A polarization-maintaining (PM) fiber Mach-Zehnder (MZ) interferometer has been established to measure the EO effect of very thin film materials with optical anisotropy. Unlike a common MZ interferometer, all the ...A polarization-maintaining (PM) fiber Mach-Zehnder (MZ) interferometer has been established to measure the EO effect of very thin film materials with optical anisotropy. Unlike a common MZ interferometer, all the components are connected via polarization-maintaining fibers. At the same time, a polarized DFB laser with a maximum power output of 10mW is adopted as the light source to induce a large extinction ratio. Here,we take it to determine the electro-optical coefficients of a very thin superlattice structure with GaAs, KTP, and GaN as comparative samples. The measured EO coefficients show good comparability with the others.展开更多
We propose and analyze a novel Si-based electro-optic modulator with an improved metal-oxide-semiconductor (MOS) capacitor configuration integrated into silicon-on-insulator (SOl). Three gate-oxide layers embedded...We propose and analyze a novel Si-based electro-optic modulator with an improved metal-oxide-semiconductor (MOS) capacitor configuration integrated into silicon-on-insulator (SOl). Three gate-oxide layers embedded in the silicon waveguide constitute a triple MOS capacitor structure, which boosts the modulation efficiency compared with a single MOS capacitor. The simulation results demonstrate that the Vπ Lπ product is 2. 4V · cm. The rise time and fall time of the proposed device are calculated to be 80 and 40ps from the transient response curve, respectively,indicating a bandwidth of 8GHz. The phase shift efficiency and bandwidth can be enhanced by rib width scaling.展开更多
A 2 × 2 electro-optic switch is experimentally demonstrated using the optical structure of a Mach-Zehnder interferometer (MZI) based on a submicron rib waveguide and the electrical structure of a PIN diode on s...A 2 × 2 electro-optic switch is experimentally demonstrated using the optical structure of a Mach-Zehnder interferometer (MZI) based on a submicron rib waveguide and the electrical structure of a PIN diode on silicon-on-insulator (SOI). The switch behaviour is achieved through the plasma dispersion effect of silicon. The device has a modulation arm of 1 mm in length and cross-section of 400 nm×340 nm. The measurement results show that the switch has a VπLπ figure of merit of 0.145 V.cm and the extinction ratios of two output ports and cross talk are 40 dB, 28 dB and -28 dB, respectively. A 3 dB modulation bandwidth of 90 MHz and a switch time of 6.8 ns for the rise edge and 2.7 ns for the fall edge are also demonstrated.展开更多
Thermally poled germanium-doped channel waveguides are presented. Multilayer waveguides containing a silicon oxynitride layer were used as charge trapper in this investigation on the effect of the internal field insid...Thermally poled germanium-doped channel waveguides are presented. Multilayer waveguides containing a silicon oxynitride layer were used as charge trapper in this investigation on the effect of the internal field inside the waveguide. Compared to waveguides without the trapping layer, experimental results showed that the induced linear electro-optic (EO) coefficient increases about 20% after poling, suggesting strongly that the internal field is relatively enhanced, and showed it is a promising means for improving nonlinearity by poling in waveguides.展开更多
In this work, the fundamental mechanism regarding the collision and pressure induced optic effect is elucidated. Based on the concept of the collision-relaxation/the pressure-release induced optic effect put forth her...In this work, the fundamental mechanism regarding the collision and pressure induced optic effect is elucidated. Based on the concept of the collision-relaxation/the pressure-release induced optic effect put forth here, a new laser technology may be developed. Furthermore, our work also makes the understanding the photon involved chemical reaction become much clear and rationalized.展开更多
