The Relationship of Sulfate-methane Interface,the Methane Flux and the Underlying Gas Hydrate

The sulfate-methane interface is an important biogeochemical identification interface for the areas with high methane flux and containing gas hydrate. Above the sulfate-methane interface, the sulfate concentration in the sediment is consumed progressively for the decomposition of the organic matter and anaerobic methane oxidation. Below the sulfate-methane interface, the methane concentration increases continuously with the depth. Based on the variation characters of the sulfate and methane concentration around the sulfate-methane interface, it is feasible to estimate the intensity of the methane flux, and thereafter to infer the possible occurrence of gas hydrate. The geochemical data of the pore water taken from the northern slope of the South China Sea show the sulfate-methane interface is relatively shallow, which indicates that this area has the high methane flux. It is considered that the high methane flux is most probably caused by the occurrence of underlying gas hydrate in the northern slope of the South China Sea.

Analysis of Divertor Heat Flux with Infrared Thermography During Gas Fuelling in the HL-2A Tokamak

In HL-2A tokamaks, the behavior of heat flux deposited on the divertor targets has been studied during deuterium gas fuelling. The heat flux is reduced significantly after supersonic molecular beam injection （SMBI） fuelling during Ohmic and electron cyclotron resonance heating （ECRH） divertor discharges. The SMBI fuelling causes an increase in the plasma density and this change results in the experienced change of the edge properties. Most of this reduction in divertor target heat flux occurs together with a high plasma radiation region located at near the X-point. The largest reduction in heat flux profiles is observed at the outboard divertor separatrix strike point, while the heat flux far from the strike point remains almost unchanged. In particular, with SMBI multi-pulses gas fuelling, a partially detached divertor regime is observed with a highly radiating region at the X-point. With the onset of the partially detached divertor regime, a sudden drop in both heat flux and power flow on the divertor target is observed. The reduction in power load on the divertor targets is roughly equal to the increase in plasma radiation loss.

Study of properties and mechanisms of backing weld of stainless steel piping with no backing gas

This work investigates the proposed welding of stainless steels with no backing gas by using solid wire ER316L-Si and mixed gases （ He ＋ Ar ＋ CO2 ）. The protection mechanism was also discussed from the view of arc physics and the alloy elements in the solid wire. The result shows that when the proportion of helium in the above-noted mixed gases excesses 45 percent, the mechanical properties and the intergranular corrosion tendency meet corresponding Chinese standards. Further, the alloy elements in the solid wire can react with oxygen during the period of high temperature boosted by helium arc ; this result in the formation of a bed of thin slag, which can avoid the oxidation of the backing weld and eliminate the need of backing gas.

Research Advances of Effects of Land Use Pattern on Greenhouse Gas Fluxes in Grassland Ecosystem

The grassland is the largest terrestrial ecosystem in China,and greenhouse gas fluxes such as CO2,CH4 and N2O play an important role in the global climate change. The differences in grazing,cultivation and management measures will affect greenhouse gas emissions in grassland ecosystem. Studies suggest that reclamation will lead to increased CO2 fluxes,and fertilization will lead to increased N2 O fluxes; no grazing in summer can reduce greenhouse gas emissions,but impacts of grazing and management measures on greenhouse gas fluxes have not yet reached the same conclusion. The different results may be related to local natural conditions,management measures and research methods. Future research should be focused on unity and standardization in these areas,making the results scientific and comparable,and finally providing the basis for emission reduction of greenhouse gases in grassland ecosystem.

Gas kinetic flux solver based finite volume weighted essentially non-oscillatory scheme for inviscid compressible flows

A high-order gas kinetic flux solver(GKFS)is presented for simulating inviscid compressible flows.The weighted essentially non-oscillatory(WENO)scheme on a uniform mesh in the finite volume formulation is combined with the circular function-based GKFS(C-GKFS)to capture more details of the flow fields with fewer grids.Different from most of the current GKFSs,which are constructed based on the Maxwellian distribution function or its equivalent form,the C-GKFS simplifies the Maxwellian distribution function into the circular function,which ensures that the Euler or Navier-Stokes equations can be recovered correctly.This improves the efficiency of the GKFS and reduces its complexity to facilitate the practical application of engineering.Several benchmark cases are simulated,and good agreement can be obtained in comparison with the references,which demonstrates that the high-order C-GKFS can achieve the desired accuracy.

