The evolution of southwest Montana’s Big Hole and Beaverhead River drainage basins is determined from topographic map evidence related to mountain passes crossing what are today high altitude drainage divides includi...The evolution of southwest Montana’s Big Hole and Beaverhead River drainage basins is determined from topographic map evidence related to mountain passes crossing what are today high altitude drainage divides including North America’s east-west Continental Divide. Map evidence, such as orientations of valleys leading away from mountain passes (and saddles) and barbed tributaries found along the downstream drainage routes, is used to reconstruct flow directions of streams and rivers that once crossed the present-day high mountain divides. Large south-oriented anastomosing complexes of diverging and converging channels are interpreted to have eroded what are today closely spaced passes and saddles now notched into high mountain ridges. Water in those south-oriented channels is interpreted to have flowed across emerging mountains and subsiding basins. Headward erosion of deeper southeast-oriented valleys, assisted by crustal warping, concentrated south-oriented water in fewer and deeper valleys as the water flowed from southwest Montana into what are today Idaho and the Snake River drainage basin. Headward erosion of the Big Hole River valley between the emerging Anaconda and Pioneer Mountains, also assisted by crustal warping, reversed all Big Hole Basin drainage so as to create the north-, east-, and south-oriented Big Hole River drainage route. A final and even more major reversal of flow in the present-day north-oriented Montana Missouri River valley, with the assistance of additional crustal warping, next ended all remaining flow to Idaho and the Snake River drainage basin and reversed and captured all drainage in the present-day north-oriented Big Hole, Beaverhead, and Red Rock River drainage basins. The observed map evidence indicates that prior to the final flow reversal events, large volumes of south-oriented water flowed across southwest Montana’s Big Hole and Beaverhead River drainage basins.展开更多
Sixty-five natural gas samples were collected from 19 oil-gasfields in theQaidam basin, China. The chemical composition and carbon isotope values of the samples weremeasured, and the geochemical characteristics and or...Sixty-five natural gas samples were collected from 19 oil-gasfields in theQaidam basin, China. The chemical composition and carbon isotope values of the samples weremeasured, and the geochemical characteristics and origin of the natural gases were studied. Thegases can be divided into biogenic gases, sapropelic oil-type gases, mixed type oil-type gases,coal-type gases and mixed gas. The delta^(13)C_1 values of the biogenic gases are very small and theC_2^+ contents of them are very low, ranging from -68.2 per thousand to -61 .8 per thousand and0.06 percent to 0.20 percent respectively. They have heavy delta D and delta^(13)C_(CO_2), showing aCO_2 reduction pathway. They ,are distributed in the East depression region and derived from theQuaternary source rocks. The sapropelic oil-type gases have small delta^(13)C_2 values and highC_2^+ ranging from -36.6 per thousand to -28.6 per thousand and from 33.01 percent to 47.15 percentrespectively. The mixed type oil-type gases have delta^(13)C_2 values and C_2^+ contents varyingfrom -28.6 per thousand to -24.8 per thousand and from 4.81 percent to 26.06 percent respectively.Both sapropelic oil-type gases and mixed type oil-type gases are associated with oil-type oils,distributed in the West depression region and derived from the Tertiary saltwater lacustrinesapropelic source rocks and humic source rocks respectively. The delta^(13)C_2 values of thecoal-type gases are extremely high and the C_2^+ contents are very low, changing from -23.3 perthousand to -12.5 per thousand and from 0.06 percent to 18.07 percent respectively. The coal-typegases in the Nanbaxian gasfield and the Lenghu oil-gasfields in the North fault block belt arederived from the Middle Jurassic coal-measures source rocks, whereas those in the West depressionregion are derived from the Tertiary saltwater lacustrine humic source rocks. Compared with someother basins in China, the natural gases there have obviously heavier delta^(13)C due to the heavierdelta^(13)C of different types of kerogens of the Tertiary saltwater lacustrine source rocks in theWest depression region of the basin. The mixing of natural gases is common in the West depressionregion, but the mixed gases are formed by sapropelic oil-type gases, mixed type oil-type gases orcoal-type gases, respectively, of different levels of maturity. Most of the sapropelic oil-typegases and mixed type oil-type gases in the west part are thermally immature and low-mature, but thecoal-type gases in the West depression region and the North fault block belt are mature and high- toover-mature.展开更多
