Quantitative Analysis of Heavy Metals in Water Based on LIBS with an Automatic Device for Sample Preparation

Abstract Heavy metals in water can be deposited on graphite flakes, which can be used as an enrichment method for laser-induced breakdown spectroscopy （LIBS） and is studied in this paper. The graphite samples were prepared with an automatic device, which was composed of a loading and unloading module, a quantitatively adding solution module, a rapid heating and drying module and a precise rotating module. The experimental results showed that the sample preparation methods had no significant effect on sample distribution and the LIBS signal accumulated in 20 pulses was stable and repeatable. With an increasing amount of the sample solution on the graphite flake, the peak intensity at Cu I 324.75 nm accorded with the exponential function with a correlation coefficient of 0.9963 and the background intensity remained unchanged. The limit of detection （LOD） was calculated through linear fitting of the peak intensity versus the concentration. The LOD decreased rapidly with an increasing amount of sample solution until the amount exceeded 20 mL and the correlation coefficient of exponential function fitting was 0.991. The LOD of Pb, Ni, Cd, Cr and Zn after evaporating different amounts of sample solution on the graphite flakes was measured and the variation tendency of their LOD with sample solution amounts was similar to the tendency for Cu. The experimental data and conclusions could provide a reference for automatic sample preparation and heavy metal in situ detection.

Design and Application of Water, Fertilizer and Pesticide Integrated Automatic Control Device

Integration of water, fertilizer and pesticide is the final stage of agricultural development, which improves the utilization efficiency of water, fertilizer and pesticide. Starting from the design and realization of water, fertilizer and pesticide integrated automatic control device, the paper discusses selection and application of fertilizer pesticides, use procedure, water, fertilizer and pesticide saving effect and receptive crowd in the application process of modern planting industry, so as to provide the basis for promotion and popularization of water, fertilizer and pesticide integration.

Effects of automatic variable preload device on performance of spindle

To increase the machine accuracy by improving the stiffness of bearings,a preload was applied to bearings.A variable preload technology was necessary to perform machining processes in both low and high speed regions.An automatic variable preload device was fabricated using an eccentric mass.By installing the fabricated device on a spindle,the effect of the automatic variable preload device on the performance of the spindle was analyzed.In the results of the vibration measurement of the spindle,the vibration is increased by 20%-37% according to measurement points at the maximum rotation speed of 5 000 r/min.And,in the results of the noise measurement of the spindle,the spindle rotation speed is increased by about 1.9% and 1.5% at the front and side of the spindle,respectively.Based on the results of this analysis,an improved method that reduces such effects on the performance of the spindle is proposed.

Design and implementation of automatic shading device for diffuse radiation measurement

Considering the problem of too large area the shading disc covered,complex shadow band coefficients and too big diffuse radiation measurement bias,an automatic shading device for diffuse radiometer is designed and realized. Set a shading ball on the automatic sun tracker,drive linkage parallelogram structure with the declination axis arm,the shading ball can rotate synchronously with the motion of the sun and shade beam radiation measured with pyranometer,thus shading beam radiation and measuring diffuse radiation can be realized automatically. The comparison test results show that the automatic shading device can realize diffuse radiation measurement automatically,the accuracy of diffuse radiation readings can get a 18. 7% improvement compared with traditional measure system,greatly improves the reliability and accuracy of the diffuse radiation measurement.

Research on Cam-linkage Mechanism of Automatic Piecing Device

The principle of an automatic piecing device is presented, and the mathematic model of a specific combined mechanism of the automatic piecing device is analysed. The kinematics and dynamics equation of the combined mechanism is established on the basis of the mathematic model. By the virtual prototype technology, the motion of this mechanism is simulated, whose result is post-processed by ADAMS. To improve the output motion, according to the simulation output and automatic piecing device's practical working condition, the optimisation of the cam mechanism is carried out by finite difference method. The simulation result of this combined mechanism turns out in accordance with its theoretical analysis of virtual prototype in this research, which, therefore, lays a principle basis for the further study of automatic piecing device.