A Study on the Combustion Characteristics and Greenhouse Gas Emissions from Rice Husks with Varied Heat Fluxes

This paper analyzes the combustion characteristics and greenhouse gas emissions from varied heat fluxes with rice husks. In general, rice husks burnt outdoors at a lower temperature range of 300-400 ℃, which cannot assure complete combustion, thus generating a large volume of toxic air pollutants. A heat flux of 40 kW/m^2, with a cone calorimeter, is the equivalent to the 700 ℃ of an incinerator. The test result shows that the mass reduction rate of the sample at this or at a higher temperature condition was 99.5% or higher, meaning that the sample was almost completely combusted. In this study using rice husks, the amount of carbon dioxide, which is a greenhouse gas, discharged were 1.57-3.61 kg/kg. This is as high as 10 times, than produced in other studies. When the rice husks are burnt outdoors, they are not completely combusted as the combustion temperature remains low, and the rice husk residuals are continuously being combusted in a smoldering phase which creates a large volume of carbon dioxide and carbon monoxide. Therefore, it is recommended to burn rice husks at 700 ℃ or higher to minimize the carbon dioxide and carbon monoxide emissions.

Methane fluxes and gas hydrates as well as seismic activity in the Okhotsk Sea

The research works of methane concentration in water column of the Okhotsk Sea from 1984 to 2005 were reviewed.And some regularities of methane distribution in water column in the North-East Sakhalin slope of the Okhotsk Sea were concluded.

Seasonal dynamics of gas regulation service in forest ecosystem

Using the 3-year observational data from ChinaFlux （Chinese Terrestrial Ecosystem Flux Research Network）, we studied the gas regulation flux dynamics and cumulative process of gas regulation value in Qianyanzhou middle subtropical plantation （QYF） and Changbai Mountain temperate mixed forest （CBF）. The gas regulation service was differentiated into vegetation gas regulation service and net ecosystem gas regulation service. Carbon tax approach, reforestation cost approach and industrial oxygen approach were employed to calculate gas regulation value. Results show that there was significant seasonal variation in vegetation gas regulation flux. Daily CO2 uptake fluxes averaged 82.00 kg·ha^-·d^-1 and 59.37 kg·ha^-·d^-1 and the corresponding 02 emission fluxes were 59.65 kg·ha^-·d^-1 and 43.19 kg·ha^-·d^-1 for QYF and CBF, respectively. The cumulative curves of vegetation gas regulation value always followed a sigmoid shape, and the annual gas regulation value produced by vegetation was RMB 14342.69 yuan·ha^-1 and RMB 10384.18 yuan·ha^-1 for both QYF and CBF, respectively. In terms of monthly net ecosystem gas regulation service, QYF appeared as a CO2 sink and O2 source for the whole year, while CBF appeared to be a CO2 sink and O2 source mainly in the period between May and September. The cumulative curves of net ecosystem gas regulation value presented a sigmoid （＂S＂） shape for QYF, while a unimodal type curve for CBF. The annual net ecosystem gas regulation value was 8470.52 yuan·ha^-1 and 5091.98yuan·ha^-1 for QYF and CBF, respectively. The economic value of both the vegetation gas regulation service and net ecosystem gas regulation service were mainly produced between May and October.

Effects of activating flux on CO_2 laser welding process of 6013 Al alloy

In order to increase the absorption of laser energy and improve the weld appearance in laser welding of Al alloy, 1.8 mm- 6013 Al alloy plate was welded by activating flux CO2 laser welding. Activating flux includes oxide and fluoride, which was coated on the workpiece surface before welding. The experimental results show that the activating flux can effectively improve the absorption of CO2 laser energy and increase the amount of the molten base metal. The improvement on the absorption of laser energy by oxide activating flux is greater than that by fluoride activating flux or two-component activating flux, but the slag detachability made from both the single activating flux and two-activating flux is poor. The gas pore sensitivity with oxide activating flux is much higher than that with fluoride activating flux in CO2 laser welding of 6013 Al alloy.

