This study prepared four types of ionic liquid-modified polypyrrole(IL-modified PPy)as conductive additives and investigated their tribological performance and conductivity in polytetrafluoroethylene lubricating greas...This study prepared four types of ionic liquid-modified polypyrrole(IL-modified PPy)as conductive additives and investigated their tribological performance and conductivity in polytetrafluoroethylene lubricating grease.The results indicated that IL-modified PPy effectively enhanced the anti-wear performance and conductivity of the base grease.Among the additives,1-octyl-3-methylimidazolium tetrafluoroborate([OMIm][BF4])modified PPy showed superior performance compared to the other three additives,with the best effect observed at a mass fraction of 0.5%.X-ray photoelectron spectroscopy analysis revealed that IL-modified PPy forms a stable friction chemical film during the friction process,effectively enhancing the lubrication performance and conductivity of the base grease.This indicates broad potential applications in the field of conductive lubrication.展开更多
In this study, the properties of hip implant material and lubricants were examined using a pin on disc apparatus, to compare the effect of metal-on-metal (MoM) contact with a bio-lubricant derived from palm oil. The...In this study, the properties of hip implant material and lubricants were examined using a pin on disc apparatus, to compare the effect of metal-on-metal (MoM) contact with a bio-lubricant derived from palm oil. The behaviour of the lubricants was observed during the experiments, in which a hemispherical pin was loaded against a rotating disc with a groove. A titanium alloy was used to modify the hemispherical pin and disc. Before and after the experiments, the weight and surface roughness were analysed, to detect any degradation. The results were compared according to the different kinematic viscosities. The wear rates and level of friction with each lubricant were also examined. The lubricant with the highest vis- cosity had the lowest frictional value. Therefore, develop- ing suitable lubricants has the potential to prolong the lifespan of prostheses or implants used in biomedical applications. The experiments collectively show that lubricants derived from palm oil could be used as efficient bio-lubricants in the future.展开更多
The surface modified TiO_2 nanoparticles were prepared by using 12-hydroxystearic acid chemically modified on the TiO_2 surface. The average size of the TiO_2 particles is about 30 nm. The optimum ratio of tetrabutyl ...The surface modified TiO_2 nanoparticles were prepared by using 12-hydroxystearic acid chemically modified on the TiO_2 surface. The average size of the TiO_2 particles is about 30 nm. The optimum ratio of tetrabutyl titanate to 12-hydroxystearic acid was 1/0.5. The bonding form between 12-hydroxystearic acid and TiO_2 nucleus was investigated by FTIR, DSC, TGA and XRD techniques. The lubricating grease containing the surface modified TiO_2 nanoparticles possesses excellent anti-wear and anti-friction properties. Compared with the grease without TiO_2, the PB value can be increased by 52% as the best performance of the grease containing surface modified TiO_2 nanoparticles, while the friction coefficient can be reduced by 33% with the addition of a small amount of TiO_2 nanoparticles, and meanwhile the wear scar diameter decreases by 25%.展开更多
Considering electromagnetic effect when investigating tribological properties of rapeseed oil is benefical not only to the improvement of green lubrication, but also to the development of tribology theories and practi...Considering electromagnetic effect when investigating tribological properties of rapeseed oil is benefical not only to the improvement of green lubrication, but also to the development of tribology theories and practices. In the present paper, the tribological properties of rapeseed oil under different intensity of electromagnetic field and normal loads were evaluated on a modified tribo-tester. The results indicated that the electromagnetic field could improve the anti-wear and friction-reducing property of the rapeseed oil. Furthermore, the influencing mechanisms were discussed from the perspective of electromagnetism according to the analytical results of SEM, EDS and XPS techniques.展开更多
