Non-point source water pollution generated by agricultural production is considered a major environmental issue in the Three Gorges Reservoir Area （TGRA） of China. The Annualised Agricultural Non-Point Source Pollut...Non-point source water pollution generated by agricultural production is considered a major environmental issue in the Three Gorges Reservoir Area （TGRA） of China. The Annualised Agricultural Non-Point Source Pollution （AnnAGNPS） model was selected to assess the impact of the application of various management treats, including seven crops, five fertilizer levels and three-group management practice scenarios, on water quality from Heigou River Watershed in TGRA. The scenario subsets include conservation tillage practice （CTP）, conservation reserve program （CRP） and conversion of cropland into forestland program （CCFP）. Results indicated that tea can not be replaced by other crops because comparatively tea resulted in a higher sediment yield. CTP with no-tillage was more effective to reduce sediment yield, but could increased nutrient loss. CRP reduced sediment yield significantly, but slightly benefited on nutrient loss. CCFP reduced not only sediment yield but also the nutrient loss significantly. The conversion of cropland with a slope greater than 10° into forestland was found to be the best scenario as the sediment yield export is less than 5 tons/ha and nutrient loss is within the permissible limit.展开更多
Highways in mountainous areas are easy to be damaged by such natural disasters as debris flows and landslides and disaster reduction decision support system (DRDSS) is one of the important means to mitigate these disa...Highways in mountainous areas are easy to be damaged by such natural disasters as debris flows and landslides and disaster reduction decision support system (DRDSS) is one of the important means to mitigate these disasters. Guided by the theories and technologies of debris flow and landslide reduction and supported by geographical information system (GIS), remote sensing and database techniques, a DRDSS against debris flow and landslide along highways in mountainous areas has been established on the basis of such principles as pertinence, systematicness, effectiveness, easy to use, open and expandability. The system consists of database, disaster analysis models and decisions on reduction of debris flows and landslides, mainly functioning to zone disaster dangerous degree, analyze debris flow activity, simulate debris flow deposition and diffusion, analyze landslide stability, select optimal highway renovation scheme and plan disaster prevention and control engineering. This system has been applied successfully to the debris flow and landslide treatment works along Palongzangbu Section of Sichuan-Tibet Highway.展开更多
The electrochemical reduction of CO2(CO2 RR) can substantially contribute to the production of useful chemicals and reduction of global CO2 emissions. Herein, we presented N and S dual-doped high-surface-area carbon m...The electrochemical reduction of CO2(CO2 RR) can substantially contribute to the production of useful chemicals and reduction of global CO2 emissions. Herein, we presented N and S dual-doped high-surface-area carbon materials(SZ-HCN) as CO2 RR catalysts. N and S were doped by one-step pyrolysis of a N-containing polymer and S powder. ZnCl2 was applied as a volatile porogen to prepare porous SZ-HCN. SZ-HCN with a high specific surface area(1510 m2 g–1) exhibited efficient electrocatalytic activity and selectivity for CO2 RR. Electrochemical measurements demonstrated that SZ-HCN showed excellent catalytic performance for CO2-to-CO reduction with a high CO Faradaic efficiency(~93%) at-0.6 V. Furthermore, SZ-HCN offered a stable current density and high CO selectivity over at least 20 h continuous operation, revealing remarkable electrocatalytic durability. The experimental results and density functional theory calculations indicated that N and S dual-doped carbon materials required lower Gibbs free energy to form the COOH* intermediate than that for single-N-doped carbon for CO2-to-CO reduction, thereby enhancing CO2 RR activity.展开更多
Sustainable Development Capacity (SDC) is a comprehensive concept. In order to obtain a relatively objective evaluation of it, many indices of various aspects are often used in assessing index systems. However, the ov...Sustainable Development Capacity (SDC) is a comprehensive concept. In order to obtain a relatively objective evaluation of it, many indices of various aspects are often used in assessing index systems. However, the overlapping information of indices is a frequent source deviating the result from the truth. In this paper, 48 indices are selected as original variables in assessing SDC of China's coastal areas. The mathematical method of dimension reducing treatment is used for eliminating the overlapping information in 48 variables. Five new comprehensive indices are extracted bearing efficient messages of original indices. On the base of new indices values, the sequencing of 12 coastal areas SDC is gained, and five patterns of sustainable development regions are sorted. Then, the leading factors and their relations of SDC in these patterns are analyzed. The gains of research are discussed in the end.展开更多