The concentration of hydrogen sulfide gas (H2S) varies greatly in the oil-bearing basins of China, from zero to 90%. At present, oil and gas reservoirs with high H2S concentration have been discovered in three basin...The concentration of hydrogen sulfide gas (H2S) varies greatly in the oil-bearing basins of China, from zero to 90%. At present, oil and gas reservoirs with high H2S concentration have been discovered in three basins, viz. the Bohai Bay Basin, Sichuan Basin and the Tarim Basin, whereas natural gas with low H2S concentration has been found in the Ordos Basin, the Songliao Basin and the Junggar Basin. Studies suggest that in China H2S origin types are very complex. In the carbonate reservoir of the Sichuan Basin, the Ordos Basin and the Tarim Basin, as well as the carbonatedominated reservoir in the Luojia area of the Jiyang depression in the Bohai Bay Basin, Wumaying areas of the Huanghua depression, and Zhaolanzhuang areas of the Jizhong depression, the H2S is of Thermochemical Sulfate Reduction (TSR) origin. The H2S is of Bacterial Sulphate Reduction (BSR) origin deduced from the waterflooding operation in the Changheng Oilfield (placanticline oil fields) in the Songliao Basin. H2S originates from thermal decomposition of sulfur-bearing crude oil in the heavy oil area in the Junggar Basin and in the Liaohe heavy oil steam pilot area in the western depression of the Bohai Bay Basin. The origin types are most complex, including TSR and thermal decomposition of sulfcompounds among other combinations of causes. Various methods have been tried to identify the origin mechanism and to predict the distribution of H2S. The origin identification methods for H2S mainly comprise sulfur and carbon isotopes, reservoir petrology, particular biomarkers, and petroleum geology integrated technologies; using a combination of these applications can allow the accurate identification of the origins of H2S. The prediction technologies for primary and secondary origin of H2S have been set up separately.展开更多
Exploration and development experience show that there is obvious oil gravity difference between the southern part and northern part of the "M1"reservoir in the Fanny oil field in the slope of the Oriente Basin, Ecu...Exploration and development experience show that there is obvious oil gravity difference between the southern part and northern part of the "M1"reservoir in the Fanny oil field in the slope of the Oriente Basin, Ecuador. The American Petroleum Institute Gravity (API) values of oils in the northern part are higher than the one in the southern part of the Fanny oil field, with the values of 20° and 10.0°-13.0°, respectively. So the primary purpose of this study was to analyze the heavy oil characteristics of biodegradation and the oil-oil correlation according to the biomarker data and the δ^13C signature of oil samples from T block. The results of the hydrocarbon gas chromatography fingermark and the inversion attribute characteristics indicated that there are fluid compartments between the "M1" reservoir of Fanny south. Finally, the models of oil-gas accumulation under the control of multiple-activities of complicated fault systems, as well as the origin of heavy oil, are contended. The early stage oils from the western part of the basin were biodegraded heavily in varying degrees in the whole basin, and the later stage oils were derived from the southern part in a large scale and were mature and lighter. Generally, oil mixing is the primary control of net oil properties, such as API gravity in Oriente Basin. We therefore predicted that the API gravity variation of oil pools radically depends on the injection amount of the later stage oil. Because of the shale barrier in the "M1"reservoir of Fanny south, the later stage hydrocarbon could not pass through and contribute to increase the oil API value.展开更多
Original organisms are the biological precursors of organic matter in source rocks. Original organisms in source rocks are informative for oil-source rock correlation and hydrocarbon potential evaluation, especially f...Original organisms are the biological precursors of organic matter in source rocks. Original organisms in source rocks are informative for oil-source rock correlation and hydrocarbon potential evaluation, especially for source rocks which have high-over level of thermal maturity. Systematic identification of original organism assemblages of the Lower Paleozoic potential source rocks and detailed carbon isotopic composition of kerogen analyses were conducted for four outcrop sections in the Tarim basin. Results indicated that the original organism assemblages of the lower part of the Lower Cambrian were composed mainly of benthic algae, whereas those of the Upper Cambrian and the Ordovician were characterized by planktonic algae. Kerogen carbon isotopic data demonstrated that the δ13 Ckerogen values of source rocks dominated by benthic algae are lower than-34‰, whereas the δ13 Ckerogen values of source rocks dominated by planktonic algae are higher than-30‰ in general. We tentatively suggested that the carbon species those are utilized by algae and the carbon isotopic fractionation during photosynthesis are the major controls for the δ13 Ckerogen values in the Lower Paleozoic source rocks in the Tarim basin. Correlating the δ13 C values of oils exploited in the Tarim basin, the original organism assemblages, and δ13 Ckerogen values of source rocks, it implied that the Lower Paleozoic oils exploited in the Tarim basin should be sourced from the source rocks with original organism assemblages dominated by planktonic algae, and the hydrocarbon sourced from the Cambrian benthic algae should be of great exploration potential in future. Original organism assemblages in source rocks can provide important clues for oil-source rocks correlation, especially for the source rocks with high thermal maturity.展开更多
