The deep mining of coal resources is accompanied by severe environmental challenges and various potential engineering hazards.The implementation of NPR(negative Poisson's ratio)bolts are capable of controlling lar...The deep mining of coal resources is accompanied by severe environmental challenges and various potential engineering hazards.The implementation of NPR(negative Poisson's ratio)bolts are capable of controlling large deformations in the surrounding rock effectively.This paper focuses on studying the mechanical properties of the NPR bolt under static disturbance load.The deep nonlinear mechanical experimental system was used to study the mechanical behavior of rock samples with different anchored types(unanchored/PR anchored/2G NPR anchored)under static disturbance load.The whole process of rock samples was taken by high-speed camera to obtain the real-time failure characteristics under static disturbance load.At the same time,the acoustic emission signal was collected to obtain the key characteristic parameters of acoustic emission such as acoustic emission count,energy,and frequency.The deformation at the failure of the samples was calculated and analyzed by digital speckle software.The findings indicate that the failure mode of rock is influenced by different types of anchoring.The peak failure strength of 2G NPR bolt anchored rock samples exhibits an increase of 6.5%when compared to the unanchored rock samples.The cumulative count and cumulative energy of acoustic emission exhibit a decrease of 62.16%and 62.90%,respectively.The maximum deformation of bearing capacity exhibits an increase of 59.27%,while the failure time demonstrates a delay of 42.86%.The peak failure strength of the 2G NPR bolt anchored ones under static disturbance load exhibits an increase of 5.94%when compared to the rock anchored by PR(Poisson's ratio)bolt.The cumulative count and cumulative energy of acoustic emission exhibit a decrease of 47.16%and 43.86%,respectively.The maximum deformation of the bearing capacity exhibits an increase of 50.43%,and the failure time demonstrates a delay of 32%.After anchoring by 2G NPR bolt,anchoring support effectively reduces the risk of damage caused by static disturbance load.These results demonstrate that the support effect of 2G NPR bolt materials surpasses that of PR bolt.展开更多
This study compares the strength characteristics of rocks anchored by NPR bolts and ordinary bolts with varied preloads,based on the mechanical properties of NPR bolts(with a negative Poisson’s ratio).The results sho...This study compares the strength characteristics of rocks anchored by NPR bolts and ordinary bolts with varied preloads,based on the mechanical properties of NPR bolts(with a negative Poisson’s ratio).The results show that the uniaxial compressive stress-strain curve of ordinary anchored rocks exhibits noticeable abrupt changes.After reaching peak strength,the bolt breaks,whereas the stress-strain curve of NPR-anchored rocks is smoother.The NPR bolt enters the stage of continuous resistance after reaching maximal strength and does not break.As the preload increases,the strength of the anchored rock grows linearly.A calculation equation for the strength of the anchored rock is proposed based on the preload.The theoretical equation fits the test results well,and the fitted parameters show that NPR bolts can better increase the strength of the rock.The concept of dynamic toughness UC of anchored rock is proposed to reflect the comprehensive mechanical properties of anchored rock,including strength and plasticity.As the preload increases,the UC of ordinary anchored rock first decreases and then increases,while the UC of the NPR anchored rock does not change significantly with the preload when the strain is small,and the UC increases with the increase of the preload when the strain is large.展开更多
A new capillary gas chromatography stationary phase, monokis (2,6 di O benzyl 3 O propyl (3’)) hexakis(2,6 di O benzyl 3 O methyl) β CD bonded polysiloxane, was synthesized. It ex...A new capillary gas chromatography stationary phase, monokis (2,6 di O benzyl 3 O propyl (3’)) hexakis(2,6 di O benzyl 3 O methyl) β CD bonded polysiloxane, was synthesized. It exhibited separation abilities to disubstituted benzene isomers and some chiral solutes. It was also found that the polarity of CD derivatives can be lowered both by chemically bonding it to polysiloxane and by diluting it in polysiloxane. The separation abilities of the polysiloxane anchored CDs (SP CD) are higher than that of the unbonded CDs (S CD) and the diluted S CD at lower column temperature. Hydrosilylation reaction is one of the best methods to lower the operating temperature of CDs.展开更多
AIM To design a miniature magnetically anchored and controlled camera system to reduce the number of trocars which are required for laparoscopy.METHODS The system consists of a miniature magnetically anchored camera w...AIM To design a miniature magnetically anchored and controlled camera system to reduce the number of trocars which are required for laparoscopy.METHODS The system consists of a miniature magnetically anchored camera with a 30° downward angle, an external magnetically anchored unit, and a vision output device. The camera weighs 12 g, measures Φ10.5 mm × 55 mm and has two magnets, a vision model, a light source, and a metal hexagonal nut. To test the prototype, the camera was inserted through a 12-mm conventional trocar in an ex vivo real liver laparoscopic training system. A trocar-less laparoscopic cholecystectomy was performed 6 times using a 12-mm and a 5-mm conventional trocar. In addition, the same procedure was performed in four canine models.RESULTS Both procedures were successfully performed using only two conventional laparoscopic trocars. The cholecystectomy was completed without any major complication in 42 min(38-45 min) in vitro and in 50 min(45-53 min) using an animal model. This camera was anchored and controlled by an external unit magnetically anchored on the abdominal wall. The camera could generate excellent image. with no instrument collisions.CONCLUSION The camera system we designed provides excellent optics and can be easily maneuvered. The number of conventional trocars is reduced without adding technical difficulties.展开更多