Metal matrix nanocomposites(MMNCs)become irreplaceable in tribology industries,due to their supreme mechanical properties and satisfactory tribological behavior.However,due to the dual complexity of MMNC systems and t...Metal matrix nanocomposites(MMNCs)become irreplaceable in tribology industries,due to their supreme mechanical properties and satisfactory tribological behavior.However,due to the dual complexity of MMNC systems and tribological process,the anti-friction and anti-wear mechanisms are unclear,and the subsequent tribological performance prediction and design of MMNCs are not easily possible:A critical up-to-date review is needed for MMNCs in tribology.This review systematically summarized the fabrication,manufacturing,and processing techniques for high-quality MMNC bulk and surface coating materials in tribology.Then,important factors determining the tribological performance(mainly anti-friction evaluation by the coefficient of friction(CoF)and anti-wear assessment with wear rate)in MMNCs have been investigated thoroughly,and the correlations have been analyzed to reveal their potential coupling/synergetic roles of tuning tribological behavior of MMNCs.Most importantly,this review combined the classical metal/alloy friction and wear theories and adapted them to give a(semi-)quantitative description of the detailed mechanisms of improved anti-friction and anti-wear performance in MMNCs.To guarantee the universal applications of these mechanisms,their links with the analyzed influencing factors(e.g.,loading forces)and characteristic features like tribo-film have been clarified.This approach forms a solid basis for understanding,predicting,and engineering MMNCs’tribological behavior,instead of pure phenomenology and experimental observation.Later,the pathway to achieve a broader application for MMNCs in tribo-related fields like smart materials,biomedical devices,energy storage,and electronics has been concisely discussed,with the focus on the potential development of modeling,experimental,and theoretical techniques in MMNCs’tribological processes.In general,this review tries to elucidate the complex tribo-performances of MMNCs in a fundamentally universal yet straightforward way,and the discussion and summary in this review for the tribological performance in MMNCs could become a useful supplementary to and an insightful guidance for the current MMNC tribology study,research,and engineering innovations.展开更多
The di-aromatics base oil and graphite powder,blended with the viscosity index improver,and the anti-oxidant and rheological additive,were used to prepare a kind of anti-seize thread lubricant.Its physical chemistry p...The di-aromatics base oil and graphite powder,blended with the viscosity index improver,and the anti-oxidant and rheological additive,were used to prepare a kind of anti-seize thread lubricant.Its physical chemistry properties,such as water resistance,thermal oxidation and aging properties,and tribological performance,were evaluated and compared with those of some commercial products.The results show that the overall performance of the anti-seize thread lubricant could meet the level of some commercial products,while its some properties such as thermal stability,anti-wear and anti-friction properties were better.The said anti-seize thread lubricant is more suitable for use under high temperature conditions.展开更多
Cutting tools are known as the“productivity”of the manufacturing industry,which affects the production efficiency and quality of the workpiece,and has become the focus of research and attention in academia and indus...Cutting tools are known as the“productivity”of the manufacturing industry,which affects the production efficiency and quality of the workpiece,and has become the focus of research and attention in academia and industry.However,traditional cutting tools often suffer from adhesion or wear during the cutting process,which considerably reduces the cutting efficiency and service life of the tools,and makes it difficult to meet current production requirements.To solve the above problems,scholars have introduced bionics into the tool’s design,applying the microscopic structure of the biological surface to the tool surface to alleviate the tool’s failure.This paper mainly summarizes the research progress of bionic textured cutting tools.Firstly,categorize whether the bionic texture design is inspired by a single organism or multiple organisms.Secondly,it is discussed that the non-smooth surface of the biological surface has five characteristics:hydrophilic lubricity,wear resistance,drag reduction and hydrophobicity,anti-adhesion,and arrangement,and the non-smooth structure of these different characteristics are applied to the surface of the tool is designed with bionic texture.Furtherly,the cutting performance of bionic textured cutting tools is discussed.The anti-friction and wear-resisting mechanism of bionic textured cutting tools is analyzed.Finally,some pending problems and perspectives have been proposed to provide new inspirations for the design of bionic textured cutting tools.展开更多
