The effects of hydrogen atoms on behaviour of low cycle fatigue of 2.25Cr-1Mo steel have been investigated in present work. The results indicate that the cyclic softening rate and low cycle fatigue life are respective...The effects of hydrogen atoms on behaviour of low cycle fatigue of 2.25Cr-1Mo steel have been investigated in present work. The results indicate that the cyclic softening rate and low cycle fatigue life are respectively increased and reduced remarkably by hydrogen atoms. In addition, hydrogen atoms make the original stress amplitude of low cycle fatigue increase, which is because of the drag effect of hydrogen atoms on the moving dislocations. Analyses using electron microscopy show that hydrogen atoms accelerate crack initiation of low cycle fatigue from inclusion and transfer the source of low cycle fatigue crack from the surface of specimen to the inclusion, which results in the marked decrease of low cycle fatigue life. The increase of cyclic softening rate for hydrogen charged specimen is due to hydrogen atoms accelerating the initiating and growing of microvoids from the secondary phase particles in the steel. The reducing of the drag effect of hydrogen atoms on moving dislocations is also helpful to the increase of the cyclic softening rate.展开更多
The influences of hydrogen on the mechanical properties and the fracture behaviour of Fe-22Mn-0.6C twinning induced plasticity steel have been investigated by slow strain rate tests and fractographic analysis.The stee...The influences of hydrogen on the mechanical properties and the fracture behaviour of Fe-22Mn-0.6C twinning induced plasticity steel have been investigated by slow strain rate tests and fractographic analysis.The steel showed high susceptibility to hydrogen embrittlement,which led to 62.9%and 74.2%reduction in engineering strain with 3.1 and 14.4 ppm diffusive hydrogen,respectively.The fracture surfaces revealed a transition from ductile to brittle dominated fracture modes with the rising hydrogen contents.The underlying deformation and fracture mechanisms were further exploited by examining the hydrogen effects on the dislocation substructure,stacking fault probability,and twinning behaviour in pre-strained slow strain rate test specimens and notched tensile specimens using coupled electron channelling contrast imaging and electron backscatter diffraction techniques.The results reveal that the addition of hydrogen promotes planar dislocation structures,earlier nucleation of stacking faults,and deformation twinning within those grains which have tensile axis orientations close to<111>//rolling direction and<112>//rolling direction.The developed twin lamellae result in strain localization and micro-voids at grain boundaries and eventually lead to grain boundary decohesion.展开更多
The Mg2Ni-type alloys with nominal compositions of Mg20Ni10-xCox(x=0,1,2,3,4,%,mass fraction) were prepared by melt-spinning technology.The structures of the alloys were studied by XRD,SEM and HRTEM.The hydrogen absor...The Mg2Ni-type alloys with nominal compositions of Mg20Ni10-xCox(x=0,1,2,3,4,%,mass fraction) were prepared by melt-spinning technology.The structures of the alloys were studied by XRD,SEM and HRTEM.The hydrogen absorption/desorption kinetics and the electrochemical performances of the alloys were measured.The results show that no amorphous phase forms in the as-spun Co-free alloy,but the as-spun alloys containing Co show a certain amount of amorphous phase.The hydrogen absorption capacities of the as-cast alloys first increase and then decrease with the incremental change of Co content.The hydrogen desorption capacities of as-cast and spun alloys rise with increasing Co content.The melt spinning significantly improves the hydrogenation and dehydrogenation capacities and kinetics of the alloys.The substitution of Co for Ni clearly enhances the discharge capacities of the alloys and the cycle stability of the as-spun alloys.展开更多
The slow tensile tests,dynamic hydrogen charging tensile tests and hydrogen evolution tests after hydrogen charging were used to study the effects of rare earth metal(REM)on hydrogen behaviour in a steel 16Mn(St.52).T...The slow tensile tests,dynamic hydrogen charging tensile tests and hydrogen evolution tests after hydrogen charging were used to study the effects of rare earth metal(REM)on hydrogen behaviour in a steel 16Mn(St.52).The ratios of RE/S were chosen as 0,0.7,2.2 and 7.7,respectively.It was shown that the steel with RE/S = 2.2 give a lower hydrogen embrittlement susceptibility than others.The steels without REM can adsorb much more amount of hydrogen than that with REM under the same hydrogen charging conditions.And the amount of adsorbed hydrogen for the foriner can be evolved easier than that for the latter at room temperature,50℃ and 80℃,respectively.The experimental results were explained by the trap theory of hydrogen,the short-circuit diffusion paths in the interfaces between the elongated MnS inclusions and the matrix,and strong ability of REM to adsorb hydrogen.展开更多
