Universal Encapsulation Adhesive for Lead Sedimentation and Attachable Perovskite Solar Cells with Enhanced Performance

In this work,a modified polyurethane adhesive(PUA)was prepared to realize a convenient encapsulation strategy for lead sedimentation and attachable perovskite solar cells(A-PSCs).The modified PUA can completely self-heal within 45 min at room temperature with an efficient lead ion-blocking rate of 99.3%.The PUA film can be coated on a metal electrode with slight efficiency improvement from 23.96%to 24.15%.The thermal stability at 65℃and the humidity stability at 55%relative humidity(RH)are superior to the devices encapsulated with polyisobutylene.The PUA film has strong adhesion to the flexible substrate and the initial efficiency of the flexible perovskite module(17.2%)encapsulated by PUA remains 92.6%within 1825 h.These results suggest that PUA encapsulation is universal for rigid and flexible PSCs with enhanced stability and low lead hazards.Moreover,it was found that flexible PSCs can be well attached to various substrates with PUA,providing a facile route for the A-PSCs in various scenarios without additional encapsulation and installation.

Attachment Styles and Traumatic Responses: Exploring the Impact of Parental Interaction on Child Development and Coping Mechanisms

This article explores the intricate relationship between attachment styles formed during early childhood and the subsequent responses to traumatic events, particularly the death of a parent. Drawing on the theoretical framework of attachment theory and incorporating contemporary research, the paper discusses how parental interactions shape the neural circuitry of infants and children, influencing their ability to form secure or insecure attachments. These attachment styles, in turn, play a critical role in determining the child’s coping mechanisms when faced with trauma. This paper focuses on trying to understand how attachment theory is connected to the reaction to trauma with a highlight on the four major styles of attachments which are secure, anxious, avoidant, and disorganized to mention but a few, and how they influence stress and adversity in children. Attachment theory holds that human beings’ ability to form affectional bonds in infancy determines their patterns of relatedness across the life cycle. The type of attachment that is secure usually supports healthy adaptation and good coping mechanisms regardless of the trauma in the childhood of the child. While secure attachment mostly facilitates favorable trauma-related outcomes, anxious or avoidant attachment can exacerbate or alter the responses. The caregiving system that is avoidant attachment has implications of autonomous self-functioning which has features of suppression of the emotional response and poor search for emotional support during stress. From the principles of developmental psychology and trauma theory, the paper also focuses on the major significance of the child’s early caregivers’ interactions that define the resilience and vulnerability factor. This knowledge is therefore critical in designing specific interventions based on the improvement of coping behaviors and emotional regulatory systems of children who have been exposed to trauma. Finally, we have the synthesis of new knowledge about the role of secure attachment relationships as its fundamental element in shaping adaptive traumatization and psychological development. The article also delves into the physiological processes involved in emotional regulation and the role of cortisol in disrupting attachment. Finally, the implications of these findings for therapeutic interventions and the challenges of addressing prolonged grief and traumatic responses in clinical settings are considered.

Mechanism of Tourists’Happiness in Traditional Village Tourism: A Perspective Grounded in Nostalgia and Cultural Attachment

In recent years,traditional villages have emerged as popular tourist destinations due to their distinctive resource value.Typically situated in remote and less developed areas,traditional villages boast primitive natural surroundings and rich historical and cultural heritage.These characteristics offer urban dwellers a temporary escape from the complexities of modern life,allowing them to experience physical and mental rejuvenation,mental relaxation,and overall happiness during their visit.By conducting a review of the existing literature concerning tourists’happiness in traditional villages,this study establishes a framework to understand tourists’happiness in traditional village tourism.Using the Qiangang ancient village in Conghua District,Guangzhou as a case study,the research examines the current state of rural characteristics,the establishment of cultural brands,and the promotion of the active utilization of ancient villages within the context of integrating culture,sports,tourism,and agriculture.Based on this analysis,the author proposes strategies to enhance tourists’happiness,including the preservation and development of rural characteristics,the promotion and preservation of local cultural attributes,and the collaborative advancement of culture,sports,tourism,and agriculture to engage key stakeholders actively.

Alleviation for contact stresses in curvic attachments

This paper studied the contact stresses in curvic attachments.The principal purpose of this research is to employ a method of alleviating the fluctuating hoop stresses which can be considered to be a major contribution to fatigue failure in curvic attachments.This method entails novel precision geometry of the contacting flat on curvic which is a tactic to get appropriate arc heights in in-plane direction as well as vary radius in out-of-plane direction.The dimensional finite elements in both directions were analyzed.These analysis results indicated that significant reduction in fluctuating hoop stresses can be achieved by the proposed method,provided that the precision geometry is controlled sufficiently precisely.