The stable isotope has been extensively applied as an effective tracer especially in precipitation. In glacierized area of arid northwest China, temperature is widely considered to be a major factor affecting isotopes...The stable isotope has been extensively applied as an effective tracer especially in precipitation. In glacierized area of arid northwest China, temperature is widely considered to be a major factor affecting isotopes in precipitation, while the influences of precipitation amount, relative humidity and other meteorological parameters are still not clear. Based on analyses on stable isotope values of water samples and NCEP/NCAR(National Centers of Environmental Prediction/National Center for Atmospheric Research, USA) re-analysis data, the moisture source and characteristics of isotopes in the precipitation, meltwater and river water isotopes at Urumqi Glacier No.1 of the upstream Urumqi River Basin, eastern Tianshan Mountains from spring to autumn during four years(from 2008 to 2011) was studied. Results indicated that meltwater are the main source of water for the upper Urumqi River. Seasonal variation of δ18 O in precipitation demonstrated that δ18 O was more enriched in summer and depleted in spring and autumn. Temperature was positively correlated with isotopes, while precipitation amount and relative humidity was negatively correlated with isotopes. The water vapor was affected by westerly air mass and regional water vapor cycle. Meanwhile, back trajectory clustering analyses showed that the moisture mainly from Europe and central Asia. The moisture was more likely to be locally sourced with the ratio was 46.8%~52.1%.展开更多
Chemical and isotopic data were measured for 51 leached brine springs in the Changdu-Lanping-Simao Basin(CD-LP-SM),China.The predominance of Cl and Na,saturation indices of carbonate minerals,and Na/Cl and Ca/SO4 rati...Chemical and isotopic data were measured for 51 leached brine springs in the Changdu-Lanping-Simao Basin(CD-LP-SM),China.The predominance of Cl and Na,saturation indices of carbonate minerals,and Na/Cl and Ca/SO4 ratios of^1 suggest that halite,sulphate,and carbonate are the solute sources.Integration of geochemical,δ18 O,andδD values suggests that springs are mainly derived from meteoric water,ice-snow melt,and water-rock interactions.B concentrations range from 0.18 to 11.9 mg/L,withδ11 B values of-4.37‰to+32.39‰,indicating a terrestrial source.Theδ11 B-B relationships suggest B sources of crustal origin(marine carbonates with minor crust-derived volcanics);we did not identify a marine or deep mantle origin.Theδ11 B values of saline springs(+4.61‰to+32.39‰)exceed those of hot(-4.37‰to+4.53‰)and cold(-3.47‰to+14.84‰)springs;this has contributed to strong water-rock interactions and strong saturation of dissolved carbonates.Conversely,the global geothermalδ11 B-Cl/B relationship suggests mixing of marine and non-marine sources.Theδ11 B-Cl/B relationships of the CD-LP-SM are similar to those of the Tibet geothermal belt and the Nangqen Basin,indicating the same B origin.These differ from thermal waters controlled by magmatic fluids and seawater,suggesting that B in CD-LP-SM springs has a crustal origin.展开更多
Having studied the biomarker composition and maturity of dissolved hydrocarbons from Ordovician formation waters, the authors presented molecular geochemical evidence for the controversial origin of natural gases in c...Having studied the biomarker composition and maturity of dissolved hydrocarbons from Ordovician formation waters, the authors presented molecular geochemical evidence for the controversial origin of natural gases in central Ordos Basin.The dissolved hydrocarbons in Well Shan 12 and Well Shan 78 are relatively high in abundance of tricylic terpane, pregnane series and dibenzothiophene series and low in Pr/Ph and hopane/sterane ratios, indicating the source input of marine carbonates. In contrast, the dissolved hydrocarbons in Well Shan 81 are free from tricyclic terpane and pregnane series, with trace dibenzothiophene series and high Pr/Ph and higher hopane/sterane ratios, which are the typical features of terrestrial organic matter. Furthermore, Well Shan 37 and Well Shan 34 are between the two situations, having a mixed source of marine carbonate and terrestrial organic matter. The maturity of biomarkers also supports the above suggestions. These results are consistent with the geological background and source rock distribution in this region.展开更多
Natural gas pools with the high contents of CO2 were discovered during exploring the middle fault zone of the Hailar-Tamtsag Basin. So far this kind of gas reservoir with CO2 with characteristics of carbon isotope is ...Natural gas pools with the high contents of CO2 were discovered during exploring the middle fault zone of the Hailar-Tamtsag Basin. So far this kind of gas reservoir with CO2 with characteristics of carbon isotope is spe-cial. The stable carbon isotope of CO2 in the study area is relatively light with δ13 CCO2 values ranging from -13.1‰ to -8.2‰. The 40Ar/36Ar values of associated argon gas range from 916 to 996, with R/Ra of 1.20-1.26. Based on comprehensive analysis, it is believed that the CO2 gas in this study area is of crust mantle source.展开更多
