Seismic prediction of cracks is of great significance in many disciplines,for which the rock physics model is indispensable.However,up to now,multitudinous analytical models focus primarily on the cracked rock with th...Seismic prediction of cracks is of great significance in many disciplines,for which the rock physics model is indispensable.However,up to now,multitudinous analytical models focus primarily on the cracked rock with the isotropic background,while the explicit model for the cracked rock with the anisotropic background is rarely investigated in spite of such case being often encountered in the earth.Hence,we first studied dependences of the crack opening displacement tensors on the crack dip angle in the coordinate systems formed by symmetry planes of the crack and the background anisotropy,respectively,by forty groups of numerical experiments.Based on the conclusion from the experiments,the analytical solution was derived for the effective elastic properties of the rock with the inclined penny-shaped cracks in the transversely isotropic background.Further,we comprehensively analyzed,according to the developed model,effects of the crack dip angle,background anisotropy,filling fluid and crack density on the effective elastic properties of the cracked rock.The analysis results indicate that the dip angle and background anisotropy can significantly either enhance or weaken the anisotropy degrees of the P-and SH-wave velocities,whereas they have relatively small effects on the SV-wave velocity anisotropy.Moreover,the filling fluid can increase the stiffness coefficients related to the compressional modulus by reducing crack compliance parameters,while its effects on shear coefficients depend on the crack dip angle.The increasing crack density reduces velocities of the dry rock,and decreasing rates of the velocities are affected by the crack dip angle.By comparing with exact numerical results and experimental data,it was demonstrated that the proposed model can achieve high-precision estimations of stiffness coefficients.Moreover,the assumption of the weakly anisotropic background results in the consistency between the proposed model and Hudson's published theory for the orthorhombic rock.展开更多
In order to investigate the synergistic effect of re-dispersible powder-ethylene-vinyl acetate copolymer(EVA) and polypropylene fiber on the crack resistance of concrete under thermal fatigue loading, the compressive ...In order to investigate the synergistic effect of re-dispersible powder-ethylene-vinyl acetate copolymer(EVA) and polypropylene fiber on the crack resistance of concrete under thermal fatigue loading, the compressive strength, ultimate tensile strength, ultimate tensile strain and tensile modulus of elasticity were tested. In addition, ultrasonic method and scanning electron microscope analysis were used to explain the microstructure mechanism. The results show that polypropylene fiberreinforced concrete presents a better performance on crack resistance than ordinary concrete, and the synergism of EVA and polypropylene fiber can improve the anti-cracking ability of concrete further.展开更多
To enrich material types applied to additive manufacturing and enlarge application scope of additive manufacturing in conformal cooling tools,M2 high-speed steel specimens were fabricated by selective laser melting(SL...To enrich material types applied to additive manufacturing and enlarge application scope of additive manufacturing in conformal cooling tools,M2 high-speed steel specimens were fabricated by selective laser melting(SLM).Effects of SLM parameters on the microstructure and mechanical properties of M2 high-speed steel were investigated.The results showed that substrate temperature and energy density had significant influence on the densification process of materials and defects control.Models to evaluate the effect of substrate temperature and energy density on hardness were studied.The optimized process parameters,laser power,scan speed,scan distance,and substrate temperature,for fabricated M2 are 220 W,960 mm/s,0.06 mm,and 200℃,respectively.Based on this,the hardness and tensile strength reached 60 HRC and 1000 MPa,respectively.Interlaminar crack formation and suppression mechanism and the relationship between temperature gradient and thermal stress were illustrated.The inhibition effect of substrate temperature on the cracks generated by residual stresses was also explained.AM showed great application potential in the field of special conformal cooling cutting tool preparation.展开更多
An AZ31 HP magnesium alloy was laser beam welded in autogenous mode with AZ61 filler using Nd-YAG laser system.Microstructural examination revealed that the laser beam weld metals obtained with or without filler mater...An AZ31 HP magnesium alloy was laser beam welded in autogenous mode with AZ61 filler using Nd-YAG laser system.Microstructural examination revealed that the laser beam weld metals obtained with or without filler material had an average grain size of about 12 μm.The microhardness and the tensile strength of the weldments were similar to those of the parent alloy.However,the stress corrosion cracking (SCC) behaviour of both the weldments assessed by slow strain rate tensile (SSRT) tests in ASTM D1384 solution was found to be slightly inferior to that of the parent alloy.It was observed that the stress corrosion cracks originated in the weld metal and propagated through the weld metal-HAZ regions in the autogenous weldment.On the other hand,in the weldment obtained with AZ61 filler material,the crack initiation and propagation was in the HAZ region.The localized damage of the magnesium hydroxide/oxide film formed on the surface of the specimens due to the exposure to the corrosive environment during the SSRT tests was found to be responsible for the SCC.展开更多
