THE EFFECT OF RARE EARTH ELEMENTS ON THE SOLIDIFICATION BEHAVIOR OF Al-Mg ALLOYS

The effect of rare earth element on the solidification behavior of Al-Mg alloy was investigated in a directional solidification apparatus.It was found that during the solidification process.the rare earth element segregated in the liquid at sold-liquid interface,changed the solidification morphology and reduced the secondary arm spacing markedly.

BEHAVIORS OF ACCESSORY ELEMENTS IN COPPER PYROMETALLURGY

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Simulation-based Estimation of Thermal Behavior of Direct Feed Drive Mechanism with Updated Finite Element Model

Linear motors generate high heat and cause significant deformation in high speed direct feed drive mechanisms.It is relevant to estimate their deformation behavior to improve their application in precision machine tools.This paper describes a method to estimate its thermal deformation based on updated finite element（FE）model methods.Firstly,a FE model is established for a linear motor drive test rig that includes the correlation between temperature rise and its resulting deformation.The relationship between the input and output variables of the FE model is identified with a modified multivariate input/output least square support vector regression machine.Additionally,the temperature rise and displacements at some critical points on the mechanism are obtained experimentally by a system of thermocouples and an interferometer.The FE model is updated through intelligent comparison between the experimentally measured values and the results from the regression machine.The experiments for testing thermal behavior along with the updated FE model simulations is conducted on the test rig in reciprocating cycle drive conditions.The results show that the intelligently updated FE model can be implemented to analyze the temperature variation distribution of the mechanism and to estimate its thermal behavior.The accuracy of the thermal behavior estimation with the optimally updated method can be more than double that of the initial theoretical FE model.This paper provides a simulation method that is effective to estimate the thermal behavior of the direct feed drive mechanism with high accuracy.

Electrochemical behaviors of gold and its associated elements in various complex agent solutions

Thermodynamic properties and electrochemical behaviors of gold and its associated elements, such as silver, copper, nickel and iron, in various complex agent solutions were studied. Within CS（NH2）2, S2O2-3 and SCN- systems, alkaline thiourea is the optimal nontoxic lixiviating agent substituting cyanide from the viewpoint of thermodynamics. The electrochemical study indicates that the anodic dissolution current densities of gold are 2.616, （1.805,） 1.267, 1.088, 0.556, and 0.145 mA·cm-2 respectively in the solutions of cyanide, alkaline thiourea containing Na2SiO3, SCN-, acidic thiourea, alkaline thiourea and thiosulfate at the potential of 0.500 V. Comparing various lixiviating agents, the alkaline thiourea solution containing Na2SiO3 is of prominent selectivity in leaching gold, in the potential range from 0.500 to 0.600 V, which is most efficient for leaching gold selectively instead of cyanide. The effect on leaching gold is similar to that in the cyanide system.

Analysis of Thermal Behavior of High Frequency Transformers Using Finite Element Method

High frequency transformer is used in many applications among the Switch Mode Power Supply (SMPS), high voltage pulse power and etc can be mentioned. Regarding that the core of these transformers is often the ferrite core;their functions partly depend on this core characteristic. One of the characteristics of the ferrite core is thermal behavior that should be paid attention to because it affects the transformer function and causes heat generation. In this paper, a typical high frequency transformer with ferrite core is designed and simulated in ANSYS software. Temperature rise due to winding current (Joule-heat) is considered as heat generation source for thermal behavior analysis of the transformer. In this simulation, the temperature rise and heat distribution are studied and the effects of parameters such as flux density, winding loss value, using a fan to cool the winding and core and thermal conductivity are investigated.

