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Quantitative calculation on atomic site occupation during precipitation of Ni_3(Al_(1-x)Fe_x) by microscopic phase-field study
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作者 廖海洪 梁敏洁 白培康 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2016年第4期1073-1078,共6页
Microscopic phase-field method was used to simulate the site occupation of a series of alloys with a stoichiometric composition of Ni75Al25?xFex (x=0, 5?10) aged at 1273 K. With the change of Fe content, quantitative ... Microscopic phase-field method was used to simulate the site occupation of a series of alloys with a stoichiometric composition of Ni75Al25?xFex (x=0, 5?10) aged at 1273 K. With the change of Fe content, quantitative calculations were made on each atomic site occupation probability (SOP) in L12-Ni3 (Al1?xFex), so as to find out the dynamic response law. The result of the study shows that, with the increase of Fe content, the Fe atom preferentially occupies the B sites (corner sites of FCC) with its SOP value being increased gradually, and the SOP of the Al atom on the B sites is greatly decreased. Meanwhile, AlNi and FeNi anti-sites form in the precipitation of L12 phase. Moreover, with the increase of Fe content, the formation of AlNi and FeNi anti-sites becomes much easier. In addition, it has been found that the instantaneous dynamic evolution of the atomic SOP is completed at the early stage of the growth of L12 phases. 展开更多
关键词 intermetallics Ni_(75)Al_(25-x)Fe_x alloy atomic site occupation PRECIPITATION microscopic phase-field
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