We study the Gaussian laser transmission in lithium niobate crystal(LiNbO3) by using the finite element method to solve the electromagnetic field's frequency domain equation and energy equation. The heat generated ...We study the Gaussian laser transmission in lithium niobate crystal(LiNbO3) by using the finite element method to solve the electromagnetic field's frequency domain equation and energy equation. The heat generated is identified by calculating the transmission loss of the electromagnetic wave in the birefringence crystal, and the calculated value of the heat generated is substituted into the energy equation. The electromagnetic wave's energy losses induced by its multiple refractions and reflections along with the resulting physical property changes of the lithium niobate crystal are considered.Influences of ambient temperature and heat transfer coefficient on refraction and walk-off angles of O-ray and E-ray in the cases of different incident powers and crystal thicknesses are analyzed. The E-ray electrical modulation instances, in which the polarized light waveform is adjusted to the rated condition via an applied electrical field in the cases of different ambient temperatures and heat transfer coefficients, are provided to conclude that there is a correlation between ambient temperature and applied electrical field intensity and a correlation between surface heat transfer coefficient and applied electrical field intensity. The applicable electrical modulation ranges without crystal breakdown are proposed. The study shows that the electrical field-adjustable heat transfer coefficient range becomes narrow as the incident power decreases and wide as the crystal thickness increases. In addition, it is pointed out that controlling the ambient temperature is easier than controlling the heat transfer coefficient. The results of the present study can be used as a quantitative theoretical basis for removing the adverse effects induced by thermal deposition due to linear laser absorption in the crystal, such as depolarization or wave front distortion, and indicate the feasibility of adjusting the refractive index in the window area by changing the heat transfer boundary conditions in a wide-spectrum laser.展开更多
Electro-optic(EO)crystals are important material for all-solid-state laser technology,which can be used to fabricate various laser modulators,such as EO switches,laser deflectors,and optical waveguide.The improvements...Electro-optic(EO)crystals are important material for all-solid-state laser technology,which can be used to fabricate various laser modulators,such as EO switches,laser deflectors,and optical waveguide.The improvements in new high-efficiency EO crystal materials have held great significance to the development of laser technology.Potassium tantalate niobate(KTN)is a popular multifunctional crystal because of its remarkable and excellent quadratic EO effect.KTN EO modulation technology offers numerous advantages,such as high efficiency,good stability,a quick response time,and inertia-free characteristics.In this paper,we summarize the research progress of KTN series crystals systemically,including the theoretical exploration on quadratic EO effect,solid-melt crystal growth technique,comprehensive physical characterization,new physical effect and mechanisms exploration,new EO devices development and design.The EO modulation technique based on the Kerr effect of KTN series crystal offers obvious advantages in reducing the drive voltage and device size,which could better meet the developmental needs of future lasers with a wide wavelength,miniaturization,and integration.This may provide theoretical guidance and an experimental basis for the design and development of new EO crystal devices and promote the development of laser technology.展开更多
In this paper, we theoretically deduce the expressions of half-wave voltage and 3-dB modulation bandwidth in which conductor loss is taken into account. The results suggest that it will affect the theoretical values o...In this paper, we theoretically deduce the expressions of half-wave voltage and 3-dB modulation bandwidth in which conductor loss is taken into account. The results suggest that it will affect the theoretical values of half-wave voltage and bandwidth as well as the optimized electrode's dimension whether considering the conductor loss or not. As an example, we present a Mach-Zehnder (MZ) type polymer waveguide amplitude modulator. The half-wave voltage increases by 1 V and the 3-dB bandwidth decreases by 30% when the conductor loss is taken into account. Besides, the effects of impedance mismatching and velocity mismatching between microwave and light wave on the half-wave voltage, and 3-dB bandwidth are discussed.展开更多
We report the numerical observation of discrete spatial solitons in a periodically poled lithium niobate waveguide array by applying an electrical field through electro-optical effect. We show that discrete spatial so...We report the numerical observation of discrete spatial solitons in a periodically poled lithium niobate waveguide array by applying an electrical field through electro-optical effect. We show that discrete spatial soliton can be controlled by applied voltage in the periodically poled lithium niobate.展开更多
