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The Determination of Average Stability Constant of NickeI-FA Complex at pH = 8,0 by the Solubility Method
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作者 Giorgi Makharadze Nazi Goliadze +1 位作者 Tamar Makharadze Guram Supatashvili 《Journal of Chemistry and Chemical Engineering》 2014年第4期344-348,共5页
At pH = 8, the complex formation process of Ni(Ⅱ) ions with FA was studied by the solubility method. FA were separated from the river Mtkvari by the adsorption-chromotographic method. The charcoal (BAU, Russia) w... At pH = 8, the complex formation process of Ni(Ⅱ) ions with FA was studied by the solubility method. FA were separated from the river Mtkvari by the adsorption-chromotographic method. The charcoal (BAU, Russia) was used as a sorbent. The old suspension of Ni(Ⅱ) hydroxide was used as the solid phase, on which was added the increasing quantity of standard solution of FA. In diluted solutions, at pH = 8.0 the dominant form of Ni(Ⅱ) is nickel dihydroxocomplex Ni(OH)2^0. It was established that in the Ni(OH)2(solid)-Ni(OH)2^0(solution)-FA2-H20 system dominates nickel dyhydroxofulvate complex with the structure 1:1, [Ni(OH)2FA]2-. The average stability constant of nickel dyhydroxofulvate complex was calculated based on experimental data flNi(OH)2FA2" = 5.3 × 105. 展开更多
关键词 NICKEL FA average stability constant nickel fulvate water.
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Method of Calculation of Stability Constants of Fulvic Complexes on the Example of Copper 被引量:1
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作者 Giorgi Makharadze Tamar Makharadze 《Journal of Chemistry and Chemical Engineering》 2014年第2期108-111,共4页
On the example of copper fulvate, it is discussed the method of calculation of stability constants of fulvic complexes. At pH = 8, the complex formation of copper(ll) ions with fulvic acids was studied by the solubi... On the example of copper fulvate, it is discussed the method of calculation of stability constants of fulvic complexes. At pH = 8, the complex formation of copper(ll) ions with fulvic acids was studied by the solubility method. Fulvic acids were separated from the river Mtkvari by the adsorption-chromotographic method. The charcoal (BAU, Russia) was used as a sorbent. The suspension of copper(If) hydroxide was used as the solid phase, on which was added the increasing quantity of standard solution of fulvic acids. In diluted solutions, at pH = 8 the dominant form of copper(lI) is copper dihydroxo complex Cu(OH)^zO. It was established that in the Cu(OH)2 (solid)-Cu(OH)^20 (solution)-FA^2-H20 system, dominates copper dyhydroxo fulvate complex with the structure 1:1, [Cu(OH)2FA]^2. The average stability constant of copper dyhydroxo fulvate complex was calculated based on experimental data fl [Cu(OH)2FAJ^2 = 4.5× l0^5. 展开更多
关键词 COPPER fulvic acids the average stability constant copper fulvate water.