To improve the accuracy of illumination estimation while maintaining a relative fast execution speed, a novel learning-based color constancy using color edge moments and regularized regression in an anchored neighborh...To improve the accuracy of illumination estimation while maintaining a relative fast execution speed, a novel learning-based color constancy using color edge moments and regularized regression in an anchored neighborhood is proposed. First, scene images are represented by the color edge moments of various orders. Then, an iterative regression with a squared Frobenius norm(F-norm) regularizer is introduced to learn the mapping between the edge moments and illuminants in the neighborhood of the anchored sample.Illumination estimation for the test image finally becomes the nearest anchored point search followed by a matrix multiplication using the associated mapping matrix which can be precalculated and stored. Experiments on two standard image datasets show that the proposed approach significantly outperforms the state-of-the-art algorithms with a performance increase of at least 10. 35% and 7. 44% with regard to median angular error.展开更多
The thinking of co evolution is applied to the optimization of retaining and protecting structure for deep foundation excavation, and the system of optimization of anchored row piles for deep foundation pit has been a...The thinking of co evolution is applied to the optimization of retaining and protecting structure for deep foundation excavation, and the system of optimization of anchored row piles for deep foundation pit has been already developed successfully. For the co evolution algorithm providing an evolutionary mechanism to simulate ever changing problem space, it is an optimization algorithm that has high performance, especially applying to the optimization of complicated system of retaining and protecting for deep foundation pit. It is shown by many engineering practices that the co evolution algorithm has obvious optimization effect, so it can be an important method of optimization of retaining and protecting for deep foundation pit. Here the authors discuss the co evolution model, object function, all kinds of constraint conditions and their disposal methods, and several key techniques of system realization.展开更多
Both aliphatic and aromatic ketones are efficiently transfer-hydrogenated by propan-2-ol under mild conditions in the presence of a catalytic amount of poly(2,6-dimethyl-1,4-Phenylene oxide) (PPO) anchored ruthenium...Both aliphatic and aromatic ketones are efficiently transfer-hydrogenated by propan-2-ol under mild conditions in the presence of a catalytic amount of poly(2,6-dimethyl-1,4-Phenylene oxide) (PPO) anchored ruthenium complex and sodium hydroxide. An important feature of this polymer anchored catalyst is its stability in air.展开更多
Oxygen reduction reaction(ORR)is the key reaction at the cathode of proton exchange membrane fuel cells(PEMFCs)and metal-air batteries(1)To address the challenges associated with Pt-based electrocatalysts having promi...Oxygen reduction reaction(ORR)is the key reaction at the cathode of proton exchange membrane fuel cells(PEMFCs)and metal-air batteries(1)To address the challenges associated with Pt-based electrocatalysts having prominent activity for ORR,e.g.scarce abundance,prohibitive cost,poor stability,and vulnerability to reaction intermediates,it is necessary to explore other cost-effective ORR electrocatalysts with competitive or even superior performance to promote the commercialization of the energy conversion devices.展开更多
Carbonylation of allyl halides catalyzed by poly(N-vinyl-2-pyrro- lidone) anchored palladium catalyst affords β,r-butonic acid under atmo- spheric pressure and at room temperature.The activity and efficiency of the c...Carbonylation of allyl halides catalyzed by poly(N-vinyl-2-pyrro- lidone) anchored palladium catalyst affords β,r-butonic acid under atmo- spheric pressure and at room temperature.The activity and efficiency of the catalyst are much higher than those of the reported catalysts for this reaction.展开更多
In order to solve the problem of experimental research on the penetration process of projectile into anchored rock mass, we derived the essential similarity conditions for the physical simulation experi- ment accordin...In order to solve the problem of experimental research on the penetration process of projectile into anchored rock mass, we derived the essential similarity conditions for the physical simulation experi- ment according to the similarity theory, carried out the experiment on the penetration process of a kind of penetrating bomb into the anchored rock mass of type III, and compared the experimental results with the values computed by the professional Young's empirical formula. The test results show that the phys- ical simulation experiment can represent the actual penetration process of projectile into anchored rock mass. The research method proposed in this paper provides technical support for the experimental research on the design and reconstruction of underground protection works.展开更多
This paper presents a design concept and acceptance test application procedure for a deep pit protection structure. The structure is intended for use in the construction of three underground levels of a residential bu...This paper presents a design concept and acceptance test application procedure for a deep pit protection structure. The structure is intended for use in the construction of three underground levels of a residential building: A, B, C and D, located in Block 10C, Budva, Montenegro. The anchored wall will consist of non-gravity cantilevered walls with three levels of ground anchors. Non-gravity cantilevered walls employ continuous walls constructed in slurry trenches (i.e., slurry (diaphragm) walls), e.g., vertical elements that are drilled to depths below the finished excavation grade. For those non-gravity cantilevered walls, support is provided through the shear and bending stiffness of the vertical wall elements and passive resistance from the soil below the finished excavation grade. Anchored wall support relies on these components as well as lateral resistance provided by the ground anchors to resist horizontal pressures (e.g., earth, water and external loads) acting on the wall. The anchored wall analyzed in this paper will be recommended for use as a temporary supporting structure necessary for the excavation and erection of the underground structure. The design life of the temporary ground anchors is two years. Dynamic loads are not considered in this analysis.展开更多
