Asymmetric resistive switching processes were observed in W：AlOx/WOy bilayer RRAM devices. During pulse programming measurements, the RESET speed is in the range of hundreds of microseconds under - 1.1 V bias, while ...Asymmetric resistive switching processes were observed in W：AlOx/WOy bilayer RRAM devices. During pulse programming measurements, the RESET speed is in the range of hundreds of microseconds under - 1.1 V bias, while the SET speed is in the range of tens of nanoseconds under 1.2 V bias. Electrical measurements with different pulse conditions and different temperatures were carded out to understand these significant differences in switching time. A redox reaction model in the W：AlOx/WOy device structure is proposed to explain this switching time difference.展开更多
In natural and artificial systems,reversible reactions are commonly asymmetric with respect to the time scale and nature of the stimuli which drive the forward and backward processes.In applications for which switchin...In natural and artificial systems,reversible reactions are commonly asymmetric with respect to the time scale and nature of the stimuli which drive the forward and backward processes.In applications for which switching behavior is required,it is desirable that the reversible reaction goes as close to symmetric as possible;however,such systems are uncommon.Herein,we report an example of ultraviolet(UV)-visible light-regulated asymmetric reversible structural switching involving a diene-based coordination polymer,CP1 and its monocyclobutane product,CP1a.It is possible to cycle at least ten times through a forward [2+2] photocycloaddition reaction and the reverse,photocleavage reaction.A single cycle can be completed within a few minutes.The transformation is accompanied by fast and distinct fluorescence changes,arising from optimisation of the reaction conditions.Density functional theory calculations allow rationalisation of the asymmetric reversible transformation between CP1 and CP1a rather than between CP1 and its dicyclobutane product CP1b.This work provides a clear illustration of reversible structural switching which approaches symmetric behaviour with respect to reaction rate and stimuli.The insights gained from this work also assist in the design of fast,reversible switching materials.展开更多
Y-branching TIR all-optical switch have been fabricated. When the switching optical intensity is 149.9W/mm2, the extinction ratio is 18dB. A theoretical model was also proposed which provided a good fit to the experim...Y-branching TIR all-optical switch have been fabricated. When the switching optical intensity is 149.9W/mm2, the extinction ratio is 18dB. A theoretical model was also proposed which provided a good fit to the experimental data.展开更多
文摘Asymmetric resistive switching processes were observed in W：AlOx/WOy bilayer RRAM devices. During pulse programming measurements, the RESET speed is in the range of hundreds of microseconds under - 1.1 V bias, while the SET speed is in the range of tens of nanoseconds under 1.2 V bias. Electrical measurements with different pulse conditions and different temperatures were carded out to understand these significant differences in switching time. A redox reaction model in the W：AlOx/WOy device structure is proposed to explain this switching time difference.
基金supported by the National Natural Science Foundation of China (22271203)the State Key Laboratory of Organometallic Chemistry of Shanghai Institute of Organic Chemistry(KF2021005)+2 种基金the Collaborative Innovation Center of Suzhou Nano Science and Technologythe Priority Academic Program Development of Jiangsu Higher Education Institutionsthe Project of Scientific and Technologic Infrastructure of Suzhou (SZS201905)。
文摘In natural and artificial systems,reversible reactions are commonly asymmetric with respect to the time scale and nature of the stimuli which drive the forward and backward processes.In applications for which switching behavior is required,it is desirable that the reversible reaction goes as close to symmetric as possible;however,such systems are uncommon.Herein,we report an example of ultraviolet(UV)-visible light-regulated asymmetric reversible structural switching involving a diene-based coordination polymer,CP1 and its monocyclobutane product,CP1a.It is possible to cycle at least ten times through a forward [2+2] photocycloaddition reaction and the reverse,photocleavage reaction.A single cycle can be completed within a few minutes.The transformation is accompanied by fast and distinct fluorescence changes,arising from optimisation of the reaction conditions.Density functional theory calculations allow rationalisation of the asymmetric reversible transformation between CP1 and CP1a rather than between CP1 and its dicyclobutane product CP1b.This work provides a clear illustration of reversible structural switching which approaches symmetric behaviour with respect to reaction rate and stimuli.The insights gained from this work also assist in the design of fast,reversible switching materials.
基金This work has been supported by project 60177012 of National Natural Science Foundation of China and project G1999033104 of Major State Basic Research Development Program in China.
文摘Y-branching TIR all-optical switch have been fabricated. When the switching optical intensity is 149.9W/mm2, the extinction ratio is 18dB. A theoretical model was also proposed which provided a good fit to the experimental data.
