Covalently Bonded Ni Sites in Black Phosphorene with Electron Redistribution for Efficient Metal‑Lightweighted Water Electrolysis

The metal-lightweighted electrocatalysts for water splitting are highly desired for sustainable and economic hydrogen energy deployments,but challengeable.In this work,a low-content Ni-functionalized approach triggers the high capability of black phosphorene(BP)with hydrogen and oxygen evolution reaction(HER/OER)bifunctionality.Through a facile in situ electro-exfoliation route,the ionized Ni sites are covalently functionalized in BP nanosheets with electron redistribution and controllable metal contents.It is found that the as-fabricated Ni-BP electrocatalysts can drive the water splitting with much enhanced HER and OER activities.In 1.0 M KOH electrolyte,the optimized 1.5 wt%Nifunctionalized BP nanosheets have readily achieved low overpotentials of 136 mV for HER and 230 mV for OER at 10 mA cm^(−2).Moreover,the covalently bonding between Ni and P has also strengthened the catalytic stability of the Ni-functionalized BP electrocatalyst,stably delivering the overall water splitting for 50 h at 20 mA cm^(−2).Theoretical calculations have revealed that Ni–P covalent binding can regulate the electronic structure and optimize the reaction energy barrier to improve the catalytic activity effectively.This work confirms that Ni-functionalized BP is a suitable candidate for electrocatalytic overall water splitting,and provides effective strategies for constructing metal-lightweighted economic electrocatalysts.

Interface and M^(3+)/M^(2+)Valence Dual-Engineering on Nickel Cobalt Sulfoselenide/Black Phosphorus Heterostructure for Efficient Water Splitting Electrocatalysis

The catalyst innovation that aims at noble-metal-free substitutes is one key aspect for future sustainable hydrogen energy deployment.In this paper,a nickel cobalt sulfoselenide/black phosphorus heterostructure(NiCoSe|S/BP)was fabricated to realize the highly active and durable water electrolysis through interface and valence dual-engineering.The NiCoSe|S/BP nanostructure was constructed by in-situ growing NiCo hydroxide nanosheet arrays on few-layer BP and subsequently one-step sulfoselenization by SeS2.Besides the conductive merit of BP substrate,holes in p-type BP are capable of oxidizing the Co^(2+)to high-valence and electron-accepting Co^(3+),benefiting the oxygen evolution reaction(OER).Meanwhile,Ni^(3+)/Ni^(2+)ratio in the heterostructure is reduced to maintain the electrical neutrality,which corresponds to the increased electron-donating character for boosting hydrogen evolution reaction(HER).As for HER and OER,the heterostructured NiCoSe|S/BP electrocatalyst exhibits small overpotentials of 172 and 285 mV at 10 mA cm^(-2)(η_(10))in alkaline media,respectively.And overall water splitting has been achieved at a low cell potential of 1.67 V at η_(10) with high stability.Molecular sensing and density functional theory(DFT)calculations are further proposed for understanding the rate-determine steps and enhanced catalytic mechanism.The investigation presents a deep-seated perception for the electrocatalytic performance enhancement of BP-based heterostructure.

Combined imbibition system with black nanosheet and low-salinity water for improving oil recovery in tight sandstone reservoirs

Nanomaterials and low-salinity water(LSW)are two popular enhanced oil recovery(EOR)methods that have been widely studied in recent years.The former is used for in-depth conformance improvement and the latter for microscopic oil displacement(by altering the potential and contact angle).However,there are few literature on combining them to achieve synergistic effects,especially for tight sandstone res-ervoirs.Based on the reservoir conditions of the Jimusar Oilfield,this study investigated the oil recovery mechanism of the combined imbibition system,which was composed of black nanosheet(BN)and LSW.Its performances including decreasing interfacial tension,emulsification,and wettability alterations were evaluated.The imbibition differences between the single system of BN and LSW and the combined BN-LsW imbibition system were then compared.Results showed that the combined imbibition system had a better emulsification effect on the crude oil and could also alter the wettability of the core surface.Moreover,the combined system could increase both the imbibition rate and the ultimate oil recovery.The nuclear magnetic T2 spectrum also indicated that the addition of black nanosheets could divert more fluid into small pores and thus improve the microscopic sweep efficiency.

