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STUDY ON POLYMER-Ru-Co BIMETALLIC COMPLEXES CATALYSTS Ⅱ.X-RAY PHOTOELECTRON SPECTROSCOPIC ANALYSIS
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作者 宗惠娟 汤琪 +1 位作者 陈宗翰 江英彦 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 1991年第2期171-176,共6页
Polymer Ru-Co bimetallic complexes have been examined by X-ray photoelectron spectroscopy.The catalyst is highly active only when the mole ratio of Co/Ru is 4: 3. The activity of catalysts does not depend on the total... Polymer Ru-Co bimetallic complexes have been examined by X-ray photoelectron spectroscopy.The catalyst is highly active only when the mole ratio of Co/Ru is 4: 3. The activity of catalysts does not depend on the total Co/Ru ratio, but on the surface stoichiometry of Co and Ru. When the relative intensities of Co_2_p and Ru_(3d) of XPS peaks are close to each other and both are high,the catalyst exhibits its maximum activity The mechanism ofcatalytic hydroformylation has been discussed. 展开更多
关键词 Polymer bimetallic complex HYDROFORMYLATION XPS Struc.ture of bimetallic complex
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STUDY ON POLYMER—Ru-Co—BIMETALLIC COMPLEXES CATALYSTS Ⅰ. SYNTHESIS OF CATALYSTS AND THEIR USE FOR THE HYDROFORMYLATION
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作者 汤琪 宗惠娟 +1 位作者 陈宗翰 江英彦 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 1991年第1期39-47,共9页
Six kinds of polymer ligands, supported on SiO_2, containing coordinating atoms P, S and N respectively, have been synthesized. The Ru(Ⅲ)-Co(Ⅱ) bimetallic complexes of these polymer ligands have been obtained and ex... Six kinds of polymer ligands, supported on SiO_2, containing coordinating atoms P, S and N respectively, have been synthesized. The Ru(Ⅲ)-Co(Ⅱ) bimetallic complexes of these polymer ligands have been obtained and examined as catalysts for the hydroformylation of cyclohexene. The effects of reaction temperature, pressure and Co/Ru ratio etc. on the activities of catalysts were investigated in detail. The catalysts are all polymer-noncarbonyl-metal complexes, easily to be prepared, active and stable. From the experimental results it can be suggested that under reaction conditions such polymer-noncarbonyl-metal complexes convert 'in situ' to polymer-carbonyl-metal complexes, thus become active catalysts. The course of this conversion is supposed as a preliminary approach. 展开更多
关键词 Polymer catalyst bimetallic complex Cydohexene HYDROFORMYLATION
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Syntheses and Crystal Structures of Two Cyano-bridged Bimetallic Complexes [Ce(DMSO)_4(H_2O)_3Fe(CN)_6]·H_2O and [La(DMSO)_4(H_2O)_3Co(CN)_6]·H_2O(DMSO = Dimethylsulfoxide)
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作者 赵振乾 陈文通 +3 位作者 刘玺 蔡丽珍 郭国聪 黄锦顺 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2006年第12期1481-1486,共6页
Two new bimetallic cyano-bridged complexes [Ce(DMSO)4(H2O)3Fe(CN)6]·H2O 1 and [La(DMSO)4(H20)3Co(CN)6].H20 2 have been prepared by the ball milling reaction method and structurally characterized by X-... Two new bimetallic cyano-bridged complexes [Ce(DMSO)4(H2O)3Fe(CN)6]·H2O 1 and [La(DMSO)4(H20)3Co(CN)6].H20 2 have been prepared by the ball milling reaction method and structurally characterized by X-ray single-crystal structure analyses. Crystallographic data for 1: C14H32CeFeN6O8S4, Mr= 736.67, monoclinic, space group P2 1/n, a = 14.952(1), b = 13.7276(9), c = 15.392(1) A, β= 108.288(1)°, V = 2999.6(4) A3, Z = 4, Dc= 1.631 g/cm^3, g = 2.304 mm^-1, F(000) = 1480, R = 0.0593 and wR = 0.1611; and those for 2: C14H32CoLaN6O8S4, Mr=738.54, monoclinic, space group P21/n, a = 14.945(3), b = 13.731(3), c = 15.300(3) A, β= 107.806(1)°, V= 2989.3(11) A^3, Z= 4, Dc = 1.641 g/cm^3, μ = 2.288 mm^-1, F(000) = 1480, R = 0.0383 and wR = 0.1132. In both complexes the lanthanide ion is eight-coordinated in a square antiprism arrangement, and the Fe(Ⅲ) or Co(Ⅲ) ion in a nearly regular octahedral environment The [LnM(CN)6(DMSO)4(H2O)3]·H2O (Ln = Ce and M = Fe for 1; Ln = La and M = Co for 2) species are held together via hydrogen bonds by coordinated water molecules, lattice water molecules and nitrogen atoms of cyanide groups to form a three-dimensional framework. 展开更多