Lithium (Li)-CO_(2) battery is rising as an attractive energy-storage system with the competence of CO_(2) conversion/fixation. However, its practical development is seriously hindered by the high overpotential. Herei...Lithium (Li)-CO_(2) battery is rising as an attractive energy-storage system with the competence of CO_(2) conversion/fixation. However, its practical development is seriously hindered by the high overpotential. Herein, a rational design on a highly catalytic Li-CO_(2) battery electrode built by graphdiyne powder as a multi-functional laminar scaffold with anchored highly dispersed Ru nanoparticles is explored. The strong interaction between the abundant acetylenic bond sites of graphdiyne scaffold and Ru nanoparticles can effectively promote the electrochemical progress and reduce the voltage polarization. The unique channels architecture of the cathodic catalyst with enough space not only accelerates CO_(2) diffusion and electrons/Li+ transport, but also allows a large amount of accommodation for discharged product (Li2CO3) to assure an advanced capacity. The corresponding Li-CO_(2) battery displays an advanced discharged capacity of 15,030 mAh/g at 500 mA/g, great capacity retention of 8873 mAh/g at 2 A/g, high coulombic efficiency of 97.6% at 500 mA/g and superior life span for 120 cycles with voltage gap of 1.67 V under a restricted capacity of 1000 mAh/g at 500 mA/g. Ex/in-situ studies prove that synergy between Ru nanoparticles and acetylene bonds of GDY can boost the round-trip CO_(2)RR and CO_(2)ER kinetics.展开更多
Rock-embedded foundations with good uplift and bearing capacity are often used in mountains or hilly areas.However,there are soil layers with a certain thickness on the rocks in these mountainous areas,and the utiliza...Rock-embedded foundations with good uplift and bearing capacity are often used in mountains or hilly areas.However,there are soil layers with a certain thickness on the rocks in these mountainous areas,and the utilization of those soil layers is a problem worthy of attention in foundation construction.Considering construction-and cost-related factors,traditional single-form foundations built on such sites often cannot provide sufficient resistance against uplift.Therefore,an anchored pier foundation composed of anchors and belled piers,specifically constructed for such conditions,can be invaluable in practice.This paper introduces an experimental and analytical study to investigate the uplift capacity and the uplift mobilization coefficients(UMCs)of the anchored pier foundation.In this study,three in-situ monotonic pullout tests were carried out to analyze the load–displacement characteristics,axial force distribution,load transfer mechanism,and failure mechanism.A hyperbolic model is used to fit the load–displacement curves and to reveal the asynchrony of the ultimate limit states(ULSs)of the anchor group and the belled pier.Based on the results,the uplift capacity can be calculated by the UMCs and the anchor group and pier uplift capacities.Finally,combined with the estimation of the deformation modulus of the soil and rock,the verification calculation of the uplift capacity and UMC was carried out on the test results from different anchored pier foundations.展开更多
According to different geological conditions and engineering disturbance,three dimensional numerical models of anchored jointed rock mass with two kinds of boundary conditions of constant normal load(CNL)and constant ...According to different geological conditions and engineering disturbance,three dimensional numerical models of anchored jointed rock mass with two kinds of boundary conditions of constant normal load(CNL)and constant normal stiffness(CNS)were constructed considering the ductility damage of rockbolt,the stiffness degradation of grouting layer and the joint surface roughness.The effects of anchorage angle,joint surface morphology,and boundary conditions on the shear performance of anchorage system were analyzed,and the failure characteristics under different working conditions were revealed.Finally,the analytical solution of shear strength of anchored system was established.Results show that the larger the anchorage angle is,the more serious the necking phenomenon of rockbolt will be.The damage degree of the bonding layer and the horizontal displacement of the bedding rock mass decrease with the increase of the joint surface roughness.The CNL condition is to instantaneously apply high normal stress,and the CNS condition is to gradually form a high normal stress environment through the superposition of increment on the basis of the initial value,which can resist greater transverse load.This is equivalent to enhancing the ductility of the rockbolt.The shear strength of the system increases with the increase of normal stress and normal stiffness.Ignoring the normal stiffness will underestimate the shear strength.展开更多
Inherent weak photon-capturing ability is a long-standing bottleneck for pristine phase change materials(PCMs)in photothermal conversion application.To conquer this difficulty,herein,magnetic Fe_(3)O_(4) nanoparticles...Inherent weak photon-capturing ability is a long-standing bottleneck for pristine phase change materials(PCMs)in photothermal conversion application.To conquer this difficulty,herein,magnetic Fe_(3)O_(4) nanoparticles were in situ anchored between the layers and the surface of two-dimensional MXene for the infiltration of myristic acid(MA)by an in situ chemical anchoring strategy.Benefiting from the synergistic localized surface plasmon resonance effect of MXene and Fe_(3)O_(4) nanoparticles,our designed MXene@Fe_(3)O_(4)-MA composite PCMs harvested an ultrahigh photothermal conversion efficiency of 97.7%.During the photothermal conversion process,MXene can capture photons and convert solar energy into heat energy efficiently,and the in situ anchored Fe_(3)O_(4) nanoparticles further enhanced the photothermal conversion efficiency.Moreover,the introduction of Fe_(3)O_(4) nanoparticles improved the thermal energy storage density(144.17 J/g)of MXene-MA composite PCMs since Fe_(3)O_(4) nanoparticles provided more heterogeneous nucleation sites for MA.Simultaneously,MXene@Fe_(3)O_(4)-MA composite PCMs were endowed with excellent paramagnetism,and realized efficient magnetic-thermal conversion.Additionally,MXene@Fe_(3)O_(4)-MA composite PCMs exhibited excellent energy conversion stability,thermal stability,and reliability after undergoing multiple thermal cycles.Therefore,high-performance MXene@Fe_(3)O_(4)-based energy conversion composite PCMs are promising candidates to accelerate efficient utilization of the practical solar energy and magnetic energy.展开更多