Research Progress and Prospects for the Evolution Process and Treatment Technology of Urban Black and Smelly Water

Water is an important material resource for human survival,and with the increasing development of society,the amount of urban industrial wastewater and domestic sewage is gradually increasing.However,wastewater collection and treatment facilities lag behind,so that a large number of wastewater enters urban water,making urban water become gradually black and smelly.In order to provide a good living environment for human beings,a large number of scholars actively explore the treatment technology of black and smelly water.In this paper,the evolution process of black and smelly water was introduced firstly,and then the treatment technology of black and smelly water was summarized.Finally,the prospects for the development of the treatment technology were put forward.

Soil structure characters of different soil and water conservation plantations in typical black soil region

A study was conducted to determine the characters of soil structure in different water and soil conservation forests in Keshan County,northwest of Heilongjiang Province,China.The soil bulk density,the ratio of non-capillary porosity and capillary porosity（NCP/CP）,and the generalized soil structure index（GSSI） were measured for Fraxinus mandshurica,Larix gmelini,Pinus sylvestris var.mongolica,and Picea koraiensis plantations as well as the abandoned land（as control） adjacent to the forests in typical black soil region.Results show that at soil depth of 0–30cm,the soil bulk density of F.mandshurica forest and L.gmelini forest was lower than that of P.sylvestris var.mongolica forest and P.koraiensis forest,with the relative decrease of 8.04%–11.01%.The soil bulk density of L.gmelini forest was significantly different from that of the P.sylvestris var.mongolica forest and P.koraiensis forest.The NCP/CP values of the four types of plantations were all higher（59.75%–128.82% relatively） than that of abandoned land（p〈0.05）,indicating that the soil aeration and permeability under forest were enhanced,especially under L.gmelini forest.GSSI values of the four types of forests were also relatively higher（2.98%–4.36%） than abandoned land（p〈0.05）,indicating that those soil and water conservation forests,especially the F.mandshurica forest and P.koraiensis forest,can promote soil condition to approximate ideal soil structure.The result of this study can provide theoretical basis for scientifically evaluating the effects of vegetation restoration on soil quality in typical black soil region.

Study on Relative Soil and Water Conservation Benefits of Ridge Tillage in Different Terrain Conditions in the Black Soil Area of Northeast China

Ridge tillage, which is a very common and important tillage measure in the black soil area of northeast China, has some soil and water conservation bene- fits, but has little attention. It is very important to explore the spatial distribution of the ridge direction of the arable land and its soil and water conservation benefits in different terrain conditions in the black soil area. So Binxian County of Heilongjiang Province was selected as the study area, and 168 field investigation units were ex- tracted by stratified sampling method and investigated. According to equations of slope gradient factor and slope gradient in ridge direction, and based on the soft- ware of Arcmap, SPSS and Excel, the investigation data of soil and water loss in Binxian County were analyzed and counted, The results show that in plain, hilly and mountainous areas, the average ground slope gradients are 1.92°, 6.20° and 8.27° respectively, and the average slope gradients along ridge direction are 1.33°, 4.52°and 6.45° respectively, which account for about 70%, 73% and 78% of the average ground slope gradients in the same terrain condition; the relative quantities of soil erosion in the present ridge tillage condition account for about 55%, 69% and 67% respectively of that in down-slope ridge tillage conditions, so the present ridge tillage has obviously relative soil and water conservation benefits. Based on these results, the reasons of the present ridge tillage status were analyzed, and some reform measures were proposed. The results could not only help to comprehend the spatial distribution and soil and water conservation benefits of ridge tillage in the black soil area of Northeast China, but also provide scientific references for the layout of local soil and water conservation measures.

Effect of Temperature, pH and Salt on Fluorescent Quality of Water Extractable Organic Matter in Black Soil

Water erosion is the major reason for the loss of soil organic carbon in the Northeast China, which leads to the soil quality deterioration and adjacent water pollution. In this study, the effect of extraction temperature, pH value, and salt on the water extractable organic matter （WEOM） was determined by means of the UV absorbance, fluorescence excitation-emission matrix, and derived fluorescence indexes. In general, the carbon content and aromaticity of WEOM increased with the increasing of extraction temperature, with the exception that there was no significant difference in the amount at 0 and 20℃. More fluorophores, especially microbially-derived organic matter were extracted at high temperature. The pH values of extractant, including 5, 7, and 10, showed no effect on the carbon amount of WEOM, whereas the aromaticity and microbially-derived component gradually increased with the increasing of pH values. The fluorescence intensity of humic acid-like fluorophore was stronger in neutral and alkali condition than that in acidic condition. The addition of 10 mmol L-1 CaCl2 significantly decreased the carbon amount of recovered WEOM. Moreover, it significantly decreased the aromaticity of WEOM and the quantity of fulvic acid-like and humic acid-like fluorophores, whereas increased the percentage of tyrosine-like and tryptophan-like fluorophores in the total fluorophores and the amount of microbially-derived organic matter. Generally, 10 mmol L-1 KCl showed the same influence trend, but with low influence degree.

