Study on desorption and regeneration of simulated decarbonization solution using ammonia method for CO2 capture was car- fled out in order to understand the feature of regeneration of decarbonization solution. The mec...Study on desorption and regeneration of simulated decarbonization solution using ammonia method for CO2 capture was car- fled out in order to understand the feature of regeneration of decarbonization solution. The mechanisms about solution desorp- tion after decarbonization were introduced briefly. Under the atmospheric pressure and in the presence of nitrogen carrier gas, several effects related to desorption of simulated decarbonization solution were analyzed, such as temperature, solution con- centration, pH, loading capacity, etc. The results showed that the CO2 desorption percentage increased with the increases of temperature, solution concentration and loading capacity, but CO2 desorption percentage increased with the increasing of pH and then decreased.展开更多
Under the conditions of tetramethyl ammonia chloride (TMAC) used as starting material, Ti-based Dimensionally Stable Anode (DSA), stainless steel used as cathode and Nafion 900 cation membrane as cell diaphragm, this ...Under the conditions of tetramethyl ammonia chloride (TMAC) used as starting material, Ti-based Dimensionally Stable Anode (DSA), stainless steel used as cathode and Nafion 900 cation membrane as cell diaphragm, this paper studies the synthesis of tetramethyl ammonium hydroxide (TMAH) by cell diaphragm electrolytic method, examining not only the effects of current density, concentration of starting material and cell temperature, on the product purity and current efficiency, but also the effects of electrolyte circulation rate on the service life of Ti-based DSA. The experiment puts forward an optimum processing condition, and experimental findings show that preparing TMAH by using this technique can obtain a current efficiency 74.7% and get product with a purity greater than 99.9%.展开更多
基金supported by the National Natural Science Foundation of China (Grant No. 21176064)
文摘Study on desorption and regeneration of simulated decarbonization solution using ammonia method for CO2 capture was car- fled out in order to understand the feature of regeneration of decarbonization solution. The mechanisms about solution desorp- tion after decarbonization were introduced briefly. Under the atmospheric pressure and in the presence of nitrogen carrier gas, several effects related to desorption of simulated decarbonization solution were analyzed, such as temperature, solution con- centration, pH, loading capacity, etc. The results showed that the CO2 desorption percentage increased with the increases of temperature, solution concentration and loading capacity, but CO2 desorption percentage increased with the increasing of pH and then decreased.
文摘Under the conditions of tetramethyl ammonia chloride (TMAC) used as starting material, Ti-based Dimensionally Stable Anode (DSA), stainless steel used as cathode and Nafion 900 cation membrane as cell diaphragm, this paper studies the synthesis of tetramethyl ammonium hydroxide (TMAH) by cell diaphragm electrolytic method, examining not only the effects of current density, concentration of starting material and cell temperature, on the product purity and current efficiency, but also the effects of electrolyte circulation rate on the service life of Ti-based DSA. The experiment puts forward an optimum processing condition, and experimental findings show that preparing TMAH by using this technique can obtain a current efficiency 74.7% and get product with a purity greater than 99.9%.