Ti6Al4V alloy manufactured by electron powder bed fusion(EPBF)was separately heat-treated by stress-relief annealing at 600℃,annealing at 800℃,and solid solution at 920℃ for 1 h.Then,the friction and wear tests wer...Ti6Al4V alloy manufactured by electron powder bed fusion(EPBF)was separately heat-treated by stress-relief annealing at 600℃,annealing at 800℃,and solid solution at 920℃ for 1 h.Then,the friction and wear tests were conducted on the samples before and after heat treatment to analyze the properties and mechanism of friction and wear behavior.Results show that the sample annealed at 600℃ for 1 h has the optimal wear resistance,and the wear mass loss reduces by 44%.The sample annealed at 800℃ for 1 h possesses the optimal anti-friction performance,and the coefficient of friction reduces by 14%.This research provides a simple heat treatment method to improve the friction and wear resistance of Ti6Al4V alloy manufactured by EPBF.展开更多
Two-dimensional materials having a layered structure comprise a monolayer or multilayers of atomic thickness and ultra-low shear strength.Their high specific surface area,in-plane strength,weak layer-layer interaction...Two-dimensional materials having a layered structure comprise a monolayer or multilayers of atomic thickness and ultra-low shear strength.Their high specific surface area,in-plane strength,weak layer-layer interaction,and surface chemical stability result in remarkably low friction and wear-resisting properties.Thus,2D materials have attracted considerable attention.In recent years,great advances have been made in the scientific research and industrial applications of anti-friction,anti-wear,and lubrication of 2D materials.In this article,the basic nanoscale friction mechanisms of 2D materials including interfacial friction and surface friction mechanisms are summarized.This paper also includes a review of reports on lubrication mechanisms based on the film-formation,self-healing,and ball bearing mechanisms and applications based on lubricant additives,nanoscale lubricating films,and space lubrication materials of 2D materials in detail.Finally,the challenges and potential applications of 2D materials in the field of lubrication were also presented.展开更多
Polyether-etherketone(PEEK)is a corrosion-resistant material that has been widely used in aqueous lubrication.However,its anti-wear performance must be improved for its application in the industry.In this study,to imp...Polyether-etherketone(PEEK)is a corrosion-resistant material that has been widely used in aqueous lubrication.However,its anti-wear performance must be improved for its application in the industry.In this study,to improve the anti-wear performance of PEEK for aqueous boundary lubrication,PEEK/MoS_(2)composites were prepared by ball-milling and spark plasma sintering processes.A competitive MoS_(2)mechanism between the low shear strength property and the role of promoting wear debris generation influences the anti-wear performance of PEEK/MoS_(2)composites.Experiments demonstrated that the coefficients of friction(COF)and wear rate of PEEK composite with 0.25 wt%MoS_(2)were significantly reduced 68%and 94%,respectively.Furthermore,this was the first time that a PEEK composite could achieve a COF of less than 0.05 in aqueous boundary lubrication.Its anti-wear performance was verified to be better than that of PEEK/carbon fiber(CF)and Thordon composites.The PEEK/MoS_(2)composite may be a potential material for underwater equipment because of its outstanding anti-wear performance in aqueous boundary lubrication.展开更多
Graphene-oxide (GO) has been recognized as an excellent lubrication material owing to its two-dimensional structure and weak interlayer interactions. However, the functional groups of GO that can contribute to anti-fr...Graphene-oxide (GO) has been recognized as an excellent lubrication material owing to its two-dimensional structure and weak interlayer interactions. However, the functional groups of GO that can contribute to anti-friction, anti-wear, and superlubricity are yet to be elucidated. Hence, further improvement in GO-family materials in tribology and superlubricity fields is impeded. In this study, macroscale superlubricity with a coefficient of friction of less than 0.01 is achieved by exploiting the high adhesive force between amino groups within aminated GO (GO–NH_(2)) nanosheets and SiO_(2). It was observed that GO–NH_(2) nanosheets form a robust adsorption layer on the worn surfaces owing to the high adsorption of amino groups. This robust GO–NH_(2) adsorption layer not only protects the contact surfaces and contributes to low wear, but also causes the shearing plane to transform constantly from solid asperities (high friction) into GO–NH_(2) interlayers (weak interlayer interactions), resulting in superlubricity. A SiO_(2)-containing boundary layer formed by tribochemical reactions and a liquid film are conducive to low friction. Such macroscale liquid superlubricity provides further insights into the effect of functional groups within functionalized GO materials and a basis for designing functionalized GO materials with excellent tribological performances.展开更多
基金The authors would like to appreciate the financial support extended for this academic work by the Beijing Natural Science Foundation(Grants 2172053,2232066)the Open Project Foundation of State Key Laboratory of Solid Lubrication(Grant LSL-2212).
