Control of aluminum distribution in ZSM-5 zeolite for enhancement of its catalytic performance for propane aromatization

Regulation of aluminum distribution in zeolite framework is an effective method for improving its catalytic performance for propane aromatization.Herein,we found that recrystallization and post-realuminization of ZSM-5 cannot only create hollow structures to enhance the diffusion ability,but also adjust the content and position of paired aluminum species in its framework.Various characterizations results confirmed that increase of paired aluminum content and inducement of more aluminum atoms sited in the intersection cavity are beneficial to the formation of aromatic products in propane aromatization.As a result,the hollow-structured ZSM-5 zeolite with more paired aluminum(H-200-hollow)showed higher propane conversion and aromatics selectivity than other samples at the same conditions.The catalytic performance of H-200-hollow can be further improved by ion-exchanging with a small amount of Ga(III)species.The propane conversion and aromatics selectivity of Ga-200-hollow reached as high as 95%and 70%,respectively,at 540℃ and 1 atm.

Deposition behavior of residual aluminum in drinking water distribution system：Effect of aluminum speciation

Finished drinking water usually contains some residual aluminum.The deposition of residual aluminum in distribution systems and potential release back to the drinking water could significantly influence the water quality at consumer taps.A preliminary analysis of aluminum content in cast iron pipe corrosion scales and loose deposits demonstrated that aluminum deposition on distribution pipe surfaces could be excessive for water treated by aluminum coagulants including polyaluminum chloride（PACl）.In this work,the deposition features of different aluminum species in PACl were investigated by simulated coil-pipe test,batch reactor test and quartz crystal microbalance with dissipation monitoring.The deposition amount of non-polymeric aluminum species was the least,and its deposition layer was soft and hydrated,which indicated the possible formation of amorphous Al（OH）3.Al（13） had the highest deposition tendency,and the deposition layer was rigid and much less hydrated,which indicated that the deposited aluminum might possess regular structure and self-aggregation of Al（13）could be the main deposition mechanism.While for Al（30）,its deposition was relatively slower and deposited aluminum amount was relatively less compared with Al（13）.However,the total deposited mass of Al（30） was much higher than that of Al（13）,which was attributed to the deposition of particulate aluminum matters with much higher hydration state.Compared with stationary condition,stirring could significantly enhance the deposition process,while the effect of pH on deposition was relatively weak in the near neutral range of 6.7 to 8.7.

Comparative study on local and global mechanical properties of bobbin tool and conventional friction stir welded 7085-T7452 aluminum thick plate

7085-T7452 plates with a thickness of 12 mm were welded by conventional single side and bobbin tool friction stir welding （SS-FSW and BB-FSW, respectively） at different welding parameters. The temperature distribution, microstructure evolution and mechanical properties of joints along the thickness direction were investigated, and digital image correlation （DIC） was utilized to evaluate quantitatively the deformation of different zones during tensile tests. The results indicated that heat-affected zone （HAZ）, the local softening region, was responsible for the early plastic deformation and also the fracture location for SS-FSW samples, while a rapid fracture was observed in weld nugget zone （WNZ） before yield behavior for all BB-FSW specimens. The ultimate tensile strength （UTS） of SS-FSW joints presented the highest value of 410 MPa, 82% of the base material, at a rotational speed of 300 rpm and welding speed of 60 mm/min, much higher than that of BB-FSW joints, with a joint efficiency of only 47%. This should be attributed to the Lazy S defect produced by a larger extent of heat input during the BB-FSW process, The whole joint exhibited a much higher elongation than the slices. Scanning electron microscopic （SEM） analysis of the fracture morphologies showed that joints failed through ductile fracture for SS-FSW and brittle fracture for BB-FSW.

Improving Joint Features and Mechanical Properties of Pinless Fiction Stir Welding of Alcald 2A12-T4 Aluminum Alloy

As a new solid state welding,pinless friction stir welding（PFSW） can be used to join thin-wall structures.In this study,four new pinless tools with different groove distributions were designed and manufactured in order to enrich technological storage of PFSW and obtain sound joint with high quality of alclad 2A12-T4 alloy.The results show that the small-obliquity tool is detrimental to the transfer of plasticized materials,resulting in the formation of kissing bond defect.For the through-groove tool or the large-curvature tool,bigger flashes form on the joint surface and alclad layer is observed in the nugget zone（NZ）,deteriorating mechanical properties.Compared with the above-mentioned three tools,using the six-groove tool with rational curvature and obliquity can not only yield sound joint with small flashes and thickness reduction,but also prevent alclad from flowing into NZ,which has potential to weld thin alclad aluminum alloys.Meanwhile,the tensile strength and elongation of joint using the six-groove tool reach the maximum values of 362 MPa and 8.3%,up to 85.1% and 64% of BM.