The stability control of fissured rock is difficult,especially under static and dynamic loads in deep coal mines.In this paper,the dynamic mechanical properties,strain rate evolution and energy dissipation of fissured...The stability control of fissured rock is difficult,especially under static and dynamic loads in deep coal mines.In this paper,the dynamic mechanical properties,strain rate evolution and energy dissipation of fissured and anchored rocks were respectively obtained by SHPB tests.It was found that bolt can provide supporting efficiency-improving effect for fissured rock against dynamic disturbance,and this effect increased quadratically with decrease in anchoring angles.Then,the energy dissipation mechanism of anchored rock was obtained by slipping model.Furthermore,bolt energy-absorbing mechanism by instantaneous tensile-shear deformation was expressed based on material mechanics,which was the larger the anchoring angle,the smaller the energy absorption,and the less the contribution to supporting efficiency improvement.On this basis,the functional relationship between energy dissipation of anchored rock and energy absorption of bolt was established.Taking the coal-gangue separation system of Longgu coal mine as an example,the optimal anchoring angle can be determined as 57.5°–67.5°.Field monitoring showed fissured rock with the optimal anchoring angle,can not only effectively control the deformation,but also fully exert the energy-absorbing and efficiency-improving effect of bolt itself.This study provides guidance to the stability control and supporting design for deep engineering under the same or similar conditions.展开更多
The angle α between the fault strike and the axial direction of the roadway produces different damage characteristics. In this paper, the research methodology includes theoretical analyses, numerical simulations and ...The angle α between the fault strike and the axial direction of the roadway produces different damage characteristics. In this paper, the research methodology includes theoretical analyses, numerical simulations and field experiments in the context of the Daqiang coal mine located in Shenyang, China. The stability control countermeasure of "pre-splitting cutting roof + NPR anchor cable"(PSCR-NPR) is simultaneously proposed. According to the different deformation characteristics of the roadway, the faults are innovatively classified into three types, with α of type I being 0°-30°, α of type II being 30°-60°, and α of type III being 60°-90°. The full-cycle stress evolution paths during mining roadway traverses across different types of faults are investigated by numerical simulation. Different pinch angles α lead to high stress concentration areas at different locations in the surrounding rock. The non-uniform stress field formed in the shallow surrounding rock is an important reason for the instability of the roadway. The pre-cracked cut top shifted the high stress region to the deep rock mass and formed a low stress region in the shallow rock mass. The high prestressing NPR anchor cable transforms the non-uniform stress field of the shallow surrounding rock into a uniform stress field. PSCR-NPR is applied in the fault-through roadway of Daqiang mine. The low stress area of the surrounding rock was enlarged by 3-7 times, and the cumulative convergence was reduced by 45%-50%. It provides a reference for the stability control of the deep fault-through mining roadway.展开更多
The deep‐sea ground contains a huge amount of energy and mineral resources,for example,oil,gas,and minerals.Various infrastructures such as floating structures,seabed structures,and foundations have been developed to...The deep‐sea ground contains a huge amount of energy and mineral resources,for example,oil,gas,and minerals.Various infrastructures such as floating structures,seabed structures,and foundations have been developed to exploit these resources.The seabed structures and foundations can be mainly classified into three types:subsea production structures,offshore pipelines,and anchors.This study reviewed the development,installation,and operation of these infrastructures,including their structures,design,installation,marine environment loads,and applications.On this basis,the research gaps and further research directions were explored through this literature review.First,different floating structures were briefly analyzed and reviewed to introduce the design requirements of the seabed structures and foundations.Second,the subsea production structures,including subsea manifolds and their foundations,were reviewed and discussed.Third,the basic characteristics and design methods of deep‐sea pipelines,including subsea pipelines and risers,were analyzed and reviewed.Finally,the installation and bearing capacity of deep‐sea subsea anchors and seabed trench influence on the anchor were reviewed.Through the review,it was found that marine environment conditions are the key inputs for any offshore structure design.The fabrication,installation,and operation of infrastructures should carefully consider the marine loads and geological conditions.Different structures have their own mechanical problems.The fatigue and stability of pipelines mainly depend on the soil‐structure interaction.Anchor selection should consider soil types and possible trench formation.These focuses and research gaps can provide a helpful guide on further research,installation,and operation of deep‐sea structures and foundations.展开更多
With the support by the National Natural Science Foundation of China,the collaborative research teams from the University of Science and Technology of China led by Prof.Lu JunLing(路军岭),Prof.Wei ShiQiang(韦世强)and ...With the support by the National Natural Science Foundation of China,the collaborative research teams from the University of Science and Technology of China led by Prof.Lu JunLing(路军岭),Prof.Wei ShiQiang(韦世强)and Prof.Yang JinLong(杨金龙),recently reported a new type of catalyst with atomically dispersed iron hydroxide anchored on Pt nanoparticles.展开更多