Cubic boron nitride (cBN) is a kind of artificial (synthetic) crystal. Transverse electro-optic modulation in a minute cBN sample was carried out. Basing on the practical form of the crystal, we established the theore...Cubic boron nitride (cBN) is a kind of artificial (synthetic) crystal. Transverse electro-optic modulation in a minute cBN sample was carried out. Basing on the practical form of the crystal, we established the theoretical and experimental method according to the sample. For the first time, the linear electro-optic effect was observed in cBN, and half-wave voltage of the cBN sample was measured successfully. Furthermore, its linear electro-optic coefficient was calculated at 1.17×10?14 m/V.展开更多
Electro-optical composites based on the product of electro-strictive and elasto-optical effects are developed. Layered composites of PbZr1-xTixO3 and polycarbonate are synthesised. Their electro-ptical properties are ...Electro-optical composites based on the product of electro-strictive and elasto-optical effects are developed. Layered composites of PbZr1-xTixO3 and polycarbonate are synthesised. Their electro-ptical properties are studied. The nominal transverse electro-optical coefficient of the composite is observed to be about 3.6 times larger than that of LiNbO3. Experiments and theoretical analyses show that the electro-optical effect of the composite has a strong 'size effect'. With the ratio of thickness/length decreasing or the width of elasto-optical phase increasing, the half-wave electric field intensity increases but the transverse electrc-optical coefficient decreases for the layered composite.展开更多
This paper describes the fundamentals of phase-only liquid crystal on silicon(LCOS)technology,which have not been previously discussed in detail.This technology is widely utilized in high efficiency applications for r...This paper describes the fundamentals of phase-only liquid crystal on silicon(LCOS)technology,which have not been previously discussed in detail.This technology is widely utilized in high efficiency applications for real-time holography and diffractive optics.The paper begins with a brief introduction on the developmental trajectory of phase-only LCOS technology,followed by the correct selection of liquid crystal(LC)materials and corresponding electro-optic effects in such devices.Attention is focused on the essential requirements of the physical aspects of the LC layer as well as the indispensable parameters for the response time of the device.Furthermore,the basic functionalities embedded in the complementary metal oxide semiconductor(CMOS)silicon backplane for phase-only LCOS devices are illustrated,including two typical addressing schemes.Finally,the application of phase-only LCOS devices in real-time holography will be introduced in association with the use of cutting-edge computer-generated holograms.展开更多
Optical links are moving to higher and higher transmission speeds while shrinking to shorter and shorter ranges where optical links are envisaged even at the chip scale.The scaling in data speed and span of the optica...Optical links are moving to higher and higher transmission speeds while shrinking to shorter and shorter ranges where optical links are envisaged even at the chip scale.The scaling in data speed and span of the optical links demands modulators to be concurrently performant and cost-effective.Silicon photonics(SiPh),a photonic integrated circuit technology that leverages the fabrication sophistication of complementary metal-oxide-semiconductor technology,is well-positioned to deliver the performance,price,and manufacturing volume for the high-speed modulators of future optical communication links.SiPh has relied on the plasma dispersion effect,either in injection,depletion,or accumulation mode,to demonstrate efficient high-speed modulators.The high-speed plasma dispersion silicon modulators have been commercially deployed and have demonstrated excellent performance.Recent years have seen a paradigm shift where the integration of various electro-refractive and electro-absorptive materials has opened up additional routes toward performant SiPh modulators.These modulators are in the early years of their development.They promise to extend the performance beyond the limits set by the physical properties of silicon.The focus of our study is to provide a comprehensive review of contemporary(i.e.,plasma dispersion modulators)and new modulator implementations that involve the integration of novel materials with SiPh.展开更多
