Two new one-dimensional zigzag chain coordination polymers, [Co（hfipbb）（2,2＇- bpy）（H2O）2]n 1 and [Co（hfipbb）（1,10-phen）（H2O）], 2, have been synthesized under hydrother- mal reactions from COCl2.6H20, 4,4...Two new one-dimensional zigzag chain coordination polymers, [Co（hfipbb）（2,2＇- bpy）（H2O）2]n 1 and [Co（hfipbb）（1,10-phen）（H2O）], 2, have been synthesized under hydrother- mal reactions from COCl2.6H20, 4,4＇-（hexafluoroisopropylidene）bis（benzoic acid） and 2,2＇ -bipyridine or 1,10-phenanthroline ligands, respectively. Single-crystal X-ray analyses revealed that the zigzag chains of 1 and 2 are linked into three-dimensional supramolecular networks by both O-H…O hydrogen-bonds and π…π stacking interactions. Crystal data for 1： CzTHajCoF6N2Os Mr = 641.38, orthorhombic, space group Pnna, a = 9.3820（19）, b = 27.366（6）, c = 10.106（2）A, V = 2594.8（9）A3, Z = 4, Dc = 1.642 g/cm3, F（000） = 1300,/t = 0.752 mm-l, R = 0.0311 and wR = 0.0924. Crystal data for 2： C29H18CoF6N2O5, Mr = 647.38, monoclinic, space group P21/n, a = 7.7626（16）, b = 29.446（6）, c = 11.281（2）A,β= 93.98（3）°, V= 2572.3（9）A3, Z = 4, Dc = 1.672 g/cm3, F（000） = 1308,μ= 0.757 mm-1, R = 0.0403 and wR = 0.0820.展开更多
基金Supported by the NNSFC (20701022)the K. C. Wong Magna Fund in Ningbo University
文摘Two new one-dimensional zigzag chain coordination polymers, [Co（hfipbb）（2,2＇- bpy）（H2O）2]n 1 and [Co（hfipbb）（1,10-phen）（H2O）], 2, have been synthesized under hydrother- mal reactions from COCl2.6H20, 4,4＇-（hexafluoroisopropylidene）bis（benzoic acid） and 2,2＇ -bipyridine or 1,10-phenanthroline ligands, respectively. Single-crystal X-ray analyses revealed that the zigzag chains of 1 and 2 are linked into three-dimensional supramolecular networks by both O-H…O hydrogen-bonds and π…π stacking interactions. Crystal data for 1： CzTHajCoF6N2Os Mr = 641.38, orthorhombic, space group Pnna, a = 9.3820（19）, b = 27.366（6）, c = 10.106（2）A, V = 2594.8（9）A3, Z = 4, Dc = 1.642 g/cm3, F（000） = 1300,/t = 0.752 mm-l, R = 0.0311 and wR = 0.0924. Crystal data for 2： C29H18CoF6N2O5, Mr = 647.38, monoclinic, space group P21/n, a = 7.7626（16）, b = 29.446（6）, c = 11.281（2）A,β= 93.98（3）°, V= 2572.3（9）A3, Z = 4, Dc = 1.672 g/cm3, F（000） = 1308,μ= 0.757 mm-1, R = 0.0403 and wR = 0.0820.
