powder particle as solidified and after heat-treated. The advantages of this method are the realization of heat treatment of powders and the TEM observation of non-interfered microstructure of powders in the size of several microns.

Electrodeposition of La-Ni Alloy Powders in Dimethylsulfoxide (DMSO)

The brown metallic luster La-Ni alloy powders were prepared by potentiostatic electrolysis technique in dimethylsulfoxide solution at room temperature. The atomic rate of La and Ni in alloy powders are 11∶1 and 10∶1. The size of metal grains is about 0.1 to 100 μm. It shows that the micrometer powders of rare earth alloys can be obtained by controlling electrodeposition conditions. The peak potentials of -2.81 and 1.75 V are attributed to reduction of La 3+ and Ni 3+ ions, respectively. The peak potentials at -2.20 and -0.168 V are the oxidation peaks of lanthanum and nickel, respectively. When potential is more negative than -1.74 V, La(Ⅲ) and Ni(Ⅱ) will codeposit. Increasing cyclic times, the value of peak current is decreasing, and the reduction peak of La(Ⅲ) was finally disappeared.

PREPARATION OF ULTRAFINE ALLOY POWDER BY REDUCTION OF COMPLEX OXIDE

The ultrafine alloy powders,CuRh,γ-Ni_(0.33)Fe_(0.66) and α-Fe_(0.66)Co_(0.33) of size less than 35 nm were prepared by reduction of complex metallic oxides under atmosphere of 15% H_2 and 85%Ar.

EFFECT OF OXIDE LAYER THICKNESS OVER Al AND Al ALLOY POWDERS ON QUALITY OF THEIR EXPLOSIVE COMPACTS

Observations of microstructure of explosive compacts made of Al or Al-Li alloy powders by atomization with water,nitrogen or ultrasoic Ar gas were carried out under optical and scanning electron microscopes.The rsults indicate that super quality explosive compact can only be obtained by powders of which the thickness of the oxide layer is less than 30 nm.

A Study of Making Iron Aluminide Alloy Powders with New Rotating Electrode Technology

A new process was used for producing FeAl alloy pow de rs with double consumable rotating electrodes and the powders made in this appar atus were analyzed. In this new technology, tungsten rod serves as a cathode ele ctrode, while the alloy rod as an anode electrode. The conventional rotating ele ctrode process must have an anode with pre-melting alloys; however, in this new process, using pure iron as cathode electrode and pure aluminum as anode electr ode can eliminate the step of pre-melting. The effects of process variables, which include electrode rotational speed, a nd electrode diameter of the mean particle diameter were determined. Results showed that both the rotational speed and diameter of electrodes would a ffect the mean diameter of particles. There are three kinds of powders with diff erent composition produced in this study and the possible mechanisms are discuss ed. The process parameters and volume mean diameter of the powders have been cor related to find an experimental equation. The results show that when the rotational speed and the diameter of the anode el ectrode are increased, the powders size will decrease. However, the powders size will increase with cathode electrode.

STRUCTURE OF Al-Mn-Zn-Mg ALLOY POWDER

The structure of Al-Mn-Zn-Mg alloy powder annealed at 800℃ has been studied by transmisston electron microscopy(TEM).An approximant phase(named as C-phase) to the decagonal phase was found and its crystal structure was determined It belongs to c-center orthorhombic lattice with a=2.35 nm,b=3.27 nm and c=1.22 nm.We stillfound a hexagonal phase with a=0.7) nm and c=0.79 nm,(named as phase) in the annealed alloy powder.The annealed alloy powder is composed of the C-phase,the phase,the decagonal phase and Al solid solution.