A novel micro-micro/mesoporous aluminosilicate ZSM-5-Y/MCM-41 composite molecular sieve with a MCM-41 type structure was synthesized through a novel process of the self-assembly of CTAB surfactant micellae with silica...A novel micro-micro/mesoporous aluminosilicate ZSM-5-Y/MCM-41 composite molecular sieve with a MCM-41 type structure was synthesized through a novel process of the self-assembly of CTAB surfactant micellae with silica-alumina source originated from alkaline treatment of ZSM-5 zeolite. The physical properties of the ZSM-5- Y/MCM-41 composite molecular sieve were characterized by XRD, Py-FTIR and N2 adsorption-desorption techniques. Different kinds of molecular sieves including ZSM-5, Y zeolite, AI-MCM-41, ZSM-5/MCM-41 and ZSM-5-Y/MCM- 41 as cracking catalysts were investigated, using 1,3,5-triisopropylbenzene (1,3,5-TIPB) as the probe molecule. Catalytic tests showed that the ZSM-5-Y/MCM-41 composite molecular sieve exhibited higher catalytic activity compared with the microporous ZSM-5 zeolite, Y zeolite, mesoporous A1-MCM-41 molecular sieve and ZSM-5/MCM-41 composite molecular sieve under the same conditions. The remarkable catalytic activity was mainly attributed to the presence of the hierarchical pore structure and proper acidity in the ZSM-5-Y/MCM-41 composite catalyst. Meanwhile, a carbcnium ion mechanism was put forward for the cracking of 1,3,5-TIPB.展开更多
Sustained casing pressure(SCP)is a crucial issue in the oil and gas production lifecycle.Epoxy resins,exhibiting exceptional compressive strength,ductility,and shear bonding strength,have the potential to form reliabl...Sustained casing pressure(SCP)is a crucial issue in the oil and gas production lifecycle.Epoxy resins,exhibiting exceptional compressive strength,ductility,and shear bonding strength,have the potential to form reliable barriers.The injectivity and sealing capacity of the epoxy resin is crucial parameters for the success of shallow remediation operations.This study aimed to develop and assess a novel solid-free resin sealant as an alternative to Portland cement for mitigating fluid leakage.The investigation evaluated the viscosity,compressive strength,and brittleness index of the epoxy resin sealant,as well as its tangential and normal shear strengths in conjunction with casing steel.The flow characteristics and sealing abilities of conventional cement and epoxy resin were comparatively analyzed in cracks.The results showed that the application of a viscosity reducer facilitated control over the curing time of the epoxy resin,ranging from 1.5 to 6 h,and reduced the initial viscosity from 865.53 to 118.71 m Pa,s.The mechanical properties of the epoxy resin initially increased with a rise in curing agent content before experiencing a minor decrease.The epoxy resin containing 30%curing agent exhibited optimal mechanical properties.After a 14-day curing period,the epoxy resin's compressive strength reached81.37 MPa,2.12 times higher than that of cement,whereas the elastic modulus of cement was 2.99 times greater than that of the epoxy resin.The brittleness index of epoxy resin is only 3.42,demonstrating high flexibility and toughness.The tangential and normal shear strengths of the epoxy resin exceeded those of cement by 3.17 and 2.82 times,respectively.In a 0.5 mm-wide crack,the injection pressure of the epoxy resin remained below 0.075 MPa,indicating superior injection and flow capabilities.Conversely,the injection pressure of cement surged dramatically to 2.61 MPa within 5 min.The breakthrough pressure of0.5 PV epoxy resin reached 7.53 MPa,decreasing the crack's permeability to 0.02 D,a mere 9.49%of the permeability observed following cement plugging.Upon sealing a 2 mm-wide crack using epoxy resin,the maximum breakthrough pressure attained 5.47 MPa,3.48 times of cement.These results suggest that epoxy resin sealant can be employed safely and effectively to seal cracks in the cement.展开更多
This study investigated the mechanical properties of beech(Fagus sylvatica L.)and fir(Abies alba)wood from Bosnia and Herzegovina under outdoor exposure.Samples were exposed for 3-month exposure to assess bending stre...This study investigated the mechanical properties of beech(Fagus sylvatica L.)and fir(Abies alba)wood from Bosnia and Herzegovina under outdoor exposure.Samples were exposed for 3-month exposure to assess bending strength,color changes,and surface quality.Results showed outdoor exposure negatively affected mechanical properties,particularly in samples with extended finger joints,causing significant surface cracks in uncoated samples.Beech wood exhibited notable color changes under exposure,with approximately 50%darkening without coating compared to 25%under covered conditions.Coated samples displayed minimal color changes,affirming the efficacy of surface treatment.Fir wood exhibited a roughness of 8.264μm,while beechwood average roughness increased from 6.767 to 13.916μm after exposure,with micro-pore development affecting water performance.Microscopic analysis identified prevalent fungal colonies,including Penicillium,Aureobasidium,Sclerophoma,and Chaetomium,underscoring their role in organic matter decomposition.This study highlights the importance of wood exposure and treatment selection for various applications.展开更多
The effects of interrupted aging on mechanical properties and corrosion resistance of 7A75 aluminum alloy extruded bar were investigated through various analyses,including electrical conductivity,mechanical properties...The effects of interrupted aging on mechanical properties and corrosion resistance of 7A75 aluminum alloy extruded bar were investigated through various analyses,including electrical conductivity,mechanical properties,local corrosion properties,and slow strain rate tensile stress corrosion tests.Microstructure characterization techniques such as metallographic microscopy,scanning electron microscopy(SEM),and transmission electron microscopy(TEM)were also employed.The results indicate that the tensile strength of the alloy produced by T6I6 aging is similar to that produced by T6I4 aging,and it even exceeds 700 MPa.Furthermore,the yield strength increases by 52.7 MPa,reaching 654.8 MPa after T6I6 aging treatment.The maximum depths of intergranular corrosion(IGC)and exfoliation corrosion(EXCO)decrease from 116.3 and 468.5μm to 89.5 and 324.3μm,respectively.The stress corrosion factor also decreases from 2.1%to 1.6%.These findings suggest that the alloy treated with T6I6 aging exhibits both high strength and excellent stress corrosion cracking resistance.Similarly,when the alloy is treated with T6I4,T6I6 and T6I7 aging,the sizes of grain boundary precipitates(GBPs)are found to be 5.2,18.4,and 32.8 nm,respectively.The sizes of matrix precipitates are 4.8,5.7 and 15.7 nm,respectively.The atomic fractions of Zn in GBPs are 9.92 at.%,8.23 at.%and 6.87 at.%,respectively,while the atomic fractions of Mg are 12.66 at.%,8.43 at.%and 7.00 at.%,respectively.Additionally,the atomic fractions of Cu are 1.83 at.%,2.47 at.%and 3.41 at.%,respectively.展开更多