Design of a Novel Semi-Automatic Coconut Tree Climbing Device

The aim of this study is to present a novel semi-automatic coconut tree climbing device and validate its strength based on actual working conditions. Firstly, the structural composition and operational principal of this device is introduced. After that, the finite element model of this device is established with CATIA. Finally, the strength analysis is executed by means of CATIA. In this study, the equivalent stress, principal stress, and displacement contours are obtained. The simulation results show that the maximum stress of this device is below 355 MPa, which is the value of the yield strength. Therefore, this device is capable of satisfying practical application requirements.

AUTOMATIC FINIT EELEMENT MODELING OF A WING

This paper is concerned about the automatic finite element modeling of a wing structure. The row and column method is used to identify the structure parts(ribs, spars, skins and pillars). A customization module of PCL(PATRAN Command Language under PATRAN 6.0) code from constructing airfoil curves to creating the entire wing FEM model is designed and developed. The geome tric, mesh density, material, load and boundary parameters can be easily and correctly input with the friendly interactive interface. A VFW614 wing is analyzed from creating airfoil curves to the show of stresses calculated by using NASTRAN 68 as an example. The results show that this customization module is very effective and efficient.

IMPLICIT-EXPLICIT MULTISTEP FINITE ELEMENT-MIXED FINITE ELEMENT METHODS FOR THE TRANSIENT BEHAVIOR OF A SEMICONDUCTOR DEVICE

The transient behavior of a semiconductor device consists of a Poisson equation for the electric potential and of two nonlinear parabolic equations for the electron density and hole density. The electric potential equation is discretized by a mixed finite element method. The electron and hole density equations are treated by implicit-explicit multistep finite element methods. The schemes are very efficient. The optimal order error estimates both in time and space are derived.

Finite Element Analysis on the Pre-load Structures of the Central Solenoid for the HT-7U Device

The central solenoid is an important part of the HT-7U device. In this paper， the computational analysis of the stress and the displacement on the pre-load structures of the central solenoid have been made by the finite element analysis system COSMOS/M2.0 under room and/or operating temperature. According to the analytical results, the clip aprons and compression plates are all satisfied with safety design criteria.

Design of Floating Mass Type Piezoelectric Actuator for Implantable Middle Ear Hearing Devices

To overcome some of the problems inherent in conventional heating aids such as low gain at high fi＇equencies due to acoustic feedback, discomfort in occlusion of the extemal ear canal and so on, implantable middle ear hearing devices （IMEHDs） have been developed over the past two decades. For such kinds of IMEHDs, this paper presents the design of a floating mass piezoelectric actuator using a PMN-30%PT stack as a new type of vibrator. The proposed piezoelectric actuator consists of only three components of a piezoelectric stack, a metal case and a clamp. For the purpose of aiding the design of this actuator, a coupling biomechanics model of human middle ear and the piezoelectric actuator was constructed. This model was built based on a complete set of computerized tomography section images of a healthy volunteer＇s left ear by reverse engineering technology. The validity of this model was confirmed by comparing the motion of the tympanic membrane and stapes footplate obtained by this model with published experimental measurements on human temporal bones. It is shown that the designed actuator can be implanted on the incus long process by a simple surgical operation, and the stapes footplate displacement by its excitation at 10.5 V root-mean-square（RMS） voltage was equivalent to that from acoustic stimulation at 100 dB sound pressure level（SPL）, which is adequate stimulation to the ossicular chain. The corresponding power consumption is 0.04 mW per volt of excitation at 1 kHz, which is low enough for the transducer to be used in an implantable middle ear device.

Automatic identification of rock discontinuity and stability analysis of tunnel rock blocks using terrestrial laser scanning

Local geometric information and discontinuity features are key aspects of the analysis of the evolution and failure mechanisms of unstable rock blocks in rock tunnels.This study demonstrates the integration of terrestrial laser scanning(TLS)with distinct element method for rock mass characterization and stability analysis in tunnels.TLS records detailed geometric information of the surrounding rock mass by scanning and collecting the positions of millions of rock surface points without contact.By conducting a fuzzy K-means method,a discontinuity automatic identification algorithm was developed,and a method for obtaining the geometric parameters of discontinuities was proposed.This method permits the user to visually identify each discontinuity and acquire its spatial distribution features(e.g.occurrences,spac-ings,trace lengths)in great detail.Compared with hand mapping in conventional geotechnical surveys,the geometric information of discontinuities obtained by this approach is more accurate and the iden-tification is more efficient.Then,a discrete fracture network with the same statistical characteristics as the actual discontinuities was generated with the distinct element method,and a representative nu-merical model of the jointed surrounding rock mass was established.By means of numerical simulation,potential unstable rock blocks were assessed,and failure mechanisms were analyzed.This method was applied to detection and assessment of unstable rock blocks in the spillway and sand flushing tunnel of the Hongshiyan hydropower project after a collapse.The results show that the noncontact detection of blocks was more labor-saving with lower safety risks compared with manual surveys,and the stability assessment was more reliable since the numerical model built by this method was more consistent with the distribution characteristics of actual joints.This study can provide a reference for geological survey and unstable rock block hazard mitigation in tunnels subjected to complex geology and active rockfalls.

