High EMI shielding effectiveness and superhydrophobic properties based on step-wise asymmetric structure constructed by one-step method

It is of significance to prepare biodegradable electromagnetic interference(EMI)shielding materials with high EMI shielding effectiveness(SE)in order to solve electromagnetic and environmental pollution problems.In this paper,environmentally friendly EMI shielding silver nanowires(AgNWs)/poly(L-lactic acid)(PLLA)/poly(D-lactic acid)(PDLA)/ferroferric oxide(Fe_(3)O_(4))composites with step-wise asymmetric structures were prepared by a facile one-step non-solvent-induced phase separation method.The conductive AgNW network was constructed at a low mass fraction of 5 wt.%on the surface of stereo-complexed crystalline poly(lactic acid)(SC-PLA)film(1.08×10^(4) S/m).Moreover,magnetic Fe_(3)O_(4)is mainly distributed in the skeleton of porous SC-PLA film.Due to the synergistic effect of AgNWs and Fe_(3)O_(4),the EMI SE of SC-PLA films reaches up to 50.3 dB.Interestingly,SC-PLA film modified with triethoxy-1H,1H,2H,2H-tridecafluoro-n-octylsilane(TTO)demonstrates an outstanding water contact angle of about 150.2°compared with the pure PLLA film(134.7°),stemming from the synergistic effect of denser SC-PLA nano-protrusions and low-surface-energy TTO.Thus,we successfully fabricated the high EMI shielding SC-PLA film with wonderful superhydrophobicity,which extends the application performance and service life of portable electronics in moist environments.

SOME RELATIONS BETWEEN ASYMMETRIC STRUCTURE AND MOTION OF TYPHOONS

The analysis of the SPECTRUM (Special Experiment Concerning Typhoon Recurvature and Unusual Movement) data indicates that the structure of recurving target typhoons 9015 (Abe),9019 (Flo) and 9020 (Gene) at different stages of moving processes showed different motion features.On different time scales,temporal variations of typhoon structure and motion speed displayed different features.

DYNAMICS OF THE ZONAL ASYMMETRIC STRUCTURE OF ARCTIC OSCILLATION

The Arctic Oscillation (AO), though basically is a zonal symmetricphenomenon, also shows zonal asymmetric variation. The dynamics of this zonal variation isconsidered here from the point of view of the planetary propagation on the earth sphere. Based onthe linear barotropic vorticity e-quation, the planetary wave ray path is calculated in the winterJanuary. It shows that NAO( North Atlantic Oscillation), AO and North Pacific could be linkedthrough the planetary wave propagation, which acts as the atmospheric bridge. The zonal symmetricand asymmetric structures both have association with these Rossby wave activities.

Gap induced mode evolution under the asymmetric structure in a plasmonic resonator system

The modulation of resonance features in microcavities is important to applications in nanophotonics.Based on the asymmetric whispering-gallery modes(WGMs)in a plasmonic resonator,we theoretically studied the mode evolution in an asymmetric WGM plasmonic system.Exploiting the gap or nano-scatter in the plasmonic ring cavity,the symmetry of the system will be broken and the standing wave in the cavity will be tunable.Based on this asymmetric structure,the output coupling rate between the two cavity modes can also be tuned.Moreover,the proposed method could further be applied for sensing and detecting the position of defects in a WGM system.

The role of viscoelastic damping on retrofitting seismic performance of asymmetric reinforced concrete structures

The primary purpose of this research is to improve the seismic response of a complex asymmetric tall structure using viscoelastic(VE) dampers. Asymmetric structures have detrimental effects on the seismic performance because such structures create abrupt changes in the stiffness or strength that may lead to undesirable stress concentrations at weak locations. Structural control devices are one of the effective ways to reduce seismic impacts, particularly in asymmetric structures. For passive vibration control of structures, VE dampers are considered among the most preferred devices for energy dissipation. Therefore, in this research, VE dampers are implemented at strategic locations in a realistic case study structure to increase the level of distributed damping without occupying significant architectural space and reducing earthquake vibrations in terms of story displacements(drifts) and other design forces. It has been concluded that the seismic response of the considered structure retrofitted with supplemental VE dampers corresponded well in controlling the displacement demands. Moreover, it has been demonstrated that seismic response in terms of interstory drifts was effectively mitigated with supplemental damping when added up to a certain level. Exceeding the supplemental damping from this level did not contribute to additional mitigation of the seismic response of the considered structure. In addition, it was found that the supplemental damping increased the total acceleration of the considered structure at all floor levels, which indicates that for irregular tall structures of this type, VE dampers were only a good retrofitting measure for earthquake induced interstory deformations and their use may not be suitable for acceleration sensitive structures. Overall, the research findings demonstrate how seismic hazards to these types of structures can be reduced by introducing additional damping into the structure.