Geochemical Behavior of Trace- and Rare-Earth Elements in the Hydrothermal Alteration Facies of the Cijulang Area, West Java, Indonesia

This study examines the behavior of trace- and rare-earth elements (REE) in different hydrothermal alteration facies (silicic, advanced argillic and argillic) of Cijulang high-sulfidation epithermal gold deposit, West Java, Indonesia. The results of the study indicate that remarkable differences in the behavior of trace elements and REE are observed in the studied alteration facies. All REE in the silicic facies are strongly depleted. In advanced argillic facies, Heavy rare-earth elements (HREE) are strongly depleted whereas light rare earth elements (LREE) are quite enriched. REE concentrations in the argillic facies show little or no variation with respect to fresh rock counterparts. A strong depletion of REE in the silicic facies is likely to be favored by the highly acidic nature of the hydrothermal fluids, the abundance of complexing ions such as Cl ˉ, F ˉ, and in the hydrothermal solutions and the absence of the secondary minerals that can fix the REE in their crystal structures. An apparent immobility of LREE in advanced argillic facies is possibly due to the presence of alunite. The immobility of REE in the argillic facies suggests the higher pH of the fluids, the lower water/rock ratios and the presence of the phyllosilicates minerals. -

Full－range nonlinear analysis of fatigue behaviors of reinforced concrete structures by finite element method

The offshore reinforced concrete structures are always subject to cyclic load, such as wave load.In this paper a new finite element analysis model is developed to analyze the stress and strain state of reinforced concrete structures including offshore concrete structures, subject to any number of the cyclic load. On the basis of the anal ysis of the experimental data,this model simplifies the number of cycles-total cyclic strain curve of concrete as three straight line segments,and it is assumed that the stress-strain curves of different cycles in each segment are the same, thus the elastoplastic analysis is only needed for the first cycle of each segment, and the stress or strain corresponding to any number of cycles can be obtained by superposition of stress or strain obtained by the above e lastoplastic analysis based on the cyclic numbers in each segment.This model spends less computer time,and can obtain the stress and strain states of the structures after any number of cycles.The endochronic-damage and ideal offshore concrete platform subject to cyclic loading are experimented and analyzed by the finite element method based on the model proposed in this paper. The results between the experiment and the finite element analysis are in good agreement,which demonstrates the validity and accuracy of the proposed model.

Asymptotic Behavior of the Finite Difference and the Finite Element Methods for Parabolic Equations

The asymptotic convergence of the solution of the parabolic equation is proved. By the eigenvalues estimation, we obtain that the approximate solutions by the finite difference method and the finite element method are asymptotically convergent. Both methods are considered in continnous time.

A method for 3D simulation of internal gas effects on thermal-mechanical behaviors in nuclear fuel elements

A new method for three-dimensional simulation of the interaction between the gas and the solid around is developed.The effects of the gas on the thermal-mechanical behaviors within the surrounded solid are performed by replacing the internal gas with an equivalent solid in the modeling,which can make it convenient to simulate the thermal-mechanical coupling effects in the solid research objects with gases in them.The applied thermal expansion coefficient,Young's modulus and Poisson's ratio of the equivalent solid material are derived.A series of tests have been conducted;and the proposed equivalent solid method to simulate the gas effects is validated.

STATISTIC MODELING OF THE CREEP BEHAVIOR OF METAL MATRIX COMPOSITES BASED ON FINITE ELEMENT ANALYSIS

The aim of the paper is to discover the general creep mechanisms for the short fiber reinforcement matrix composites (MMCs) under uniaxial stress states and to build a relationship between the macroscopic steady creep behavior and the material micro geometric parameters. The unit cell models were used to calculate the macroscopic creep behavior with different micro geometric parameters of fibers on different loading directions. The influence of the geometric parameters of the fibers and loading directions on the macroscopic creep behavior had been obtained, and described quantitatively. The matrix/fiber interface had been considered by a third layer, matrix/fiber interlayer, in the unit cells with different creep properties and thickness. Based on the numerical results of the unit cell models, a statistic model had been presented for the plane randomly-distributed-fiber MMCs. The fiber breakage had been taken into account in the statistic model for it starts experimentally early in the creep life. With the distribution of the geometric parameters of the fibers, the results of the statistic model agree well with the experiments. With the statistic model, the influence of the geometric parameters and the breakage of the fibers as well as the properties and thickness of, the interlayer on the macroscopic steady creep rate have been discussed.