Numerical simulation of constricted and diffusive arc–anode attachments in wall-stabilized transferred argon arcs

A numerical simulation is conducted to investigate arc-anode attachment behavior, especially the formation mechanism of the constricted arc attachment mode for the water-cooled anode of wall-stabilized transferred argon arcs. Argon molecular ions and the corresponding kinetic processes are included to the finite-rate chemistry model in order to capture the chemical nonequilibrium characteristics of the arc near the anode region. Modeling results show that constricted and diffusive arc–anode attachments can be self-consistently obtained at different arc currents while keeping other parameters unchanged. The dominant kinetic processes contributing to ionization and recombination in the arc center and fringes are presented. The results show that in arc fringes and the arc attachment region, molecular ion recombination plays an important role which leads to the rapid loss of electrons. The radial evolution of the production, loss and transport processes of electrons is further analyzed. It is found that for the constricted arc attachment mode, both the recombination and convection transport caused by the anode jet result in the loss of electrons at the arc fringes, which leads to the shrinkage of the arc column at the anode. The formation of the anode jet is due to the combined action of radial and axial Lorentz forces in the anode region.

New Mini Dental Implant Attachments versus O-ring Attachment after Cyclic Aging: Analysis of Retention Strength and Gap Space

Overdenture as a treatment modality for both partially and fully edentulous patients is costeffective and less expensive. The purpose of the present study was to examine the newly fabricated attachments by comparing them with conventional O-ring attachment in vitro in terms of retention force and cyclic aging resistance. A total of 150 samples were prepared and divided into five groups according to the materials used(O-ring attachment, Deflex M10 XR, Deflex Classic SR, Deflex Acrilato FD, and flexible acrylic resin). The retention force of different attachments was measured by a mini dental implant after three subsequent aging(0, 63, and 126) cycles in the circumstances similar to the oral environment. The gap space between the head of the implant and the inner surface of the attachments was detected. Two-way analysis of variance(ANOVA) analysis with multiple comparisons test was applied for statistical analysis. The results showed that Deflex M10 XR had the highest retention force and the lowest gap space after cyclic aging; in addition, by comparing the relative force reduction, the lowest values were obtained in the O-ring attachment and the highest values in the flexible acrylic resin attachment. The retention force measured after cyclic aging for the Deflex M10 XR attachment was greatly improved when compared with the O-ring attachment and other types of attachment materials; in addition, the Deflex M10 XR attachment exhibited the minimum gap space between the inner surface and the mini dental implant head. In conclusion, Deflex M10 XR has the ability to withstand weathering conditions and retains its durable and retentive properties after aging when compared with other attachments.

The characteristics of the spindle fiber attachments (SFAs) enriched fraction from mouse nuclei

The characteristics of the particulate mouse centromere enriched fraction from isolated nuclei obtained in our laboratory were investigated by indirect immunoflu-orescence, test of the activity of microtubule organizing center(MTOC), SDS-PAGE, and fluorescence in situ hybridization. Most of the particles of the fraction are complexes of DNA and kinetochore proteins and show MTOC activity. The DNA isolated from the fraction can hybridize with DNA in the regions of the primary constrictions of all chromosomes of ascites cells. The kinetochore proteins isolated from the fraction are mainly those with molecular weight of 55 KD and 59 KD. Results suggested that the fraction obtained is a centromere enriched nuclear fraction as indicated in our previous report.

Ecological Loss & Our Passionate Attachments

The ecological conditions that underlie much of human flourishing still receive scant attention from moral philosophers.While interest in philosophy of ecology has grown in recent years,ethicists are still reluctant to grant ecological issues the status they arguably deserve.These issues are not restricted to custodianship of the natural world;they also pertain to our ability to enjoy love relationships and other passionate attachments.While the connection between human flourishing and love relationships has an ancient provenance,recently philosophers such as Harry Frankfurt,Bernard Williams,and Susan Wolf have emphasised it.Nevertheless,the ecological conditions of our passionate attachments remain obscure.This chapter investigates the extent that passionate attachments are underwritten by a delicate balance of ecological conditions.To do this,the author examines the effects of the pandemic caused by the novel coronavirus,SARS-CoV-2,which has threatened a key aspect of passionate attachments:our sociality.