Stable single longitudinal mode erbium-doped silica fiber laser based on an asymmetric linear three-cavity structure

We present a stable linear-cavity single longitudinal mode （SLM） erbium-doped silica fiber laser. It consists of four fiber Bragg gratings （FBGs） directly written in a section of photosensitive erbium-doped fiber （EDF） to form an asymmetric three-cavity structure. The stable SLM operation at a wavelength of 1545.112 nm with a 3-dB bandwidth of 0.012 nm and an optical signal-to-noise ratio （OSNR） of about 60 dB is verified experimentally. Under laboratory conditions, the performance of a power fluctuation of less than 0.05 dB observed from the power meter for 6 h and a wavelength variation of less than 0.01 nm obtained from the optical spectrum analyzer （OSA） for about 1.5 h are demonstrated. The gain fiber length is no longer limited to only several centimeters for SLM operation because of the excellent mode-selecting ability of the asymmetric three-cavity structure. The proposed scheme provides a simple and cost-effective approach to realizing a stable SLM fiber laser.

Seismic Responses of Asymmetric Base-Isolated Structures under Near-Fault Ground Motion

An inter-story shear model of asymmetric base-isolated structures incorporating deformation of each isolation bearing was built, and a method to simultaneously simulate bi-directional near-fault and far-field ground motions was proposed. A comparative study on the dynamic responses of asymmetric base-isolated structures under near-fault and far-field ground motions were conducted to investigate the effects of eccentricity in the isolation system and in the superstructures, the ratio of the uncoupled torsional to lateral frequency of the superstructure and the pulse period of near-fault ground motions on the nonlinear seismic response of asymmetric base-isolated structures. Numerical results show that eccentricity in the isolation system makes asymmetric base-isolated structure more sensitive to near-fault ground motions, and the pulse period of near-fault ground motions plays an import role in governing the seismic responses of asymmetric base-isolated structures.

SYNTHESIS AND STRUCTURE OF AN ASYMMETRIC TRICOBALT COMPOUND Co_3(o-HOC_6H_4S)_2(o-OC_6H_4S)_2(PEt_3)_3

Compound Co_3(o-HOC_6H_4S)_2(o-OC_6H_4S)_2(PEt_3)_3 was obtained by reaction of CoCl_2, o-HOC_6H_4SH(H_2mD)and PEt_3 in ethanol in the presence of NaOCH_3.The three Co atoms are triangularly arranged and asymmetrically bridged by four S and one O atoms from the four H_2mp ligands and terminally ligated by one O and three P atoms.Two free hydroxyl groups form two internal hydrogen bonds with adjacent oxo donor atoms.

Recent Progress on Asymmetric Carbon- and Silica-Based Nanomaterials: From Synthetic Strategies to Their Applications

Carbon-and silica-based nanomaterials possess a set of merits including large surface area,good structural stability,diversified morphology,adjustable structure,and biocompatibility.These outstanding features make them widely applied in different fields.However,limited by the surface free energy effect,the current studies mainly focus on the symmetric structures,such as nanospheres,nanoflowers,nanowires,nanosheets,and core-shell structured composites.By comparison,the asymmetric structure with ingenious adjustability not only exhibits a larger effective surface area accompanied with more active sites,but also enables each component to work independently or corporately to harness their own merits,thus showing the unusual performances in some specific applications.The current review mainly focuses on the recent progress of design principles and synthesis methods of asymmetric carbon-and silica-based nanomaterials,and their applications in energy storage,catalysis,and biomedicine.Particularly,we provide some deep insights into their unique advantages in related fields from the perspective of materials’structure-performance relationship.Furthermore,the challenges and development prospects on the synthesis and applications of asymmetric carbon-and silica-based nanomaterials are also presented and highlighted.