Since creation of spatial data is a costly and time consuming process, researchers, in this domain, in most of the cases rely on open source spatial attributes for their specific purpose. Likewise, the present researc...Since creation of spatial data is a costly and time consuming process, researchers, in this domain, in most of the cases rely on open source spatial attributes for their specific purpose. Likewise, the present research aims at mapping landslide susceptibility at the metropolitan area of Chittagong district of Bangladesh utilizing obtainable open source spatial data from various web portals. In this regard, we targeted a study region where rainfall induced landslides reportedly causes causalities as well as property damage each year. In this study, however, we employed multi-criteria evaluation (MCE) technique i.e., heuristic, a knowledge driven approach based on expert opinions from various discipline for landslide susceptibility mapping combining nine causative factors—geomorphology, geology, land use/land cover (LULC), slope, aspect, plan curvature, drainage distance, relative relief and vegetation in geographic information system (GIS) environment. The final susceptibility map was devised into five hazard classes viz., very low, low, moderate, high, and very high, representing 22 km2 (13%), 90 km2 (53%);24 km2 (15%);22 km2 (13%) and 10 km2 (6%) areas respectively. This particular study might be beneficial to the local authorities and other stake-holders, concerned in disaster risk reduction and mitigation activities. Moreover this study can also be advantageous for risk sensitive land use planning in the study area.展开更多
The effect of spatial pattern on the nutrient reduction is investigated based on the spatial simulation model developed for the study area of the Liaohe Delta, China. Four scenarios are designed to test the effect of ...The effect of spatial pattern on the nutrient reduction is investigated based on the spatial simulation model developed for the study area of the Liaohe Delta, China. Four scenarios are designed to test the effect of different landscape components on the nutrient reduction in the reed marsh: Canal density, reed area size, reed area shrinking pattern, and pumping station position. Based on a spatial model designed for the study area, the nutrient reduction in each case of these scenarios is simulated. The results indicate that each factor brings less than 10% change in the total nutrient reduction rate. More canals will not help much to improve nutrient reduction. Smaller areas are more efficient than larger ones. The shrinkage pattern is better than others in keeping a higher nutrient reduction rate. It is also more efficient to keep the pumping station near the border of the area to be irrigated. These conclusions provide theoretical supports to strategy makers for local land use planning, and contribute to the understanding of the relationship between landscape patterns and functions.展开更多
Colloidal synthesis of metal nanoclusters will inevitably lead to the blockage of catalytically active sites by organic ligands.Here,taking[Au_(25)(PET)_(18)]-(PET=2-phenylethanethiol)nanocluster as a model catalyst,t...Colloidal synthesis of metal nanoclusters will inevitably lead to the blockage of catalytically active sites by organic ligands.Here,taking[Au_(25)(PET)_(18)]-(PET=2-phenylethanethiol)nanocluster as a model catalyst,this work reports a feasible procedure to achieve the controllably partial removal of thiolate ligands from unsupported[Au_(25)(PET)_(18)]-nanoclusters with the preservation of the core structure.This procedure shortens the processing duration by rapid heating and cooling on the basis of traditional annealing treatment,avoiding the reconfiguration or agglomeration of Au_(25)nanoclusters,where the degree of dethiolation can be regulated by the control of duration.This work finds that a moderate degree of dethiolation can expose the Au active sites while maintaining the suppression of the competing hydrogen evolution reaction.Consequently,the activity and selectivity towards CO formation in electrochemical CO_(2)reduction reaction of Au_(25)nanoclusters can be promoted.This work provides a new approach for the removal of thiolate ligands from atomically precise gold nanoclusters.展开更多
History matching is a critical step in reservoir numerical simulation algorithms.It is typically hindered by difficulties associated with the high-dimensionality of the problem and the gradient calculation approach.He...History matching is a critical step in reservoir numerical simulation algorithms.It is typically hindered by difficulties associated with the high-dimensionality of the problem and the gradient calculation approach.Here,a multi-step solving method is proposed by which,first,a Fast marching method(FMM)is used to calculate the pressure propagation time and determine the single-well sensitive area.Second,a mathematical model for history matching is implemented using a Bayesian framework.Third,an effective decomposition strategy is adopted for parameter dimensionality reduction.Finally,a localization matrix is constructed based on the single-well sensitive area data to modify the gradient of the objective function.This method has been verified through a water drive conceptual example and a real field case.The results have shown that the proposed method can generate more accurate gradient information and predictions compared to the traditional analytical gradient methods and other gradient-free algorithms.展开更多