ONE CASE REPORT OF REHABILITATION OF MIDFACIAL DEFECT USING SEMI-PRECISION ATTACHMENTS

Objective To discuss the application of semi-precision attachment in restoring a midfacial defect, including a nasal, upper lip, and anterior maxillary defect. Methods A splinted metal-ceramic crowns （from the upper right first molar to left molar） and a bar with stud attachments was done. A removable partial denture （RPD） containing the patrix portion of the attachment was then designed to restore the missing maxillary anterior teeth and alveolar ridge. Finally,, The facial prosthesis was joined to the denture utilizing two retentive metal posts on the superior aspect of the removable partial. Results A splinted metal-ceramic crowns （from the upper right frst molar to left molar） and a bar with stud attachments was done. A RPD containing the patrix portion of the attachment was then designed to restore the missing maxillary anterior teeth and alveolar ridge. Finally, The facial prosthesis was joined to the denture utilizing two retentive metal posts on the superior aspect of the removable partial. The prosthesis markedly improved the appearance of the patient and demonstrated good retention. Conclusion Using attachment in restoring rnaxillofacial defect may provide adequate retetion which lead to a sucessful treatment outcome.

Numerical Study on the Pulsation Characteristics of An Attached Air Bubble Under A Nearby Oscillating Bubble

Numerical simulations of the non-spherical evolution of a pulsating bubble interacting with a stationary air bubble attached to a fixed structure were performed using a three-dimensional boundary integral method by implementing the mirror image method to simplify the processing of the numerical model. Code validation was accomplished by comparing the numerical results with the laboratory experimental data obtained in our previous study. Complex phenomena were observed, including three types of bubble jet forms, which depended strongly on the distance parameter with respect to the initial location of the bubble from the plate, the bubble strength parameter and the initial air bubble radius parameters. The results of the simulations provide detail insight into interesting bubble jetting phenomena,such as bubble splitting, jets moving away from the plate, and bubble shedding. The dimensionless distance parameter and the initial air bubble radius parameter play a major role in determining the shapes of two bubbles and the jetting direction. The air bubble strength parameter did not change the bubble jet direction but influenced the bubble shape.The detachment of the attached air bubble under oscillating bubble suction was easily observed for a small initial air bubble. These results showed that bubble jetting toward the plate was manipulated through the effect of attached air bubble, and that cavitation-based applications and underwater explosion bubble may benefit from this erosion mitigation approach.

Morphology prediction of dihydroxylammonium 5,5'-bistetrazole-1,1'-diolate (TKX-50) crystal in different solvent systems using modified attachment energy model

In order to theoretically study the growth morphology of dihydroxylammonium 5,5’-bistetrazole-1,1’-dio late(TKX-50)crystal in different solvent systems,crystal–solvent models were established,and then molecular dynamics(MD)methods were adopted as a means to simulate particle motion.Modified attachment energy(MAE)model was employed to calculate the growth morphology of TKX-50.The simulation results demonstrate that COMPASS force field and RESP charge are suitable for molecular dynamics simulation of TKX-50.The morphologically dominant growth surfaces of TKX-50 in vacuum are(020),(011),(11–1),(100)and(120),respectively.In water(H_(2)O)and N,N-dimethylformamide(DMF)solvents,the(11–1)face is the largest in the habit face,the growth rate of(020)face becomes faster.With the increase of temperature,the aspect ratios of TKX-50 crystal in DMF solvent increase,and the areas of the(120)faces decrease.In ethylene glycol/H_(2)O mixed solvent system with volume ratio of 1/1,aspect ratio of TKX-50 is relatively small.In formic acid/H_(2)O mixed solvents with different volume ratios(1/4,1/3,1/2,1/1 and 2/1),aspect ratio of TKX-50 is relatively small when volume ratio is 1/2.

Relationship between Parent-Child Attachment and Problem Behaviors among Chinese Firstborn Children in Family Transitions: A Meta-Analysis

The implementation of China’s three-child fertility policy has led to a notable increase in multiple-child families.Notably,firstborn children experience a significant transition from being an only child to a non-only child.This transition is associated with problematic behaviors,affecting their social adjustment,sibling relationships,and family harmony.Although several studies have examined the relationship between parent-child attachment and problem behaviors exhibited byfirstborn children during family transitions,thefindings have been inconsistent.Hence,a meta-analytic study was undertaken to elucidate the inconsistencies in this relationship and explore the moderating factors that may contribute to these discrepancies.Using a systematic literature retrieval and screening method,12 effect sizes were derived from the 10 eligible articles,encompassing a sample size of 5319.The meta-analysis demonstrated a low negative association between parent-child secure attachment and problem behaviors exhibited byfirstborn children during family transitions.Furthermore,the present study investigates potential moderator factors,such as children’s age and geographic region,to gain a more nuanced understanding of the relationship.Consequently,the establishment of parent-child attachment relationships has the potential to mitigate problem behaviors observed infirst-born children during family transitions.The implications of thesefindings indicate that parents can nurture secure attachment bonds with their children by demonstrating sensitive responsiveness,employing positive parenting practices,and fostering emotional availability.These efforts contribute to the cultivation of secure internal working models and positive behavioral manifestations withinfirst-born children,which in turn affect their relationships with siblings.