Experimental research and finite element analysis of bridge piers failed in flexure-shear modes

In recent earthquakes, a large number of reinforced concrete （RC） bridges were severely damaged due to mixed flexure-shear failure modes of the bridge piers. An integrated experimental and finite element （FE） analysis study is described in this paper to study the seismic performance of the bridge piers that failed in flexure-shear modes. In the first part, a nonlinear cyclic loading test on six RC bridge piers with circular cross sections is carried out experimentally. The damage states, ductility and energy dissipation parameters, stiffness degradation and shear strength of the piers are studied and compared with each other. The experimental results suggest that all the piers exhibit stable flexural response at displacement ductilities up to four before exhibiting brittle shear failure. The ultimate performance of the piers is dominated by shear capacity due to significant shear cracking, and in some cases, rupturing of spiral bars. In the second part, modeling approaches describing the hysteretic behavior of the piers are investigated by using ANSYS software. A set of models with different parameters is selected and evaluated through comparison with experimental results. The influences of the shear retention coefficients between concrete cracks, the Bauschinger effect in longitudinal reinforcement, the bond-slip relationship between the longitudinal reinforcement and the concrete and the concrete failure surface on the simulated hysteretic curves are discussed. Then, a modified analysis model is presented and its accuracy is verified by comparing the simulated results with experimental ones. This research uses models available in commercial FE codes and is intended for researchers and engineers interested in using ANSYS software to predict the hysteretic behavior of reinforced concrete structures.

Cu Partitioning Behavior and Its Effect on Microstructure and Mechanical Properties of 0.12C-1.33Mn-0.55Cu Q&P Steel

Cu, as an austenitic stable element, is added to steel in order to suppress the adverse effects of high content of C and Mn on welding. Based on C partitioning, Cu and Mn partitioning can further improve the stability of retained austenite in the intercritical annealing process. A sample of low carbon steel containing Cu was treated by the intercritical annealing, then quenching process（I＆Q）. Subsequently, another sample was treated by the intercritical annealing, subsequent austenitizing, then quenching and partitioning process（I＆Q＆P）. The effects of element partitioning behavior in intercritical region on the microstructure and mechanical properties of the steel were studied. The results showed that after the I＆Q process ferrite and martensite could be obtained, with C, Cu and Mn enriched in the martensite. When intercritically heated at 800 ℃, Cu and Mn were partitioned from ferrite to austenite, which was enhanced gradually as the heating time was increased. This partitioning effect was the most obvious when the sample was heated at 800 ℃ for 40 min. At the early stage of α→γ transformation, the formation of γ was controlled by the partitioning of carbon, while at the later stage, it was mainly affected by the partitioning of Cu and Mn. After the I＆Q＆P process, the partitioning effect of Cu and Mn element could be retained. C was assembled in retained austenite during the quenching and partitioning process. The strength and elongation of I＆Q＆P steel was increased by 5 305 MPa% compared with that subjected to Q＆P process. The volume fraction of retained autensite was increased from 8.5% to 11.2%. Hence, the content of retained austenite could be improved significantly by Mn and Cu partitioning, which increased the elongation of steel.

Virtual ballistic impact testing of Kevlar soft armor:Predictive and validated finite element modeling of the V0-V100 probabilistic penetration response

This works presents the first fully validated and predictive capability to model the V_0-V_(100) probabilistic penetration response of a woven fabric using a yarn-level fabric finite element model. The V_0-V_(100) curve describes the probability of complete fabric penetration as a function of projectile impact velocity. The exemplar case considered in this paper comprises of a single-layer, fully-clamped, plain-weave Kevlar fabric impacted at the center by a 17-gr, 0.22 cal FSP or fragment-simulating projectile. Each warp and fill yarn in the fabric is individually modeled using 3 D finite elements and the virtual fabric microstructure is validated in detail against the experimental fabric microstructure. Material and testing sources of statistical variability including yarn strength and modulus, inter-yarn friction, precise projectile impact location, and projectile rotation are mapped into the finite element model. A series of impact simulations at varying projectile impact velocities is executed using LS-DYNA on the fabric models, with each model comprising unique mappings. The impact velocities together with the outcomes(penetration, nonpenetration) are used to generate the numerical V_0-V_(100) curve which is then validated against the experimental V_0-V_(100) curve. The numerical Vi-Vrdata(impact, residual velocities) is also validated against the experimental Vi-Vrdata. For completeness, this paper also reports the experimental characterization data and its statistical analysis used for model input, viz. the Kevlar yarn tensile strengths, moduli, and inter-yarn friction, and the experimental ballistic test data used for model validation.

