Navigating challenges and opportunities of machine learning in hydrogen catalysis and production processes: Beyond algorithm development

With the projected global surge in hydrogen demand, driven by increasing applications and the imperative for low-emission hydrogen, the integration of machine learning(ML) across the hydrogen energy value chain is a compelling avenue. This review uniquely focuses on harnessing the synergy between ML and computational modeling(CM) or optimization tools, as well as integrating multiple ML techniques with CM, for the synthesis of diverse hydrogen evolution reaction(HER) catalysts and various hydrogen production processes(HPPs). Furthermore, this review addresses a notable gap in the literature by offering insights, analyzing challenges, and identifying research prospects and opportunities for sustainable hydrogen production. While the literature reflects a promising landscape for ML applications in hydrogen energy domains, transitioning AI-based algorithms from controlled environments to real-world applications poses significant challenges. Hence, this comprehensive review delves into the technical,practical, and ethical considerations associated with the application of ML in HER catalyst development and HPP optimization. Overall, this review provides guidance for unlocking the transformative potential of ML in enhancing prediction efficiency and sustainability in the hydrogen production sector.

Process Development and Design of Chlorine Dioxide Production Based on Hydrogen Peroxide

This paper presents a process development and design of chlorine dioxide production based on hydrogen peroxide. The process is characterized by cleaner production, high efficiency, and waste minimization. Optimization of process conditions, selection of equipment, and experiment of recycle of waste acid are carried out. The process design is realized in consideration of several aspects such as operation, material, equipment design and safety. An industrialized process flowsheet is developed according to experiment. A pilot testing is carried out to confirm the lab results. Process design of chlorine dioxide production based on hydrogen peroxide is realized.

A Novel Close-loop Strategy for Integrating Process Operations of Fluidized Catalytic Cracking Unit with Production Planning Optimization

Production planning models generated by common modeling systems do not involve constraints for process operations, and a solution optimized by these models is called a quasi-optimal plan. The quasi-optimal plan cannot be executed in practice some time for no corresponding operating conditions. In order to determine a practi- cally feasible optimal plan and corresponding operating conditions of fluidized catalytic cracking unit （FCCU）, a novel close-loop integrated strategy, including determination of a quasi-optimal plan, search of operating conditions of FCCU and revision of the production planning model, was proposed in this article. In the strategy, a generalized genetic algorithm （GA） coupled with a sequential process simulator of FCCU was applied to search operating conditions implementing the quasi-optimal plan of FCCU and output the optimal individual in the GA search as a final genetic individual. When no corresponding operating conditions were found, the final genetic individual based correction （FGIC） method was presented to revise the production planning model, and then a new quasi-optimal production plan was determined. The above steps were repeated until a practically feasible optimal plan and corresponding operating conditions of FCCU were obtained. The close-loop integrated strategy was validated by two cases, and it was indicated that the strategy was efficient in determining a practically executed optimal plan and corresponding operating conditions of FCCU.

Comparative evaluation of energy and resource consumption for vacuum carbothermal reduction and Pidgeon process used in magnesium production

With the fast development of the application of magnesium based alloys,the demand for primary magnesium is increasing dramatically all over the world.The Pidgeon process is the most widely used process for producing magnesium in China,but suffers from problems such as high energy,resource consumption and environmental pollution.While the process of vacuum carbothermal reduction to produce magnesium(VCTRM)has attracted more and more attention as its advantages,but it has not been well-practiced in industrial applications and there also is no comprehensive and quantitative analysis of this process.This study quantified the flows of resource and energy for the Pidgeon process and the VCTRM process,then compared and analyzed these two processes with each other from three aspects.The VCTRM process results in 63.14%and 69.16%lower of non-renewable mineral resources and energy consumptions when compared to the Pidgeon process,respectively.Moreover,the low energy consumption(2.675 tce vs.8.681 tce)and material to magnesium ratio(2.953:1 vs.6.429:1)of the VCTRM process,which lead to lower greenhouse gas(GHG)emissions(8.777 t vs.26.337 t)and solid waste generation(0.522 t vs.5.465 t)with a decrease of 66.67%and 90.45%,respectively.Results indicate that the VCTRM process is a more environmentally friendly process for magnesium production with high efficiency but low cost and low pollution,and it shows a good potential to be industrialized in the future after solving the bottleneck problem of the reverse reaction.