Cytokine changes and embryo attachment in mouse endometrial cells following treated with peripheral blood mononuclear cells(PBMCs)expressing ectopic hCG,and hCG-activated PBMCs

Objective:To compare the effect of human chorionic gonadotropin(hCG)-producing peripheral blood mononuclear cells(PBMCs)and PBMCs activated by hCG in vitro and expressions of related immune genes in mouse implantation.Methods:hCG-producing PBMCs(transfected PBMC)and PBMCs activated by hCG in vitro were introduced into isolated mouse endometrial cells,while cell cultures were divided into four groups:the control,PBMC,transfected,and activated PBMC groups.The expression of studied genes(IL-1β,IL-6,Lif,and Vegf)was evaluated and blastocyst attachment on the cocultured cells(isolated endometrial cells and PBMC cells)was monitored in all four groups.Results:Data showed that expression decreased in the PBMC group compared to the treated PBMC(transfected and activated PBMCs)and increased in transfected PBMC compared to the activated PBMC.Attachment and migration of blastocysts were dramatically enhanced in the transfected PBMC group compared to the activated PBMC group(P<0.05).Conclusions:Use of hCG-producing PBMCs(transfected PBMC)has more influence on endometrial receptivity.

Landscape Upgrading and Transformation of Old Urban Parks from the Perspective of Place Attachment:A Case Study of Nanchang Bayi Park

On the basis of combing the relevant theories of place attachment, the planning framework of upgrading and reconstruction of old parks based on place attachment was put forward. Taking Nanchang Bayi Park as an example, the methods and key points of landscape improvement and transformation of old urban parks based on place attachment were explained to provide new ways and references for the renewal of old urban parks.

The Evolving Bipartite Network and Semi-Bipartite Network Models with Adjustable Scale and Hybrid Attachment Mechanisms

The bipartite graph structure exists in the connections of many objects in the real world, and the evolving modeling is a good method to describe and understand the generation and evolution within various real complex networks. Previous bipartite models were proposed to mostly explain the principle of attachments, and ignored the diverse growth speed of nodes of sets in different bipartite networks. In this paper, we propose an evolving bipartite network model with adjustable node scale and hybrid attachment mechanisms, which uses different probability parameters to control the scale of two disjoint sets of nodes and the preference strength of hybrid attachment respectively. The results show that the degree distribution of single set in the proposed model follows a shifted power-law distribution when parameter r and s are not equal to 0, or exponential distribution when r or s is equal to 0. Furthermore, we extend the previous model to a semi-bipartite network model, which embeds more user association information into the internal network, so that the model is capable of carrying and revealing more deep information of each user in the network. The simulation results of two models are in good agreement with the empirical data, which verifies that the models have a good performance on real networks from the perspective of degree distribution. We believe these two models are valuable for an explanation of the origin and growth of bipartite systems that truly exist.

基于残余砂浆附着特征的再生混凝土硫酸盐传输模型

已有再生混凝土计算模型未充分考虑残余砂浆附着特征,导致模型中缺少新砂浆-原生骨料界面过渡区,道路工程混凝土硫酸盐传输模型与实际情况不符。本工作根据瓦拉文公式将三维骨料体积转换为二维平面圆形,并根据图像分析法测得的残余砂浆附着特征将不同粒径的骨料分割成残余砂浆和裸露骨料两部分,随后利用蒙特卡罗方程将分割后的再生骨料于混凝土体系中随机投放,构建了再生混凝土的六相数字化模型。通过再生骨料截面面积确定、再生骨料数据库建立等过程,提出六相混凝土数字化模型中再生骨料残余砂浆附着特征的表达方法。基于Fick第二定律,结合孔隙率对再生混凝土中各相扩散系数的影响分析,提出再生混凝土中各相扩散系数方程。通过有限元软件实现了六相再生混凝土的二维可视化,建立了六相再生混凝土硫酸根离子传输模型。通过将试验测试值与模型计算值进行对比,得出试验结果与计算结果总体吻合度良好,理论计算结果与实验所测离子传输深度的变化规律是一致的,建立的基于残余砂浆附着特征的再生混凝土硫酸盐传输模型具有一定的合理性。