We design and fabricate an unbalanced Mach–Zehnder interferometer(MZI)via electron beam lithography and inductively coupled plasma etching on lithium niobate thin film.The single unbalanced MZI exhibits a maximum ext...We design and fabricate an unbalanced Mach–Zehnder interferometer(MZI)via electron beam lithography and inductively coupled plasma etching on lithium niobate thin film.The single unbalanced MZI exhibits a maximum extinction ratio of 32.4 dB and a low extra loss of 1.14 dB at the telecommunication band.Furthermore,tunability of the unbalanced MZI by harnessing the thermo-optic and electro-optic effect is investigated,achieving a linear tuning efficiency of 42.8 pm/℃ and 55.2 pm/V,respectively.The demonstrated structure has applications for sensing and filtering in photonic integrated circuits.展开更多
The determination of nonlinearities near the band edge of organic and polymeric electro-optic(EO)materials is important from the viewpoint of molecular nonlinear optics(NLO)and photonic device applications.Based on tr...The determination of nonlinearities near the band edge of organic and polymeric electro-optic(EO)materials is important from the viewpoint of molecular nonlinear optics(NLO)and photonic device applications.Based on transmission-mode Stark effect electromodulation(EM)spectroscopy,we study the electric-field-induced changes in optical absorption and refraction of newly developed EO polymers from the visible to near-infrared(NIR)wavelengths and report record-high near-band-edge complex EO effects from poled thin films.Values ofΔn andΔk up to 10^(-3) and 10^(-2) are found at an applied electric field of 2.0×10^(5)-3.0×10^(5)V/cm.The study of linear optical properties of poled films by spectroscopic ellipsometry shows large polinginduced birefringence and a nearly two-fold increase in the extinction coefficients at the extraordinary polarization.Through the Kramers-Kronig analysis,we obtained the real and imaginary second-order nonlinear coefficients up to~3,500 and~5,600 pm/V,respectively,which are believed to be the highest NLO coefficients of poled polymers through the resonance enhancement.Our approach goes beyond the previous works,applicable only to several discrete wavelengths,to a full-spectral analysis with independent verification of slab waveguide measurements.By considering both the electroabsorption and electrorefraction effects,our study overcomes the limitation of the classic qualitative two-level model and provides a quantitative understanding of near-resonance optical nonlinearities of organic EO materials.It can inspire the exploration of high-speed,absorptive,or phase-shifting light-modulators using EO polymers for on-chip applications.展开更多
文摘A polarization-maintaining (PM) fiber Mach-Zehnder (MZ) interferometer has been established to measure the EO effect of very thin film materials with optical anisotropy. Unlike a common MZ interferometer, all the components are connected via polarization-maintaining fibers. At the same time, a polarized DFB laser with a maximum power output of 10mW is adopted as the light source to induce a large extinction ratio. Here,we take it to determine the electro-optical coefficients of a very thin superlattice structure with GaAs, KTP, and GaN as comparative samples. The measured EO coefficients show good comparability with the others.
文摘We propose and analyze a novel Si-based electro-optic modulator with an improved metal-oxide-semiconductor (MOS) capacitor configuration integrated into silicon-on-insulator (SOl). Three gate-oxide layers embedded in the silicon waveguide constitute a triple MOS capacitor structure, which boosts the modulation efficiency compared with a single MOS capacitor. The simulation results demonstrate that the Vπ Lπ product is 2. 4V · cm. The rise time and fall time of the proposed device are calculated to be 80 and 40ps from the transient response curve, respectively,indicating a bandwidth of 8GHz. The phase shift efficiency and bandwidth can be enhanced by rib width scaling.
基金supported by the National Natural Science Foundation of China (Grant No 60577044)the State Key Development Program for Basic Research of China (Grant No 2007CB613405)the National High Technology Research and Development Program of China (Grant No 2006AA032424)
文摘A 2 × 2 electro-optic switch is experimentally demonstrated using the optical structure of a Mach-Zehnder interferometer (MZI) based on a submicron rib waveguide and the electrical structure of a PIN diode on silicon-on-insulator (SOI). The switch behaviour is achieved through the plasma dispersion effect of silicon. The device has a modulation arm of 1 mm in length and cross-section of 400 nm×340 nm. The measurement results show that the switch has a VπLπ figure of merit of 0.145 V.cm and the extinction ratios of two output ports and cross talk are 40 dB, 28 dB and -28 dB, respectively. A 3 dB modulation bandwidth of 90 MHz and a switch time of 6.8 ns for the rise edge and 2.7 ns for the fall edge are also demonstrated.