基金provided by the National Natural Science Foundation of China(52074300)the Program of China Scholarship Council(202206430024)+2 种基金the National Natural Science Foundation of China Youth Science(52104139)Yueqi Young Scholars Project of China University of Mining and Technology Beijing(2602021RC84)Guizhou province science and technology planning project([2020]3007,[2020]3008)。
文摘The deep mining of coal resources is accompanied by severe environmental challenges and various potential engineering hazards.The implementation of NPR(negative Poisson's ratio)bolts are capable of controlling large deformations in the surrounding rock effectively.This paper focuses on studying the mechanical properties of the NPR bolt under static disturbance load.The deep nonlinear mechanical experimental system was used to study the mechanical behavior of rock samples with different anchored types(unanchored/PR anchored/2G NPR anchored)under static disturbance load.The whole process of rock samples was taken by high-speed camera to obtain the real-time failure characteristics under static disturbance load.At the same time,the acoustic emission signal was collected to obtain the key characteristic parameters of acoustic emission such as acoustic emission count,energy,and frequency.The deformation at the failure of the samples was calculated and analyzed by digital speckle software.The findings indicate that the failure mode of rock is influenced by different types of anchoring.The peak failure strength of 2G NPR bolt anchored rock samples exhibits an increase of 6.5%when compared to the unanchored rock samples.The cumulative count and cumulative energy of acoustic emission exhibit a decrease of 62.16%and 62.90%,respectively.The maximum deformation of bearing capacity exhibits an increase of 59.27%,while the failure time demonstrates a delay of 42.86%.The peak failure strength of the 2G NPR bolt anchored ones under static disturbance load exhibits an increase of 5.94%when compared to the rock anchored by PR(Poisson's ratio)bolt.The cumulative count and cumulative energy of acoustic emission exhibit a decrease of 47.16%and 43.86%,respectively.The maximum deformation of the bearing capacity exhibits an increase of 50.43%,and the failure time demonstrates a delay of 32%.After anchoring by 2G NPR bolt,anchoring support effectively reduces the risk of damage caused by static disturbance load.These results demonstrate that the support effect of 2G NPR bolt materials surpasses that of PR bolt.
基金supported by the National Natural Science Foundation of China(Grant Nos.52174096 and 51874311)。
文摘This study compares the strength characteristics of rocks anchored by NPR bolts and ordinary bolts with varied preloads,based on the mechanical properties of NPR bolts(with a negative Poisson’s ratio).The results show that the uniaxial compressive stress-strain curve of ordinary anchored rocks exhibits noticeable abrupt changes.After reaching peak strength,the bolt breaks,whereas the stress-strain curve of NPR-anchored rocks is smoother.The NPR bolt enters the stage of continuous resistance after reaching maximal strength and does not break.As the preload increases,the strength of the anchored rock grows linearly.A calculation equation for the strength of the anchored rock is proposed based on the preload.The theoretical equation fits the test results well,and the fitted parameters show that NPR bolts can better increase the strength of the rock.The concept of dynamic toughness UC of anchored rock is proposed to reflect the comprehensive mechanical properties of anchored rock,including strength and plasticity.As the preload increases,the UC of ordinary anchored rock first decreases and then increases,while the UC of the NPR anchored rock does not change significantly with the preload when the strain is small,and the UC increases with the increase of the preload when the strain is large.
文摘A new capillary gas chromatography stationary phase, monokis (2,6 di O benzyl 3 O propyl (3’)) hexakis(2,6 di O benzyl 3 O methyl) β CD bonded polysiloxane, was synthesized. It exhibited separation abilities to disubstituted benzene isomers and some chiral solutes. It was also found that the polarity of CD derivatives can be lowered both by chemically bonding it to polysiloxane and by diluting it in polysiloxane. The separation abilities of the polysiloxane anchored CDs (SP CD) are higher than that of the unbonded CDs (S CD) and the diluted S CD at lower column temperature. Hydrosilylation reaction is one of the best methods to lower the operating temperature of CDs.
基金Supported by National Natural Science Foundation of China(Major Instrumental Program)No.81127005the Science and Technology Innovation Project of Shaanxi Province,China,No.S2016TNGY0119
文摘AIM To design a miniature magnetically anchored and controlled camera system to reduce the number of trocars which are required for laparoscopy.METHODS The system consists of a miniature magnetically anchored camera with a 30° downward angle, an external magnetically anchored unit, and a vision output device. The camera weighs 12 g, measures Φ10.5 mm × 55 mm and has two magnets, a vision model, a light source, and a metal hexagonal nut. To test the prototype, the camera was inserted through a 12-mm conventional trocar in an ex vivo real liver laparoscopic training system. A trocar-less laparoscopic cholecystectomy was performed 6 times using a 12-mm and a 5-mm conventional trocar. In addition, the same procedure was performed in four canine models.RESULTS Both procedures were successfully performed using only two conventional laparoscopic trocars. The cholecystectomy was completed without any major complication in 42 min(38-45 min) in vitro and in 50 min(45-53 min) using an animal model. This camera was anchored and controlled by an external unit magnetically anchored on the abdominal wall. The camera could generate excellent image. with no instrument collisions.CONCLUSION The camera system we designed provides excellent optics and can be easily maneuvered. The number of conventional trocars is reduced without adding technical difficulties.