无托槽隐形矫治器扩展上颌牙弓时附件差异对后牙位移的三维有限元分析

目的:利用全牙列精准扫描建模分析无托槽隐形矫治器扩展上颌牙弓时对后牙三维位移的影响。方法:选择2017年1月-2022年6月就诊于笔者医院口腔正畸科的86例成年患者为研究对象。所有患者均为安氏I类错牙合,矫治方案设计为仅通过邻面去釉的方式排齐上下前牙,在全牙列精准扫描建模的基础上,构建无托槽隐形矫治器进行上颌牙弓扩弓前以及扩弓后的后牙三维方向有限元模型的对比。结果:第5组位移量的最大值(3.315 17)与最小值(3.139 25)的比值均为所有组别中最小的。与其他组相比,第5组位移最小值与根尖的距离更近;第5组的第二前磨牙对应得到的等效应力值最小,应力的分布更为均匀。结论:施加附件作用时,对前磨牙的控根效果显著优于磨牙,其中优化后扩弓支持附件对后牙的控根效果更为优秀。

乡村性感知、地方依恋与未来行为意向关系研究——以江西省靖安县三坪村寄宿避暑度假者为例

乡村旅游吸引力的本质在于乡村性,以往研究鲜有以乡村性感知为驱动因素探讨度假者的未来行为意向影响机制。本文选取江西省靖安县三坪村为案例地,开发寄宿避暑度假者乡村性感知、地方依恋与未来行为意向关系测量量表并构建概念模型。实证研究表明:度假者乡村性感知显著正向影响地方依赖、地方认同、未来行为意向;度假者地方依赖显著正向影响地方认同、未来行为意向,地方认同显著正向影响未来行为意向;度假者地方依赖、地方认同在乡村性感知与未来行为意向间均具有显著中介效应,地方依赖与地方认同在度假者乡村性感知和未来行为意向间具有显著链式中介效应。因此,三坪村应关注具身范式旅游体验,精准把控度假者乡村性感知;多维度提升乡村性感知,助力度假者正向行为生成。

湍流环境下颗粒与气泡黏附过程的数值模拟研究

研究湍流环境中颗粒与气泡的黏附过程对于探究浮选微观过程具有重要意义。基于EDEM的API(应用程序编程接口)二次开发模块,建立了颗粒与气泡黏附过程相互作用的三维离散元法(DEM)模型。在Fluent软件中通过构建规则格栅以激发各向同性的湍流,并将湍流环境通过计算流体力学-离散元(CFD-DEM)加入到EDEM软件中。模拟了颗粒粒径为0.10、0.15、0.20、0.25和0.30 mm,颗粒密度为1500、2000和2500 kg/m^(3),球形度为0.746~0.854的不规则颗粒,和气泡直径为1.00、1.20、1.60和2.00 mm,在气泡与格栅间距离为1.00、1.50、2.00和3.00 mm的湍流环境下颗粒与气泡的黏附过程。研究了颗粒、气泡、流场各参数对于颗粒与气泡黏附过程的影响。结果发现,无论规则颗粒还是不规则颗粒在湍流环境中与气泡的黏附均存在临界脱附流速(颗粒与气泡发生脱附的最小湍流流场流速)。密度大的颗粒和粒径大的颗粒与气泡黏附的临界脱附流速更小,表明粒径和密度大的颗粒与气泡难以稳定黏附。气泡的直径越大,颗粒与气泡稳定黏附的临界脱附流速越小,颗粒越难以稳定黏附。在相同的流速下,气泡与格栅间距离越小,则流场湍流强度越大,颗粒与气泡稳定黏附的临界脱附流速越小,表明湍流强度的增加不利于颗粒与气泡的稳定黏附。球形度小的颗粒与气泡稳定黏附的临界脱附流速也较小,表明球形度小的颗粒与气泡难以稳定黏附。

大学生自杀意念与亲子依恋和同伴依恋及生命意义感的关系

目的:探讨大学生自杀意念与亲子依恋的关系,以及同伴依恋和生命意义感在其中的作用。方法:选取1137名大学生,采用自杀意念量表(PANSI)考察自杀意念、修订版父母同伴依恋量表(IPPA-R)考察亲子依恋和同伴依恋、生命意义量表(MLQ)考察生命意义感。结果:父子依恋、母子依恋、同伴依恋、拥有意义、寻求意义得分与PANSI得分均呈负相关(r=-0.51~-0.19,均P<0.001)。同伴依恋与拥有意义的中介作用及链式中介作用效应值分别是-0.08、-0.16、-0.04,分别占总效应的13.83%、25.83%、6.17%。结论:大学生亲子依恋与自杀意念相关,可以通过提升同伴依恋水平、提高拥有意义感来降低自杀意念。