2A14-T62 butt joint was successfully welded by stationary shoulder friction stir welding(SSFSW)method.The results showed that using a pin with small shoulder could broaden the process window,and under a rotation speed...2A14-T62 butt joint was successfully welded by stationary shoulder friction stir welding(SSFSW)method.The results showed that using a pin with small shoulder could broaden the process window,and under a rotation speed of 2000 r/min and welding speed of 30 mm/min,joint with smooth surface,small reduction in thickness and little inner defects was obtained.The weld nugget zone was approx-imately circular,which was a unique morphology for SSFSW.The heat-affected zone(HAZ)and thermo-mechanically affected zone(TMAZ)were both quite narrow due to the lower heat input and slight mechanical action of the stationary shoulder.The fraction of high angle grain boundaries(HAGBs)exhibited a“W”shape along horizontal direction(from advancing side to retreating side),and the minim-um value located at HAZ.The average ultimate tensile strength and elongation of the joint were 325 MPa and 4.5%,respectively,with the joint efficiency of 68.3%.The joint was ductile fractured and the fracture surface contained two types of dimples morphology in different re-gions of the joint.Microhardness distribution in the joint exhibited a“W”shape,and the difference along the thickness direction was negli-gible.The joint had strong stress corrosion cracking susceptibility,and the slow stain rate tensile strength was 139 MPa.Microcrack and Al2O3 particulates were observed at the fracture surface.展开更多
Tackling the problems of underground water storage in collieries in arid regions requires knowledge of the effect of water intrusion and loading rate on the mechanical properties of and crack development in coal–rock...Tackling the problems of underground water storage in collieries in arid regions requires knowledge of the effect of water intrusion and loading rate on the mechanical properties of and crack development in coal–rock combinations. Fifty-four coal–rock combinations were prepared and split equally into groups containing different moisture contents(dry, natural moisture and saturated) to conduct acoustic emission testing under uniaxial compression with loading rates ranging from 0.1 mm/min to 0.6 mm/min. The results show that the peak stress and strength-softening modulus, elastic modulus, strain-softening modulus, and post-peak modulus partly decrease with increasing moisture content and loading rate. In contrast, peak strain increases with increasing moisture content and fluctuates with rising loading rate. More significantly, the relationship between stiffness and stress, combined with accumulated counts of acoustic emission, can be used to precisely predict all phases of crack propagation. This is helpful in studying the impact of moisture content and loading rate on crack propagation and accurately calculating mechanical properties. We also determined that the stress thresholds of crack closure, crack initiation, and crack damage do not vary with changes of moisture content and loading rate, constituting 15.22%, 32.20%, and 80.98% of peak stress, respectively. These outcomes assist in developing approaches to water storage in coal mines, determining the necessary width of waterproof coal–rock pillars, and methods of supporting water-enriched roadways, while also advances understanding the mechanical properties of coal–rock combinations and laws of crack propagation.展开更多
During the process of liquid forging, a host of hot cracking defects were found in the Al-CuMg-Zn aluminum alloy. Therefore, mechanical tests and analyses by optical microscope, scanning electron microscope, and X-ray...During the process of liquid forging, a host of hot cracking defects were found in the Al-CuMg-Zn aluminum alloy. Therefore, mechanical tests and analyses by optical microscope, scanning electron microscope, and X-ray diffraction were performed to research the influences of zinc, magnesium, and copper(three main alloying elements) on hot cracking tendency and mechanical properties. It was concluded that all the three alloying elements exerted different effects on the performances of newly designed alloys. And the impact of microstructures on properties of alloys was stronger than that of solution strengthening. Among new alloys, Al-5 Cu-4.5 Mg-2.5 Zn alloy shows better properties as follows: σb=327 MPa, δ=2.7%, HB=107 N/mm^2, and HCS=40.展开更多
While pre-deformation is often conducted before aging treatment to increase the strength and microhardness of 2195 Al-Li alloy, it often increases the fatigue crack growth(FCG) rate and thus reduces the fatigue life o...While pre-deformation is often conducted before aging treatment to increase the strength and microhardness of 2195 Al-Li alloy, it often increases the fatigue crack growth(FCG) rate and thus reduces the fatigue life of the alloy.To determine the effects and causes of pre-deformation and heat treatment on the mechanical properties and FCG rate of2195 Al-Li alloy, and to provide a suitable calculation model for the FCG rate under different pre-deformation conditions, 2195 Al-Li alloy specimens with different degrees of pre-rolling(0, 3%, 6%, and 9%) were investigated. The experimental results indicate that with the increase of pre-rolling, the density of the T1phase and the uniformity of the S′distribution and the microhardness, tensile strength, and yield strength of the alloy increase and at the same time the FCG rate increases, and thus the fatigue life is reduced. It was also found that the normalized stress intensity factor of elastic modulus(E) can be applied to correlate the FCG rate of pre-rolled 2195 Al-Li alloy with constant C and K parameters.展开更多