基金The National Natural Science Foundation of China(No.61503303,51409215)the Fundamental Research Funds for the Central Universities(No.G2015KY0102)
文摘To improve the accuracy of illumination estimation while maintaining a relative fast execution speed, a novel learning-based color constancy using color edge moments and regularized regression in an anchored neighborhood is proposed. First, scene images are represented by the color edge moments of various orders. Then, an iterative regression with a squared Frobenius norm(F-norm) regularizer is introduced to learn the mapping between the edge moments and illuminants in the neighborhood of the anchored sample.Illumination estimation for the test image finally becomes the nearest anchored point search followed by a matrix multiplication using the associated mapping matrix which can be precalculated and stored. Experiments on two standard image datasets show that the proposed approach significantly outperforms the state-of-the-art algorithms with a performance increase of at least 10. 35% and 7. 44% with regard to median angular error.
基金National Natural Science Foundation of China( 5 986 80 0 1)
文摘The thinking of co evolution is applied to the optimization of retaining and protecting structure for deep foundation excavation, and the system of optimization of anchored row piles for deep foundation pit has been already developed successfully. For the co evolution algorithm providing an evolutionary mechanism to simulate ever changing problem space, it is an optimization algorithm that has high performance, especially applying to the optimization of complicated system of retaining and protecting for deep foundation pit. It is shown by many engineering practices that the co evolution algorithm has obvious optimization effect, so it can be an important method of optimization of retaining and protecting for deep foundation pit. Here the authors discuss the co evolution model, object function, all kinds of constraint conditions and their disposal methods, and several key techniques of system realization.
文摘Both aliphatic and aromatic ketones are efficiently transfer-hydrogenated by propan-2-ol under mild conditions in the presence of a catalytic amount of poly(2,6-dimethyl-1,4-Phenylene oxide) (PPO) anchored ruthenium complex and sodium hydroxide. An important feature of this polymer anchored catalyst is its stability in air.
文摘Oxygen reduction reaction(ORR)is the key reaction at the cathode of proton exchange membrane fuel cells(PEMFCs)and metal-air batteries(1)To address the challenges associated with Pt-based electrocatalysts having prominent activity for ORR,e.g.scarce abundance,prohibitive cost,poor stability,and vulnerability to reaction intermediates,it is necessary to explore other cost-effective ORR electrocatalysts with competitive or even superior performance to promote the commercialization of the energy conversion devices.
文摘Carbonylation of allyl halides catalyzed by poly(N-vinyl-2-pyrro- lidone) anchored palladium catalyst affords β,r-butonic acid under atmo- spheric pressure and at room temperature.The activity and efficiency of the catalyst are much higher than those of the reported catalysts for this reaction.
文摘In order to solve the problem of experimental research on the penetration process of projectile into anchored rock mass, we derived the essential similarity conditions for the physical simulation experi- ment according to the similarity theory, carried out the experiment on the penetration process of a kind of penetrating bomb into the anchored rock mass of type III, and compared the experimental results with the values computed by the professional Young's empirical formula. The test results show that the phys- ical simulation experiment can represent the actual penetration process of projectile into anchored rock mass. The research method proposed in this paper provides technical support for the experimental research on the design and reconstruction of underground protection works.
文摘This paper presents a design concept and acceptance test application procedure for a deep pit protection structure. The structure is intended for use in the construction of three underground levels of a residential building: A, B, C and D, located in Block 10C, Budva, Montenegro. The anchored wall will consist of non-gravity cantilevered walls with three levels of ground anchors. Non-gravity cantilevered walls employ continuous walls constructed in slurry trenches (i.e., slurry (diaphragm) walls), e.g., vertical elements that are drilled to depths below the finished excavation grade. For those non-gravity cantilevered walls, support is provided through the shear and bending stiffness of the vertical wall elements and passive resistance from the soil below the finished excavation grade. Anchored wall support relies on these components as well as lateral resistance provided by the ground anchors to resist horizontal pressures (e.g., earth, water and external loads) acting on the wall. The anchored wall analyzed in this paper will be recommended for use as a temporary supporting structure necessary for the excavation and erection of the underground structure. The design life of the temporary ground anchors is two years. Dynamic loads are not considered in this analysis.
基金the National Natural Science Foundation of China(Nos.21971132 and 52072197)Outstanding Youth Foundation of Shandong Province,China(No.ZR2019JQ14)+7 种基金Youth Innovation and Technology Foundation of Shandong Higher Education Institutions,China(No.2019KJC004)Major Scientific and Technological Innovation Project(No.2019JZZY020405)Major Basic Research Program of Natural Science Foundation of Shandong Province(No.ZR2020ZD09)Taishan Scholar Young Talent Program(No.tsqn201909114)the Key Laboratory of Resource Chemistry,Ministry of Education(No.KLRC_ME2101)Scientific and Technological Innovation Promotion Project for Small-medium Enterprises of Shandong Province(No.2022TSGC1257)Major Research Program of Jining City(No.2020ZDZP024)The 111 Project of China(No.D20017).