Daily Variation of Natural Emission of Methane to the Atmosphere and Source Identification in the Luntai Fault Region of the Yakela Condensed Oil/Gas Field in the Tarim Basin,Xinjiang,China

The static flux chamber method was applied to study natural emissions of methane to the atmosphere in the Luntai fault region of Yakela Condensed Oil/Gas Field in the Tarim Basin, Xinjiang Municipality, northwestern China. Using an online method, which couples together a gas chromatography/high-temperature conversion/isotope ratio mass spectrometry （GC/C/MS）, 13^C/12^C ratios of methane in flux chambers were measured and showed that methane gases are liable to migrate from deep oil/gas reservoirs to the surface through fault regions and that a part of the migrated methane, which remains unoxidized can be emitted into the atmosphere. Methane emission rates were found to be highest in the mornings, lowest in the afternoons and then increase gradually in the evenings. Methane emission rates varied dramatically in different locations in the fault region. The highest methane emission rate was 10.96 mg/m^2·d, the lowest 4.38 mg/m^2, and the average 7.55 mg/ m^2·d. The 13^C/12^C ratios of the methane in the flux chambers became heavier as the enclosed methane concentrations increased gradually, which reveals that methane released from the fault region might come from thermogenic methane of the deep condensed oil/gas reservoir.

Non-equilibrium Molecular Dynamics Simulation on Pure Gas Permeability Through Carbon Membranes

The permeation of various pure gas （H2, He, Ne, CH4 and At） through carbon membranes is investigated using a dual control volume grand canonical molecular dynamics method. A two-dimensional slit pore is employed instead of the one-dimensional pore. Compared with the experiments, simulation results show that the improvement of pore model is very necessary. The effects of membrane thickness, pore width and temperature on gas permeance and ideal separation factor are also discussed. Results show that gas permeates through membrane according to Knudsen diffusion in large pore, while Knudsen diffusion is accompanied by molecular sieving in small pore. Moreover, methane is easily adsorbed on the membrane surface due to strong attractive interactions of membrane and shows higher permeance than that of Knudsen flow. In addition, it is noted that when membrane thickness is thin enough the permeance of gas does not decrease with the increase of membrane thickness due to the strong adsorption until membrane resistance becomes dominant.

Geological emission of methane from the Yakela condensed oil/gas field in Talimu Basin, Xinjiang, China

A static flux chamber method was applied to study natural emissions of methane into the atmosphere in the Yakela condensed oil/gas field in Talimu Basin, Xinjiang, China. Using an online method, which couples a gas chromatography/high-temperature conversion/isotope ratio mass spectrometry (GC/C/MS) together, the 13C/12C ratios of methane in the flux chambers were measured. The results demonstrated that methane gases were liable to migrate from deep oil/gas reservoir to the surface through microseepage and p...

Comparisons of the effects of different drying methods on soil nitrogen fractions:Insights into emissions of reactive nitrogen gases(HONO and NO)

Reactive nitrogen(Nr)emission from soils,e.g.,nitrous acid(HONO)and nitric oxide(NO),is a key process of the global nitrogen(N)cycle and has significant implications for atmospheric chemistry.To understand the underlying mechanisms of soil Nr emissions,air-dried or oven-dried soils are commonly used in the laboratory.To date,few studies have compared the effects of different drying methods on soil Nr gas fluxes and N fractions.Here,the authors studied soil water content,pH,(in)organic N content,and Nr gas fluxes of air-dried,freeze-dried,oven-dried,and fresh soils from different land-use types.The results showed that the soil pH of air-dried and oven-dried samples was significantly lower compared with fresh soil from farmland and grassland,but higher compared with forest soil.The difference in soil pH between freeze-dried and fresh soil(mean±standard deviation:0.52±0.31)was the lowest.In general,all drying methods increased the soil NH4+-N,NO3−-N,and dissolved organic N contents compared with fresh soil(P<0.05).The maximum HONO and NO flux and total emissions during a full wetting–drying cycle of fresh soil were also increased by air-drying and oven-drying(P<0.001),but comparable with freeze-dried soil(P>0.2).In conclusion,all drying methods should be considered for use in studies on the land–atmosphere interface and biogeochemical N cycling,whereas the freeze-drying method might be better for studies involving the measurement of soil Nr gas fluxes.