Two batches of commercial IN738LC alloy powders with different Zr contents were printed under the same parameters.The influences of Zr content(0.024 wt.% and 0.12 wt.%,respectively) in powders on crack density,distrib...Two batches of commercial IN738LC alloy powders with different Zr contents were printed under the same parameters.The influences of Zr content(0.024 wt.% and 0.12 wt.%,respectively) in powders on crack density,distribution,formation mechanism and mechanical properties of selective laser melting(SLM)-treated parts were systematically studied.It was found that the crack density(area ratio) increases from 0.15% to 0.87% in the XOY plane and from 0.21% to 1.81% in the XOZ plane along with the Zr content increase from 0.024 wt.% to 0.12 wt.% in the original powders.Solidification cracks are formed along the epitaxially grown <001>-oriented columnar grain boundaries in molten pool center.The ultimate tensile strength of Sample 1(0.024 wt.% Zr) is 1113 MPa,and there are dimples in tensile fracture.With an increase in the Zr content to 0.12 wt.%(Sample 2),the ultimate tensile strength of Sample 2 decreases to 610 MPa,and there are numerous original cracks and exposed columnar grain boundaries in tensile fracture.The optimization of printing parameters of Sample 2 considerably increases the ultimate tensile strength by 55.2% to 947 MPa,and the plasticity is greatly improved.展开更多
The extrudability,microstructural characteristics,and tensile properties of the Mg–5Bi–3Al(BA53)alloy are investigated herein by comparing them with those of a commercial Mg–8Al–0.5 Zn(AZ80)alloy.When AZ80 is extr...The extrudability,microstructural characteristics,and tensile properties of the Mg–5Bi–3Al(BA53)alloy are investigated herein by comparing them with those of a commercial Mg–8Al–0.5 Zn(AZ80)alloy.When AZ80 is extruded at 400℃,severe hot cracking occurs at exit speeds of 4.5 m/min or more.In contrast,BA53 is successfully extruded without any surface cracking at 400℃ and at high exit speeds of 21–40 m/min.When extruded at 3 m/min(AZ80–3)and 40 m/min(BA53–40),both AZ80 and BA53 exhibited completely recrystallized microstructures with a<10–10>basal texture.However,BA53–40 has a coarser grain structure owing to grain growth promoted by the high temperature in the deformation zone.AZ80–3 contains a continuous network of Mg_(17)Al_(12) particles along the grain boundaries,which form via static precipitation during natural air-cooling after the material exits the extrusion die.BA53–40 contains coarse Mg_(3)Bi_(2) particles aligned parallel to the extrusion direction along with numerous uniformly distributed fine Mg_(3)Bi_(2) particles.AZ80–3 has higher tensile strength than BA53–40 because the relatively finer grains and larger number of solute atoms in AZ80–3 result in stronger grain-boundary and solid-solution hardening effects,respectively.Although BA53 is extruded at a high temperature and extrusion speed of 400℃ and 40 m/min,respectively,the extruded material has a high tensile yield strength of 188 MPa.This can be primarily attributed to the large particle hardening effect resulting from the numerous fine Mg_(3)Bi_(2) particles.展开更多
Cracking in concrete occurs from volumetric instability, mechanical loading, and/or environmental attack. Compared to conventional vibrated concrete, self-consolidating concrete often has a higher susceptibility to cr...Cracking in concrete occurs from volumetric instability, mechanical loading, and/or environmental attack. Compared to conventional vibrated concrete, self-consolidating concrete often has a higher susceptibility to crack due to different mixture design, material properties and construction practices. To obtain a better understanding of self-consolidating concrete cracking behaviors for designing and constructing crack-controlled structural elements, reported current research and practices are reviewed and analyzed in this paper. It has been believed that when well designed and welt constructed, high quality self- consolidating concrete can be successfully used in various structures with cracks properly controlled.展开更多
Fine-grained magnesium was tested under stress-controlled tension-tension cyclic loading at -30 ℃ and the tested sample was observed using scanning electron microscope and electron backscatter diffraction to explore ...Fine-grained magnesium was tested under stress-controlled tension-tension cyclic loading at -30 ℃ and the tested sample was observed using scanning electron microscope and electron backscatter diffraction to explore the fatigue behavior and crack propagation. The fatigue data showed that the material experienced cyclic softening followed by cyclic hardening before the final fracture failure. The microscopic observations demonstrated that the cracks were almost perpendicular to the loading direction with some zigzags and the cracks progressed along both small angle grain boundaries and large angle grain boundaries. Although the cracks were mainly propagated along large angle grain boundaries, the value of grain boundary angle was not the primary factor to determine the crack propagation direction. The local residual strain from the rolling process was released due to the crack propagation and there was more strain relaxation at regions closer to the cracks.展开更多
The paper describes use of self-consistent finite element method (SCFEM) for predicting effective properties of fiber composite with partially debonded interface. The effective longitudinal Young's modulus and she...The paper describes use of self-consistent finite element method (SCFEM) for predicting effective properties of fiber composite with partially debonded interface. The effective longitudinal Young's modulus and shear modulus for unidirectional fiber reinforced composites with fiber-end cracks are calculated. Numerical results show that the effective properties are considerably influenced by the fiber-end cracks. The effects of microstructural parameters, such as fiber volume fraction, modulus ratio of the constituents and fiber aspect, on the effective properties of the composites were discussed.展开更多
基金We would like to acknowledge all the reviewers and editors and the sponsorship of National Natural Science Foundation of China(42030103)the Marine S&T Fund of Shandong Province for Pilot National Laboratory for Marine Science and Technology(Qingdao)(2021QNLM020001-6)the Laoshan National Laboratory of Science and Technology Foundation(LSKJ202203400).