The properties of Sn-Zn-Al-La fusible alloy for mitigation devices of solid propellant rocket motors

The Al and La elements are added to the Sn9Zn alloy to obtain the fusible alloy for the mitigation devices of solid propellant rocket motors. Differential scanning calorimetry(DSC), metallographic analysis,scanning electron microscopy(SEM), energy dispersive spectroscopy(EDS), tensile testing and fracture analysis were used to study the effect of Al and La elements on the microstructure, melting characteristics, and mechanical properties of the Sn9Zn alloy. Whether the fusible diaphragm can effectively relieve pressure was investigated by the hydrostatic pressure at high-temperature test. Experimental results show that the melting point of the Sn9Zn-0.8Al0·2La and Sn9Zn-3Al0·2La fusible alloys can meet the predetermined working temperature of ventilation. The mechanical properties of those are more than 35% higher than that of the Sn9Zn alloy at-50°C-70°C, and the mechanical strength is reduced by 80% at 175°C. It is proven by the hydrostatic pressure at high-temperature test that the fusible diaphragm can relieve pressure effectively and can be used for the design of the mitigation devices of solid propellant rocket motors.

MODES COMPUTATION AND ANALYSIS FOR LONG MULTI-SPAN BUNDLE CONDUCTORS OF POWER TRANSMISSION LINES WITH GALLOPING CONTROL DEVICES

A new type of element which is suitable for solving the modes of thegalloping long multi-span bundle conductor structures is presented. The element is composed of allsub-conductor segments between two spacers. Based on the linearized governing differential equationsof the conductors, the mass matrix and stiffness matrix of the element in consideration of theconstrained relations imposed on the conductors by spacers are derived. The dynamic characteristicsof the galloping control devices can be directly added to the element. The modes for an actual powerline structure are computed by using the element formula and FEM procedures, where seven cases ofdifferent galloping control device allocations are considered. Compared with the measured data, themethod is shown to be reliable and effective. Analysis and discussions of the computational resultsare given. Some hints that are helpful to further investigation of galloping are also obtained .

DEM Simulation to Determine the Influence on the Experimental Results of Tests of Iron Pellets When the Dimensions of the Test Device Are Varied

The current study is based on the DEM computer simulation of three experimental test devices with different dimensions to determine the difference in the results of the formation of shear and repose angles that the particles experience when grouped under the action of the gravitational force. In this respect, the experimental test devices with different height, width, and depth were geometrically modeled with iron pellet particles using morphology and a granulometric variation from 6 mm to 9 mm of equivalent diameter in its spherical shape. Depending on the results obtained, a reliable size of the experimental test device will be available to obtain the necessary data for a correct adjustment of the calibration parameters for the DEM simulation of mining-metallurgical processes that use granulated material of iron pellet.

Analysis and Calculation for Heating and Temperature Rise of Magnetic Levitation Device

准确的热分析是磁悬浮系统电磁装置优化设计、防止过热的前提。提出了基于等效热路模型的电磁装置发热及温升计算方法,并与基于＂场＂的仿真分析结果进行比较,验证其正确性。首先,利用ANSYS软件建立电磁装置的瞬态温度场模型,并将装置中动铁心随大轴旋转时与空气产生的风摩擦损耗包含在模型中,通过仿真分析,得到电磁装置温度分布;然后,通过对散热路径的分析建立了电磁装置的等效热路模型,从＂路＂的角度计算出本电磁装置各位置的温升;最后,将基于＂路＂的计算结果与基于＂场＂的仿真结果进行了比较分析,各部分温升误差均在允许范围内,验证了等效热路模型计算电磁装置发热及温升方法的准确性和可行性。在基于＂场＂和＂路＂的两种分析中,均考虑了电阻率随温升的变化,散热分析中均计及了导热系数和对流散热系数随温度的变化。