The effect of hydrogen addition on compression deformation behaviour of Ti-0.3Mo-0.8Ni alloy argon-arc welded joint has been investigated.Evolution mechanism of hydrogen-induced flow stress was discussed in detail.The...The effect of hydrogen addition on compression deformation behaviour of Ti-0.3Mo-0.8Ni alloy argon-arc welded joint has been investigated.Evolution mechanism of hydrogen-induced flow stress was discussed in detail.The results show that with increasing hydrogen content,the stretching and bending extent of fully lamellar microstructures including ot lamellas and acicular hydride continued to increase,the morphology of dynamic recrystallization(DRX)grains tended to change from approximately equiaxed to large lamellar shape,and the quantity of DRX grains and recrystallization degree of grains increased obviously.A large number of dislocations concentrated in the vicinity of the hydride.Steady stress was decreased continuously with increasing hydrogen content,while peak stress of the hydrogenated 0.12 wt.% H weld zone was decreased to the minimum value and then increased slowly.A slight decrease in flow stress of the hydrogenated 0.05 wt.% H weld zone was caused by limited increase in the volume fraction of softer βphase.Hydrogen-induced DRX of a phase and improved dislocation movement by strong interaction between the hydride and dislocation directly resulted in a sharp drop in flow stress of the hydrogenated 0.12 and 0.21 wt.% H weld zone.Solute hydrogen also finitely contributed to a sharp drop in flow stress of the hydrogenated 0.12 and 0.21 wt.% H weld zone by promoted local softening,which induced continuous DRX and more movable dislocations to participate in slipping or climbing.The reinforcement effect and plastic deformation of the hydride and solution strengthening of P phase induced by solute hydrogen finally led to the increase in flow stress of the hydrogenated 0.21 wt.% H weld zone in its true strain range from 0 to 0.36.展开更多
An extra-low interstitial near alpha alloy Ti-3Al-2Zr-2Mo(wt%) was fabricated by hydrogenation and thermomechanical consolidation(TMC) of the coarse and spherical pre-alloyed powder with particle sizes of 60 to 270 μ...An extra-low interstitial near alpha alloy Ti-3Al-2Zr-2Mo(wt%) was fabricated by hydrogenation and thermomechanical consolidation(TMC) of the coarse and spherical pre-alloyed powder with particle sizes of 60 to 270 μm. The coarse powder is a byproduct of pre-alloyed powder produced for selective laser and electron beam additive manufacturing. The TMC process involves powder compaction, fast sintering,in-situ dehydrogenation and an immediate hot extrusion to form a fully dense and fine-grained martensitic microstructure. Further dehydrogenation in vaccum at 700 °C converted the martensitic microstructure into an interwoven α/β microstructure which exhibited an improved yield strength, apparent necking and premature cracking at grain boundary α(α_(GB)) ribbons. A further annealing of 880 ℃/1 h/AC led to the formation of a fine-grained α/β_(t)composite structure, which achieved an enhance ultimate tensile strength of 835 MPa and excellent tensile ductility of 16.0%. Analysis of the deformation behavior of the alloy in different states revealed that the α/β_(t)composite structures brought about an enhanced strain hardening capability by heterogeneous deformation effect of hard β_(t)and soft α-laths, which inhibited the formation of microcracks and consequently improved the coordinated deformation.展开更多
文摘The effects of hydrogen atoms on behaviour of low cycle fatigue of 2.25Cr-1Mo steel have been investigated in present work. The results indicate that the cyclic softening rate and low cycle fatigue life are respectively increased and reduced remarkably by hydrogen atoms. In addition, hydrogen atoms make the original stress amplitude of low cycle fatigue increase, which is because of the drag effect of hydrogen atoms on the moving dislocations. Analyses using electron microscopy show that hydrogen atoms accelerate crack initiation of low cycle fatigue from inclusion and transfer the source of low cycle fatigue crack from the surface of specimen to the inclusion, which results in the marked decrease of low cycle fatigue life. The increase of cyclic softening rate for hydrogen charged specimen is due to hydrogen atoms accelerating the initiating and growing of microvoids from the secondary phase particles in the steel. The reducing of the drag effect of hydrogen atoms on moving dislocations is also helpful to the increase of the cyclic softening rate.
