LiMn2-xMxO4-yFy(x=0.05; y=0.05; M=Al, Co, Cr and Mg, separately), as the cathode material, was synthesized by the method of high temperature solid-state reaction in laboratory. The results of charge-discharge test sho...LiMn2-xMxO4-yFy(x=0.05; y=0.05; M=Al, Co, Cr and Mg, separately), as the cathode material, was synthesized by the method of high temperature solid-state reaction in laboratory. The results of charge-discharge test show that the properties of LiMn1.95M0.05O3.95F0.05(M= Al, Mg) are obviously superior to those of LiMn2O4. Through the condition experiments on sintering temperature, it is found that the materials present the integrate crystal structure and favorable cycle performance at 800 ℃. The research on the effects of different Mg2+ sources on the properties of LiMn2-xMgxO4-yFy shows that, with Mg(OH)2 and LiF as the reagents respectively offering Mg2+ and F?, LiMn1.95Mg0.05O3.95F0.05 synthesized has integrate crystal structure and its capacity hardly fades. The results of cyclic voltammetry indicate that the shape of two couples of redox peaks of the material synthesized by co-doping anti-electricity ions is more integrate and symmetrical than that of pure spinel LiMn2O4, which reveals that the co-doping material possesses preferable electrochemical reversibility.展开更多
In the study organic-inorganic hybrid composite, epoxy modified silicone coating and vinyl ester flake mastic were comparatively used as several anti-corrosion materials that provided protection for flue gas desulfu-r...In the study organic-inorganic hybrid composite, epoxy modified silicone coating and vinyl ester flake mastic were comparatively used as several anti-corrosion materials that provided protection for flue gas desulfu-rization (FGD). The relationship between curing conversion rate of hybrid polymer and temperature was investigated by differential scanning calorimeter (DSC). The adhesion strength, coefficient of thermal expansion and flame retardant properties of three anti-corrosion materials were measured and analyzed. A corrosion test in 8% H2SO4 and 5% HCl at temperature cycle of 40°C~ 160°C was applied to study corrosion resistance of several anti-corrosion materials. Gravimetric measurement and morphological observation of three materials before and after corrosion test were comparatively analyzed in the paper. The small weight change and good morphological structure of hybrid composite during corrosion test demonstrate that hybrid composite has better anti-corrosion properties than epoxy modified silicone coating and vinyl ester flake mastic.展开更多
The present paper is exposed theoretically to the influence on the dynamic stress intensity factor (DSIF) in the piezoelectric bi-materials model with two symmet- rically permeable interracial cracks near the edges ...The present paper is exposed theoretically to the influence on the dynamic stress intensity factor (DSIF) in the piezoelectric bi-materials model with two symmet- rically permeable interracial cracks near the edges of a circular cavity, subjected to the dynamic incident anti-plane shearing wave (SH-wave). An available theoretical method to dynamic analysis in the related research field is provided. The formulations are based on Green's function method. The DSIFs at the inner and outer tips of the left crack are obtained by solving the boundary value problems with the conjunction and crack- simulation technique. The numerical results are obtained by the FORTRAN language program and plotted to show the influence of the variations of the physical parameters, the structural geometry, and the wave frequencies of incident wave on the dimensionless DSIFs. Comparisons with previous work and between the inner and outer tips are con- cluded.展开更多
Aiming at the harmfulness of and protection from ionizing radiation, this paper will centre on the design and synthesis technology of a new type of polymeric material which is stable at the ionizing radiation from 10-...Aiming at the harmfulness of and protection from ionizing radiation, this paper will centre on the design and synthesis technology of a new type of polymeric material which is stable at the ionizing radiation from 10-11 to 10-8 meter wave. The material is made up of epoxy resin 6101, curing agent phenolic-aniline resin, which is developed by the authors, and other auxilliary agents. This material is stable at the radiation of 107Gy,and its physical and chemical properties are excellent.展开更多
The problem of an anti-plane Griffith crack moving along the interface of dissimilar piezoelectric materials is solved by using the integral transform technique. It is shown from the result that the intensity factors ...The problem of an anti-plane Griffith crack moving along the interface of dissimilar piezoelectric materials is solved by using the integral transform technique. It is shown from the result that the intensity factors of anti-plane stress and electric displacement around the crack tip are dependent on the speed of the Griffith crack as well as the material coefficients. When the two piezoelectric materials are identical, the present result will be reduced to the result far the problem of an anti-plane moving Griffith crack in homogeneous piezoelectric materials.展开更多
