In order to clarify the extraction process with saponified extractant, the solvent extraction experiments of rare earth elements(REEs), lanthanum and cerium, by using partly saponified 2-ethylhexyl phosphoric acid mon...In order to clarify the extraction process with saponified extractant, the solvent extraction experiments of rare earth elements(REEs), lanthanum and cerium, by using partly saponified 2-ethylhexyl phosphoric acid mono-2-ethylhexyl ester(EHEHPA, HL) from hydrochloric acidic solutions have been performed. The concentration of initial aqueous rare earth ion was in a range of 0.0010–0.1000 mol·L^(-1); EHEHPA in a range of 0.2877–0.8631 mol·L^(-1) with saponification rate of 0.3(mole fraction), and the initial aqueous p H in a range of 1.00–4.00. Firstly, the extracted species were determined by the saturation extraction capacity method. Secondly, according to the equilibrium aqueous pH values, the extraction processes were divided into three different categories: extraction with saponified EHEHPA, extraction with un-saponified EHEHPA, and hydrolysis process. Finally, for the first two processes, in order to predict the distribution ratio, two semi-empirical calculation models were developed with.The calculation results are in good agreement well with the experimental data.展开更多
The solubization of the W/O microemulsion of NA（naphthenic acid）/kerosene/NH3· H2O system has been investigated.The effect of salt,cosurfactant （- alcohol） on solubization of the microemulsion has been studie...The solubization of the W/O microemulsion of NA（naphthenic acid）/kerosene/NH3· H2O system has been investigated.The effect of salt,cosurfactant （- alcohol） on solubization of the microemulsion has been studied by the theory of cohesive energies（theory of R- ratio）.The results show that theory of R- ratio may explain the effect of concentration of salt,such as LiCl,NaCl,KCl,NaNO3,Na2SO4,NH4Cl,on maximum solubization （Φ m） of the microemulsion,but can not explain the differences of the effect of these salt onΦ m（to see Fig.1）.We have found that,the rateQ（Q=z/r） of salt was correlated with the effect of salt on Φ m（to see Tab.1）.Theory of R- ratio can only explain the effect of fraction mass of part alconols,such as n- octyl and n- heptyl and n- hexyl alcohol onΦ m,but can not explain the effect of isobutyl alcohol,n- butyl alcohol,n- pentanol and isoamyl alconol onΦ m （to see Fig.2）.So theory of R- ratio has it’s limitations in explaination of the phenomenons of solubization of W/O microemulsion.展开更多
基金Supported by the National Basic Research Program of China(2012CBA01203)the National Natural Science Foundation of China(9021003420221603)
文摘In order to clarify the extraction process with saponified extractant, the solvent extraction experiments of rare earth elements(REEs), lanthanum and cerium, by using partly saponified 2-ethylhexyl phosphoric acid mono-2-ethylhexyl ester(EHEHPA, HL) from hydrochloric acidic solutions have been performed. The concentration of initial aqueous rare earth ion was in a range of 0.0010–0.1000 mol·L^(-1); EHEHPA in a range of 0.2877–0.8631 mol·L^(-1) with saponification rate of 0.3(mole fraction), and the initial aqueous p H in a range of 1.00–4.00. Firstly, the extracted species were determined by the saturation extraction capacity method. Secondly, according to the equilibrium aqueous pH values, the extraction processes were divided into three different categories: extraction with saponified EHEHPA, extraction with un-saponified EHEHPA, and hydrolysis process. Finally, for the first two processes, in order to predict the distribution ratio, two semi-empirical calculation models were developed with.The calculation results are in good agreement well with the experimental data.
文摘The solubization of the W/O microemulsion of NA（naphthenic acid）/kerosene/NH3· H2O system has been investigated.The effect of salt,cosurfactant （- alcohol） on solubization of the microemulsion has been studied by the theory of cohesive energies（theory of R- ratio）.The results show that theory of R- ratio may explain the effect of concentration of salt,such as LiCl,NaCl,KCl,NaNO3,Na2SO4,NH4Cl,on maximum solubization （Φ m） of the microemulsion,but can not explain the differences of the effect of these salt onΦ m（to see Fig.1）.We have found that,the rateQ（Q=z/r） of salt was correlated with the effect of salt on Φ m（to see Tab.1）.Theory of R- ratio can only explain the effect of fraction mass of part alconols,such as n- octyl and n- heptyl and n- hexyl alcohol onΦ m,but can not explain the effect of isobutyl alcohol,n- butyl alcohol,n- pentanol and isoamyl alconol onΦ m （to see Fig.2）.So theory of R- ratio has it’s limitations in explaination of the phenomenons of solubization of W/O microemulsion.