Dolostones in the Cambrian Longwangmiao Formation have become one of the most significant gas exploration domains in China. Over a trillion cubic meters of gas reservoirs have been discovered in the Gaoshiti-Moxi area...Dolostones in the Cambrian Longwangmiao Formation have become one of the most significant gas exploration domains in China. Over a trillion cubic meters of gas reservoirs have been discovered in the Gaoshiti-Moxi area; however, the origins and distribution of the dolostone reservoirs are not well understood. This work discussed the geology and geochemistry of the dolostone reservoirs in the Longwangmiao Formation to determine their origin and distribution. Two understandings are acquired: firstly, a carbonate ramp provided excellent conditions for grain beach deposition, while the presence of a hypersaline lake was favorable for the contemporaneous dolomitization of grain beach deposits. Petrographic and geochemical evidence further confirm that the Longwangmiao dolostone was formed during the contemporaneous stage. Secondly, the reservoir characteristics indicate that the grain beach sediments provide material basis for the development of the Longwangmiao dolostone reservoirs. Reservoir dissolution simulation experiments show that the porosity of the reservoirs was formed by dissolution during contemporaneous and burial stages. The dissolution pores formed during the contemporaneous stage were controlled by sequence interfaces. The large scale dissolution vugs formed during the burial stage subsequently spread along the pre-existing porosity and fracture zones. This study therefore identified that the development of grain dolostone reservoirs in a shallow water ramp under arid climatic conditions generally met the following conditions:(1) reefal beach deposits lay a foundation for reservoir development;(2) superficial conditions are an important determining factor for reservoir porosity; and(3) burial conditions provide environment for porosity preservation and modification.展开更多
The Yacheng gas field lies in the foot wall of the No. 1 fault, the boundary fault between the Yinggehai and Qiongdongnan basins. An overpressured system developed in the Meishan Formation near the No. 1 fault in the ...The Yacheng gas field lies in the foot wall of the No. 1 fault, the boundary fault between the Yinggehai and Qiongdongnan basins. An overpressured system developed in the Meishan Formation near the No. 1 fault in the gas field and in the adjacent Yinggehai basin. Away from this fault into the Qiongdongnan basin, the overpressure diminishes. Below 3 600 m in the gas field, an obvious thermal anomaly occurs. The gases show obvious compositional heterogeneities which reflect reservoir filling process and origin of the gas field. The gas field was charged from both the Qiongdongnan and the Yinggehai basins but mainly from the former. Hydrocarbons sourced from the Qiongdongnan basin have relatively low maturities while hydrocarbons from the Yinggehai basin have relatively high maturities.展开更多
Chemistry of major and minor elements,87Sr/86Sr,δD,δ18O and δ34S of brines were measured from Tertiary strata and Quaternary salt lakes in the western Qaidam Basin.The water chemistry data show that all oilfield br...Chemistry of major and minor elements,87Sr/86Sr,δD,δ18O and δ34S of brines were measured from Tertiary strata and Quaternary salt lakes in the western Qaidam Basin.The water chemistry data show that all oilfield brines are CaCl2 type.They were enriched in Ca2+,B3+,Li+,Sr2+,Br-,and were depleted in Mg2+,SO42-,which indicated that these brines had the characteristics of deeply circulated water.The relationship between δD and δ18O shows that all data of these brines decline towards the Global Meteoric Water Line(GWL) and Qaidam Meteoric Water Line(QWL),and that the intersection between oilfield brines and Meteoric Water Lines was close to the local spring and fresh water in the piedmont in the western Qaidam Basin.The results suggest that oilfield brines has initially originated from meteoric water,and then might be affected by water-rock metamorphose,because most oilfield brines distribute in the range of metamorphosing water.The 87Sr/86Sr values of most oilfield brines range from 0.71121 to 0.71194,and was less than that in salt lake water(>0.712),but close to that of halite in the study area.These imply that salt dissolution occurred in the process of migration.In addition,all oilfield brines have obviously much positive δ34S values(ranging from 26.46‰ to 54.57‰) than that of salt lake brines,which was caused by bacterial sulfate reduction resulting in positive shift of δ34S value and depleteed SO42-in oilfield brines.Combined with water chemical data and δD,δ18O,87Sr/86Sr,δ34S values,we concluded that oilfield brines mainly originate from the deeply circulated meteoric waters,and then are affected by salt dissolution,water-rock metamorphose,sulfate reduction and dolomitization during the process of migration.These processes alter the chemical compositions of oilfield brines and accumulate rich elements(such as B,Li,Sr,Br,K and so on) for sustainable utilization of salt lake resources in the Qaidam Basin.展开更多
Based on the analytical data of over 30 gas samples, combined with geochemical and geological backgrounds, the composition and distribution characteristics of shallow biogenetic gases in the Baise Basin, a Tertiary re...Based on the analytical data of over 30 gas samples, combined with geochemical and geological backgrounds, the composition and distribution characteristics of shallow biogenetic gases in the Baise Basin, a Tertiary residual basin in southern China, were extensively investigated, and the origin and formation mechanism tentatively approached. The shallow gases are primarily composed of gaseous hydrocarbons, generally accounting for over 90%. The abundances of methane and C2+ homologues show a relatively wide range of variation, mainly 50%-100% and 0%-50%, respectively, depending on the mixing proportions between biogenetic and thermogenic gases. A highly negative carbon isotope is the significant signature for the shallow gases with δ^13C1 values of -55‰ to -75‰. According to molecular and isotopic compositions and light hydrocarbon parameters, the shallow gases in the basin can be classified into three types of origins: biogenetic gas, biogenetic/thermogenic mixed gas, and oii-biodegraded gas. They exhibit regular distribution both spatially and temporally, and are believed to be associated with the maturity of adjoining gas source rocks and biodegraded oil accumulation. The Baigang and Nadu source rocks can be considered to have experienced early and late gas generation during early burial and after basin uplift respectively. A late accumulation mechanism of multiple gas sources is put forward for the formation of the shallow gas reservoirs, which is responsible for the variations in chemical and isotopic composition of the gases in depth profile.展开更多