Contribution of winter fluxes to the annual CH_4, CO_2 and N_2O emissions from fres hwater marshes in the Sanjiang Plain

Wetlands at the interface of the terrestrial and aquatic ecosystems are intensive sites for mineralization of organic matter, but the contribution of winter season fluxes of CH4, CO2 and N2O from wetland ecosystems to annual budgets is poorly known. By using the static opaque chamber and GC techniques, fluxes of CH4, CO2 and N2O at two freshwater marshes in the Sanjiang Plain were measured during the winter seasons of 2002/2003 and 2003/2004 with contrasting snow conditions and flooding regimes. The results showed that there were significant interannual and spatial differences in CH4, CO2 and N2O fluxes. The Carex lasiocarpa marsh emitted more CH4 and CO2 while absorbed less N2O than the Deyeuxia angustifolia marsh during the winter seasons. Over the winter season, emissions of CH4, CO2 and N2O ranged from 0.42 to 2.41 gC/m^2, from 24.13 to 50.16 gC/m^2, and from -25,20 to -148.96 mgN/m^2, respectively. The contributions of winter season CH4 and CO2 emission to the annual budgets were 2.32% 4.62% and 22.17%- 27.97%, respectively. Marshes uptake N2O during the freezing period, while release N2O during the thawing period. The winter uptake equaled to 13.70%-86.69% of the growing-season loss. We conclude that gas exchange between soil/snow and the atmosphere in the winter season contributed greatly to the annual budgets and cannot be ignored in a cool temperate freshwater marsh in Northeast China.

GLOBAL L~∞ SOLUTIONS TO SYSTEM OF ISENTROPIC GAS DYNAMICS IN A DIVERGENT NOZZLE WITH FRICTION

In this article, we study the global L^∞ entropy solutions for the Cauchy problem of system of isentropic gas dynamics in a divergent nozzle with a friction. Especially when the adiabatic exponent γ=3, we apply for the maximum principle to obtain the L^∞ estimates w(ρ^δ,ε, u^δ,ε)≤ B(t) and z(ρ^δ,ε, u^δ,ε)≤ B(t) for the viscosity solutions (ρ^δ,ε, u^δ,ε), where B(t) is a nonnegative bounded function for any finite time t. This work, in the special case γ≥ 3, extends the previous works, which provided the global entropy solutions for the same Cauchy problem with the restriction w(ρ^δ,ε, u^δ,ε)≤ 0 or z(ρ^δ,ε, u^δ,ε)≤ 0.

Carbon Dioxide Concentration and Flux in an Urban Residential Area in Seoul,Korea

The carbon dioxide （CO2） concentrations and fluxes measured at a height of 17.5 m above the ground by a sonic anemometer and an open-path gas analyzer at an urban residential site in Seoul, Korea from February 2011 to January 2012 were analyzed. The annual mean CO2 concentration was found to be 750 mg m-3, with a maximum monthly mean concentration of 827 mg m-3 in January and a minimum value of 679 mg m-3 in August. Meanwhile, the annual mean CO2 flux was found to be 0.45 mg m-2 s-1, with a maximum monthly mean flux of 0.91 mg m-2 s-1 in January and a minimum value of 0.19 mg m-2 s-1 in June. The hourly mean CO2 concentration was found to show a significant diurnal variation; a maximum at 0700-0900 LST and a minimum at 1400-1600 LST, with a large diurnal range in winter and a small one in summer, mainly caused by diurnal changes in mixing height, CO2 flux, and surface complexity. The hourly mean CO2 flux was also found to show a significant diurnal variation, but it showed two maxima at 0700-0900 LST and 2100-2400 LST, and two minima at 1100-1500 LST and 0300-0500 LST, mainly caused by a diurnal pattern in CO2 emissions and sinks from road traffic, domestic heating and cooking by liquefied natural gas use, and the different horizontal distribution of CO2 sources and sinks near the site. Differential advection with respect to wind direction was also found to be a cause of diurnal variations in both the CO2 concentration and flux.