关键词 crystal structure eyano-bridged bimetallic complex hydrogen bond lanthanide complex
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Syntheses and Crystal Structures of Two Cyano-bridged Bimetallic Complexes [Ln(DMSO)_2(H_2O)(μ-CN)_4Fe(CN)_2] (Ln = Ce and Eu, DMSO = Dimethylsulfoxide) with Layered Structure
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作者 赵振乾 蔡丽珍 +2 位作者 陈文通 郭国聪 黄锦顺 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2008年第6期753-756,共4页
Two new bimetallic cyano-bridged complexes [Ln(DMSO)2(H2O)(μ-CN)4Fe(CN)2] (Ln = Ce 1, Eu 2) have been prepared by the grinding reaction method and structurally characterized by X-ray single-crystal structur... Two new bimetallic cyano-bridged complexes [Ln(DMSO)2(H2O)(μ-CN)4Fe(CN)2] (Ln = Ce 1, Eu 2) have been prepared by the grinding reaction method and structurally characterized by X-ray single-crystal structure analysis. Crystallographic data for 1: C10H14CeFeN6O3S2, Mr = 526.36, monoclinic, P2/n, a = 7.852(4), b = 10.729(5), c = 11.181(5)A,β = 96.992(8)°, V = 935.0(7) A^3, Z = 2, Dc = 1.870 g/cm^3,/1 = 3.421 mm^-1, F(000) = 512, R = 0.0363 and wR = 0.0971; and those for 2: C10H14EuFeN6O3S2, Mr = 538.20, monoclinic, P21n, a = 7.739(5), b = 10.668(7), c = 11.008(7) A,β = 96.943(3)°, V = 902.1(11) A^3, Z = 2, Dc = 1.981 g/cm^3,/1 = 4.499 mm^-1, F(000) = 522, R = 0.0345 and wR = 0.0855. In each complex the lanthanide ion is seven-coordinated in a pentagonal bipyramidal arrangement, and the Fe(Ⅲ) ion is in a nearly regular octahedral environment. The title complexes can be described as two- dimensional (2-D) stair-like structures, which are further connected by hydrogen bonds to form three-dimensional (3-D) frameworks. 展开更多
关键词 crystal structure cyano-bridged bimetallic complex grinding reaction method
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CATALYTIC BEHAVIOR OF SILICA-SUPPORTED POLY-γ- AMINOPROPYL- SILOXANE-Co-Ru BIMETALLIC COMPLEX FOR THE HYDROFORMYLATION OF CYCLOHEXENE 被引量:1
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作者 关士友 黄美玉 江英彦 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 1993年第2期103-108,共6页
The cobalt and ruthenium bimetallic complex of poly-γ-amino-propylsiloxane( abbr. as Si-CH_2-Co-Ru) was prepared, and it was found that it can catalyze the hydroformylation of cyclobexene effectively with the convers... The cobalt and ruthenium bimetallic complex of poly-γ-amino-propylsiloxane( abbr. as Si-CH_2-Co-Ru) was prepared, and it was found that it can catalyze the hydroformylation of cyclobexene effectively with the conversion amounting to over 90%. Cyclohexanecarboxaldehyde was first formed in the hydroformylation, and then further hydrogenated to form cylcohexanemethanol. The coversion was affected obviously by the Co/Ru ratio.When Co/Ru molar ratio was 100-150, i.e. in the very low content of noble metal Ru, the catalytic activity of Si-NH_2 -Co-Ru was also very high. The product composition was affected by CO/H_2 ratio in the reaction gas. Aldehyde can be got high selectively by controlling CO/H_2 ratio. Compared with other catalyst system, the Si-NH_2-Co-Ru catalyst has higher catalytic activity and efficiency with very low Ru/Co ratio. The total turnover number was more than 28,800 (based on the amount of ruthenium used). 展开更多
关键词 Cobalt and ruthenium bimetallic complex of poly-γ-aminopropylsiloxane catalyst CYCLOHEXENE HYDROFORMYLATION Cyclohexanecarboxaldehyde
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Syntheses and Structural Characterizations of η~5-2,4-Cyclopentadien-1-yl Di-carbonyliron Heteronuclear Bi-Metallic Complexes
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作者 GAO Jin sheng MA Zhong guo +5 位作者 YE Ling BU Wei ming MA Dong sheng YU Chang hua GE Yue FAN Yu guo 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2001年第1期63-68,共6页