Torsionally coupled dynamic performance analysis of asymmetric offshore platforms subjected to wave and earthquake loadings

The dynamic equations of motion of asymmetric offshore platforms under three different environmental conditions:seismic action,wave action and their combination are established in this paper. In establishing these motion equations,three typical eccentricity types including mass eccentricity,rigidity eccentricity and their combination were considered,as are eccentricities that occur un-idirectionally and bi-directionally. The effects of the eccentricity type,the dynamic characteristics and the environmental conditions on the torsional coupling response of platforms are investigated and compared. An effort has also been made to analyze the inffluence of accidental eccentricity on asymmetric platforms with different eccentricity in two horizontally orthogonal directions. The results are given in terms of non-dimensional parameters,accounting for the uncoupled torsional to lateral frequency ratio. Numerical results reveal that the eccentricity type has a great inffluence on the torsionally coupled response under different environmental conditions. Therefore,it is necessary to consider the combination of earthquake and wave action in the seismic response analysis of some offshore platforms.

The Analysis of the Asymmetric Precipitation Caused by the No.10 Tropical Cyclone “Damrey” in 2012 Based on Observation and Numerical Simulation

The No.10 tropical cyclone “Damrey” in 2012 is the first landing typhoon on the north of the Yangtze River after 1949. After its landing, Damrey showed an obvious asymmetric structure and precipitation. Using the ERA-interim reanalysis data from the European Centre for Medium-Range Weather Forecasting (ECMWF), the study simulated the whole process of Damrey from pre-landing to extinct by using WRF model. Based on the model result and FY-2E satellite data and observation data, the study analysis the causes of the asymmetric structure of Damrey. It is found that the descending motion is strong on the west and south sides of the typhoon, they blocked the southwest water vapor transport. So the development of convective cloud system was hindered, and the wind shear on the west and south sides on the typhoon was stronger than on the east and north. It caused the result of the precipitation on the east and north sides of typhoon much more than on the west and south. Q-vector, upper level jets and other factors are also analyzed in this study.

Enhancing performance of GaN-based LDs by using GaN/InGaN asymmetric lower waveguide layers

The effects of Ga N/In Ga N asymmetric lower waveguide(LWG)layers on photoelectrical properties of In Ga N multiple quantum well laser diodes(LDs)with an emission wavelength of around 416 nm are theoretically investigated by tuning the thickness and the indium content of In Ga N insertion layer(In Ga N-IL)between the Ga N lower waveguide layer and the quantum wells,which is achieved with the Crosslight Device Simulation Software(PIC3D,Crosslight Software Inc.).The optimal thickness and the indium content of the In Ga N-IL in lower waveguide layers are found to be 300 nm and 4%,respectively.The thickness of In Ga N-IL predominantly affects the output power and the optical field distribution in comparison with the indium content,and the highest output power is achieved to be 1.25 times that of the reference structure(symmetric Ga N waveguide),which is attributed to the reduced optical absorption loss as well as the concentrated optical field nearby quantum wells.Furthermore,when the thickness and indium content of In Ga N-IL both reach a higher level,the performance of asymmetric quantum wells LDs will be weakened rapidly due to the obvious decrease of optical confinement factor(OCF)related to the concentrated optical field in the lower waveguide.

Synthesis,Crystal Structure and Heterogeneous Catalysis of a New Chiral Manganese Coordination Polymer Based on the Schiff-base Ligand

A homochrial manganese（Ⅲ） complex（1） derived from chiral salen ligand（1 R,2 R）-（-）-1,2-diphenylethane-1,2-diamine-N,N？-bicarboxyl-salicylidene） has been synthesized through solvothermal procedure and characterized by IR,elemental analysis,TGA,circular dichroism（CD）,powder and single-crystal X-ray crystallography.It crystallizes in orthorhombic,space group P212121 with a = 9.108（3）,b = 16.431（5）,c = 26.531（6） A,V = 3970.4（19） A^3,Z = 4,Dc = 1.248 g/cm^3,F（000） = 1568,Mr = 745.73,μ = 0.383 mm^-1,the final GOOF = 0.957,R = 0.0631 and wR = 0.1079 for 13250 observed reflections with I 〉 2σ（I）.The coordination polymer 1 possesses a 1 D infinite zigzag chain architecture constructed by the dicarboxyl-functionalized metallosalen ligand（Mn-salen）,and the polymeric chains are further assembled into a 3D supramolecular network structure via strong intermolecular hydrogen bonding interactions between adjacent zigzag chains.As a heterogeneous catalyst,1 was used as an efficient heterogeneous catalyst for the asymmetric olefin epoxidation.