Groundwater over-exploitation is a major problem in groundwater development, utilization and protection. At present, the area of shallow groundwater over-exploitation in the High-tech Zone is 76 km^(2). In this study,...Groundwater over-exploitation is a major problem in groundwater development, utilization and protection. At present, the area of shallow groundwater over-exploitation in the High-tech Zone is 76 km^(2). In this study, the system and mechanism construction, engineering measure construction, and control effect of national comprehensive control project of groundwater over-exploitation areas in the High-tech Zone in 2020 were evaluated, and the comprehensive control of groundwater over-exploitation in the High-tech Zone in the year was summarized to provide effective basis for the continuous implementation of comprehensive control of groundwater over-exploitation. At the same time, the water-saving and exploitation reduction effect and generalizability of different measures were studied to provide useful reference for other over-exploitation areas.展开更多
The article presents a new approach to the tasks of noise assessment and reduction in the urbanized environment endangered by road noise sources. It was proposed to include the acoustic quality model in the currently ...The article presents a new approach to the tasks of noise assessment and reduction in the urbanized environment endangered by road noise sources. It was proposed to include the acoustic quality model in the currently applied quantitative noise assessment in the management of urbanized environment. In particular, this model takes into account subjective features of sound quality, i.e.： loudness, sharpness, roughness, and fluctuation strength as well as noise mmoya^ce assessment obtained in laboratory conditions. The proposed way can be used in estimating investment costs of an acoustic barrier at the design stage展开更多
基金supported by the 11th-Five Year Scientific Support Program of China (No.2006BAD03A13,2006BAD03A07)
文摘Non-point source water pollution generated by agricultural production is considered a major environmental issue in the Three Gorges Reservoir Area （TGRA） of China. The Annualised Agricultural Non-Point Source Pollution （AnnAGNPS） model was selected to assess the impact of the application of various management treats, including seven crops, five fertilizer levels and three-group management practice scenarios, on water quality from Heigou River Watershed in TGRA. The scenario subsets include conservation tillage practice （CTP）, conservation reserve program （CRP） and conversion of cropland into forestland program （CCFP）. Results indicated that tea can not be replaced by other crops because comparatively tea resulted in a higher sediment yield. CTP with no-tillage was more effective to reduce sediment yield, but could increased nutrient loss. CRP reduced sediment yield significantly, but slightly benefited on nutrient loss. CCFP reduced not only sediment yield but also the nutrient loss significantly. The conversion of cropland with a slope greater than 10° into forestland was found to be the best scenario as the sediment yield export is less than 5 tons/ha and nutrient loss is within the permissible limit.
基金Supported by the Knowledge Innovation Program of Chinese Academy of Sciences(KZCX2-306)the National Natural Science Foundation of China(90202007)
文摘Highways in mountainous areas are easy to be damaged by such natural disasters as debris flows and landslides and disaster reduction decision support system (DRDSS) is one of the important means to mitigate these disasters. Guided by the theories and technologies of debris flow and landslide reduction and supported by geographical information system (GIS), remote sensing and database techniques, a DRDSS against debris flow and landslide along highways in mountainous areas has been established on the basis of such principles as pertinence, systematicness, effectiveness, easy to use, open and expandability. The system consists of database, disaster analysis models and decisions on reduction of debris flows and landslides, mainly functioning to zone disaster dangerous degree, analyze debris flow activity, simulate debris flow deposition and diffusion, analyze landslide stability, select optimal highway renovation scheme and plan disaster prevention and control engineering. This system has been applied successfully to the debris flow and landslide treatment works along Palongzangbu Section of Sichuan-Tibet Highway.