Powder Microstructure and Overlay Coating Property ofNiCrAlY Alloy

这被显示出更好(20-30 亩 m ) 粉末粒子经历快速的复辉和热抽取到导致微细胞的结构的环境，而更粗糙(40-50 亩 m ) 因为慢冷却跟随的复辉，粉末粒子展出粗糙的细胞、树枝状的混合结构。另外，这也被显示越好粉末粒子尺寸，越 higher 机械性质并且冶金热稳定性过分，涂层由把同样分裂成原子的粉末扔了，它大概为粉末的好尺寸部分被归因于稠密的好谷物结构和氧化物层的形成。(编辑作者摘要) 9 个裁判员。

Microstructure and Tribological Properties of Fe-Cr-B-Si-based Alloy Coating on the Surface of Scraper Conveyor Middle Trough NM450

This paper aims to develop a surface modification process to improve the surface properties of the middle trough.The coatings were prepared by plasma cladding with Fe-Cr-B-Si-based alloy powders (Ig 6 and Ig7).The organizational structure and micro-hardness of the coatings were analyzed by laboratory equipments.The friction and wear tests were performed to investigate the friction-wear properties of middle trough.The coatings have higher hardness and good friction-wear properties than the substrate.The hardness and friction wear properties of the coating with Ig7 powder are better than those with Ig6 powder.The experimental results show that the surface properties of the middle trough are improved by Fe-Cr-B-Si-based alloy coating,which can improve the middle trough service life.The plasma cladding can be widely used in the surface-modification of middle trough to reduce the waste of resources.

Wear-resistance Performance of Spray-welding Coating by Plasma Weld-surfacing

Alloy powders including Ni60, WC, CrC, and TiC with different mass ratios were deposited on medium carbon low alloy steel by plasma welding. Through the experiments, the optimal alloy powder reinforcing cutter tool surface properties were discovered. The wear resistance properties were investigated on the impact abrasive wear tester. The experimental results show that in terms of microstructure, there exists the shape of herringbone, spider mesh, broken flower structures in coatings. In addition, fusion area of four specimens surfacing welding layer displays a large number of acicular martensite with a small amount of austenite. The coating mainly consists of Ni-Cr-Fe austenitic phase and the other precipitates. TiC density is smaller, its content is less in alloy powder, in the process of surfacing welding, TiC is melted fully, which is mainly distributed in surface layer and middle layer of hard facing layer. The content of TiC gradually reduces from surface layer of hard facing layer to the fusion area. Compared to TiC, the density of tungsten carbide and chromium carbide is larger, there exist tungsten carbide and chromium carbide particles, which are not completely melted near the fusion area. The micro-hardness presents gradient change from the fusion area to the surface layer of hard facing layer, and the hardness of the middle layer is slightly lower than that of the fusion area, and the hardness increases near the surface layer.

Effect of Spark Plasma Sintering on Microstructures and Properties of Al-Fe Alloy

2024 Aluminum alloy powder( 60wt%) and Fe-based amorphous powder( 40 wt%) were adopted. They were mechanical machined for 48hours after being mixed. Bulk material was gained after Spark Plasma Sintering. The sintering parameters included sintering temperature,heating or cooling rates,pressure and holding time. 300 ℃- 800 ℃ were adopted while the heating or cooling rate was 100 ℃ / min and with the pressure of 50 MPa in the experiments. The holding time was 10 min or 20 min at different temperatures, respectively. Bulk materials after sintering were examined by Scanning Electron Microscopy and X-Ray Diffraction. The micro-hardness and relative density also were tested. The sintering temperature had the most significant influence on the microstructure and property of the bulk material. The influence of holding time came second while the heating or cooling rates and pressure were fixed. The density became larger with the increase of the temperature. The compactness was best at 500℃. The pressure and generation of high-temperature phases were the factors which affected the density and the compactness.