Research on Anti-noise Processing Method of Production Signal Based on Ensemble Empirical Mode Decomposition(EEMD)

The grain production prediction is one of the most important links in precision agriculture. In the process of grain production prediction, mechanical noise caused by the factors of difference in field topography and mechanical vibration will be mixed in the original signal, which undoubtedly will affect the prediction accuracy. Therefore, in order to reduce the influence of vibration noise on the prediction accuracy, an adaptive Ensemble Empirical Mode Decomposition(EEMD) threshold filtering algorithm was applied to the original signal in this paper: the output signal was decomposed into a finite number of Intrinsic Mode Functions(IMF) from high frequency to low frequency by using the Empirical Mode Decomposition(EMD) algorithm which could effectively restrain the mode mixing phenomenon; then the demarcation point of high and low frequency IMF components were determined by Continuous Mean Square Error criterion(CMSE), the high frequency IMF components were denoised by wavelet threshold algorithm, and finally the signal was reconstructed. The algorithm was an improved algorithm based on the commonly used wavelet threshold. The two algorithms were used to denoise the original production signal respectively, the adaptive EEMD threshold filtering algorithm had significant advantages in three denoising performance indexes of signal denoising ratio, root mean square error and smoothness. The five field verification tests showed that the average error of field experiment was 1.994% and the maximum relative error was less than 3%. According to the test results, the relative error of the predicted yield per hectare was 2.97%, which was relative to the actual yield. The test results showed that the algorithm could effectively resist noise and improve the accuracy of prediction.

Global production, processing and utilization of lentil： A review

Lentil is a highly nutritious legume with an ample quantity of carbohydrates and good amount of proteins, minerals, vitamins, phytochemicals and fibres. Although it has been used as staple food since ancient times, its usage has been limited in developed countries, especially due to the lower protein digestibility, presence of anti-nutritional factors, flatulence and poor cooking qualities. Processing of lentils including dehulling and splitting and isolation of major fractions, e.g., proteins and starches are some of the strategies that can be adopted to add value and increase consumption of these legumes. This review paper intends to provide detailed overview of lentil＇s global production, nutritional composition and processing methods of lentil. Methods of isolation/characterization of lentil protein and starch and their subsequent application in foods are also presented.

Change and control of nitrogen in molten steel production process

The change and control of nitrogen content in molten steel was investigated through the production process of "LDBAr-LF-RH-CC". Results show that nitrogen content reduces gradually in converter-steelmaking stage, rises rapidly from the end of converter process to the end of argon station process, continues to increase in ladle furnace process, and decreases slightly in RH refining stage. Since nitrogen is removed mainly by BOF steelmaking and vacuum refining operations, nitrogen in molten steel should be removed as much as possible in these two operations. However, nitrogen uptake should be minimized in other operations of molten steel production process.

ENTROPY PRODUCTION RATE OF THE MINIMAL DIFFUSION PROCESS

The entropy production rate of stationary minimal diffusion processes with smooth coefficients is calculated. As a byproduct, the continuity of paths of the minimal diffusion processes is discussed, and that the point at infinity is absorbing is proved.

Assessing environmental impact of magnesium production using Pidgeon process in China

Based on the practice of magnesium production in China, a quantitative evaluation of the environment impact was carried out according to the theory and framework of life cycle assessment(LCA) study. The major gaseous pollutants including CO2, SO2, NOx, CH4, HF and particulates were calculated. The accumulative environmental performances of different energy use strategies and the characterization results, including abiotic depletion potential(ADP), global warming potential(GWP), acidification potential(AP) and human-toxicity potential(HTP) were compared. The results show that the direct emission of fuel combustion in the process is the major contributor to the pollutants emission of magnesium production. Global warming potential and acidification potential make the main contribution to the accumulative environmental impact. The different fuel use strategies in the practice of magnesium production cause much different impacts on the environmental performance. The accumulative environmental impact of coal burned directly is the highest, and that of producer-gas comes to the next, while that of coke-oven gas is the lowest.