文摘The electrochemical reduction of CO2(CO2 RR) can substantially contribute to the production of useful chemicals and reduction of global CO2 emissions. Herein, we presented N and S dual-doped high-surface-area carbon materials(SZ-HCN) as CO2 RR catalysts. N and S were doped by one-step pyrolysis of a N-containing polymer and S powder. ZnCl2 was applied as a volatile porogen to prepare porous SZ-HCN. SZ-HCN with a high specific surface area(1510 m2 g–1) exhibited efficient electrocatalytic activity and selectivity for CO2 RR. Electrochemical measurements demonstrated that SZ-HCN showed excellent catalytic performance for CO2-to-CO reduction with a high CO Faradaic efficiency(~93%) at-0.6 V. Furthermore, SZ-HCN offered a stable current density and high CO selectivity over at least 20 h continuous operation, revealing remarkable electrocatalytic durability. The experimental results and density functional theory calculations indicated that N and S dual-doped carbon materials required lower Gibbs free energy to form the COOH* intermediate than that for single-N-doped carbon for CO2-to-CO reduction, thereby enhancing CO2 RR activity.
基金Knowledge Innovation Project of Chinese Academy of Sciences (KZCX2-307-05) Knowledge Innovation Project of Institute of Geograp
文摘Sustainable Development Capacity (SDC) is a comprehensive concept. In order to obtain a relatively objective evaluation of it, many indices of various aspects are often used in assessing index systems. However, the overlapping information of indices is a frequent source deviating the result from the truth. In this paper, 48 indices are selected as original variables in assessing SDC of China's coastal areas. The mathematical method of dimension reducing treatment is used for eliminating the overlapping information in 48 variables. Five new comprehensive indices are extracted bearing efficient messages of original indices. On the base of new indices values, the sequencing of 12 coastal areas SDC is gained, and five patterns of sustainable development regions are sorted. Then, the leading factors and their relations of SDC in these patterns are analyzed. The gains of research are discussed in the end.
文摘Since creation of spatial data is a costly and time consuming process, researchers, in this domain, in most of the cases rely on open source spatial attributes for their specific purpose. Likewise, the present research aims at mapping landslide susceptibility at the metropolitan area of Chittagong district of Bangladesh utilizing obtainable open source spatial data from various web portals. In this regard, we targeted a study region where rainfall induced landslides reportedly causes causalities as well as property damage each year. In this study, however, we employed multi-criteria evaluation (MCE) technique i.e., heuristic, a knowledge driven approach based on expert opinions from various discipline for landslide susceptibility mapping combining nine causative factors—geomorphology, geology, land use/land cover (LULC), slope, aspect, plan curvature, drainage distance, relative relief and vegetation in geographic information system (GIS) environment. The final susceptibility map was devised into five hazard classes viz., very low, low, moderate, high, and very high, representing 22 km2 (13%), 90 km2 (53%);24 km2 (15%);22 km2 (13%) and 10 km2 (6%) areas respectively. This particular study might be beneficial to the local authorities and other stake-holders, concerned in disaster risk reduction and mitigation activities. Moreover this study can also be advantageous for risk sensitive land use planning in the study area.
基金National Natural Science Foundation of China, NSFC 49631040, 40001002 Wageningen Agricultural University, the Netherlands Co-s
文摘The effect of spatial pattern on the nutrient reduction is investigated based on the spatial simulation model developed for the study area of the Liaohe Delta, China. Four scenarios are designed to test the effect of different landscape components on the nutrient reduction in the reed marsh: Canal density, reed area size, reed area shrinking pattern, and pumping station position. Based on a spatial model designed for the study area, the nutrient reduction in each case of these scenarios is simulated. The results indicate that each factor brings less than 10% change in the total nutrient reduction rate. More canals will not help much to improve nutrient reduction. Smaller areas are more efficient than larger ones. The shrinkage pattern is better than others in keeping a higher nutrient reduction rate. It is also more efficient to keep the pumping station near the border of the area to be irrigated. These conclusions provide theoretical supports to strategy makers for local land use planning, and contribute to the understanding of the relationship between landscape patterns and functions.