文摘This study prepared four types of ionic liquid-modified polypyrrole(IL-modified PPy)as conductive additives and investigated their tribological performance and conductivity in polytetrafluoroethylene lubricating grease.The results indicated that IL-modified PPy effectively enhanced the anti-wear performance and conductivity of the base grease.Among the additives,1-octyl-3-methylimidazolium tetrafluoroborate([OMIm][BF4])modified PPy showed superior performance compared to the other three additives,with the best effect observed at a mass fraction of 0.5%.X-ray photoelectron spectroscopy analysis revealed that IL-modified PPy forms a stable friction chemical film during the friction process,effectively enhancing the lubrication performance and conductivity of the base grease.This indicates broad potential applications in the field of conductive lubrication.
基金support by the Research University Grant(RUG)from Universiti Teknologi Malaysia(Grant No.03H58)Fundamental Research Grant Scheme(FRGS)from Ministry of Higher Education(MOHE)Malaysia+2 种基金E-Science Fund Grant and Exploratory Research Grant Scheme(ERGS)from Ministry of Sciencethe awards of the UTM-RMC Postdoctoral Fellowship(Norzahir Sapawe)the Faculty of Mechanical Engineering Universiti Teknologi Malaysia
文摘In this study, the properties of hip implant material and lubricants were examined using a pin on disc apparatus, to compare the effect of metal-on-metal (MoM) contact with a bio-lubricant derived from palm oil. The behaviour of the lubricants was observed during the experiments, in which a hemispherical pin was loaded against a rotating disc with a groove. A titanium alloy was used to modify the hemispherical pin and disc. Before and after the experiments, the weight and surface roughness were analysed, to detect any degradation. The results were compared according to the different kinematic viscosities. The wear rates and level of friction with each lubricant were also examined. The lubricant with the highest vis- cosity had the lowest frictional value. Therefore, develop- ing suitable lubricants has the potential to prolong the lifespan of prostheses or implants used in biomedical applications. The experiments collectively show that lubricants derived from palm oil could be used as efficient bio-lubricants in the future.
文摘The surface modified TiO_2 nanoparticles were prepared by using 12-hydroxystearic acid chemically modified on the TiO_2 surface. The average size of the TiO_2 particles is about 30 nm. The optimum ratio of tetrabutyl titanate to 12-hydroxystearic acid was 1/0.5. The bonding form between 12-hydroxystearic acid and TiO_2 nucleus was investigated by FTIR, DSC, TGA and XRD techniques. The lubricating grease containing the surface modified TiO_2 nanoparticles possesses excellent anti-wear and anti-friction properties. Compared with the grease without TiO_2, the PB value can be increased by 52% as the best performance of the grease containing surface modified TiO_2 nanoparticles, while the friction coefficient can be reduced by 33% with the addition of a small amount of TiO_2 nanoparticles, and meanwhile the wear scar diameter decreases by 25%.
基金financially supported by the National Natural Science Foundation of China (Project No. 51375491)the Natural Science Foundation of Chongqing(Project No. CSTC, 2014JCYJAA50021)the Youth Fund of Logistical Engineering University (No. YQ16-420801)
文摘Considering electromagnetic effect when investigating tribological properties of rapeseed oil is benefical not only to the improvement of green lubrication, but also to the development of tribology theories and practices. In the present paper, the tribological properties of rapeseed oil under different intensity of electromagnetic field and normal loads were evaluated on a modified tribo-tester. The results indicated that the electromagnetic field could improve the anti-wear and friction-reducing property of the rapeseed oil. Furthermore, the influencing mechanisms were discussed from the perspective of electromagnetism according to the analytical results of SEM, EDS and XPS techniques.
基金This work is financially supported by the National Natural Science Foundation of China(Nos.51875343 and 12072191)the Key Fund Project of Equipment Pre-Research(No.61409230607)the State Key Laboratory of Mechanical System and Vibration Project(No.MSVZD202108).
