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Estimation of the Kinetic Parameters and the Critical Rate of Temperature Rise in the Thermal Explosion from the Exothermic Autocatalytic Decomposition of 3,4-Bis(4′-nitrofurazan-3′-yl)-2-oxofurazan (BNFOF) Using Non-isothermal Differential Scanning Calorimetry 被引量:4
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作者 赵凤起 郭鹏江 +12 位作者 胡荣祖 张海 夏志明 高红旭 陈沛 罗阳 张志忠 周彦水 赵宏安 高胜利 史启祯 路桂娥 江劲勇 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2006年第5期631-636,共6页
A method of estimating the kinetic parameters and the critical rate of temperature rise in the thermal explosion for the autocatalytic decomposition of 3,4-bis(4'-nitrofurazan-3'-yl)-2-oxofurazan (BNFOF) with no... A method of estimating the kinetic parameters and the critical rate of temperature rise in the thermal explosion for the autocatalytic decomposition of 3,4-bis(4'-nitrofurazan-3'-yl)-2-oxofurazan (BNFOF) with non-isothermal differential scanning calorimetry (DSC) was presented. The rate equation for the decomposition of BNFOF was cstablished, and information was obtained on the rate of temperature increase in BNFOF when the empiric-order autocatalytic decomposition was converted into thermal explosion. 展开更多
关键词 3 4-bis(4'-nitrofurazan-3'-yl)-2-oxofurazan (BNFOF) autocatalytic decomposition kinetic parameter critical rate of temperature rise thermal explosion NON-ISOTHERMAL DSC
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