文摘Thermally poled germanium-doped channel waveguides are presented. Multilayer waveguides containing a silicon oxynitride layer were used as charge trapper in this investigation on the effect of the internal field inside the waveguide. Compared to waveguides without the trapping layer, experimental results showed that the induced linear electro-optic (EO) coefficient increases about 20% after poling, suggesting strongly that the internal field is relatively enhanced, and showed it is a promising means for improving nonlinearity by poling in waveguides.
文摘In this work, the fundamental mechanism regarding the collision and pressure induced optic effect is elucidated. Based on the concept of the collision-relaxation/the pressure-release induced optic effect put forth here, a new laser technology may be developed. Furthermore, our work also makes the understanding the photon involved chemical reaction become much clear and rationalized.
基金Project supported by the National Natural Science Foundation of China(Grant No.51176039)
文摘We study the Gaussian laser transmission in lithium niobate crystal(LiNbO3) by using the finite element method to solve the electromagnetic field's frequency domain equation and energy equation. The heat generated is identified by calculating the transmission loss of the electromagnetic wave in the birefringence crystal, and the calculated value of the heat generated is substituted into the energy equation. The electromagnetic wave's energy losses induced by its multiple refractions and reflections along with the resulting physical property changes of the lithium niobate crystal are considered.Influences of ambient temperature and heat transfer coefficient on refraction and walk-off angles of O-ray and E-ray in the cases of different incident powers and crystal thicknesses are analyzed. The E-ray electrical modulation instances, in which the polarized light waveform is adjusted to the rated condition via an applied electrical field in the cases of different ambient temperatures and heat transfer coefficients, are provided to conclude that there is a correlation between ambient temperature and applied electrical field intensity and a correlation between surface heat transfer coefficient and applied electrical field intensity. The applicable electrical modulation ranges without crystal breakdown are proposed. The study shows that the electrical field-adjustable heat transfer coefficient range becomes narrow as the incident power decreases and wide as the crystal thickness increases. In addition, it is pointed out that controlling the ambient temperature is easier than controlling the heat transfer coefficient. The results of the present study can be used as a quantitative theoretical basis for removing the adverse effects induced by thermal deposition due to linear laser absorption in the crystal, such as depolarization or wave front distortion, and indicate the feasibility of adjusting the refractive index in the window area by changing the heat transfer boundary conditions in a wide-spectrum laser.
基金supported by the National Natural Science Foundation of China(52072189,and 51972179)Natural Science Foundation of Shandong Province(ZR2020KE019 and ZR2020QE041)+3 种基金Science and Technology Program for Young Innovation Team in Colleges and Universities of Shandong Province,China(2019KJA003)Studio for the Leader of Scientific Research in Jinan(2019GXRC059)Major Innovation Project for Integrating Science,Education&Industry of Qilu University of Technology(Shandong Academy of Sciences)(2022PYI015 and 2022JBZ01-07)Innovation Capability Improvement Project for Small and Mediumsized Technology-based Enterprise of Shandong Province,China(2022TSGC1357).
文摘Electro-optic(EO)crystals are important material for all-solid-state laser technology,which can be used to fabricate various laser modulators,such as EO switches,laser deflectors,and optical waveguide.The improvements in new high-efficiency EO crystal materials have held great significance to the development of laser technology.Potassium tantalate niobate(KTN)is a popular multifunctional crystal because of its remarkable and excellent quadratic EO effect.KTN EO modulation technology offers numerous advantages,such as high efficiency,good stability,a quick response time,and inertia-free characteristics.In this paper,we summarize the research progress of KTN series crystals systemically,including the theoretical exploration on quadratic EO effect,solid-melt crystal growth technique,comprehensive physical characterization,new physical effect and mechanisms exploration,new EO devices development and design.The EO modulation technique based on the Kerr effect of KTN series crystal offers obvious advantages in reducing the drive voltage and device size,which could better meet the developmental needs of future lasers with a wide wavelength,miniaturization,and integration.This may provide theoretical guidance and an experimental basis for the design and development of new EO crystal devices and promote the development of laser technology.