文摘The evolution of southwest Montana’s Big Hole and Beaverhead River drainage basins is determined from topographic map evidence related to mountain passes crossing what are today high altitude drainage divides including North America’s east-west Continental Divide. Map evidence, such as orientations of valleys leading away from mountain passes (and saddles) and barbed tributaries found along the downstream drainage routes, is used to reconstruct flow directions of streams and rivers that once crossed the present-day high mountain divides. Large south-oriented anastomosing complexes of diverging and converging channels are interpreted to have eroded what are today closely spaced passes and saddles now notched into high mountain ridges. Water in those south-oriented channels is interpreted to have flowed across emerging mountains and subsiding basins. Headward erosion of deeper southeast-oriented valleys, assisted by crustal warping, concentrated south-oriented water in fewer and deeper valleys as the water flowed from southwest Montana into what are today Idaho and the Snake River drainage basin. Headward erosion of the Big Hole River valley between the emerging Anaconda and Pioneer Mountains, also assisted by crustal warping, reversed all Big Hole Basin drainage so as to create the north-, east-, and south-oriented Big Hole River drainage route. A final and even more major reversal of flow in the present-day north-oriented Montana Missouri River valley, with the assistance of additional crustal warping, next ended all remaining flow to Idaho and the Snake River drainage basin and reversed and captured all drainage in the present-day north-oriented Big Hole, Beaverhead, and Red Rock River drainage basins. The observed map evidence indicates that prior to the final flow reversal events, large volumes of south-oriented water flowed across southwest Montana’s Big Hole and Beaverhead River drainage basins.
基金supported by the Major Program(Grant No.KZCX2-111)of Knowledge Innovation in the Field of Resources and Environment funded by the Chinese Academy of SciencesChinese National Natural Science Foundation(Grant nos.49972051 and 40172053).
文摘Sixty-five natural gas samples were collected from 19 oil-gasfields in theQaidam basin, China. The chemical composition and carbon isotope values of the samples weremeasured, and the geochemical characteristics and origin of the natural gases were studied. Thegases can be divided into biogenic gases, sapropelic oil-type gases, mixed type oil-type gases,coal-type gases and mixed gas. The delta^(13)C_1 values of the biogenic gases are very small and theC_2^+ contents of them are very low, ranging from -68.2 per thousand to -61 .8 per thousand and0.06 percent to 0.20 percent respectively. They have heavy delta D and delta^(13)C_(CO_2), showing aCO_2 reduction pathway. They ,are distributed in the East depression region and derived from theQuaternary source rocks. The sapropelic oil-type gases have small delta^(13)C_2 values and highC_2^+ ranging from -36.6 per thousand to -28.6 per thousand and from 33.01 percent to 47.15 percentrespectively. The mixed type oil-type gases have delta^(13)C_2 values and C_2^+ contents varyingfrom -28.6 per thousand to -24.8 per thousand and from 4.81 percent to 26.06 percent respectively.Both sapropelic oil-type gases and mixed type oil-type gases are associated with oil-type oils,distributed in the West depression region and derived from the Tertiary saltwater lacustrinesapropelic source rocks and humic source rocks respectively. The delta^(13)C_2 values of thecoal-type gases are extremely high and the C_2^+ contents are very low, changing from -23.3 perthousand to -12.5 per thousand and from 0.06 percent to 18.07 percent respectively. The coal-typegases in the Nanbaxian gasfield and the Lenghu oil-gasfields in the North fault block belt arederived from the Middle Jurassic coal-measures source rocks, whereas those in the West depressionregion are derived from the Tertiary saltwater lacustrine humic source rocks. Compared with someother basins in China, the natural gases there have obviously heavier delta^(13)C due to the heavierdelta^(13)C of different types of kerogens of the Tertiary saltwater lacustrine source rocks in theWest depression region of the basin. The mixing of natural gases is common in the West depressionregion, but the mixed gases are formed by sapropelic oil-type gases, mixed type oil-type gases orcoal-type gases, respectively, of different levels of maturity. Most of the sapropelic oil-typegases and mixed type oil-type gases in the west part are thermally immature and low-mature, but thecoal-type gases in the West depression region and the North fault block belt are mature and high- toover-mature.