The special case of a crack under mode Ⅲ conditions was treated, lying parallel to the edges of an infinite strip with finite width and with the shear modulus varying exponentially perpendicular to the edges. By usin...The special case of a crack under mode Ⅲ conditions was treated, lying parallel to the edges of an infinite strip with finite width and with the shear modulus varying exponentially perpendicular to the edges. By using Fourier transforms the problem was formulated in terms of a singular integral equation. It was numerically solved by representing the unknown dislocation density by a truncated series of Chebyshev polynomials leading to a linear system of equations. The stress intensity factor (SIF) results were discussed with respect to the influences of different geometric parameters and the strength of the non-homogeneity. It was indicated that the SIF increases with the increase of the crack length and decreases with the increase of the rigidity of the material in the vicinity of crack. The SIF of narrow strip is very sensitive to the change of the non-homogeneity parameter and its variation is complicated. With the increase of the non-homogeneity parameter, the stress intensity factor may increase, decrease or keep constant, which is mainly determined by the strip width and the relative crack location. If the crack is located at the midline of the strip or if the strip is wide, the stress intensity factor is not sensitive to the material non-homogeneity parameter.展开更多
A mode Ⅲ crack problem in a transversely isotropic piezoelectric material subjected to uniform loads at infinity is studied based on exact boundary conditions. The complex potential approach is used to reduce the pro...A mode Ⅲ crack problem in a transversely isotropic piezoelectric material subjected to uniform loads at infinity is studied based on exact boundary conditions. The complex potential approach is used to reduce the problem to Hilbert problem. As a result, closed form field solutions in the piezoelectric material and inside the crack are presented. It is shown that the stresses and electric displacement have square root singularities at the crack tips, but the electric field is uniform everywhere in the material and equal to the remote applied one. It is also found that the electric displacement intensity factor depends on both material properties and the mechanical loads, but not the electric loads. Hence it may be concluded that the electric loads have no influence on the field singularities.展开更多
The properties of road base course materials of granular soils stabilized by AGS granular soil stabilizing cement were studied.The AGS cement has an expansibility to a certain degree,so the dry shrinkage of AGS cemen...The properties of road base course materials of granular soils stabilized by AGS granular soil stabilizing cement were studied.The AGS cement has an expansibility to a certain degree,so the dry shrinkage of AGS cement paste and AGS stabilized granular is much lower than that of Portland slag cement.AGS has a good suitability to granular soils.Granular soils stabilized by AGS have a much higher strength than that of soils stabilized by P S cement.The same strength can be reached with 20% reduction of cement dosage for AGS cement.And their elastic and resilient modulus are similar,but the former has a much higher tensile splitting strength,so the AGS stabilized granular has a much better anti-cracking performance than that of the P S stabilized granular.The reduced value of the strength and the density with the retard time for the granular soils stabilized by AGS is lower than that for P S cement.展开更多
文摘LiMn2-xMxO4-yFy(x=0.05; y=0.05; M=Al, Co, Cr and Mg, separately), as the cathode material, was synthesized by the method of high temperature solid-state reaction in laboratory. The results of charge-discharge test show that the properties of LiMn1.95M0.05O3.95F0.05(M= Al, Mg) are obviously superior to those of LiMn2O4. Through the condition experiments on sintering temperature, it is found that the materials present the integrate crystal structure and favorable cycle performance at 800 ℃. The research on the effects of different Mg2+ sources on the properties of LiMn2-xMgxO4-yFy shows that, with Mg(OH)2 and LiF as the reagents respectively offering Mg2+ and F?, LiMn1.95Mg0.05O3.95F0.05 synthesized has integrate crystal structure and its capacity hardly fades. The results of cyclic voltammetry indicate that the shape of two couples of redox peaks of the material synthesized by co-doping anti-electricity ions is more integrate and symmetrical than that of pure spinel LiMn2O4, which reveals that the co-doping material possesses preferable electrochemical reversibility.
文摘In the study organic-inorganic hybrid composite, epoxy modified silicone coating and vinyl ester flake mastic were comparatively used as several anti-corrosion materials that provided protection for flue gas desulfu-rization (FGD). The relationship between curing conversion rate of hybrid polymer and temperature was investigated by differential scanning calorimeter (DSC). The adhesion strength, coefficient of thermal expansion and flame retardant properties of three anti-corrosion materials were measured and analyzed. A corrosion test in 8% H2SO4 and 5% HCl at temperature cycle of 40°C~ 160°C was applied to study corrosion resistance of several anti-corrosion materials. Gravimetric measurement and morphological observation of three materials before and after corrosion test were comparatively analyzed in the paper. The small weight change and good morphological structure of hybrid composite during corrosion test demonstrate that hybrid composite has better anti-corrosion properties than epoxy modified silicone coating and vinyl ester flake mastic.