文摘Seismic prediction of cracks is of great significance in many disciplines,for which the rock physics model is indispensable.However,up to now,multitudinous analytical models focus primarily on the cracked rock with the isotropic background,while the explicit model for the cracked rock with the anisotropic background is rarely investigated in spite of such case being often encountered in the earth.Hence,we first studied dependences of the crack opening displacement tensors on the crack dip angle in the coordinate systems formed by symmetry planes of the crack and the background anisotropy,respectively,by forty groups of numerical experiments.Based on the conclusion from the experiments,the analytical solution was derived for the effective elastic properties of the rock with the inclined penny-shaped cracks in the transversely isotropic background.Further,we comprehensively analyzed,according to the developed model,effects of the crack dip angle,background anisotropy,filling fluid and crack density on the effective elastic properties of the cracked rock.The analysis results indicate that the dip angle and background anisotropy can significantly either enhance or weaken the anisotropy degrees of the P-and SH-wave velocities,whereas they have relatively small effects on the SV-wave velocity anisotropy.Moreover,the filling fluid can increase the stiffness coefficients related to the compressional modulus by reducing crack compliance parameters,while its effects on shear coefficients depend on the crack dip angle.The increasing crack density reduces velocities of the dry rock,and decreasing rates of the velocities are affected by the crack dip angle.By comparing with exact numerical results and experimental data,it was demonstrated that the proposed model can achieve high-precision estimations of stiffness coefficients.Moreover,the assumption of the weakly anisotropic background results in the consistency between the proposed model and Hudson's published theory for the orthorhombic rock.
基金Funded by National Key R&D Program(No.2016YFC0701003)of Chinathe Fundamental Research Funds for the Central Universities
文摘In order to investigate the synergistic effect of re-dispersible powder-ethylene-vinyl acetate copolymer(EVA) and polypropylene fiber on the crack resistance of concrete under thermal fatigue loading, the compressive strength, ultimate tensile strength, ultimate tensile strain and tensile modulus of elasticity were tested. In addition, ultrasonic method and scanning electron microscope analysis were used to explain the microstructure mechanism. The results show that polypropylene fiberreinforced concrete presents a better performance on crack resistance than ordinary concrete, and the synergism of EVA and polypropylene fiber can improve the anti-cracking ability of concrete further.
基金Supported by National Natural Science Foundation of China (Grant No.52005154)Hebei Provincial Natural Science Foundation (Grant No.E2020202035)。
文摘To enrich material types applied to additive manufacturing and enlarge application scope of additive manufacturing in conformal cooling tools,M2 high-speed steel specimens were fabricated by selective laser melting(SLM).Effects of SLM parameters on the microstructure and mechanical properties of M2 high-speed steel were investigated.The results showed that substrate temperature and energy density had significant influence on the densification process of materials and defects control.Models to evaluate the effect of substrate temperature and energy density on hardness were studied.The optimized process parameters,laser power,scan speed,scan distance,and substrate temperature,for fabricated M2 are 220 W,960 mm/s,0.06 mm,and 200℃,respectively.Based on this,the hardness and tensile strength reached 60 HRC and 1000 MPa,respectively.Interlaminar crack formation and suppression mechanism and the relationship between temperature gradient and thermal stress were illustrated.The inhibition effect of substrate temperature on the cracks generated by residual stresses was also explained.AM showed great application potential in the field of special conformal cooling cutting tool preparation.
文摘An AZ31 HP magnesium alloy was laser beam welded in autogenous mode with AZ61 filler using Nd-YAG laser system.Microstructural examination revealed that the laser beam weld metals obtained with or without filler material had an average grain size of about 12 μm.The microhardness and the tensile strength of the weldments were similar to those of the parent alloy.However,the stress corrosion cracking (SCC) behaviour of both the weldments assessed by slow strain rate tensile (SSRT) tests in ASTM D1384 solution was found to be slightly inferior to that of the parent alloy.It was observed that the stress corrosion cracks originated in the weld metal and propagated through the weld metal-HAZ regions in the autogenous weldment.On the other hand,in the weldment obtained with AZ61 filler material,the crack initiation and propagation was in the HAZ region.The localized damage of the magnesium hydroxide/oxide film formed on the surface of the specimens due to the exposure to the corrosive environment during the SSRT tests was found to be responsible for the SCC.
