A novel Cu?6.5Ni?1Al?1Si?0.15Mg?0.15Ce alloy with super-high strength was designed and its corrosion behavior in3.5%NaCl solution at25°C was investigated by the means of SEM observation,TEM observation and XPS an...A novel Cu?6.5Ni?1Al?1Si?0.15Mg?0.15Ce alloy with super-high strength was designed and its corrosion behavior in3.5%NaCl solution at25°C was investigated by the means of SEM observation,TEM observation and XPS analysis.The alloy after solution treatment,80%cold rolling and aging at450°C for1h had the best comprehensive properties with hardness of HV314,electrical conductivity of19.4%IACS,tensile strength of1017MPa,and average annual corrosion rate of0.028mm/a.The oxides and chloride products formed at first,followed by the formation of dyroxides products.The alloy showed super-high strength,good electrical conductivity and corrosion resistant because Ni2Si hindered the precipitation of large NiAl at the grain boundary and the denickelefication of the alloy.展开更多
The dissimilar metals 1Crl8Ni9 and 16MnR are welded by shielded metal arc welding process using electrode A312. The corrosion experiments are carried out on welded joint samples, which is as-welded and post-weld heat ...The dissimilar metals 1Crl8Ni9 and 16MnR are welded by shielded metal arc welding process using electrode A312. The corrosion experiments are carried out on welded joint samples, which is as-welded and post-weld heat treatment at 650 ℃, 750 ℃ and 850 ℃, for 2 h in 70% sodium hydroxide solution. EDS and X-ray diffraction analysis are carried out on the samples after corrosion. Average corrosion rate calculation and microhardness measurement are conducted on both as- welded and post-weld heat treatment samples. The results indicate that average corrosion rate of as-welded joint metal is smaller than that of post-weld heat treatment joint metal. Compared with that of post-weld heat treatment at 750 ℃ and 850 ℃ for 2 h, the average corrosion rate of welded joint after post-weld heat treatment at 650 ℃ for 2 h increases greatly.展开更多
基金Project(51271203)supported by the National Natural Science Foundation of China
文摘A novel Cu?6.5Ni?1Al?1Si?0.15Mg?0.15Ce alloy with super-high strength was designed and its corrosion behavior in3.5%NaCl solution at25°C was investigated by the means of SEM observation,TEM observation and XPS analysis.The alloy after solution treatment,80%cold rolling and aging at450°C for1h had the best comprehensive properties with hardness of HV314,electrical conductivity of19.4%IACS,tensile strength of1017MPa,and average annual corrosion rate of0.028mm/a.The oxides and chloride products formed at first,followed by the formation of dyroxides products.The alloy showed super-high strength,good electrical conductivity and corrosion resistant because Ni2Si hindered the precipitation of large NiAl at the grain boundary and the denickelefication of the alloy.
文摘The dissimilar metals 1Crl8Ni9 and 16MnR are welded by shielded metal arc welding process using electrode A312. The corrosion experiments are carried out on welded joint samples, which is as-welded and post-weld heat treatment at 650 ℃, 750 ℃ and 850 ℃, for 2 h in 70% sodium hydroxide solution. EDS and X-ray diffraction analysis are carried out on the samples after corrosion. Average corrosion rate calculation and microhardness measurement are conducted on both as- welded and post-weld heat treatment samples. The results indicate that average corrosion rate of as-welded joint metal is smaller than that of post-weld heat treatment joint metal. Compared with that of post-weld heat treatment at 750 ℃ and 850 ℃ for 2 h, the average corrosion rate of welded joint after post-weld heat treatment at 650 ℃ for 2 h increases greatly.