The black water around the Changjiang (Yangtze) Estuary in the spring of 2003

The Changjiang （Yangtze） Estuary is located in the East China Sea shelf with shallow water. Affected by the tide mixing and the runoff of the Changjiang River and the Qiantang River the turbidity is very high. Generally, the water-leaving radiance is high in the turbid water because of the large particle scattering. Based on the in-situ data and ocean color remote sensing data of SeaWiFS, it was found that there was a black water region with the normalized water-leaving radiances less than 0.5 mW/（cm2-μm2-sr）. The optical principle of the occurrence of this black water was analyzed by the inherent optical properties and the ocean color components. The results show that black water is caused by the relative low values of the suspended particle matter concentration and the back scattering ratio. In the black water region, the percentage of the phytoplankton absorption was relatively high, and the large size of the phytoplankton caused the low value of the particle backscattering ratio.

Effect of water and fertilizer coupling optimization test on water use efficiency of rice in black soil regions

How to improve the water use efficiency of rice in black soil regions was studied. The black soil region in paddy fields was chosen as the research object. The research showed the fertilizer coupling mathematical model with N,P,K,irrigation water( W) and water use efficiency( WUE),which was set up under the condition of controlled irrigation with quadratic D- 416 optimized saturation design. The results show that the decending order of single factor' s influence on the WUE was N,K,P and W. All the interactions between N&P,N&K,N&W,K&P,P&W and K&W on the WUE were raised initially,and when reached a certain value,they began to decline. The decending order of each interaction on the WUE was K&P,K&W,N&K,N&P,P&W and N&W. When the WUE was targeted within 1. 8- 2. 5 kg / km^3,an optimized proportion plan was obtained in the 95% confidence interval,i. e. N 87. 76- 103. 32 kg / hm^2,K_2 O 52. 37- 66. 53 kg / hm^2 and P_2O_536. 80- 46. 71 kg / hm^2. Furthermore,the late tillering of the soil moisture content was 70. 07%- 72. 57% of the saturated moisture content.

Influence of Water Content on Conductivity and Piezoresistivity of Cement-based Material with both Carbon Fiber and Carbon Black

The influence of water content on the conductivity and piezoresistivity of cement-based material with carbon fiber （CF） and carbon black （CB） was investigated. The piezoresistivity of cement-based material with both CF and CB was compared with that of cement-based material with CF only, and the changes in electrical resistivity of cement-based material with both CF and CB under static and loading conditions in different drying and soaking time were studied. It is found that the piezoresistivity of cement-based material with both CF and CB has better repeatability and linearity than that of cement-based material with CF only. The conductivity and the sensitivity of piezoresistive cement-based material with both CF and CB are enhanced as the water content in piezoresistive cement-based material increases.

Analysis of black water aggregation in Taihu Lake

Black water aggregation （BWA） in Taihu Lake is a disaster for the lake environment. It is a phenomenon resulting from water environmental deterioration and eutrophication caused by accumulation of pollutants in the lake, according to research on the water quality, pollutants of BWA, and occurrence mechanisms of BWA. Dead algae are the material base of BWA, the polluted sediment is an important factor for the formation of BWA, and hydrological and meteorological conditions such as sun light, air temperature, wind speed, and water flow are the other factors that may lead to the formation of BWA. Thioether substances such as dimethyl trisulfide are the representative pollutants of BWA. Parameters such as chlorophyll-a, DO, pH, and water temperature are sensitive indicators of BWA. Measures such as algae collection, ecological dredging, pollution control, and water diversion from the Yangtze River to the lake, are effective, and strengthening aeration is an emergency measure to control BWA.

