Electrospray,as a liquid source supply system,has been applied to chemical vapour deposition（CVD）.In thermal CVD,the microstructure of the obtained films changes from dense to coarse granular because of the decreasi...Electrospray,as a liquid source supply system,has been applied to chemical vapour deposition（CVD）.In thermal CVD,the microstructure of the obtained films changes from dense to coarse granular because of the decreasing surface temperature during deposition.Using the electrospray laser chemical vapour deposition method,we prepared homogenous alumina coatings.We found that laser irradiation was effective in compensating the surface temperature decrease,and an alpha-alumina coating with dense columnar microstructures was obtained at a deposition rate of 200 μm/h using 200 W Nd：YAG laser irradiation.展开更多
Sodium beta alumina（Na-β-alumina） films were synthesized by heat treatment of NaAl6O（9.5）and γ-NaA1O2 films at temperatures of 1 373-1 573 K.Single-phase γ-NaA1O2 and NaAl6O（9.5） films were prepared by laser ...Sodium beta alumina（Na-β-alumina） films were synthesized by heat treatment of NaAl6O（9.5）and γ-NaA1O2 films at temperatures of 1 373-1 573 K.Single-phase γ-NaA1O2 and NaAl6O（9.5） films were prepared by laser chemical vapor deposition at the deposition temperatures of 976 and 1 100 K,respectively.Subsequent heat treatment of the films resulted in the formation of Na-β-alumina with α-Al2O3 at temperatures above 1 373 K for NaAl6O（9.5） and 1 473 K for γ-NaA1O2.On heat treatment at temperatures of 1 473-1 573 K,the faceted morphology with terraces of the as-deposited（110）-oriented γ-NaAlO2 films transformed to a porous morphology with platelet grains comprising Na-β-alumina and α-Al2O3.On heat treatment at temperatures of1 373-1 473 K,the pyramidal,faceted grains of as-deposited NaAl6O（9.5） films transformed to planer,shapeanisotropic morphology in the film of mixed Na-β-alumina and α-Al2O3.A dense morphology was observed in both the as-deposited and heat-treated NaAl6O（9.5） films.展开更多
文摘Electrospray,as a liquid source supply system,has been applied to chemical vapour deposition（CVD）.In thermal CVD,the microstructure of the obtained films changes from dense to coarse granular because of the decreasing surface temperature during deposition.Using the electrospray laser chemical vapour deposition method,we prepared homogenous alumina coatings.We found that laser irradiation was effective in compensating the surface temperature decrease,and an alpha-alumina coating with dense columnar microstructures was obtained at a deposition rate of 200 μm/h using 200 W Nd：YAG laser irradiation.
基金Funded by the Ministry of Education,Culture,Sports,Science and Technology,a Grant-in-Aid for Challenging Exploratory Research(No.26560235)the ARCMG–IMR Cooperative Program(No.14G0402)of Tohoku Universitythe China Scholarship Council and the 111 Project(No.B13035)of China
文摘Sodium beta alumina（Na-β-alumina） films were synthesized by heat treatment of NaAl6O（9.5）and γ-NaA1O2 films at temperatures of 1 373-1 573 K.Single-phase γ-NaA1O2 and NaAl6O（9.5） films were prepared by laser chemical vapor deposition at the deposition temperatures of 976 and 1 100 K,respectively.Subsequent heat treatment of the films resulted in the formation of Na-β-alumina with α-Al2O3 at temperatures above 1 373 K for NaAl6O（9.5） and 1 473 K for γ-NaA1O2.On heat treatment at temperatures of 1 473-1 573 K,the faceted morphology with terraces of the as-deposited（110）-oriented γ-NaAlO2 films transformed to a porous morphology with platelet grains comprising Na-β-alumina and α-Al2O3.On heat treatment at temperatures of1 373-1 473 K,the pyramidal,faceted grains of as-deposited NaAl6O（9.5） films transformed to planer,shapeanisotropic morphology in the film of mixed Na-β-alumina and α-Al2O3.A dense morphology was observed in both the as-deposited and heat-treated NaAl6O（9.5） films.