High-temperature Creep Behavior Characterization of Asphalt Mixture based on Micromechanical Modeling and Virtual Test

The high-temperature creep behavior of asphalt mixture was investigated based on micromechanical modeling and virtual test by using three-dimensional discrete element method（DEM）. A user-defined micromechanical model of asphalt mixture was established after analyzing the irregular shape and gradation of coarse aggregates, the viscoelastic property of asphalt mastic, and the random distribution of air voids within the asphalt mixture. Virtual uniaxial static creep test at 60 ℃ was conducted by using Particle Flow Code in three dimensions（PFC3D） and was validated by laboratory test. Based on virtual creep test, the micromechanical characteristics between aggregates, within asphalt mastic, and between aggregate and asphalt mastic were analyzed for the asphalt mixture. It is proved that the virtual test based on the micromechanical model can efficiently predict the creep deformation of asphalt mixture. And the high-temperature behavior of asphalt mixture was characterized from micromechanical perspective.

Flexible Pavement Analysis Considering Temperature Profile and Anisotropy Behavior in Hot Mix Ashalt Layer

A three Dimensional finite element model (FEM) incorporating the anisotropic properties and temperature profile of hot mix asphalt (HMA) pavement was developed to predict the structural responses of HMA pavement subject to heavy loads typically encountered in the field. In this study, ABAQUS was adopted to model the stress and strain relationships within the pavement structure. The results of the model were verified using data collected from the Korean Highway Corporation Test Road (KHCTR). The results demonstrated that both the base course and surface course layers follow the anisotropic behavior and the incorporation of the temperature profile throughout the pavement has a substantial effect on the pavement response predictions that impact pavement design. The results also showed that the anisotropy level of HMA and base material can be reduced to as low as 80% and 15% as a result of repeated loading, respectively.

SIMULATIONS OF MECHANICAL BEHAVIOR OF POLYCRYSTALLINE COPPER WITH NANO-TWINS

Mechanical behavior and microstructure evolution of polycrystalline copper with nano-twins were investigated in the present work by finite element simulations. The fracture of grain boundaries are described by a cohesive interface constitutive model based on the strain gradient plasticity theory. A systematic study of the strength and ductility for different grain sizes and twin lamellae distributions is performed. The results show that the material strength and ductility strongly depend on the grain size and the distribution of twin lamellae microstructures in the polycrystalline copper.

Finite Element Modelling of Steel Beams with Web Openings

Height limitations are not uncommon in multi-storey buildings due to economic requirements and esthetical considerations. Substantial spaces are normally required to enable the passage of large pipes and ducts beneath steel beams leading to uneconomic floor heights. The most adopted solution for this issue is the use of steel beam web openings to provide the required space for services. These openings could lead to a significant decrease of the beam load carrying capacity depending on the adopted openings shape, size and location. These aspects motivated the present study based on FE simulations calibrated against numerical and test results. The results accuracy enabled a comprehensive parametric analysis of beams with web openings to be made focused on the profile size, web opening location, among others. The study also investigated the efficiency of longitudinal stiffeners welded at the opening region and benefits of using an adequate edge concordance radius in beams with rectangular and square openings. The obtained results showed the need of using welded longitudinal stiffeners in order to increase the beams ultimate load carrying capacity. This adoption can double or even triple the ultimate load of beams with rectangular and square opening heights equal to 0.75 H, respectively.

Dissolution of Rare Earth Elements from Coal Fly Ash Particles in a Dilute H₂SO₄Solvent

Recently, the worldwide supply of rare earth element (REE) resources will be severely restricted. On the other hand, coal fly ash particles emitted from coal-fired electric power plants contain relatively high concentrations of REEs. The contents of REEs in coal fly ash are regularly several hundreds of ppmw. In order to extract and recover REEs from coal fly ash particles, as a first step, we have investigated their dissolution behavior in a dilute H2SO4 solvent. The REE content of coal fly ash specimens has been precisely determined, and their presence in the ash component of the original coal and their enrichment in coal fly ash particles during coal combustion have been suggested. REEs in coal fly ash dissolve gradually in H2SO4 over time, and this implies two types of occurrences of the REEs in coal fly ash particles. By applying the unreacted core model to the dissolution behavior of REEs in a H2SO4 solvent, we can explain both types of occurrences.