The novel complexes, Cp(CO) 2FeTiCp 2Cl(1) and Cp(CO) 2FeSn(CH 2CMe 2Ph) 3(2), were synthesized and characterized by means of elemental analyses and IR spectra, Cp(CO) 2FeSn· (CH 2CMe 2Ph) 3 was addi... The novel complexes, Cp(CO) 2FeTiCp 2Cl(1) and Cp(CO) 2FeSn(CH 2CMe 2Ph) 3(2), were synthesized and characterized by means of elemental analyses and IR spectra, Cp(CO) 2FeSn· (CH 2CMe 2Ph) 3 was additionally characterized by X ray crystal structure analysis. The results of the elemental analyses are in good agreement with the theoretical values. The IR spectra show the existence of η 5 2,4 cyclopentadien 1 yl, carbonyl and methyl groups in the title complexes. The above experimental results show that the M-M bond exists in Cp(CO) 2FeSn· (CH 2Me 2Ph) 3, while the existence of the M-M bond in Cp(CO) 2FeTiCp 2Cl is highly possible, too. Both the two complexes are rather stable towards air and moisture, easily soluble in tetrahydrofuran and toluene, while their solubilities are greatly different in n hexane. 展开更多
关键词 Metal metal bond Heteronuclear bimetallic complex Synthesis Characterization Crystal structure
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Synthesis and Molecular Structure of A Bimetallic Salen Complex Containing Zn and La: A Disordered Nitrate Group Dancing between Two Metal Centers
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作者 Leon Dyers Jr Donald Van Derveer Xiu R Bu 《Journal of Rare Earths》 SCIE EI CAS CSCD 2005年第3期257-261,共5页
A new bimetallic complex containing Zn and La was prepared from a salen ligand possessing methoxyl groups at the 3, 3′-positions. The structural feature is that one of nitrate groups is disordered and displaced betwe... A new bimetallic complex containing Zn and La was prepared from a salen ligand possessing methoxyl groups at the 3, 3′-positions. The structural feature is that one of nitrate groups is disordered and displaced between two metal centers. Crystal system: Triclinic space group:P-1, Z=2. a=0.82714(17) nm, b=1.3484(3) (1) nm, and c=1 3898(3) (1) nm, α=79.89(3)°, β=76.67(3)°, and γ=72.43(3)°. V=1 428 6(5) nm3, Dx=1.812 g·cm-3. (Δρ)max=1 510×10-3 enm3, (Δρ)min=-1.503×10-3 enm3. Accordingly, two water molecules occupy the metal centers in the apical positions via the syn-geometry. 展开更多
关键词 bimetallic complex zinc lanthannm rare earths
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HYDROFORMYLATION OF MMA CATALYZED BY SILICA-SUPPORTED POLY-γ-AMINO PROPYLSILOXANE-Rh-Co BIMETALLIC COMPLEX
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作者 唐黎明 黄美玉 江英彦 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 1995年第4期331-337,共7页
A silica-supported poly-γ- aminopropylsiloxane-rhodium-cobalt bimetallic complex(abbreviated as SiO_2-NH_2-Rh-Co)has been prepared and used as catalyst for hydroformylationof methyl methacrylate. The results showed t... A silica-supported poly-γ- aminopropylsiloxane-rhodium-cobalt bimetallic complex(abbreviated as SiO_2-NH_2-Rh-Co)has been prepared and used as catalyst for hydroformylationof methyl methacrylate. The results showed that the catalyst could catalyze the reaction in95.6% conversion with 92.8% selectivity for the normal aldehyde, methyl β-formylisobu-tyrate. Such catalyst also showed high stability during the reaction and could be used repeat-edly. 展开更多
关键词 Silica-supported poly-γ-aminopropylsiloxane Rhodium-cobalt bimetallic complex HYDROFORMYLATION Methyl methacrylate
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Synthesis and Crystal Structure of a Cyano- bridged Bimetallic Complex[La(DMSO)_3(H_2O)_3- Cr(CN)_6]·H_2O (DMSO = Dimethylsulfoxide) with One-dimensional Chain Molecular Structure
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作者 梁淑惠 车云霞 郑吉民 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2004年第11期1226-1229,共4页
The title complex [La(DMSO)3(H2O)3Cr(CN)6]H2O was obtained by the reaction of LaCl37H2O, DMSO and K3[Cr(CN)6] in aqueous solution on a hot water bath. The crystal crystallizes in orthorhombic, space group P212121 with... The title complex [La(DMSO)3(H2O)3Cr(CN)6]H2O was obtained by the reaction of LaCl37H2O, DMSO and K3[Cr(CN)6] in aqueous solution on a hot water bath. The crystal crystallizes in orthorhombic, space group P212121 with a = 9.827(3), b = 15.037(4), c = 17.633(5) ? C12H26CrLaN6O7S3, Mr = 653.48, Z = 4, V = 2605.7(13) ?, Dc = 1.666 g/m3, (MoKa) = 2.314 mm-1, F(000) = 1300, R = 0.0205 and wR = 0.0481 for 5038 observed reflec- tions (I > 2s(I)). La3+ ion is eight-coordinated by three DMSO molecules, three H2O molecules and two [Cr(CN)6]3- units. The structure of the title complex possesses a cyano-bridged one- dimensional zigzag chain structure with alternating La(DMSO)3(H2O)3 and Cr(CN)6 moieties, which are linked by some hydrogen bonds to form a 3D network structure. 展开更多