文摘Metal matrix nanocomposites(MMNCs)become irreplaceable in tribology industries,due to their supreme mechanical properties and satisfactory tribological behavior.However,due to the dual complexity of MMNC systems and tribological process,the anti-friction and anti-wear mechanisms are unclear,and the subsequent tribological performance prediction and design of MMNCs are not easily possible:A critical up-to-date review is needed for MMNCs in tribology.This review systematically summarized the fabrication,manufacturing,and processing techniques for high-quality MMNC bulk and surface coating materials in tribology.Then,important factors determining the tribological performance(mainly anti-friction evaluation by the coefficient of friction(CoF)and anti-wear assessment with wear rate)in MMNCs have been investigated thoroughly,and the correlations have been analyzed to reveal their potential coupling/synergetic roles of tuning tribological behavior of MMNCs.Most importantly,this review combined the classical metal/alloy friction and wear theories and adapted them to give a(semi-)quantitative description of the detailed mechanisms of improved anti-friction and anti-wear performance in MMNCs.To guarantee the universal applications of these mechanisms,their links with the analyzed influencing factors(e.g.,loading forces)and characteristic features like tribo-film have been clarified.This approach forms a solid basis for understanding,predicting,and engineering MMNCs’tribological behavior,instead of pure phenomenology and experimental observation.Later,the pathway to achieve a broader application for MMNCs in tribo-related fields like smart materials,biomedical devices,energy storage,and electronics has been concisely discussed,with the focus on the potential development of modeling,experimental,and theoretical techniques in MMNCs’tribological processes.In general,this review tries to elucidate the complex tribo-performances of MMNCs in a fundamentally universal yet straightforward way,and the discussion and summary in this review for the tribological performance in MMNCs could become a useful supplementary to and an insightful guidance for the current MMNC tribology study,research,and engineering innovations.
基金The authors gratefully acknowledge the financial support from the National Science and Technology for Major Project of China(Project No.2019ZX06004002).
文摘The di-aromatics base oil and graphite powder,blended with the viscosity index improver,and the anti-oxidant and rheological additive,were used to prepare a kind of anti-seize thread lubricant.Its physical chemistry properties,such as water resistance,thermal oxidation and aging properties,and tribological performance,were evaluated and compared with those of some commercial products.The results show that the overall performance of the anti-seize thread lubricant could meet the level of some commercial products,while its some properties such as thermal stability,anti-wear and anti-friction properties were better.The said anti-seize thread lubricant is more suitable for use under high temperature conditions.
基金supported by National Natural Science Foundation of China(52175431)Natural Science Foundation of Tianjin of China(22JCZDJC00730).
文摘Cutting tools are known as the“productivity”of the manufacturing industry,which affects the production efficiency and quality of the workpiece,and has become the focus of research and attention in academia and industry.However,traditional cutting tools often suffer from adhesion or wear during the cutting process,which considerably reduces the cutting efficiency and service life of the tools,and makes it difficult to meet current production requirements.To solve the above problems,scholars have introduced bionics into the tool’s design,applying the microscopic structure of the biological surface to the tool surface to alleviate the tool’s failure.This paper mainly summarizes the research progress of bionic textured cutting tools.Firstly,categorize whether the bionic texture design is inspired by a single organism or multiple organisms.Secondly,it is discussed that the non-smooth surface of the biological surface has five characteristics:hydrophilic lubricity,wear resistance,drag reduction and hydrophobicity,anti-adhesion,and arrangement,and the non-smooth structure of these different characteristics are applied to the surface of the tool is designed with bionic texture.Furtherly,the cutting performance of bionic textured cutting tools is discussed.The anti-friction and wear-resisting mechanism of bionic textured cutting tools is analyzed.Finally,some pending problems and perspectives have been proposed to provide new inspirations for the design of bionic textured cutting tools.