橄榄石微量元素:分析、地球化学行为与地球科学应用

橄榄石化学成分记录了幔源岩浆性质、结晶演化、喷发速率等重要信息。近十年来,橄榄石微量元素分析技术飞速进步,积累了丰富的数据。本文系统综述了电子探针和激光剥蚀电感耦合等离子体质谱法在橄榄石微量元素分析领域的最新研究进展,总结了橄榄石中微量元素的分配系数与扩散系数等地球化学行为,分析了全球不同岩石单元的橄榄石微量元素特征,重点介绍了岩浆铜镍矿床中橄榄石微量元素的研究进展。实验岩石学表明,控制元素在橄榄石中分配系数的主要因素有温度、压力、岩浆成分等,且不同微量元素行为的主控因素各不相同。在确定的温压条件下,橄榄石中多数元素的配分可由晶格应变模型预测,而Ni、Co和轻稀土元素主要受晶体场效应和结晶动力学控制。橄榄石中元素的扩散速率由快到慢依次为:H和Li(快)→Fe-Mg-Ni(中等)→Ca(较慢)→P-O-Si(慢)。对比全球不同岩石单元中橄榄石微量元素得出:(1)火山岩系列的科马提岩-苦橄岩-玄武岩中橄榄石的Fo值和Ni、Cr、Al、Mn等元素呈演化趋势,但在二元相关性图中不同岩石类型间存在较大重叠区域,机器学习等多维分析手段可大大提升分类准确率;(2)地幔橄榄岩与侵入岩系列(地壳堆晶岩)中的橄榄石微量元素特征相近,难以使用单元素指标区分,例如常用的Ca亏损;(3)碳酸岩中橄榄石的Ni、Mn含量有别于其他岩石,可能与其来源和元素在橄榄石-碳酸岩熔体中特殊的分配行为有关;(4)石榴子石地幔橄榄岩与尖晶石地幔橄榄岩的橄榄石微量元素存在一定差异,橄榄石V/Sc比值和Fe-Mg-Mn-Ca-Ni含量是判别地幔橄榄岩类型和来源深度的重要变量。岩浆铜镍矿床橄榄石微量元素的研究进展有:(1)堆晶-后堆晶阶段再平衡作用驱使Ca-Cr-Al元素向其他矿物迁移,使橄榄石普遍亏损上述元素;(2)橄榄石Ni-Co变化可记录其与硫化物的元素交换反应,Ni-Co正相关可用于指示岩体深边部的找矿潜力;(3)与硫化物共生橄榄石的Ni富集(>5000×10^(-6))或亏损(<500×10^(-6))可能与较高或较低氧逸度有关。未来橄榄石重点研究与突破方向有:堆晶-后堆晶阶段元素行为、多元素-多矿物扩散联合限定岩浆时空演化、机器学习判别橄榄石成因类型与镁铁-超镁铁岩体含矿性、挥发份与新兴非传统金属稳定同位素等。

Effect of Al Layer on Oxidation Behavior of NbCrAl Coating

NbCrAl coatings in the presence or absence of Al outer layer were prepared on C103 Nb based alloy and alumina substrate by direct current magnetron sputtering technique. The oxidation performance of coating systems was evaluated by isothermal oxidation tests. The element diffusion and oxidation behavior of the coating systems were investigated. The results indicate that the mass gains of NbCrAl and Al/NbCrAl coatings are 2.02 mg/cm^2 and 0.79 mg/cm^2 at 1 000 ℃ for short time. Al/NbCrAl coatings exhibit more effective protection than NbCrAl coatings. The addition of Al layer can improve the oxidation resistance of NbCrAl coatings, which is attributed to the Al layer offering enough Al content to react with oxygen to form a continuous and dense Al_2O_3 scale on NbCrAl coating and it can inhibit the further internal oxidation.