文摘In this paper, we theoretically deduce the expressions of half-wave voltage and 3-dB modulation bandwidth in which conductor loss is taken into account. The results suggest that it will affect the theoretical values of half-wave voltage and bandwidth as well as the optimized electrode's dimension whether considering the conductor loss or not. As an example, we present a Mach-Zehnder (MZ) type polymer waveguide amplitude modulator. The half-wave voltage increases by 1 V and the 3-dB bandwidth decreases by 30% when the conductor loss is taken into account. Besides, the effects of impedance mismatching and velocity mismatching between microwave and light wave on the half-wave voltage, and 3-dB bandwidth are discussed.
基金This work was supported by the National Natural Science Foundation of China (No. 60007001)the Foundation for Development of Science and Technology of Shanghai (No. OOJC14027)
文摘We report the numerical observation of discrete spatial solitons in a periodically poled lithium niobate waveguide array by applying an electrical field through electro-optical effect. We show that discrete spatial soliton can be controlled by applied voltage in the periodically poled lithium niobate.
基金supported by the National Natural Science Foundation of China(Grant Nos.60176009,69976013 and 69676025)the Science and Technology Bureau Foundation of Jilin Province(Grant No.20010580).
文摘Cubic boron nitride (cBN) is a kind of artificial (synthetic) crystal. Transverse electro-optic modulation in a minute cBN sample was carried out. Basing on the practical form of the crystal, we established the theoretical and experimental method according to the sample. For the first time, the linear electro-optic effect was observed in cBN, and half-wave voltage of the cBN sample was measured successfully. Furthermore, its linear electro-optic coefficient was calculated at 1.17×10?14 m/V.
基金supported by the National Natural Science Foundation of China (Grant No. 50977046)
文摘Electro-optical composites based on the product of electro-strictive and elasto-optical effects are developed. Layered composites of PbZr1-xTixO3 and polycarbonate are synthesised. Their electro-ptical properties are studied. The nominal transverse electro-optical coefficient of the composite is observed to be about 3.6 times larger than that of LiNbO3. Experiments and theoretical analyses show that the electro-optical effect of the composite has a strong 'size effect'. With the ratio of thickness/length decreasing or the width of elasto-optical phase increasing, the half-wave electric field intensity increases but the transverse electrc-optical coefficient decreases for the layered composite.
基金This work was supported by the National Natural Science Foundation of China(61307077)Beijing Natural Science Foundation(4144076)+1 种基金China Postdoctoral Science Foundation(2013M530613)This work was also supported by an EPSRC Platform Grant for LC Photonics(EP/F00897X/1).
文摘This paper describes the fundamentals of phase-only liquid crystal on silicon(LCOS)technology,which have not been previously discussed in detail.This technology is widely utilized in high efficiency applications for real-time holography and diffractive optics.The paper begins with a brief introduction on the developmental trajectory of phase-only LCOS technology,followed by the correct selection of liquid crystal(LC)materials and corresponding electro-optic effects in such devices.Attention is focused on the essential requirements of the physical aspects of the LC layer as well as the indispensable parameters for the response time of the device.Furthermore,the basic functionalities embedded in the complementary metal oxide semiconductor(CMOS)silicon backplane for phase-only LCOS devices are illustrated,including two typical addressing schemes.Finally,the application of phase-only LCOS devices in real-time holography will be introduced in association with the use of cutting-edge computer-generated holograms.