Recent Advances in Asymmetric Structural Composites for Excellent Electromagnetic Interference Shielding:A Review

Since electromagnetic pollution is detrimental to human health and the environment,numerous efforts have been successively made to achieve excellent electromagnetic interference shielding effectiveness(EMI SE)via designing the hierarchical structures for electromagnetic interference(EMI)shielding polymer composites.Among the plentiful structures,the asymmetric structures are currently a hot spot,principally categorizing into multi-layered,porous,fibrous,and segregated asymmetric structures,which endows the high EMI shielding performance for polymer composites incorporated with magnetic,conductive,and/or dielectric micro/nano-fillers,due to the“absorption-reflection-reabsorption”shielding mechanism.Therefore,this review provides the retrospection and summary of the efforts with respect to abundant asymmetric structures and multifunctional micro/nano-fillers for enhancing EMI shielding properties,which is conducive to the booming development of polymeric EMI shielding materials for the promising prospect in modern electronics and 5-generation(5G)technology.

Gradient-structure-enhanced dielectric energy storage performance of flexible nanocomposites containing controlled preparation of defective TiO_(2) and ferroelectric KNbO_(3) nanosheets

Next generation power system needs dielectrics with increased dielectric energy density.However,the low energy density of dielectrics limits their development.Here,an asymmetric trilayered nanocomposite,with a transition layer(TL),an insulation layer(IL),and a polarization layer(PL),is designed based on poly(vinylidene fluoride)-polymethyl methacrylate(PVDF-PMMA)matrix using KNbO_(3)(KN)and TiO_(2)(TO)as the nanofillers.The morphology and defect control of the two-dimensional nano KN and nano TO fillers are realized via a hydrothermal method to increase the composite breakdown strength(E_(b))and the composite energy density(U_(e)).The asymmetric trilayered structure leads to a gradient electric field distribution,and the KN and TO nanosheets block charges transfer along z direction.As a result,the development path of the electrical trees is greatly curved,and E_(b) is effectively improved.And the Ue value of the nanocomposites reaches 17.79 J·cm^(-3) at 523 MV·m^(-1).On the basis,the composite Ue is further improved by defect control in TO nanosheets.The nanocomposite KN/TO/PVDF-PMMA containing TO with less oxygen vacancy concentration(calcined at oxygen atmosphere)acquires a high Ue of 21.61 J·cm^(-3) at 548 MV·m^(-1).This study provides an idea for improving the energy storage performance by combining the design of the composite dielectric structure and the control of nanofillers’defect and morphology.

Asymmetric reversible structural switching of a diene coordination polymer promoted by UV-visible light

In natural and artificial systems,reversible reactions are commonly asymmetric with respect to the time scale and nature of the stimuli which drive the forward and backward processes.In applications for which switching behavior is required,it is desirable that the reversible reaction goes as close to symmetric as possible;however,such systems are uncommon.Herein,we report an example of ultraviolet(UV)-visible light-regulated asymmetric reversible structural switching involving a diene-based coordination polymer,CP1 and its monocyclobutane product,CP1a.It is possible to cycle at least ten times through a forward [2+2] photocycloaddition reaction and the reverse,photocleavage reaction.A single cycle can be completed within a few minutes.The transformation is accompanied by fast and distinct fluorescence changes,arising from optimisation of the reaction conditions.Density functional theory calculations allow rationalisation of the asymmetric reversible transformation between CP1 and CP1a rather than between CP1 and its dicyclobutane product CP1b.This work provides a clear illustration of reversible structural switching which approaches symmetric behaviour with respect to reaction rate and stimuli.The insights gained from this work also assist in the design of fast,reversible switching materials.