文摘Lithium (Li)-CO_(2) battery is rising as an attractive energy-storage system with the competence of CO_(2) conversion/fixation. However, its practical development is seriously hindered by the high overpotential. Herein, a rational design on a highly catalytic Li-CO_(2) battery electrode built by graphdiyne powder as a multi-functional laminar scaffold with anchored highly dispersed Ru nanoparticles is explored. The strong interaction between the abundant acetylenic bond sites of graphdiyne scaffold and Ru nanoparticles can effectively promote the electrochemical progress and reduce the voltage polarization. The unique channels architecture of the cathodic catalyst with enough space not only accelerates CO_(2) diffusion and electrons/Li+ transport, but also allows a large amount of accommodation for discharged product (Li2CO3) to assure an advanced capacity. The corresponding Li-CO_(2) battery displays an advanced discharged capacity of 15,030 mAh/g at 500 mA/g, great capacity retention of 8873 mAh/g at 2 A/g, high coulombic efficiency of 97.6% at 500 mA/g and superior life span for 120 cycles with voltage gap of 1.67 V under a restricted capacity of 1000 mAh/g at 500 mA/g. Ex/in-situ studies prove that synergy between Ru nanoparticles and acetylene bonds of GDY can boost the round-trip CO_(2)RR and CO_(2)ER kinetics.
基金supported by the National Natural Science Foundation of China(No.U2006225)the European Union’s Horizon 2020 Marie Sklodowska-Curie Research and Innovation Staff Exchange Programme(No.778360)。
文摘Rock-embedded foundations with good uplift and bearing capacity are often used in mountains or hilly areas.However,there are soil layers with a certain thickness on the rocks in these mountainous areas,and the utilization of those soil layers is a problem worthy of attention in foundation construction.Considering construction-and cost-related factors,traditional single-form foundations built on such sites often cannot provide sufficient resistance against uplift.Therefore,an anchored pier foundation composed of anchors and belled piers,specifically constructed for such conditions,can be invaluable in practice.This paper introduces an experimental and analytical study to investigate the uplift capacity and the uplift mobilization coefficients(UMCs)of the anchored pier foundation.In this study,three in-situ monotonic pullout tests were carried out to analyze the load–displacement characteristics,axial force distribution,load transfer mechanism,and failure mechanism.A hyperbolic model is used to fit the load–displacement curves and to reveal the asynchrony of the ultimate limit states(ULSs)of the anchor group and the belled pier.Based on the results,the uplift capacity can be calculated by the UMCs and the anchor group and pier uplift capacities.Finally,combined with the estimation of the deformation modulus of the soil and rock,the verification calculation of the uplift capacity and UMC was carried out on the test results from different anchored pier foundations.
基金supported by the National Natural Science Foundation of China(Grant Nos.51774196 and 52074169).
文摘According to different geological conditions and engineering disturbance,three dimensional numerical models of anchored jointed rock mass with two kinds of boundary conditions of constant normal load(CNL)and constant normal stiffness(CNS)were constructed considering the ductility damage of rockbolt,the stiffness degradation of grouting layer and the joint surface roughness.The effects of anchorage angle,joint surface morphology,and boundary conditions on the shear performance of anchorage system were analyzed,and the failure characteristics under different working conditions were revealed.Finally,the analytical solution of shear strength of anchored system was established.Results show that the larger the anchorage angle is,the more serious the necking phenomenon of rockbolt will be.The damage degree of the bonding layer and the horizontal displacement of the bedding rock mass decrease with the increase of the joint surface roughness.The CNL condition is to instantaneously apply high normal stress,and the CNS condition is to gradually form a high normal stress environment through the superposition of increment on the basis of the initial value,which can resist greater transverse load.This is equivalent to enhancing the ductility of the rockbolt.The shear strength of the system increases with the increase of normal stress and normal stiffness.Ignoring the normal stiffness will underestimate the shear strength.
基金National Natural Science Foundation of China,Grant/Award Number:51902025Fundamental Research Funds for the Central Universities,Grant/Award Numbers:2019NTST29,FRF-BD-20-07A+1 种基金China Postdoctoral Science Foundation,Grant/Award Numbers:2020T130060,2019M660520Scientific and Technological Innovation Foundation of Shunde Graduate School,University of Science and Technology Beijing,Grant/Award Number:BK20AE003。
文摘Inherent weak photon-capturing ability is a long-standing bottleneck for pristine phase change materials(PCMs)in photothermal conversion application.To conquer this difficulty,herein,magnetic Fe_(3)O_(4) nanoparticles were in situ anchored between the layers and the surface of two-dimensional MXene for the infiltration of myristic acid(MA)by an in situ chemical anchoring strategy.Benefiting from the synergistic localized surface plasmon resonance effect of MXene and Fe_(3)O_(4) nanoparticles,our designed MXene@Fe_(3)O_(4)-MA composite PCMs harvested an ultrahigh photothermal conversion efficiency of 97.7%.During the photothermal conversion process,MXene can capture photons and convert solar energy into heat energy efficiently,and the in situ anchored Fe_(3)O_(4) nanoparticles further enhanced the photothermal conversion efficiency.Moreover,the introduction of Fe_(3)O_(4) nanoparticles improved the thermal energy storage density(144.17 J/g)of MXene-MA composite PCMs since Fe_(3)O_(4) nanoparticles provided more heterogeneous nucleation sites for MA.Simultaneously,MXene@Fe_(3)O_(4)-MA composite PCMs were endowed with excellent paramagnetism,and realized efficient magnetic-thermal conversion.Additionally,MXene@Fe_(3)O_(4)-MA composite PCMs exhibited excellent energy conversion stability,thermal stability,and reliability after undergoing multiple thermal cycles.Therefore,high-performance MXene@Fe_(3)O_(4)-based energy conversion composite PCMs are promising candidates to accelerate efficient utilization of the practical solar energy and magnetic energy.