基金supported by the 973 plan item under Grants(2003CB615802)
文摘A novel micro-micro/mesoporous aluminosilicate ZSM-5-Y/MCM-41 composite molecular sieve with a MCM-41 type structure was synthesized through a novel process of the self-assembly of CTAB surfactant micellae with silica-alumina source originated from alkaline treatment of ZSM-5 zeolite. The physical properties of the ZSM-5- Y/MCM-41 composite molecular sieve were characterized by XRD, Py-FTIR and N2 adsorption-desorption techniques. Different kinds of molecular sieves including ZSM-5, Y zeolite, AI-MCM-41, ZSM-5/MCM-41 and ZSM-5-Y/MCM- 41 as cracking catalysts were investigated, using 1,3,5-triisopropylbenzene (1,3,5-TIPB) as the probe molecule. Catalytic tests showed that the ZSM-5-Y/MCM-41 composite molecular sieve exhibited higher catalytic activity compared with the microporous ZSM-5 zeolite, Y zeolite, mesoporous A1-MCM-41 molecular sieve and ZSM-5/MCM-41 composite molecular sieve under the same conditions. The remarkable catalytic activity was mainly attributed to the presence of the hierarchical pore structure and proper acidity in the ZSM-5-Y/MCM-41 composite catalyst. Meanwhile, a carbcnium ion mechanism was put forward for the cracking of 1,3,5-TIPB.
基金funded by the National Natural Science(Grant No.52274015)。
文摘Sustained casing pressure(SCP)is a crucial issue in the oil and gas production lifecycle.Epoxy resins,exhibiting exceptional compressive strength,ductility,and shear bonding strength,have the potential to form reliable barriers.The injectivity and sealing capacity of the epoxy resin is crucial parameters for the success of shallow remediation operations.This study aimed to develop and assess a novel solid-free resin sealant as an alternative to Portland cement for mitigating fluid leakage.The investigation evaluated the viscosity,compressive strength,and brittleness index of the epoxy resin sealant,as well as its tangential and normal shear strengths in conjunction with casing steel.The flow characteristics and sealing abilities of conventional cement and epoxy resin were comparatively analyzed in cracks.The results showed that the application of a viscosity reducer facilitated control over the curing time of the epoxy resin,ranging from 1.5 to 6 h,and reduced the initial viscosity from 865.53 to 118.71 m Pa,s.The mechanical properties of the epoxy resin initially increased with a rise in curing agent content before experiencing a minor decrease.The epoxy resin containing 30%curing agent exhibited optimal mechanical properties.After a 14-day curing period,the epoxy resin's compressive strength reached81.37 MPa,2.12 times higher than that of cement,whereas the elastic modulus of cement was 2.99 times greater than that of the epoxy resin.The brittleness index of epoxy resin is only 3.42,demonstrating high flexibility and toughness.The tangential and normal shear strengths of the epoxy resin exceeded those of cement by 3.17 and 2.82 times,respectively.In a 0.5 mm-wide crack,the injection pressure of the epoxy resin remained below 0.075 MPa,indicating superior injection and flow capabilities.Conversely,the injection pressure of cement surged dramatically to 2.61 MPa within 5 min.The breakthrough pressure of0.5 PV epoxy resin reached 7.53 MPa,decreasing the crack's permeability to 0.02 D,a mere 9.49%of the permeability observed following cement plugging.Upon sealing a 2 mm-wide crack using epoxy resin,the maximum breakthrough pressure attained 5.47 MPa,3.48 times of cement.These results suggest that epoxy resin sealant can be employed safely and effectively to seal cracks in the cement.
基金financial support of the Slovenian Research Agency(ARRS)within Research Program P4-0015(Wood and Lignocellulosic Composites)Ministry of Education,Science,Culture,and Sports of the Una-Sana Canton,Co-Financing of Scientific Research and Research and Development Projects of Special Interest to the Una-Sana Canton(03-02-2190-647/2023)Assessment of the Structural Integrity of Cultural Buildings in Bosnia and Herzegovina(Una-Sana Canton)Using Non-Destructive Testing Methods.
文摘This study investigated the mechanical properties of beech(Fagus sylvatica L.)and fir(Abies alba)wood from Bosnia and Herzegovina under outdoor exposure.Samples were exposed for 3-month exposure to assess bending strength,color changes,and surface quality.Results showed outdoor exposure negatively affected mechanical properties,particularly in samples with extended finger joints,causing significant surface cracks in uncoated samples.Beech wood exhibited notable color changes under exposure,with approximately 50%darkening without coating compared to 25%under covered conditions.Coated samples displayed minimal color changes,affirming the efficacy of surface treatment.Fir wood exhibited a roughness of 8.264μm,while beechwood average roughness increased from 6.767 to 13.916μm after exposure,with micro-pore development affecting water performance.Microscopic analysis identified prevalent fungal colonies,including Penicillium,Aureobasidium,Sclerophoma,and Chaetomium,underscoring their role in organic matter decomposition.This study highlights the importance of wood exposure and treatment selection for various applications.
基金the Tianjin Key Laboratory of Fastening and Connection Technology Enterprises 2022—2023,China(No.TKLF2022-02-C-02)the technical support from the School of Materials Science and Engineering,Central South University,China.
文摘The effects of interrupted aging on mechanical properties and corrosion resistance of 7A75 aluminum alloy extruded bar were investigated through various analyses,including electrical conductivity,mechanical properties,local corrosion properties,and slow strain rate tensile stress corrosion tests.Microstructure characterization techniques such as metallographic microscopy,scanning electron microscopy(SEM),and transmission electron microscopy(TEM)were also employed.The results indicate that the tensile strength of the alloy produced by T6I6 aging is similar to that produced by T6I4 aging,and it even exceeds 700 MPa.Furthermore,the yield strength increases by 52.7 MPa,reaching 654.8 MPa after T6I6 aging treatment.The maximum depths of intergranular corrosion(IGC)and exfoliation corrosion(EXCO)decrease from 116.3 and 468.5μm to 89.5 and 324.3μm,respectively.The stress corrosion factor also decreases from 2.1%to 1.6%.These findings suggest that the alloy treated with T6I6 aging exhibits both high strength and excellent stress corrosion cracking resistance.Similarly,when the alloy is treated with T6I4,T6I6 and T6I7 aging,the sizes of grain boundary precipitates(GBPs)are found to be 5.2,18.4,and 32.8 nm,respectively.The sizes of matrix precipitates are 4.8,5.7 and 15.7 nm,respectively.The atomic fractions of Zn in GBPs are 9.92 at.%,8.23 at.%and 6.87 at.%,respectively,while the atomic fractions of Mg are 12.66 at.%,8.43 at.%and 7.00 at.%,respectively.Additionally,the atomic fractions of Cu are 1.83 at.%,2.47 at.%and 3.41 at.%,respectively.