基金supported by the National Natural Science Foundation of China (Grant Nos 4060201640773032)the National Basic Research Program of China (contract No.2007CB209500)
文摘The concentration of hydrogen sulfide gas (H2S) varies greatly in the oil-bearing basins of China, from zero to 90%. At present, oil and gas reservoirs with high H2S concentration have been discovered in three basins, viz. the Bohai Bay Basin, Sichuan Basin and the Tarim Basin, whereas natural gas with low H2S concentration has been found in the Ordos Basin, the Songliao Basin and the Junggar Basin. Studies suggest that in China H2S origin types are very complex. In the carbonate reservoir of the Sichuan Basin, the Ordos Basin and the Tarim Basin, as well as the carbonatedominated reservoir in the Luojia area of the Jiyang depression in the Bohai Bay Basin, Wumaying areas of the Huanghua depression, and Zhaolanzhuang areas of the Jizhong depression, the H2S is of Thermochemical Sulfate Reduction (TSR) origin. The H2S is of Bacterial Sulphate Reduction (BSR) origin deduced from the waterflooding operation in the Changheng Oilfield (placanticline oil fields) in the Songliao Basin. H2S originates from thermal decomposition of sulfur-bearing crude oil in the heavy oil area in the Junggar Basin and in the Liaohe heavy oil steam pilot area in the western depression of the Bohai Bay Basin. The origin types are most complex, including TSR and thermal decomposition of sulfcompounds among other combinations of causes. Various methods have been tried to identify the origin mechanism and to predict the distribution of H2S. The origin identification methods for H2S mainly comprise sulfur and carbon isotopes, reservoir petrology, particular biomarkers, and petroleum geology integrated technologies; using a combination of these applications can allow the accurate identification of the origins of H2S. The prediction technologies for primary and secondary origin of H2S have been set up separately.
文摘Exploration and development experience show that there is obvious oil gravity difference between the southern part and northern part of the "M1"reservoir in the Fanny oil field in the slope of the Oriente Basin, Ecuador. The American Petroleum Institute Gravity (API) values of oils in the northern part are higher than the one in the southern part of the Fanny oil field, with the values of 20° and 10.0°-13.0°, respectively. So the primary purpose of this study was to analyze the heavy oil characteristics of biodegradation and the oil-oil correlation according to the biomarker data and the δ^13C signature of oil samples from T block. The results of the hydrocarbon gas chromatography fingermark and the inversion attribute characteristics indicated that there are fluid compartments between the "M1" reservoir of Fanny south. Finally, the models of oil-gas accumulation under the control of multiple-activities of complicated fault systems, as well as the origin of heavy oil, are contended. The early stage oils from the western part of the basin were biodegraded heavily in varying degrees in the whole basin, and the later stage oils were derived from the southern part in a large scale and were mature and lighter. Generally, oil mixing is the primary control of net oil properties, such as API gravity in Oriente Basin. We therefore predicted that the API gravity variation of oil pools radically depends on the injection amount of the later stage oil. Because of the shale barrier in the "M1"reservoir of Fanny south, the later stage hydrocarbon could not pass through and contribute to increase the oil API value.
基金funded by National Natural Science Foundation of China (Grant No. U1663201, 41472099 and 41872155)the Strategic Priority Research Program of the Chinese Academy of Science (Grant No. XDA14010404)CNPC innovation Foundation (2016D-5007-0102)
文摘Original organisms are the biological precursors of organic matter in source rocks. Original organisms in source rocks are informative for oil-source rock correlation and hydrocarbon potential evaluation, especially for source rocks which have high-over level of thermal maturity. Systematic identification of original organism assemblages of the Lower Paleozoic potential source rocks and detailed carbon isotopic composition of kerogen analyses were conducted for four outcrop sections in the Tarim basin. Results indicated that the original organism assemblages of the lower part of the Lower Cambrian were composed mainly of benthic algae, whereas those of the Upper Cambrian and the Ordovician were characterized by planktonic algae. Kerogen carbon isotopic data demonstrated that the δ13 Ckerogen values of source rocks dominated by benthic algae are lower than-34‰, whereas the δ13 Ckerogen values of source rocks dominated by planktonic algae are higher than-30‰ in general. We tentatively suggested that the carbon species those are utilized by algae and the carbon isotopic fractionation during photosynthesis are the major controls for the δ13 Ckerogen values in the Lower Paleozoic source rocks in the Tarim basin. Correlating the δ13 C values of oils exploited in the Tarim basin, the original organism assemblages, and δ13 Ckerogen values of source rocks, it implied that the Lower Paleozoic oils exploited in the Tarim basin should be sourced from the source rocks with original organism assemblages dominated by planktonic algae, and the hydrocarbon sourced from the Cambrian benthic algae should be of great exploration potential in future. Original organism assemblages in source rocks can provide important clues for oil-source rocks correlation, especially for the source rocks with high thermal maturity.