基金National Natural Science Foundation of China(51975036)Guangdong Province Key R&D Project(2018B090904004)。
文摘Ti6Al4V alloy manufactured by electron powder bed fusion(EPBF)was separately heat-treated by stress-relief annealing at 600℃,annealing at 800℃,and solid solution at 920℃ for 1 h.Then,the friction and wear tests were conducted on the samples before and after heat treatment to analyze the properties and mechanism of friction and wear behavior.Results show that the sample annealed at 600℃ for 1 h has the optimal wear resistance,and the wear mass loss reduces by 44%.The sample annealed at 800℃ for 1 h possesses the optimal anti-friction performance,and the coefficient of friction reduces by 14%.This research provides a simple heat treatment method to improve the friction and wear resistance of Ti6Al4V alloy manufactured by EPBF.
基金supported by the National Natural Science Foundation of China(Grant No.51505442)Guangxi Natural Science Foundation(Grant No.2018GXNSFAA138174)
文摘Two-dimensional materials having a layered structure comprise a monolayer or multilayers of atomic thickness and ultra-low shear strength.Their high specific surface area,in-plane strength,weak layer-layer interaction,and surface chemical stability result in remarkably low friction and wear-resisting properties.Thus,2D materials have attracted considerable attention.In recent years,great advances have been made in the scientific research and industrial applications of anti-friction,anti-wear,and lubrication of 2D materials.In this article,the basic nanoscale friction mechanisms of 2D materials including interfacial friction and surface friction mechanisms are summarized.This paper also includes a review of reports on lubrication mechanisms based on the film-formation,self-healing,and ball bearing mechanisms and applications based on lubricant additives,nanoscale lubricating films,and space lubrication materials of 2D materials in detail.Finally,the challenges and potential applications of 2D materials in the field of lubrication were also presented.
基金This work was financially supported by the National Natural Science Foundation of China(Grant No.51425502).
文摘Polyether-etherketone(PEEK)is a corrosion-resistant material that has been widely used in aqueous lubrication.However,its anti-wear performance must be improved for its application in the industry.In this study,to improve the anti-wear performance of PEEK for aqueous boundary lubrication,PEEK/MoS_(2)composites were prepared by ball-milling and spark plasma sintering processes.A competitive MoS_(2)mechanism between the low shear strength property and the role of promoting wear debris generation influences the anti-wear performance of PEEK/MoS_(2)composites.Experiments demonstrated that the coefficients of friction(COF)and wear rate of PEEK composite with 0.25 wt%MoS_(2)were significantly reduced 68%and 94%,respectively.Furthermore,this was the first time that a PEEK composite could achieve a COF of less than 0.05 in aqueous boundary lubrication.Its anti-wear performance was verified to be better than that of PEEK/carbon fiber(CF)and Thordon composites.The PEEK/MoS_(2)composite may be a potential material for underwater equipment because of its outstanding anti-wear performance in aqueous boundary lubrication.
基金the National Key R&D Program of China(Nos.2020YFB2007300,2020YFA0711003)the Foundation from State Key Laboratory of Tribology(No.SKLTKF20B01)+1 种基金Beijing Institute of Technology Research Fund Program for Young Scholars,the Fund of Key Laboratory of Advanced Materials of Ministry of Education(No.ADV21-4)the National Natural Science Foundation of China(No.52005287).
文摘Graphene-oxide (GO) has been recognized as an excellent lubrication material owing to its two-dimensional structure and weak interlayer interactions. However, the functional groups of GO that can contribute to anti-friction, anti-wear, and superlubricity are yet to be elucidated. Hence, further improvement in GO-family materials in tribology and superlubricity fields is impeded. In this study, macroscale superlubricity with a coefficient of friction of less than 0.01 is achieved by exploiting the high adhesive force between amino groups within aminated GO (GO–NH_(2)) nanosheets and SiO_(2). It was observed that GO–NH_(2) nanosheets form a robust adsorption layer on the worn surfaces owing to the high adsorption of amino groups. This robust GO–NH_(2) adsorption layer not only protects the contact surfaces and contributes to low wear, but also causes the shearing plane to transform constantly from solid asperities (high friction) into GO–NH_(2) interlayers (weak interlayer interactions), resulting in superlubricity. A SiO_(2)-containing boundary layer formed by tribochemical reactions and a liquid film are conducive to low friction. Such macroscale liquid superlubricity provides further insights into the effect of functional groups within functionalized GO materials and a basis for designing functionalized GO materials with excellent tribological performances.