基金the financial support of the Training Program of the Major Research Plan of the National Natural Science Foundation of China(92061124)the National Natural Science Foundation of China(21975292,21978331,22068008,and 52101186)+3 种基金the Guangdong Basic and Applied Basic Research Foundation(2021A1515010167 and 2022A1515011196)the Guangzhou Key R&D Program/Plan Unveiled Flagship Project(20220602JBGS02)the Guangzhou Basic and Applied Basic Research Project(202201011449)the Research Fund Program of Guangdong Provincial Key Laboratory of Fuel Cell Technology(FC202220 and FC202216)。
文摘Colloidal synthesis of metal nanoclusters will inevitably lead to the blockage of catalytically active sites by organic ligands.Here,taking[Au_(25)(PET)_(18)]-(PET=2-phenylethanethiol)nanocluster as a model catalyst,this work reports a feasible procedure to achieve the controllably partial removal of thiolate ligands from unsupported[Au_(25)(PET)_(18)]-nanoclusters with the preservation of the core structure.This procedure shortens the processing duration by rapid heating and cooling on the basis of traditional annealing treatment,avoiding the reconfiguration or agglomeration of Au_(25)nanoclusters,where the degree of dethiolation can be regulated by the control of duration.This work finds that a moderate degree of dethiolation can expose the Au active sites while maintaining the suppression of the competing hydrogen evolution reaction.Consequently,the activity and selectivity towards CO formation in electrochemical CO_(2)reduction reaction of Au_(25)nanoclusters can be promoted.This work provides a new approach for the removal of thiolate ligands from atomically precise gold nanoclusters.
基金This study was supported by National Natural Science Foundation of China(Nos.52104017,51874044,51922007)Southern Marine Science and Engineering Guangdong Laboratory(Zhanjiang)(No.zjw-2019-04).
文摘History matching is a critical step in reservoir numerical simulation algorithms.It is typically hindered by difficulties associated with the high-dimensionality of the problem and the gradient calculation approach.Here,a multi-step solving method is proposed by which,first,a Fast marching method(FMM)is used to calculate the pressure propagation time and determine the single-well sensitive area.Second,a mathematical model for history matching is implemented using a Bayesian framework.Third,an effective decomposition strategy is adopted for parameter dimensionality reduction.Finally,a localization matrix is constructed based on the single-well sensitive area data to modify the gradient of the objective function.This method has been verified through a water drive conceptual example and a real field case.The results have shown that the proposed method can generate more accurate gradient information and predictions compared to the traditional analytical gradient methods and other gradient-free algorithms.
文摘Groundwater over-exploitation is a major problem in groundwater development, utilization and protection. At present, the area of shallow groundwater over-exploitation in the High-tech Zone is 76 km^(2). In this study, the system and mechanism construction, engineering measure construction, and control effect of national comprehensive control project of groundwater over-exploitation areas in the High-tech Zone in 2020 were evaluated, and the comprehensive control of groundwater over-exploitation in the High-tech Zone in the year was summarized to provide effective basis for the continuous implementation of comprehensive control of groundwater over-exploitation. At the same time, the water-saving and exploitation reduction effect and generalizability of different measures were studied to provide useful reference for other over-exploitation areas.
文摘The article presents a new approach to the tasks of noise assessment and reduction in the urbanized environment endangered by road noise sources. It was proposed to include the acoustic quality model in the currently applied quantitative noise assessment in the management of urbanized environment. In particular, this model takes into account subjective features of sound quality, i.e.： loudness, sharpness, roughness, and fluctuation strength as well as noise mmoya^ce assessment obtained in laboratory conditions. The proposed way can be used in estimating investment costs of an acoustic barrier at the design stage