Variable-mass Thermodynamics Calculation Model for Gas-operated Automatic Weapon

Aiming at the fact that the energy and mass exchange phenomena exist between barrel and gas-operated device of the automatic weapon, for describing its interior ballistics and dynamic characteristics of the gas-operated device accurately, a new variable-mass thermodynamics model is built. It is used to calculate the automatic mechanism velocity of a certain automatic weapon, the calculation results coincide with the experimental results better, and thus the model is validated. The influences of structure parameters on gas-operated device's dynamic characteristics are discussed. It shows that the model is valuable for design and accurate performance prediction of gas-operated automatic weapon.

Study on Mesh-Control Device for the Mesh Generator Based on Tree Structures

In this paper, a process of the quadtree mesh generation is described, then a mesh control device of the tree based mesh generators is analyzed in detail. Some examples are given to demonstrate that the mesh control device allows for efficient a priori and a posteriori mesh refinements.

Analysis of a two-grid method for semiconductor device problem

The mathematical model of a semiconductor device is governed by a system of quasi-linear partial differential equations.The electric potential equation is approximated by a mixed finite element method,and the concentration equations are approximated by a standard Galerkin method.We estimate the error of the numerical solutions in the sense of the Lqnorm.To linearize the full discrete scheme of the problem,we present an efficient two-grid method based on the idea of Newton iteration.The main procedures are to solve the small scaled nonlinear equations on the coarse grid and then deal with the linear equations on the fine grid.Error estimation for the two-grid solutions is analyzed in detail.It is shown that this method still achieves asymptotically optimal approximations as long as a mesh size satisfies H=O(h^1/2).Numerical experiments are given to illustrate the efficiency of the two-grid method.

Multi-Physics Numerical Simulation of Thermoelectric Devices

To optimize the performance of a thermoelectric device for a specific application, the device should be uniquely designed for the application. Achieving an optimum design requires accurate measurements and credible analysis to evaluate the performance of the device and its relationship with the device parameters. To do that, we designed, fabricated, and tested four devices based on Bi2Te3 and Sb2Te3. To evaluate the accuracy of our analysis, experimental measurements were compared with the numerical simulation performed using COMSOLTM. The two sets of results were found to be in full agreement. This is a proof of the accuracy of our experimental measurements and the credibility of our simulation. The study shows that testing or simulating the devices without heat sink will lead to skewed results. This is because the junction will not hold its temperatures value, but will, instead, automatically change its value to the direction of thermal equilibrium. The study shows also that there is no reciprocity between the input and the output characteristics of the devices. Therefore, a device optimized for cooling and heating may not be automatically optimized for energy harvesting. For heating and cooling, temperature sensitivity should be optimized;while for energy harvesting, voltage sensitivity should be optimized. Using heat sink, our devices achieved a voltage sensitivity of 187.77 μV/K and a temperature sensitivity of 6.12 K/mV.

Mechanical Design of Long-Term Body-Adhered Medical Devices to Maximize On-Body Survival

Long-term, body-adhered medical devices rely on an adhesive interface to maintain contact with the patient. The greatest threat to on-body adhesion is mechanical stress imparted on the medical device. Several factors contribute to the ability of the device to withstand such stresses, such as the mechanical design, shape, and size of the device. This analysis investigates the impact that design changes to the device have on the stress and strain experienced by the system when acted on by a stressor. The analysis also identifies the design changes that are most effective at reducing the stress and strain. An explicit dynamic finite element analysis method was used to simulate several design iterations and a regression analysis was performed to quantify the relationship between design and resultant stress and strain. The shape, height, size, and taper of the medical device were modified, and the results indicate that, to reduce stress and strain in the system, the device should resemble a square in shape, be short in height, and small in size with a large taper. The square shape experienced 17.5% less stress compared to the next best performing shape. A 10% reduction in device height resulted in a 21% reduction in stress and 24% reduction in strain. A 20% reduction in device size caused a 7% reduction in stress and 2% reduction in strain. A 20% increase in device taper size led to a negligible reduction in stress and a 6% reduction in strain. The height of the device had the greatest impact on the resultant stress and strain.