基金supported by the Strategic Priority Research Program of Chinese Academy of Sciences (XDA20020102 XDA20060201)+2 种基金National Natural Science Foundation of China (International (regional) cooperation and exchange projects) (41761134093)National Natural Science Foundation of China (41471058 41771077)
文摘The stable isotope has been extensively applied as an effective tracer especially in precipitation. In glacierized area of arid northwest China, temperature is widely considered to be a major factor affecting isotopes in precipitation, while the influences of precipitation amount, relative humidity and other meteorological parameters are still not clear. Based on analyses on stable isotope values of water samples and NCEP/NCAR(National Centers of Environmental Prediction/National Center for Atmospheric Research, USA) re-analysis data, the moisture source and characteristics of isotopes in the precipitation, meltwater and river water isotopes at Urumqi Glacier No.1 of the upstream Urumqi River Basin, eastern Tianshan Mountains from spring to autumn during four years(from 2008 to 2011) was studied. Results indicated that meltwater are the main source of water for the upper Urumqi River. Seasonal variation of δ18 O in precipitation demonstrated that δ18 O was more enriched in summer and depleted in spring and autumn. Temperature was positively correlated with isotopes, while precipitation amount and relative humidity was negatively correlated with isotopes. The water vapor was affected by westerly air mass and regional water vapor cycle. Meanwhile, back trajectory clustering analyses showed that the moisture mainly from Europe and central Asia. The moisture was more likely to be locally sourced with the ratio was 46.8%~52.1%.
基金funded by the National Key Basic Research Project of China(973 program,No.2011CB403004)
文摘Chemical and isotopic data were measured for 51 leached brine springs in the Changdu-Lanping-Simao Basin(CD-LP-SM),China.The predominance of Cl and Na,saturation indices of carbonate minerals,and Na/Cl and Ca/SO4 ratios of^1 suggest that halite,sulphate,and carbonate are the solute sources.Integration of geochemical,δ18 O,andδD values suggests that springs are mainly derived from meteoric water,ice-snow melt,and water-rock interactions.B concentrations range from 0.18 to 11.9 mg/L,withδ11 B values of-4.37‰to+32.39‰,indicating a terrestrial source.Theδ11 B-B relationships suggest B sources of crustal origin(marine carbonates with minor crust-derived volcanics);we did not identify a marine or deep mantle origin.Theδ11 B values of saline springs(+4.61‰to+32.39‰)exceed those of hot(-4.37‰to+4.53‰)and cold(-3.47‰to+14.84‰)springs;this has contributed to strong water-rock interactions and strong saturation of dissolved carbonates.Conversely,the global geothermalδ11 B-Cl/B relationship suggests mixing of marine and non-marine sources.Theδ11 B-Cl/B relationships of the CD-LP-SM are similar to those of the Tibet geothermal belt and the Nangqen Basin,indicating the same B origin.These differ from thermal waters controlled by magmatic fluids and seawater,suggesting that B in CD-LP-SM springs has a crustal origin.
文摘Having studied the biomarker composition and maturity of dissolved hydrocarbons from Ordovician formation waters, the authors presented molecular geochemical evidence for the controversial origin of natural gases in central Ordos Basin.The dissolved hydrocarbons in Well Shan 12 and Well Shan 78 are relatively high in abundance of tricylic terpane, pregnane series and dibenzothiophene series and low in Pr/Ph and hopane/sterane ratios, indicating the source input of marine carbonates. In contrast, the dissolved hydrocarbons in Well Shan 81 are free from tricyclic terpane and pregnane series, with trace dibenzothiophene series and high Pr/Ph and higher hopane/sterane ratios, which are the typical features of terrestrial organic matter. Furthermore, Well Shan 37 and Well Shan 34 are between the two situations, having a mixed source of marine carbonate and terrestrial organic matter. The maturity of biomarkers also supports the above suggestions. These results are consistent with the geological background and source rock distribution in this region.
文摘Natural gas pools with the high contents of CO2 were discovered during exploring the middle fault zone of the Hailar-Tamtsag Basin. So far this kind of gas reservoir with CO2 with characteristics of carbon isotope is spe-cial. The stable carbon isotope of CO2 in the study area is relatively light with δ13 CCO2 values ranging from -13.1‰ to -8.2‰. The 40Ar/36Ar values of associated argon gas range from 916 to 996, with R/Ra of 1.20-1.26. Based on comprehensive analysis, it is believed that the CO2 gas in this study area is of crust mantle source.