Construction Method of Civil Aircraft Airborne⁃system Supplier Development Process System

Based on the analysis of the development process system status of domestic and foreign civil aircraft airborne system suppliers,this paper proposes the overall construction idea of"a set of civil aircraft process system"based on IPD(Integrated product development)in the organization.The development stage,process,activity and task are the logical framework elements of the system construction."Based on process decomposition,vertical stratification,horizontal segmentation,combination of special and common,process customized to tools,role and process integration,giving full consideration to the interface between supplier management and process modules"etc.are the concrete ideas.Moreover,formulate top⁃level system construction standards,implemented by process system management tool platform,so that the process system and development work can be effectively integrated to effectively guide the development work of airborne system suppliers,and meet the quality and airworthiness requirements of civil aircraft development.Through the development application of a certain type of flight control system,the process system and tool platform were verified and optimized in practice.

A Typical Production and Elimination Process of Particles in Beijing during Early 2008 Olympic Games

[Objective] The aim was to discuss he produce and elimination rules of particles in Beijing during early 2008 Olympic Games. [Method] Based on the analysis of particulate matter online observation data and meteorological data during the corresponding period in Chinese environmental science college, Hysplit Back trace model and Numerical weather prediction graphs, and combined with the different analytical methods on meteorological flow fields, a typical process of particles in Beijing during early 2008 Olympic Games was studied. [Result] The results indicated that during the ascent stage of PM2.5 concentration, the PM showed gradually aging phenomena; the process controlled by large scale synoptic system mainly. And the weak wind and the high humidity were not in favor of dispersion; the prolonged southerly air mass to bring the pollutant of Hebei, Taijin and Shandong to Beijing; mixing height and temperature curve took the importance role to the pollution. [Conclusion] The study provided theoretical basis for the discussion on factors influencing the production and elimination of particles in the air pollution process.

The Decision-Making Processes of the Agents Belonging to the Biodiesel Production Chain in Southern Brazil

The aim of this paper is to present and analyze the factors, motivations and criteria considered in the decision-making processes of the actors belonging to the biodiesel production chain in Brazil. The biodiesel production chain consists of three main agents： the farmers, the soybean processing plants and the oil refinery/distributor. For the farmers organized in cooperatives the central decision is whether to sell oil-bearing crops for the production of biodiesel. In contrast, for the soybean processing plants that convert the crops into vegetable and/or biodiesel, the decision to produce this fuel is based on the wish to expand their market portfolio. Government tax incentives strongly influence both decisions regarding which oil-bearing crop to use and the amount of vegetable oil to be transformed into biodiesel. Finally, the oil refinery/distributor is obliged by law to mix the biodiesel with the mineral diesel and perceives this as a liability. The results show the existence of different characteristics linked to the decision-making process and a significant lack of synchronicity in the aims and motivations behind the agents＇ decisions. This state of decisional misalignment leads to heightened uncertainty regarding the sustainability of the Brazilian biodiesel production program.

Production of High-p_T Kaon and Pion in PP and Au-Au Collisions by Resolved Photoproduction Processes

Taking into account the effects of shadowing and jet quenching, the large transverse momentum distribution of K＋, π＋ and K＋/π＋ ratios at s = 200 GeV originating from resolved photoproduction processes is calculated based on perturbative quantum chromodynamics. It is found that the contribution of K＋ and π＋ produced by photoproduction processes is evident. The K＋ /π＋ ratios in Au-Au collisions show an obvious enhancement compared with p p collisions. The numerical results indicate that the photoproduetion processes are good modification for kaon and pion production.

NEW BREAKTHROUGH OF HEAVY OIL UPGRADING TECHNOLOGY——INTEGRATION PROCESSES OF VRFCC/RMC FOR PRODUCTION OF HIGH VALUE PRODUCTS AND STEAM CRACKING FEED

An integration process of vacuum residue FCC(VRFCC)and moderate pressure hydro cracking(RMC),developed by RIPP and BDI,opens a new route for maximizing production of both high value products and the feed for steam cracking(SC).VRFCC technology has been put on stream at Yanshan Petrochemical Co (YPC)since November 1998.A 79 2%(mass percent)high value product(LPG+GSL+LCO)was surprisingly made on the test run from a resid feedstock of 85 0%(mass percent)Daqing crude VR content.No facility coking was found during the operation.RMC is a renovating moderate pressure hydrocracking technology,the end point of the heavy VGO feed is as high as 534 ℃,and the RMC catalyst performance shows high hydrodenitrogenation activity and high ring opening selectivity.The process highlights the flexibility of product slates——maximum premium mid distillates yield(38 0%(mass percent))and/or maximum hydro unconverted bottoms(Hydro BTMs)yield(50%～70%(mass percent)).Over 30%(mass percent)ethylene was produced from SC process based on Hydro BTMs feed. The application of VRFCC/RMC integration at YPC not only covers the shortages of SC feed for 660 kt/a ethylene production capacity,but also increases the total yield of premium fuel products.