Analysis of Formation and Mechanisms of Black and Smelly River Water in Island Cities

The causes of formation of black and smelly river water were summarized,including the entry of organic pollutants into rivers,such as domestic waste,three industrial wastes,thermal pollution caused by industrial hot drainage,pollution of the river bottom and resuspension movement,and so on. The existing modes and valence changes of iron,sulfur and other elements in black and smelly water were discussed. It is clear that the formation of the black and stink is mainly caused by blackening factors and stink-causing factors. It is concluded that the main blackening factors are ferrous sulfide,manganese sulphide,and the main stink-causing factors are hydrogen sulfide,ammonia or sulfides( VOSCs),josamidine and 2-dimethyl isobenol based on sulfur elements. It provides theoretical reference for the control of black and smelly river water in island cities.

Black phosphorus-based heterostructures for photocatalysis and photoelectrochemical water splitting

Semiconductor-based photocatalytic and photoelectrochemical(PEC) processes can convert solar energy into high-density chemical energy or for the treatment of environmental pollutants, which are ideal ways to deal with environmental and energy crises. The development of high-efficiency photocatalysts and photoelectrodes is the key to the in-depth development and practical application of the two technologies.Black phosphorus(BP) has excellent physicalcochemical properties such as adjustable band gap, high carrier mobility, large specific surface area and anisotropy, making it one of the most promising catalysts.BP-based heterostructure can not only realize the effective separation of photogenerated carriers but also improve the stability of BP, and is widely used in photocatalytic and PEC reactions. In this review, we first introduce the crystal structure, band structure, anisotropy, and preparation of BP with different dimensions(bulk, zero-dimension and two-dimension). Then, according to the transfer path of the photogenerated carriers and the components, the BP-based heterostructures are divided into type I heterojunction, type II heterojunction, Z-scheme heterojunction, S-scheme heterojunction, BP/carbonbased material heterostructure, BP/metal heterostructure and multi-component heterostructure.Highlighted are the diverse photocatalytic applications of BP-based heterostructure, such as water splitting and CO_(2)reduction, N_(2)fixation, pollutant degradation, photothermal and photodynamic therapy.Finally, some concluding views and opinions are stated on the challenges and opportunities faced by the further development of BP-based heterostructures in photocatalysis and PEC water splitting.

An Explanation of the Black Color of River Nyong Water’s and Associated Alluviums (Cameroon)

The River Nyong is situated in Akonolinga (central-south of Cameroon). In order to search for raw materials in ceramic use, samples of alluvium obtained from the deposits in the Nyong River clays have been studied. The results obtained show that, the samples contain important quantity of organic matter and the soil is acidic .These two parameters are necessary to understand the origin of the characteristic color of alluvium and water of the River Nyong.

Study on Dyeing Performance of Cationic Water-soluble Sulphur Black on Silk

A novel polyquaternaryammonium cationic sulphur black dye was synthesized and its dyeing behavior on silk was studied. The dye exhibited excellent dyeing fixation of up to 98.2 %, as well as excellent dyeing fastness on silk.

Pollution control of urban black-odor water bodies

On the basis of on-the-spot investigation, the causes of urban black-odor water bodies and the problems existing in the treatment are analyzed, and the control techniques and management countermeasures for black-odor water bodies were put forward. The countermeasures include: treating from both the roots and the symptoms and combining multiple technologies; comprehensively managing and improve the monitoring systems; coordinating functions and implementing long-term management; opening information and innovating supervision platform; coordinating advance and promoting the construction of sponge city; diversified financing to form the market-oriented model of water pollution control.

Paludification reduces black spruce growth rate but does not alter tree water use efficiency in Canadian boreal forested peatlands

