The details of ternary fluoride crystallization in the system NaF-CaF2-AlF3 have been specified. The phases NaCaAlF6, Na2Ca3Al2F14 and NaAlF4 have been obtained by high-temperature synthesis. Their thermal transformat...The details of ternary fluoride crystallization in the system NaF-CaF2-AlF3 have been specified. The phases NaCaAlF6, Na2Ca3Al2F14 and NaAlF4 have been obtained by high-temperature synthesis. Their thermal transformations have been studied using high-temperature X-ray diffraction. The occurring transformations can be considered in a quasibinary system CaF2-NaAlF4, where at T = 745°C - 750°C invariant equilibrium is established with the phases CaF2-NaCaAlF6-Na2Ca3Al2F14-(NaAlF4). The compounds NaCaAlF6 and Na2Ca3Al2F14 are stable in different temperature ranges. The phase NaCaAlF6 was fixed by rapid quenching from the melt. It decomposes at heating before 640°C yielding Na2Ca3Al2F14 and NaAlF4. Direct and inverse transformations between NaCaAlF6 and Na2Ca3Al2F14 occur in the bulk samples of the electrolyte. A thermal treatment procedure was proposed for the solid electrolyte sample to get a sample corresponding to the composition of the melt and providing high phase crystallinity for the purposes of quantitative X-ray phase diffraction analysis.展开更多
The thick target neutron yields (TTNYs) of deuteron-induced reaction on AI and Cu isotopes are analyzed by combining the improved nuclear models and particle transport effects. The modified Glauber model is employed...The thick target neutron yields (TTNYs) of deuteron-induced reaction on AI and Cu isotopes are analyzed by combining the improved nuclear models and particle transport effects. The modified Glauber model is employed mainly to produce the peak of double differential cross section for the breakup process, and the exciton model and the Hauser-Feshbach theory are used for the statistical processes. The thin-layer accumulation method is used to calculate the TTNYs considering the neutron attenuation effects in the target. The calculated results are compared with the existing experimental data, and the analysis method can predict the TTNY data well at the deuteron energy of 40 MeV.展开更多
文摘The details of ternary fluoride crystallization in the system NaF-CaF2-AlF3 have been specified. The phases NaCaAlF6, Na2Ca3Al2F14 and NaAlF4 have been obtained by high-temperature synthesis. Their thermal transformations have been studied using high-temperature X-ray diffraction. The occurring transformations can be considered in a quasibinary system CaF2-NaAlF4, where at T = 745°C - 750°C invariant equilibrium is established with the phases CaF2-NaCaAlF6-Na2Ca3Al2F14-(NaAlF4). The compounds NaCaAlF6 and Na2Ca3Al2F14 are stable in different temperature ranges. The phase NaCaAlF6 was fixed by rapid quenching from the melt. It decomposes at heating before 640°C yielding Na2Ca3Al2F14 and NaAlF4. Direct and inverse transformations between NaCaAlF6 and Na2Ca3Al2F14 occur in the bulk samples of the electrolyte. A thermal treatment procedure was proposed for the solid electrolyte sample to get a sample corresponding to the composition of the melt and providing high phase crystallinity for the purposes of quantitative X-ray phase diffraction analysis.
基金Supported by the Project of China Academy of Engineering Physics under Grant No 2013B0103015
文摘The thick target neutron yields (TTNYs) of deuteron-induced reaction on AI and Cu isotopes are analyzed by combining the improved nuclear models and particle transport effects. The modified Glauber model is employed mainly to produce the peak of double differential cross section for the breakup process, and the exciton model and the Hauser-Feshbach theory are used for the statistical processes. The thin-layer accumulation method is used to calculate the TTNYs considering the neutron attenuation effects in the target. The calculated results are compared with the existing experimental data, and the analysis method can predict the TTNY data well at the deuteron energy of 40 MeV.