基金granted by the National Major Science and Technology Projects (grant No.2016ZX05004002)PetroChina Major Science and Technology Projects (grant No.2014E-32)PetroChina Science and Technology Projects (grant No.2016B-0402-01)
文摘Dolostones in the Cambrian Longwangmiao Formation have become one of the most significant gas exploration domains in China. Over a trillion cubic meters of gas reservoirs have been discovered in the Gaoshiti-Moxi area; however, the origins and distribution of the dolostone reservoirs are not well understood. This work discussed the geology and geochemistry of the dolostone reservoirs in the Longwangmiao Formation to determine their origin and distribution. Two understandings are acquired: firstly, a carbonate ramp provided excellent conditions for grain beach deposition, while the presence of a hypersaline lake was favorable for the contemporaneous dolomitization of grain beach deposits. Petrographic and geochemical evidence further confirm that the Longwangmiao dolostone was formed during the contemporaneous stage. Secondly, the reservoir characteristics indicate that the grain beach sediments provide material basis for the development of the Longwangmiao dolostone reservoirs. Reservoir dissolution simulation experiments show that the porosity of the reservoirs was formed by dissolution during contemporaneous and burial stages. The dissolution pores formed during the contemporaneous stage were controlled by sequence interfaces. The large scale dissolution vugs formed during the burial stage subsequently spread along the pre-existing porosity and fracture zones. This study therefore identified that the development of grain dolostone reservoirs in a shallow water ramp under arid climatic conditions generally met the following conditions:(1) reefal beach deposits lay a foundation for reservoir development;(2) superficial conditions are an important determining factor for reservoir porosity; and(3) burial conditions provide environment for porosity preservation and modification.
文摘The Yacheng gas field lies in the foot wall of the No. 1 fault, the boundary fault between the Yinggehai and Qiongdongnan basins. An overpressured system developed in the Meishan Formation near the No. 1 fault in the gas field and in the adjacent Yinggehai basin. Away from this fault into the Qiongdongnan basin, the overpressure diminishes. Below 3 600 m in the gas field, an obvious thermal anomaly occurs. The gases show obvious compositional heterogeneities which reflect reservoir filling process and origin of the gas field. The gas field was charged from both the Qiongdongnan and the Yinggehai basins but mainly from the former. Hydrocarbons sourced from the Qiongdongnan basin have relatively low maturities while hydrocarbons from the Yinggehai basin have relatively high maturities.
基金supported by CAS Major Basic Preliminary Program (2004CCA03500)the National Natural Science Foundation of China (No. 40603007)
文摘Chemistry of major and minor elements,87Sr/86Sr,δD,δ18O and δ34S of brines were measured from Tertiary strata and Quaternary salt lakes in the western Qaidam Basin.The water chemistry data show that all oilfield brines are CaCl2 type.They were enriched in Ca2+,B3+,Li+,Sr2+,Br-,and were depleted in Mg2+,SO42-,which indicated that these brines had the characteristics of deeply circulated water.The relationship between δD and δ18O shows that all data of these brines decline towards the Global Meteoric Water Line(GWL) and Qaidam Meteoric Water Line(QWL),and that the intersection between oilfield brines and Meteoric Water Lines was close to the local spring and fresh water in the piedmont in the western Qaidam Basin.The results suggest that oilfield brines has initially originated from meteoric water,and then might be affected by water-rock metamorphose,because most oilfield brines distribute in the range of metamorphosing water.The 87Sr/86Sr values of most oilfield brines range from 0.71121 to 0.71194,and was less than that in salt lake water(>0.712),but close to that of halite in the study area.These imply that salt dissolution occurred in the process of migration.In addition,all oilfield brines have obviously much positive δ34S values(ranging from 26.46‰ to 54.57‰) than that of salt lake brines,which was caused by bacterial sulfate reduction resulting in positive shift of δ34S value and depleteed SO42-in oilfield brines.Combined with water chemical data and δD,δ18O,87Sr/86Sr,δ34S values,we concluded that oilfield brines mainly originate from the deeply circulated meteoric waters,and then are affected by salt dissolution,water-rock metamorphose,sulfate reduction and dolomitization during the process of migration.These processes alter the chemical compositions of oilfield brines and accumulate rich elements(such as B,Li,Sr,Br,K and so on) for sustainable utilization of salt lake resources in the Qaidam Basin.
文摘Based on the analytical data of over 30 gas samples, combined with geochemical and geological backgrounds, the composition and distribution characteristics of shallow biogenetic gases in the Baise Basin, a Tertiary residual basin in southern China, were extensively investigated, and the origin and formation mechanism tentatively approached. The shallow gases are primarily composed of gaseous hydrocarbons, generally accounting for over 90%. The abundances of methane and C2+ homologues show a relatively wide range of variation, mainly 50%-100% and 0%-50%, respectively, depending on the mixing proportions between biogenetic and thermogenic gases. A highly negative carbon isotope is the significant signature for the shallow gases with δ^13C1 values of -55‰ to -75‰. According to molecular and isotopic compositions and light hydrocarbon parameters, the shallow gases in the basin can be classified into three types of origins: biogenetic gas, biogenetic/thermogenic mixed gas, and oii-biodegraded gas. They exhibit regular distribution both spatially and temporally, and are believed to be associated with the maturity of adjoining gas source rocks and biodegraded oil accumulation. The Baigang and Nadu source rocks can be considered to have experienced early and late gas generation during early burial and after basin uplift respectively. A late accumulation mechanism of multiple gas sources is put forward for the formation of the shallow gas reservoirs, which is responsible for the variations in chemical and isotopic composition of the gases in depth profile.