基金supported by the Research and Development Project of“Jianbing”in Zhejiang Province(2024C01085)Natural Science and Foundation of Ningbo(2022J052).
文摘2A14-T62 butt joint was successfully welded by stationary shoulder friction stir welding(SSFSW)method.The results showed that using a pin with small shoulder could broaden the process window,and under a rotation speed of 2000 r/min and welding speed of 30 mm/min,joint with smooth surface,small reduction in thickness and little inner defects was obtained.The weld nugget zone was approx-imately circular,which was a unique morphology for SSFSW.The heat-affected zone(HAZ)and thermo-mechanically affected zone(TMAZ)were both quite narrow due to the lower heat input and slight mechanical action of the stationary shoulder.The fraction of high angle grain boundaries(HAGBs)exhibited a“W”shape along horizontal direction(from advancing side to retreating side),and the minim-um value located at HAZ.The average ultimate tensile strength and elongation of the joint were 325 MPa and 4.5%,respectively,with the joint efficiency of 68.3%.The joint was ductile fractured and the fracture surface contained two types of dimples morphology in different re-gions of the joint.Microhardness distribution in the joint exhibited a“W”shape,and the difference along the thickness direction was negli-gible.The joint had strong stress corrosion cracking susceptibility,and the slow stain rate tensile strength was 139 MPa.Microcrack and Al2O3 particulates were observed at the fracture surface.
基金Project(2014QNB31)supported by the Fundamental Research Funds for the Central Universities,ChinaProjects(51674248)supported by the National Natural Science Foundation of ChinaProject supported by the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD),China
文摘Tackling the problems of underground water storage in collieries in arid regions requires knowledge of the effect of water intrusion and loading rate on the mechanical properties of and crack development in coal–rock combinations. Fifty-four coal–rock combinations were prepared and split equally into groups containing different moisture contents(dry, natural moisture and saturated) to conduct acoustic emission testing under uniaxial compression with loading rates ranging from 0.1 mm/min to 0.6 mm/min. The results show that the peak stress and strength-softening modulus, elastic modulus, strain-softening modulus, and post-peak modulus partly decrease with increasing moisture content and loading rate. In contrast, peak strain increases with increasing moisture content and fluctuates with rising loading rate. More significantly, the relationship between stiffness and stress, combined with accumulated counts of acoustic emission, can be used to precisely predict all phases of crack propagation. This is helpful in studying the impact of moisture content and loading rate on crack propagation and accurately calculating mechanical properties. We also determined that the stress thresholds of crack closure, crack initiation, and crack damage do not vary with changes of moisture content and loading rate, constituting 15.22%, 32.20%, and 80.98% of peak stress, respectively. These outcomes assist in developing approaches to water storage in coal mines, determining the necessary width of waterproof coal–rock pillars, and methods of supporting water-enriched roadways, while also advances understanding the mechanical properties of coal–rock combinations and laws of crack propagation.
基金Funded by the International Cooperation Project of the Ministry of Science and Technology of China(No.2014DFR50320)the National Natural Science Foundation of China(No.51174064).
文摘During the process of liquid forging, a host of hot cracking defects were found in the Al-CuMg-Zn aluminum alloy. Therefore, mechanical tests and analyses by optical microscope, scanning electron microscope, and X-ray diffraction were performed to research the influences of zinc, magnesium, and copper(three main alloying elements) on hot cracking tendency and mechanical properties. It was concluded that all the three alloying elements exerted different effects on the performances of newly designed alloys. And the impact of microstructures on properties of alloys was stronger than that of solution strengthening. Among new alloys, Al-5 Cu-4.5 Mg-2.5 Zn alloy shows better properties as follows: σb=327 MPa, δ=2.7%, HB=107 N/mm^2, and HCS=40.
基金Project(U21A20132) supported by the National Natural Science Foundation of ChinaProject(Gui Renzi2019(13))supported by the Guangxi Specially-invited Experts Foundation of Guangxi Zhuang Autonomous Region,China。
文摘While pre-deformation is often conducted before aging treatment to increase the strength and microhardness of 2195 Al-Li alloy, it often increases the fatigue crack growth(FCG) rate and thus reduces the fatigue life of the alloy.To determine the effects and causes of pre-deformation and heat treatment on the mechanical properties and FCG rate of2195 Al-Li alloy, and to provide a suitable calculation model for the FCG rate under different pre-deformation conditions, 2195 Al-Li alloy specimens with different degrees of pre-rolling(0, 3%, 6%, and 9%) were investigated. The experimental results indicate that with the increase of pre-rolling, the density of the T1phase and the uniformity of the S′distribution and the microhardness, tensile strength, and yield strength of the alloy increase and at the same time the FCG rate increases, and thus the fatigue life is reduced. It was also found that the normalized stress intensity factor of elastic modulus(E) can be applied to correlate the FCG rate of pre-rolled 2195 Al-Li alloy with constant C and K parameters.