文摘Optical links are moving to higher and higher transmission speeds while shrinking to shorter and shorter ranges where optical links are envisaged even at the chip scale.The scaling in data speed and span of the optical links demands modulators to be concurrently performant and cost-effective.Silicon photonics(SiPh),a photonic integrated circuit technology that leverages the fabrication sophistication of complementary metal-oxide-semiconductor technology,is well-positioned to deliver the performance,price,and manufacturing volume for the high-speed modulators of future optical communication links.SiPh has relied on the plasma dispersion effect,either in injection,depletion,or accumulation mode,to demonstrate efficient high-speed modulators.The high-speed plasma dispersion silicon modulators have been commercially deployed and have demonstrated excellent performance.Recent years have seen a paradigm shift where the integration of various electro-refractive and electro-absorptive materials has opened up additional routes toward performant SiPh modulators.These modulators are in the early years of their development.They promise to extend the performance beyond the limits set by the physical properties of silicon.The focus of our study is to provide a comprehensive review of contemporary(i.e.,plasma dispersion modulators)and new modulator implementations that involve the integration of novel materials with SiPh.
基金supported by the National Natural Science Foundation of China(Nos.12074252,62022058,62005159,and 11734011)National Key Research and Development Program of China(Nos.2017YFA0303701 and 2018YFA0306301)+2 种基金Shanghai Municipal Science and Technology Major Project(No.2019SHZDZX01-ZX06)Shanghai Rising-Star Program(No.20QA1405400)Shanghai Jiao Tong University(No.21X010200828)。
文摘We design and fabricate an unbalanced Mach–Zehnder interferometer(MZI)via electron beam lithography and inductively coupled plasma etching on lithium niobate thin film.The single unbalanced MZI exhibits a maximum extinction ratio of 32.4 dB and a low extra loss of 1.14 dB at the telecommunication band.Furthermore,tunability of the unbalanced MZI by harnessing the thermo-optic and electro-optic effect is investigated,achieving a linear tuning efficiency of 42.8 pm/℃ and 55.2 pm/V,respectively.The demonstrated structure has applications for sensing and filtering in photonic integrated circuits.
基金supported by the Fundamental Research Project Funding from Shenzhen Science & Technology Innovation Committee (JCYJ20180507181718203)the National Natural Science Foundation of China (21975213)+2 种基金the Research Grants Council (RGC) of Hong Kong (11306320, 11303618, 11210218)the City University of Hong Kong (9610389, 9680263, 9610454)the Innovation and Technology Commission of Hong Kong (ITS/461/18)。
文摘The determination of nonlinearities near the band edge of organic and polymeric electro-optic(EO)materials is important from the viewpoint of molecular nonlinear optics(NLO)and photonic device applications.Based on transmission-mode Stark effect electromodulation(EM)spectroscopy,we study the electric-field-induced changes in optical absorption and refraction of newly developed EO polymers from the visible to near-infrared(NIR)wavelengths and report record-high near-band-edge complex EO effects from poled thin films.Values ofΔn andΔk up to 10^(-3) and 10^(-2) are found at an applied electric field of 2.0×10^(5)-3.0×10^(5)V/cm.The study of linear optical properties of poled films by spectroscopic ellipsometry shows large polinginduced birefringence and a nearly two-fold increase in the extinction coefficients at the extraordinary polarization.Through the Kramers-Kronig analysis,we obtained the real and imaginary second-order nonlinear coefficients up to~3,500 and~5,600 pm/V,respectively,which are believed to be the highest NLO coefficients of poled polymers through the resonance enhancement.Our approach goes beyond the previous works,applicable only to several discrete wavelengths,to a full-spectral analysis with independent verification of slab waveguide measurements.By considering both the electroabsorption and electrorefraction effects,our study overcomes the limitation of the classic qualitative two-level model and provides a quantitative understanding of near-resonance optical nonlinearities of organic EO materials.It can inspire the exploration of high-speed,absorptive,or phase-shifting light-modulators using EO polymers for on-chip applications.