The Role of β-effect and a Uniform Current on Tropical Cyclone Intensity

A limited-area primitive equation model is used to study the role of the β-effect and a uniform current on tropical cyclone (TC) intensity. It is found that TC intensity is reduced in a non-quiescent environment compared with the case of no uniform current. On an f-plane, the rate of intensification of a tropical cyclone is larger than that of the uniform flow. A TC on a β-plane intensifies slower than one on an f-plane. The main physical characteristic that distinguishes the experiments is the asymmetric thermodynamic (including convective) and dynamic structures present when either a uniform flow or β-effect is introduced. But a fairly symmetric TC structure is simulated on an f-plane. The magnitude of the warm core and the associated subsidence are found to be responsible for such simulated intensity changes. On an f-plane, the convection tends to be symmetric, which results in strong upper-level convergence near the center and hence strong forced subsidence and a very warm core. On the other hand, horizontal advection of temperature cancels part of the adiabatic heating and results in less warming of the core, and hence the TC is not as intense. This advective process is due to the tilt of the vortex as a result of the β-effect. A similar situation occurs in the presence of a uniform flow. Thus, the asymmetric horizontal advection of temperature plays an important role in the temperature distribution. Dynamically, the asymmetric angular momentum (AM) flux is very small on an f-plane throughout the troposphere. However, the total AM exports at the upper levels for a TC either on a β-plane or with a uniform flow environment are larger because of an increase of the asymmetric as well as symmetric AM export on the plane at radii >450 km, and hence there is a lesser intensification.

Enhancement effect of asymmetry on the thermal conductivity of double-stranded chain systems

Using nonequilibrium molecular dynamics simulations, we study the thermal conductivity of asymmetric double chains. We couple two different single chains through interchain coupling to build three kinds of asymmetric double- stranded chain system： intrachain interaction, external potential, and mass asymmetric double chains. It is reported that asymmetry is helpful in improving the thermal conductivity of the system. We first propose double-heat flux channels to explain the influence of asymmetric structures on the thermal conductivity. The phonon spectral behaviour and finite size effect are also included.

Analysis of the Rainstorm Falling Zone in Guangxi during Influence Period of the 0906 Typhoon "Molave"

[ Objective] The research aimed to analyze rainstorm falling zone in Guangxi during influence period of the 0906 typhoon ＂ Molave＂. [ Method] For the heavy precipitation falling zone in southern and central parts of Guangxi after 0906 typhoon ＂ Molave＂ landed, 500 hPa circula- tion, physical quantity field, satellite cloud chart and terrain effect were analyzed. [ Result] 500 hPa subtropical high caused asymmetry of the ＂Me- lave＂ circulation, playing a key role for the strong precipitation falling zone in Guangxi. Physical quantity field analysis pointed out that after ＂ Me- lave＂ landed, water vapor convergence center was in southeast Guangxi, providing adequate moisture condition for the heavy precipitation in south- ern and central parts of Guangxi. The maximum positive vorticity center appeared at the middle and low layers in southern and central parts of Guangxi for a long time. At 200 hPa, there was a maximum divergence center. At 700 hPa, there was a maximum convergence center. High-level divergence and low-level convergence created conditions for heavy precipitation in the region. From satellite cloud chart, the heavy precipitation fall- ing zone related to asymmetric structure of the ~ Molave＂. In addition, uplifting effect of the terrain was conducive to occurrence of the large precipi- tation. [ Conclusion] The research provided reference for reduction and prevention of this kind of heavy precipitation.

Vibration and Noise Optimization of New Asymmetric Modular PMaSynRM

An optimized structure to weaken the vibration and noise of a new asymmetric permanent magnet-assisted synchronous reluctance motor(PMaSynRM)is proposed.The new asymmetric PMaSynRM has the advantages of a low torque ripple and high fault tolerance.However,the asymmetric structure generates an unbalanced magnetic force(UMF),which results in vibration and noise problems.In this study,the vibration and noise of the motor are analyzed and optimized.First,the radial pressure is analyzed,and an optimized structure is proposed.The electromagnetic performance of the motor before and after optimization is analyzed using the finite element method.Second,a three-dimensional model is established,and modal analysis is conducted considering the orthotropy of the stator and effective windings.Finally,the vibration and noise are simulated and analyzed,and the validity of the analysis results is verified experimentally.The analysis results indicate that the optimized motor realizes a reduction in the motor vibration and noise.