基金the financial supports from the Major Project of Science and Technology of Gansu Province,China(No.17ZD2GC011)the Hongliu First-class Discipline Construction Plan of Lanzhou University of Technology,China(No.CGZH001).
文摘Two batches of commercial IN738LC alloy powders with different Zr contents were printed under the same parameters.The influences of Zr content(0.024 wt.% and 0.12 wt.%,respectively) in powders on crack density,distribution,formation mechanism and mechanical properties of selective laser melting(SLM)-treated parts were systematically studied.It was found that the crack density(area ratio) increases from 0.15% to 0.87% in the XOY plane and from 0.21% to 1.81% in the XOZ plane along with the Zr content increase from 0.024 wt.% to 0.12 wt.% in the original powders.Solidification cracks are formed along the epitaxially grown <001>-oriented columnar grain boundaries in molten pool center.The ultimate tensile strength of Sample 1(0.024 wt.% Zr) is 1113 MPa,and there are dimples in tensile fracture.With an increase in the Zr content to 0.12 wt.%(Sample 2),the ultimate tensile strength of Sample 2 decreases to 610 MPa,and there are numerous original cracks and exposed columnar grain boundaries in tensile fracture.The optimization of printing parameters of Sample 2 considerably increases the ultimate tensile strength by 55.2% to 947 MPa,and the plasticity is greatly improved.
基金supported by the National Research Foundation of Korea(NRF)grant(No.2019R1A2C1085272)funded by the Ministry of Science,ICT,and Future Planning(MSIP,South Korea)by the Materials and Components Technology Development Program(No.20011091)funded by the Ministry of Trade,Industry,and Energy(MOTIE,South Korea)。
文摘The extrudability,microstructural characteristics,and tensile properties of the Mg–5Bi–3Al(BA53)alloy are investigated herein by comparing them with those of a commercial Mg–8Al–0.5 Zn(AZ80)alloy.When AZ80 is extruded at 400℃,severe hot cracking occurs at exit speeds of 4.5 m/min or more.In contrast,BA53 is successfully extruded without any surface cracking at 400℃ and at high exit speeds of 21–40 m/min.When extruded at 3 m/min(AZ80–3)and 40 m/min(BA53–40),both AZ80 and BA53 exhibited completely recrystallized microstructures with a<10–10>basal texture.However,BA53–40 has a coarser grain structure owing to grain growth promoted by the high temperature in the deformation zone.AZ80–3 contains a continuous network of Mg_(17)Al_(12) particles along the grain boundaries,which form via static precipitation during natural air-cooling after the material exits the extrusion die.BA53–40 contains coarse Mg_(3)Bi_(2) particles aligned parallel to the extrusion direction along with numerous uniformly distributed fine Mg_(3)Bi_(2) particles.AZ80–3 has higher tensile strength than BA53–40 because the relatively finer grains and larger number of solute atoms in AZ80–3 result in stronger grain-boundary and solid-solution hardening effects,respectively.Although BA53 is extruded at a high temperature and extrusion speed of 400℃ and 40 m/min,respectively,the extruded material has a high tensile yield strength of 188 MPa.This can be primarily attributed to the large particle hardening effect resulting from the numerous fine Mg_(3)Bi_(2) particles.
基金Funded by National Cooperative Highway Research Program(NCHRP) 18-16 in the US: Self-Consolidating Concrete for Cast-in-Place Bridge Components
文摘Cracking in concrete occurs from volumetric instability, mechanical loading, and/or environmental attack. Compared to conventional vibrated concrete, self-consolidating concrete often has a higher susceptibility to crack due to different mixture design, material properties and construction practices. To obtain a better understanding of self-consolidating concrete cracking behaviors for designing and constructing crack-controlled structural elements, reported current research and practices are reviewed and analyzed in this paper. It has been believed that when well designed and welt constructed, high quality self- consolidating concrete can be successfully used in various structures with cracks properly controlled.
基金the support from the Basic Energy Sciences Office at the US Department of Energy under Award no.DESC0016333。
文摘Fine-grained magnesium was tested under stress-controlled tension-tension cyclic loading at -30 ℃ and the tested sample was observed using scanning electron microscope and electron backscatter diffraction to explore the fatigue behavior and crack propagation. The fatigue data showed that the material experienced cyclic softening followed by cyclic hardening before the final fracture failure. The microscopic observations demonstrated that the cracks were almost perpendicular to the loading direction with some zigzags and the cracks progressed along both small angle grain boundaries and large angle grain boundaries. Although the cracks were mainly propagated along large angle grain boundaries, the value of grain boundary angle was not the primary factor to determine the crack propagation direction. The local residual strain from the rolling process was released due to the crack propagation and there was more strain relaxation at regions closer to the cracks.
基金The project supported by the National Natural Science Foundation of China
文摘The paper describes use of self-consistent finite element method (SCFEM) for predicting effective properties of fiber composite with partially debonded interface. The effective longitudinal Young's modulus and shear modulus for unidirectional fiber reinforced composites with fiber-end cracks are calculated. Numerical results show that the effective properties are considerably influenced by the fiber-end cracks. The effects of microstructural parameters, such as fiber volume fraction, modulus ratio of the constituents and fiber aspect, on the effective properties of the composites were discussed.