Effect of Nano-sized B4C Addition on the Mechanical Properties of ZA27 Composites

In order to understand the influence of nano-sized B4C additive on ZA27 alloy, mechanical and physical properties of ZA27-B4C nanocomposites were investigated in terms of B4C content. While physical properties were determined in terms of microstructural studies, density and porosity tests, mechanical properties were determined in terms of ultimate tensile strength（UTS） and hardness experiments. Morphological and microstructural studies were carried out with scanning electron microscopy（SEM）. The experimental results indicate that nano-sized B4C can be used to enhance the mechanical properties of ZA27 alloy effectively. The highest mechanical performance can be obtained at ZA27-0.5% B4C（in weight） nanocomposite with values of tensile strength（247 MPa） and hardness（141,18 BH） and low partial porosity（0.5%）. After a pick point, increasing B4C ratio may cause the formation of agglomeration in grain boundaries, that＇s why density, tensile strength, and hardness values are declined.

Characteristics of Biometallic Alloy to Additive Manufacturing Using Selective Laser Melting Technology

Biomaterial powders are in high development due to expansion of additive manufacturing (AM) processes. Selective laser melting (SLM) is a particular AM technology, which completely melts a powder bed layer by laser beam. Investigations of appropriated physical properties of feedstock (powder alloy) were the aim of this study. Cobalt-chromium-molybdenum (Co-Cr-Mo) alloy was used to overview of gas-atomized powder properties in different granulometric ranges (D1 12 - 19 μm, D2 20 - 46 μm and D3 76 - 106 μm), as their: physical, chemical properties and thermal analysis. SLM manufactured standard tensile specimens of usually granulometric range powder size provided mechanical, chemical and thermal properties of biocompatible Co-Cr-Mo alloy. The physical properties showed that powders in the range of 20 to 50 μm provide a better flow ability and packed density, which are relevant characteristics to SLM processing. Manufacturing by SLM process provided suitable mechanical properties in the health area, as well as, maintained the biocompatible properties of the Co-Cr-Mo alloy.

Effect of cerium on wettability of mechanically milled Cu-based brazing alloy powder

CuSn powders and Till2 powders were milled using high energy mechanical milling to prepare Cu-based alloy powders for brazing diamond. And Ce was added to the milled Cu-based alloy powders to improve the wettability. It is found that the wetting angle reaches the minimum value 13.2° and the maximum spreading area 178 mm2 is achieved when the amount of Ce is 0.75 wt%. And Ce remarkably reduces the surface tension of liquid alloy, which improves the climbing height along the diamond and forms a massive support profile. And the results show that Ce can effectively improve the transverse rupture strength （TRS） due to high wettability. The wear characteristics of the diamonds brazed with Cu-based alloy containing 0.75 wt% Ce mainly consist of integrity, micro-fracture, fracture and rubdown, diamonds pull-out can not easily happen.

Hot Deformation Mechanism and Ring Rolling Behavior of Powder Metallurgy Ti_2AlNb Intermetallics

Powder metallurgy（PM） Ti–22Al–24Nb–0.5Mo（at.%） alloys were prepared by hot isostatic pressing. In order to study the feasibility of PM ＋ ring rolling combined process for preparing Ti_2AlNb rings, thermal mechanical simulation tests of PM Ti_2AlNb alloys were conducted and two rectangular PM rings（150 mm in height, 75 mm in thickness,350 mm in external diameter） were rolled as a validation experiment. Experimental results show that the flow stress of Ti_2AlNb alloys exhibited a significant drop at the very beginning of the deformation（true strain／0.1）, and became stable with the increase in strain. Stress instability phenomenon of PM Ti_2AlNb alloys was more obvious than that of wrought alloy. Flow stress fluctuation at the initial stage of deformation is related to phase transition of Ti_2AlNb alloys which strongly depends on heat treatment and thermal mechanical deformation process. Processing windows during initial stage of ring rolling process is very crucial. A sound PM Ti_2AlNb rectangular ring blank（height = 150 mm, thickness = 30 mm, external diameter = 750 mm） was successfully rolled in two passes by using the improved heat preservation method and optimized rolling parameters. Tensile properties of PM Ti_2AlNb alloy were improved, and the porosity was reduced after ring rolling.