Estimate of Global Sea-Air CO_2 Flux with Sea-State-Dependent Parameterization

Although the annual global sea-air CO2 flux has been estimated extensively with various wind-dependent-k parameterizations,uncertainty still exists in the estimates. The sea-state-dependent-k parameterization is expected to improve the uncertainty existing in these estimates. In the present study,the annual global sea-air CO2 flux is estimated with the sea-state-dependent-k parameterization proposed by Woolf(2005) ,using NOAA/NCEP reanalysis wind speed and hindcast wave data from 1998 to 2006,and a new estimate,-2.18 Gt C year-1,is obtained,which is comparable with previous estimates with biochemical methods. It is interesting to note that the averaged value of previous estimates with various wind-dependent-k parameterizations is almost identical to that of previous estimates with biochemical methods by various authors,and that the new estimate is quite consistent with these averaged estimates.

Experiences in using gas dispersion measurements to evaluate metallurgical performance of scavenger cleaner and recleaner circuit at Vale's Thompson Mill

The performance of a flotation circuit is largely the result of the operator's response to visual clues. This includes manipulation of the gas input and how it is distributed to cells in a bank. A new gas dispersion technology was presented which was conducted to perform characterization tests in Outokumpu 30 m3 and 50 m3 flotation cells installed at Thompson Vale's concentrator, and subsequent data analysis. The experimental program was designed to establish "as-found" baseline conditions for each cell of the two-parallel banks in the scavenger-cleaner and recleaner circuit, to select and characterize one typical cell in the two banks with either different frother concentrations or different air flow rates, and establish what variables can be manipulated in future characterization work. A three-parameter model was developed in order to link the bubble size and frother concentration. This relationship can be used to correlate gas dispersion change to improved metallurgical performance.

Global air-sea surface carbon-dioxide transfer velocity and flux estimated using ERS-2 data and a new parametric formula

Using data from the European remote sensing scatterometer （ERS-2） from July 1997 to August 1998, glob- al distributions of the air-sea CO2 transfer velocity and flux are retrieved. A new model of the air-sea CO2 transfer velocity with surface wind speed and wave steepness is proposed. The wave steepness （6） is re- trieved using a neural network （NN） model from ERS-2 scatterometer data, while the wind speed is directly derived by the ERS-2 scatterometer. The new model agrees well with the formulations based on the wind speed and the variation in the wind speed dependent relationships presented in many previous studies can be explained by this proposed relation with variation in wave steepness effect. Seasonally global maps of gas transfer velocity and flux are shown on the basis of the new model and the seasonal variations of the transfer velocity and flux during the 1 a period. The global mean gas transfer velocity is 30 cm/h after area-weighting and Schmidt number correction and its accuracy remains calculation with in situ data. The highest transfer velocity occurs around 60°N and 60°S, while the lowest on the equator. The total air to sea CO2 flux （calcu- lated by carbon） in that year is 1.77 Pg. The strongest source of CO2 is in the equatorial east Pacific Ocean, while the strongest sink is in the 68°N. Full exploration of the uncertainty of this estimate awaits further data. An effectual method is provided to calculate the effect of waves on the determination of air-sea CO2 transfer velociW and fluxes with ERS-2 scatterometer data.

A Re-examination of Density Effects in Eddy Covariance Measurements of CO_2 Fluxes

Corrections of density effects resulting from air-parcel expansion/compression are important in interpreting eddy covariance fluxes of water vapor and CO2 when open-path systems are used. To account for these effects, mean vertical velocity and perturbation of the density of dry air are two critical parameters in treating those physical processes responsible for density variations. Based on various underlying assumptions, different studies have obtained different formulas for the mean vertical velocity and perturbation of the density of dry air, leading to a number of approaches to correct density effects. In this study, we re-examine physical processes related to different assumptions that are made to formulate the density effects. Specifically, we re-examine the assumptions of a zero dry air flux and a zero moist air flux in the surface layer, used for treating density variations, and their implications for correcting density effects. It is found that physical processes in relation to the assumption of a zero dry air flux account for the influence of dry air expansion/compression on density variations. Meanwhile, physical processes in relation to the assumption of a zero moist air flux account for the influence of moist air expansion/compression on density variations. In this study, we also re-examine mixing ratio issues. Our results indicate that the assumption of a zero dry air flux favors the use of the mixing ratio relative to dry air, while the assumption of a zero moist air flux favors the use of the mixing ratio relative to the total moist air. Additionally, we compare different formula for the mean vertical velocity, generated by air-parcel expansion/compression, and for density effect corrections using eddy covariance data measured over three boreal ecosystems.