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Dynamic flight stability of hovering model insects:theory versus simulation using equations of motion coupled with Navier-Stokes equations 被引量:9
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作者 Yan-Lai Zhang Mao Sun 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2010年第4期509-520,共12页
In the present paper, the longitudinal dynamic flight stability properties of two model insects are predicted by an approximate theory and computed by numerical sim- ulation. The theory is based on the averaged model ... In the present paper, the longitudinal dynamic flight stability properties of two model insects are predicted by an approximate theory and computed by numerical sim- ulation. The theory is based on the averaged model (which assumes that the frequency of wingbeat is sufficiently higher than that of the body motion, so that the flapping wings' degrees of freedom relative to the body can be dropped and the wings can be replaced by wingbeat-cycle-average forces and moments); the simulation solves the complete equations of motion coupled with the Navier-Stokes equations. Comparison between the theory and the simulation provides a test to the validity of the assumptions in the theory. One of the insects is a model dronefly which has relatively high wingbeat frequency (164 Hz) and the other is a model hawkmoth which has relatively low wingbeat frequency (26 Hz). The results show that the averaged model is valid for the hawkmoth as well as for the dronefly. Since the wingbeat frequency of the hawkmoth is relatively low (the characteristic times of the natural modes of motion of the body divided by wingbeat period are relatively large) compared with many other insects, that the theory based on the averaged model is valid for the hawkmoth means that it could be valid for many insects. 展开更多
关键词 Insect Hovering Dynamic flight stability averaged model Equations-of-motion Navier-Stokes simulation
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Effects of switching frequency and leakage inductance on slow-scale stability in a voltage controlled flyback converter 被引量:2
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作者 王发强 马西奎 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第12期133-140,共8页
The effects of both the switching frequency and the leakage inductance on the slow-scale stability in a voltage controlled flyback converter are investigated in this paper. Firstly, the system description and its math... The effects of both the switching frequency and the leakage inductance on the slow-scale stability in a voltage controlled flyback converter are investigated in this paper. Firstly, the system description and its mathematical model are presented. Then, the improved averaged model, which covers both the switching frequency and the leakage inductance, is established, and the effects of these two parameters on the slow-scale stability in the system are analyzed. It is found that the occurrence of Hopf bifurcation in the system is the main reason for losing its slow-scale stability and both the switching frequency and the leakage inductance have an important effect on this slow-scale stability. Finally, the effectiveness of the improved averaged model and that of the corresponding theoretical analysis are confirmed by the simulation results and the experimental results. 展开更多
关键词 flyback converter slow-scale stability improved averaged model Hopf bifurcation
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THE AVERAGE AGGREGATE NUMBER OF ELECTROSTATICALLY STABILIZED AGGREGATE(ESAg)
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作者 Jin Tao ZHANG Bo TU Guo Zhen JI Xi Kui JIANG Shanghai Institute of Organic Chemistry,Academia Sinica,345 Lingling Lu,Shanghai 200032Zhen He TONG Laboratory of Photochemistry,Institute of Photographic Chemistry,Academia Sinica,Beijing 100101 《Chinese Chemical Letters》 SCIE CAS CSCD 1993年第10期879-882,共4页
The average aggregate number(N)of electrostatically stabilized aggregate(ESAg)composed of oppositely-charged long-chain molecules,i.e., sodium ω-[α-(nathphyl)ethoxyl]undecanoate(FP^-)and cetyltrimethyl ammonium chlo... The average aggregate number(N)of electrostatically stabilized aggregate(ESAg)composed of oppositely-charged long-chain molecules,i.e., sodium ω-[α-(nathphyl)ethoxyl]undecanoate(FP^-)and cetyltrimethyl ammonium chloride(CTAC),in aqueous solution at 25℃ has been measured to be 11 to 16 in the CTAC-concentration range of 11×10^(-5) M to 30×10^(-5) M at a fixed FP- concentration of 1.0×10^(-5)M by the photon counting method. 展开更多
关键词 CTAC ESAg THE average AGGREGATE NUMBER OF ELECTROSTATICALLY STABILIZED AGGREGATE FP WANG
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Stabilization of stochastic Hopfield neural network with distributed parameters 被引量:11
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作者 LUOQi DENGFeiqi +2 位作者 BAOJundong ZHAOBirong FUYuli 《Science in China(Series F)》 2004年第6期752-762,共11页
In this paper, the stability of stochastic Hopfield neural network with distributed parameters is studied. To discuss the stability of systems, the main idea is to integrate the solution to systems in the space variab... In this paper, the stability of stochastic Hopfield neural network with distributed parameters is studied. To discuss the stability of systems, the main idea is to integrate the solution to systems in the space variable. Then, the integration is considered as the solution process of corresponding neural networks described by stochastic ordinary differential equations. A Lyapunov function is constructed and Ito formula is employed to compute the derivative of the mean Lyapunov function along the systems, with respect to the space variable. It is difficult to treat stochastic systems with distributed parameters since there is no corresponding Ito formula for this kind of system. Our method can overcome this difficulty. Till now, the research of stability and stabilization of stochastic neural networks with distributed parameters has not been considered. 展开更多
关键词 Hopfield neural networks distributed parameters average exponential stability in mean square.
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