基金supported by the National Natural Science Foundation of China(No.51108113)
文摘The present paper is exposed theoretically to the influence on the dynamic stress intensity factor (DSIF) in the piezoelectric bi-materials model with two symmet- rically permeable interracial cracks near the edges of a circular cavity, subjected to the dynamic incident anti-plane shearing wave (SH-wave). An available theoretical method to dynamic analysis in the related research field is provided. The formulations are based on Green's function method. The DSIFs at the inner and outer tips of the left crack are obtained by solving the boundary value problems with the conjunction and crack- simulation technique. The numerical results are obtained by the FORTRAN language program and plotted to show the influence of the variations of the physical parameters, the structural geometry, and the wave frequencies of incident wave on the dimensionless DSIFs. Comparisons with previous work and between the inner and outer tips are con- cluded.
文摘Aiming at the harmfulness of and protection from ionizing radiation, this paper will centre on the design and synthesis technology of a new type of polymeric material which is stable at the ionizing radiation from 10-11 to 10-8 meter wave. The material is made up of epoxy resin 6101, curing agent phenolic-aniline resin, which is developed by the authors, and other auxilliary agents. This material is stable at the radiation of 107Gy,and its physical and chemical properties are excellent.
基金the National Natural Science Foundationthe National Post-doctoral Science Foundation of China
文摘The problem of an anti-plane Griffith crack moving along the interface of dissimilar piezoelectric materials is solved by using the integral transform technique. It is shown from the result that the intensity factors of anti-plane stress and electric displacement around the crack tip are dependent on the speed of the Griffith crack as well as the material coefficients. When the two piezoelectric materials are identical, the present result will be reduced to the result far the problem of an anti-plane moving Griffith crack in homogeneous piezoelectric materials.
基金Project supported by the National Natural Science Foundation of China (No.90305023)
文摘The special case of a crack under mode Ⅲ conditions was treated, lying parallel to the edges of an infinite strip with finite width and with the shear modulus varying exponentially perpendicular to the edges. By using Fourier transforms the problem was formulated in terms of a singular integral equation. It was numerically solved by representing the unknown dislocation density by a truncated series of Chebyshev polynomials leading to a linear system of equations. The stress intensity factor (SIF) results were discussed with respect to the influences of different geometric parameters and the strength of the non-homogeneity. It was indicated that the SIF increases with the increase of the crack length and decreases with the increase of the rigidity of the material in the vicinity of crack. The SIF of narrow strip is very sensitive to the change of the non-homogeneity parameter and its variation is complicated. With the increase of the non-homogeneity parameter, the stress intensity factor may increase, decrease or keep constant, which is mainly determined by the strip width and the relative crack location. If the crack is located at the midline of the strip or if the strip is wide, the stress intensity factor is not sensitive to the material non-homogeneity parameter.
文摘A mode Ⅲ crack problem in a transversely isotropic piezoelectric material subjected to uniform loads at infinity is studied based on exact boundary conditions. The complex potential approach is used to reduce the problem to Hilbert problem. As a result, closed form field solutions in the piezoelectric material and inside the crack are presented. It is shown that the stresses and electric displacement have square root singularities at the crack tips, but the electric field is uniform everywhere in the material and equal to the remote applied one. It is also found that the electric displacement intensity factor depends on both material properties and the mechanical loads, but not the electric loads. Hence it may be concluded that the electric loads have no influence on the field singularities.
文摘The properties of road base course materials of granular soils stabilized by AGS granular soil stabilizing cement were studied.The AGS cement has an expansibility to a certain degree,so the dry shrinkage of AGS cement paste and AGS stabilized granular is much lower than that of Portland slag cement.AGS has a good suitability to granular soils.Granular soils stabilized by AGS have a much higher strength than that of soils stabilized by P S cement.The same strength can be reached with 20% reduction of cement dosage for AGS cement.And their elastic and resilient modulus are similar,but the former has a much higher tensile splitting strength,so the AGS stabilized granular has a much better anti-cracking performance than that of the P S stabilized granular.The reduced value of the strength and the density with the retard time for the granular soils stabilized by AGS is lower than that for P S cement.