文摘The influences of hydrogen on the mechanical properties and the fracture behaviour of Fe-22Mn-0.6C twinning induced plasticity steel have been investigated by slow strain rate tests and fractographic analysis.The steel showed high susceptibility to hydrogen embrittlement,which led to 62.9%and 74.2%reduction in engineering strain with 3.1 and 14.4 ppm diffusive hydrogen,respectively.The fracture surfaces revealed a transition from ductile to brittle dominated fracture modes with the rising hydrogen contents.The underlying deformation and fracture mechanisms were further exploited by examining the hydrogen effects on the dislocation substructure,stacking fault probability,and twinning behaviour in pre-strained slow strain rate test specimens and notched tensile specimens using coupled electron channelling contrast imaging and electron backscatter diffraction techniques.The results reveal that the addition of hydrogen promotes planar dislocation structures,earlier nucleation of stacking faults,and deformation twinning within those grains which have tensile axis orientations close to<111>//rolling direction and<112>//rolling direction.The developed twin lamellae result in strain localization and micro-voids at grain boundaries and eventually lead to grain boundary decohesion.
基金Project(2006AA05Z132) supported by the National High-tech Research and Development Program of ChinaProjects(50871050,50701011) supported by the National Natural Science Foundation of China+1 种基金Project(200711020703) supported by Natural Science Foundation of Inner Mongolia,ChinaProject(NJzy08071) supported by High Education Science Research Program of Inner Mongolia,China
文摘The Mg2Ni-type alloys with nominal compositions of Mg20Ni10-xCox(x=0,1,2,3,4,%,mass fraction) were prepared by melt-spinning technology.The structures of the alloys were studied by XRD,SEM and HRTEM.The hydrogen absorption/desorption kinetics and the electrochemical performances of the alloys were measured.The results show that no amorphous phase forms in the as-spun Co-free alloy,but the as-spun alloys containing Co show a certain amount of amorphous phase.The hydrogen absorption capacities of the as-cast alloys first increase and then decrease with the incremental change of Co content.The hydrogen desorption capacities of as-cast and spun alloys rise with increasing Co content.The melt spinning significantly improves the hydrogenation and dehydrogenation capacities and kinetics of the alloys.The substitution of Co for Ni clearly enhances the discharge capacities of the alloys and the cycle stability of the as-spun alloys.
文摘The slow tensile tests,dynamic hydrogen charging tensile tests and hydrogen evolution tests after hydrogen charging were used to study the effects of rare earth metal(REM)on hydrogen behaviour in a steel 16Mn(St.52).The ratios of RE/S were chosen as 0,0.7,2.2 and 7.7,respectively.It was shown that the steel with RE/S = 2.2 give a lower hydrogen embrittlement susceptibility than others.The steels without REM can adsorb much more amount of hydrogen than that with REM under the same hydrogen charging conditions.And the amount of adsorbed hydrogen for the foriner can be evolved easier than that for the latter at room temperature,50℃ and 80℃,respectively.The experimental results were explained by the trap theory of hydrogen,the short-circuit diffusion paths in the interfaces between the elongated MnS inclusions and the matrix,and strong ability of REM to adsorb hydrogen.