Background:Black spruce(Picea mariana(Mill.)BSP)-forested peatlands are widespread ecosystems in boreal North America in which peat accumulation,known as the paludification process,has been shown to induce forest growth decline.The continuously evolving environmental conditions(e.g.,water table rise,increasing peat thickness)in paludified forests may require tree growth mechanism adjustments over time.In this study,we investigate tree ecophysiological mechanisms along a paludification gradient in a boreal forested peatland of eastern Canada by combining peat-based and tree-ring analyses.Carbon and oxygen stable isotopes in tree rings are used to document changes in carbon assimilation rates,stomatal conductance,and water use efficiency.In addition,paleohydrological analyses are performed to evaluate the dynamical ecophysiological adjustments of black spruce trees to site-specific water table variations.Results:Increasing peat accumulation considerably impacts forest growth,but no significant differences in tree water use efficiency(iWUE)are found between the study sites.Tree-ring isotopic analysis indicates no iWUE decrease over the last 100 years,but rather an important increase at each site up to the 1980 s,before iWUE stabilized.Surprisingly,inferred basal area increments do not reflect such trends.Therefore,iWUE variations do not reflect tree ecophysiological adjustments required by changes in growing conditions.Local water table variations induce no changes in ecophysiological mechanisms,but a synchronous shift in iWUE is observed at all sites in the mid-1980 s.Conclusions:Our study shows that paludification induces black spruce growth decline without altering tree water use efficiency in boreal forested peatlands.These findings highlight that failing to account for paludification-related carbon use and allocation could result in the overestimation of aboveground biomass production in paludified sites.Further research on carbon allocation strategies is of utmost importance to understand the carbon sink capacity of these widespread ecosystems in the context of climate change,and to make appropriate forest management decisions in the boreal biome.

Combustion and Sulfur-fixing Performance of Pulping Black Liquor Coal-water Slurry

The effects of adding pulping black liquor and other additives to coal-water slurry(CWS) on the sulfur-fixing performance of the resultant mixture(pulping black liquor coal-water slurry) were evaluated. The experimental results demonstrated that the ash content of the black liquor coalwater slurry decreased as the addition of pulping black liquor in the mixture increased. Nevertheless, the addition amount should be appropriately selected to ensure that the black liquor coal-water slurry had a moderate calorific value. Addition of black liquor improved the combustion performance of CWS by lowering the ignition point and stabilizing the combustion process; moreover, the sulfur-fixation ratio after combustion increased by 12 to 16 percentage points than that of CWS, and the content of high-melting-point salt in the ash from CWS after adding black liquor was low. The sulfur-fixing ratio of CWS after adding a sulfur-fixing agent was effectively increased by 25 to 30 percenatge points, but with compromise of the fluidity and stability of the CWS; thus, the addition amount of a sulfur-fixing agent should be optimized.

Black Water Fever in Severe Falciparum Malaria: A Case Report

Introduction: Black water fever (BWF) is a complication of severe Plasmodium falciparum infection in hemolysis of erythrocytes into the bloodstream releasing the hemoglobin directly into the blood vessels and causes severe anemia and passage of dark/cola color urine, leading to acute renal failure. Hemoglobinuria or BWF is a rare and severe manifestation of falciparum malaria characterized by sudden intravascular hemolysis followed by fever and presence of abnormal hemoglobin in the urine. Aim: The aim of this study was to diagnose and treat severe malaria infection in a Nigerian patient admitted to the Casualty of the IDH Hospital. Case Presentation: A 20-year-old Nigerian boy came to Kuwait and started complaining abdominal pain, nausea, vomiting and fever two days after his arrival. The investigation revealed high fever (40.8˚C), heart rate 125, blood pressure of 100/60 mmHg. The physical examination was unremarkable, including a normal neurologic examination, no hepatosplenomegaly, rash and neck rigidity. The Giemsa stained thick and thin blood examination confirmed the severe infection of Plasmodium falciparum with 41.0% parasitemia. The patient was admitted to the hospital and started intravenous Quinine (1200 mg loading dose in 5% glucose over 4 hours). The patient was feeling much better on next morning but became unconscious by evening and shifted to ICU. His all CBC parameters were higher and started passing dark/cola color urine. The 12 units of whole blood were exchanged on next morning and became fully conscious on 4th day and his anemia and thrombocytopenia were improved and the color of the urine also became normal. Conclusion: Quinine is used in both complicated and uncomplicated malaria and may cause black water fever in severe infection of P. falciparum. It is caused by the hemolysis of erythrocytes due to malaria and also with the metabolism of quinine, making these cells more vulnerable to hemolysis in falciparum malaria and also in G6PD deficiency.

Heavy Metals in Water and Bottom Sediments of Odessa Region of the Black Sea

The paper presents the results of a comprehensive monitoring of the polygon： ＂Odessa Region, north-western part of the Black Sea＂ for the period 2009-2011. It is shown that most of the copper and nickel is brought into the sea from the catchment area, and zinc and cadmium are mainly of the autochthonous origin. It is found that in 2010, after heavy rains, the area of bottom sediments contaminated by copper and nickel was increased. The main source of copper in the sea is vast vineyards.