On Structure,production,and market of bamboo-based panels in China

Since bamboo has the advantages of straight grain, beautiful color, high strength and toughness, and excellent abrasion resistance, bamboo-based panels have been widely used in the fields of vehicle, construction, ship building, furniture, and decoration to partly take the place of wood, steel, plastic etc in China. This paper briefly described the basic component units, including strip, sliver, and particle, of bamboo-based panel and pointed out that to design the structure of bamboo-based panels should follow the principle of symmetric structure, surface forming method, and structuring principle of equalizing stress. According to the processing methods and formation of component units, the authors classified the bamboo-based panels in China into 13 types and presented the manufacturing technique and uses of the bamboo products, such as plybamboo, bamboo flooring, and bamboo-wood composite products in detail. In the last part of the paper, much information were offered on the output, market, and selling prospect of each type of bamboo-based panels.

Construction of Value Models of Consumer Creation for Agricultural Products Based on the Analytic Hierarchy Process(AHP)

With the increased competition of modern economy and globalization,consumer creation which based on the analysis of consumer behavior was more and more attentioned and respected by business.Based on the meaning and characteristics of agricultural product consumer creation,index system of value model of agricultural product consumer creation was put forward through analytical hierarchy process（AHP）.The weights of the indicators and related indicators of impact on the value were analyzed,and value models of agricultural product consumer creation were constructed to provide ideas for development of agricultural product consumer market and research of consumer value.Consumer creation was constructed to provide ideas for development of agricultural product consumer market and research of consumer value.

Comparative Study on the Development Levels of Cold Chain Logistics for Agricultural Products between China and Developed Countries Based on Analytic Hierarchy Process

By introducing the analytic hierarchy process （AHP）, a model is constructed to compare the logistics development level of cold chain for agricultural products between China and other developed countries such as United States, Japan and Euro- pean. The paper makes a comparative study on the development levels of agricultural cold chain logistics in China and developed countries from the aspects of the level of cold chain logistics facilities and equipments, the degree of cold chain logistics market-oriented and the capacity of cold chain logistics, then determines the problems of cold chain logistics in China. With the experiences learning from developed countries, some countermeasures are proposed to resolve those problems of cold chain logistics for agricultural products development combining with the national conditions in China.

Operation optimization of the steel manufacturing process: A brief review

Against the realistic background of excess production capacity, product structure imbalance, and high material and energy consumption in steel enterprises, the implementation of operation optimization for the steel manufacturing process is essential to reduce the production cost, increase the production or energy efficiency, and improve production management. In this study, the operation optimization problem of the steel manufacturing process, which needed to go through a complex production organization from customers' orders to workshop production, was analyzed. The existing research on the operation optimization techniques, including process simulation, production planning, production scheduling, interface scheduling, and scheduling of auxiliary equipment, was reviewed. The literature review reveals that, although considerable research has been conducted to optimize the operation of steel production, these techniques are usually independent and unsystematic.Therefore, the future work related to operation optimization of the steel manufacturing process based on the integration of multi technologies and the intersection of multi disciplines were summarized.

Integrated Assessment of Environmental and Economic Performance of Chemical Products Using Analytic Hierarchy Process Approach

With the increasing public consciousness on environmental issues, chemical products and process designs require simultaneous satisfaction and compromise of environmental and economical requirements. To fulfill the two conflicting while complementary objectives, a systematic approach for life cycle design of a chemical product is proposed in this article. Multiattribute decision-making is adopted in a trade-off consideration of both technical economical evaluation and environmental impacts assessment using the analytic hierarchy process （AHP） approach. On the basis of an evaluation of the relative importance of the criteria multicriteria decision making is performed. In this study, an AHP model is used to derive single a criteria score by analyzing the environmental impact and life cycle cost of a product, respectively. And a fluctuant weight analysis is put forth to calculate the integrated index of the product to enable products to be ranked or selected intuitionally and conveniently. The proposed AHP model has been applied to a case study, a comparative study on chamber cleaning with NF3 and C2F6. The resuits show that the protposed AHP model is Capable of providing a rational and relevant evaluation.