基金The authors would like to gratefully acknowledge that this work was supported by the China Postdoctoral Science Foundation(Grant No.2020M672306)National Natural Science Foundation of China(Grant Nos.51874225 and 51671152).
文摘The effect of hydrogen addition on compression deformation behaviour of Ti-0.3Mo-0.8Ni alloy argon-arc welded joint has been investigated.Evolution mechanism of hydrogen-induced flow stress was discussed in detail.The results show that with increasing hydrogen content,the stretching and bending extent of fully lamellar microstructures including ot lamellas and acicular hydride continued to increase,the morphology of dynamic recrystallization(DRX)grains tended to change from approximately equiaxed to large lamellar shape,and the quantity of DRX grains and recrystallization degree of grains increased obviously.A large number of dislocations concentrated in the vicinity of the hydride.Steady stress was decreased continuously with increasing hydrogen content,while peak stress of the hydrogenated 0.12 wt.% H weld zone was decreased to the minimum value and then increased slowly.A slight decrease in flow stress of the hydrogenated 0.05 wt.% H weld zone was caused by limited increase in the volume fraction of softer βphase.Hydrogen-induced DRX of a phase and improved dislocation movement by strong interaction between the hydride and dislocation directly resulted in a sharp drop in flow stress of the hydrogenated 0.12 and 0.21 wt.% H weld zone.Solute hydrogen also finitely contributed to a sharp drop in flow stress of the hydrogenated 0.12 and 0.21 wt.% H weld zone by promoted local softening,which induced continuous DRX and more movable dislocations to participate in slipping or climbing.The reinforcement effect and plastic deformation of the hydride and solution strengthening of P phase induced by solute hydrogen finally led to the increase in flow stress of the hydrogenated 0.21 wt.% H weld zone in its true strain range from 0 to 0.36.
基金"863" Program (2007AA03Z227)National Natural Science Foundations of China (50871050 and 50701011)+1 种基金Natural Science Foundation of Inner Mongolia of China (200711020703)High Education Science Research Project of Inner Mongolia of China (NJzy08071)
基金financially supported by the“Xing Liao Talent Plan”of Liaoning Province,China(No.XLYC1802080)the Fundamental Research Fund for the Central Universities(No.02080022117003)。
文摘An extra-low interstitial near alpha alloy Ti-3Al-2Zr-2Mo(wt%) was fabricated by hydrogenation and thermomechanical consolidation(TMC) of the coarse and spherical pre-alloyed powder with particle sizes of 60 to 270 μm. The coarse powder is a byproduct of pre-alloyed powder produced for selective laser and electron beam additive manufacturing. The TMC process involves powder compaction, fast sintering,in-situ dehydrogenation and an immediate hot extrusion to form a fully dense and fine-grained martensitic microstructure. Further dehydrogenation in vaccum at 700 °C converted the martensitic microstructure into an interwoven α/β microstructure which exhibited an improved yield strength, apparent necking and premature cracking at grain boundary α(α_(GB)) ribbons. A further annealing of 880 ℃/1 h/AC led to the formation of a fine-grained α/β_(t)composite structure, which achieved an enhance ultimate tensile strength of 835 MPa and excellent tensile ductility of 16.0%. Analysis of the deformation behavior of the alloy in different states revealed that the α/β_(t)composite structures brought about an enhanced strain hardening capability by heterogeneous deformation effect of hard β_(t)and soft α-laths, which inhibited the formation of microcracks and consequently improved the coordinated deformation.