基金the financial support from the National Natural Science Foundation of China(Nos.52374094,52174122 and 52374218)Excellent Youth Fund of Shandong Natural Science Foundation(No.ZR2022YQ49)Taishan Scholar Project in Shandong Province(Nos.tspd20210313 and tsqn202211150)。
文摘The stability control of fissured rock is difficult,especially under static and dynamic loads in deep coal mines.In this paper,the dynamic mechanical properties,strain rate evolution and energy dissipation of fissured and anchored rocks were respectively obtained by SHPB tests.It was found that bolt can provide supporting efficiency-improving effect for fissured rock against dynamic disturbance,and this effect increased quadratically with decrease in anchoring angles.Then,the energy dissipation mechanism of anchored rock was obtained by slipping model.Furthermore,bolt energy-absorbing mechanism by instantaneous tensile-shear deformation was expressed based on material mechanics,which was the larger the anchoring angle,the smaller the energy absorption,and the less the contribution to supporting efficiency improvement.On this basis,the functional relationship between energy dissipation of anchored rock and energy absorption of bolt was established.Taking the coal-gangue separation system of Longgu coal mine as an example,the optimal anchoring angle can be determined as 57.5°–67.5°.Field monitoring showed fissured rock with the optimal anchoring angle,can not only effectively control the deformation,but also fully exert the energy-absorbing and efficiency-improving effect of bolt itself.This study provides guidance to the stability control and supporting design for deep engineering under the same or similar conditions.
基金funded by the National Natural Science Foundation of China (52174096, 52304110)the Fundamental Research Funds for the Central Universities (2022YJSSB03)the Scientific and Technological Projects of Henan Province (232102320238)。
文摘The angle α between the fault strike and the axial direction of the roadway produces different damage characteristics. In this paper, the research methodology includes theoretical analyses, numerical simulations and field experiments in the context of the Daqiang coal mine located in Shenyang, China. The stability control countermeasure of "pre-splitting cutting roof + NPR anchor cable"(PSCR-NPR) is simultaneously proposed. According to the different deformation characteristics of the roadway, the faults are innovatively classified into three types, with α of type I being 0°-30°, α of type II being 30°-60°, and α of type III being 60°-90°. The full-cycle stress evolution paths during mining roadway traverses across different types of faults are investigated by numerical simulation. Different pinch angles α lead to high stress concentration areas at different locations in the surrounding rock. The non-uniform stress field formed in the shallow surrounding rock is an important reason for the instability of the roadway. The pre-cracked cut top shifted the high stress region to the deep rock mass and formed a low stress region in the shallow rock mass. The high prestressing NPR anchor cable transforms the non-uniform stress field of the shallow surrounding rock into a uniform stress field. PSCR-NPR is applied in the fault-through roadway of Daqiang mine. The low stress area of the surrounding rock was enlarged by 3-7 times, and the cumulative convergence was reduced by 45%-50%. It provides a reference for the stability control of the deep fault-through mining roadway.
基金Key Research and Development program of Zhejiang ProvinceGrant/Award Number:2018C03031+3 种基金The Open Foundation of Key Laboratory of Offshore Geotechnical and Material Engineering of Zhejiang Province,Grant/Award Number:OGME21003Natural Science Foundation of Zhejiang Province,Grant/Award Numbers:LHZ19E090003,LY15E090002Norges Forskningsr?d,Grant/Award Number:OGME21003National Natural Science Foundation of China,Grant/Award Numbers:51209183,51779220,52101334。
文摘The deep‐sea ground contains a huge amount of energy and mineral resources,for example,oil,gas,and minerals.Various infrastructures such as floating structures,seabed structures,and foundations have been developed to exploit these resources.The seabed structures and foundations can be mainly classified into three types:subsea production structures,offshore pipelines,and anchors.This study reviewed the development,installation,and operation of these infrastructures,including their structures,design,installation,marine environment loads,and applications.On this basis,the research gaps and further research directions were explored through this literature review.First,different floating structures were briefly analyzed and reviewed to introduce the design requirements of the seabed structures and foundations.Second,the subsea production structures,including subsea manifolds and their foundations,were reviewed and discussed.Third,the basic characteristics and design methods of deep‐sea pipelines,including subsea pipelines and risers,were analyzed and reviewed.Finally,the installation and bearing capacity of deep‐sea subsea anchors and seabed trench influence on the anchor were reviewed.Through the review,it was found that marine environment conditions are the key inputs for any offshore structure design.The fabrication,installation,and operation of infrastructures should carefully consider the marine loads and geological conditions.Different structures have their own mechanical problems.The fatigue and stability of pipelines mainly depend on the soil‐structure interaction.Anchor selection should consider soil types and possible trench formation.These focuses and research gaps can provide a helpful guide on further research,installation,and operation of deep‐sea structures and foundations.
文摘With the support by the National Natural Science Foundation of China,the collaborative research teams from the University of Science and Technology of China led by Prof.Lu JunLing(路军岭),Prof.Wei ShiQiang(韦世强)and Prof.Yang JinLong(杨金龙),recently reported a new type of catalyst with atomically dispersed iron hydroxide anchored on Pt nanoparticles.