关键词 crystal structure synthesis cyano-bridged bimetallic complex hydrogen bond
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Synthesis and Crystal Structure of a Cyano-bridged Bimetallic Complex[La(betaine)_2(H_2O)_6Fe(CN)_6]·2H_2O
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作者 LIANGShu-Hui CHEYun-Xia ZHENGJi-Min 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2005年第4期424-428,共5页
The title complex [La(betaine)2(H2O)6Fe(CN)6]?2H2O (betaine = (CH3)3NCH2CO2) has been synthesized and characterized by X-ray single-crystal structure analysis. The crystal crystallizes in monoclinic, space group P21... The title complex [La(betaine)2(H2O)6Fe(CN)6]?2H2O (betaine = (CH3)3NCH2CO2) has been synthesized and characterized by X-ray single-crystal structure analysis. The crystal crystallizes in monoclinic, space group P21/n with a = 15.793(5), b = 8.927(3), c = 22.257(7) ?, β = 110.147(5)o, C16H38FeLaN8O12, Mr = 729.31, Z = 4, V = 2946.0(15) ?3, Dc = 1.640 g/m3, μ(MoKα) = 1.988 mm-1, F(000) =1476, R = 0.0388 and wR = 0.0827 for 4237 observed reflections (I > 2σ(I)). The La3+ ion is nine-coordinated by one cyano nitrogen atom and eight oxygen atoms of two betaine and six water molecules. Each complex molecule is connected to form a 3D network structure by some O–H…O and O–H…N hydrogen bonds. 展开更多
关键词 crystal structure SYNTHESIS cyano-bridged bimetallic complex hydrogen bond
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Synthesis and Crystal Structure of a Cyano-bridged Bimetallic Complex:[NdFe(CN)_6(DMF)_4(H_2O)_3]H_2O
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作者 LiJian-Rong BUXian-He 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2003年第2期182-186,共5页
A new bimetallic cyano-bridged complex, [NdFe(CN)6(DMF)4(H2O)3]H2O (DMF = N,N-dimethylformamide) 1, has been obtained by the reaction of hexacyanoferrate potassium with neodymium (Ⅲ) chloride in H2O/EtOH/DMF (volume ... A new bimetallic cyano-bridged complex, [NdFe(CN)6(DMF)4(H2O)3]H2O (DMF = N,N-dimethylformamide) 1, has been obtained by the reaction of hexacyanoferrate potassium with neodymium (Ⅲ) chloride in H2O/EtOH/DMF (volume ratio: 2:2:1), and its structure was determined by means of single-crystal X-ray diffraction. The compound crystallizes in space group P21/n of monoclinic system with cell parameters: a = 17.646(1), b = 8.9011(3), c = 19.945(1) ? b = 95.835(2)? V = 3116.6(3) ?, Z = 4, Dc = 1.536 g/cm3, Mr = 720.66, F(000) = 1456, m = 2.166 mm-1, R = 0.0386, wR = 0.1120 and S = 1.061. The central Nd (Ⅲ) ion is coordinated by seven oxygen atoms of four DMF molecules and three water molecules and one nitrogen atom of the bridging cyanide in a slightly distorted square-antiprism arrangement, and the Fe (Ⅲ) ion is in an almost octahedral environment coordinated to six cyano-ligands, of which one cyanide ligand bridges the Nd (Ⅲ) ion to form a bimetallic complex. Molecules of complexes in the crystal lattice are held together by hydrogen bonding, forming a three-dimensional framework. 展开更多
关键词 crystal structure cyano-bridged bimetallic complex neodymium (Ⅲ) complex ion (Ⅲ) complex
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SPECTROPHOTOMETRIC STUDY OF BIMETALLIC TERNARY COMPLEX OF LANTHANUM——COPPER WITH ALIZARIN FLUORINE BLUE
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《Chemical Research in Chinese Universities》 SCIE CAS 1986年第1期65-75,共11页
The bimetallic ternary complex formation in the aqueous solution of La and Cu with alizarin fluorine blue (AFB) was studied by spectrophotometry.The ternary complex LaCu3(AFB)3 has maximum light absorption at 550nm.Th... The bimetallic ternary complex formation in the aqueous solution of La and Cu with alizarin fluorine blue (AFB) was studied by spectrophotometry.The ternary complex LaCu3(AFB)3 has maximum light absorption at 550nm.The colour reaction selectivity is fairly good and the method can be applied to the direct photometric determination of copper in lanthanum or some pure metals.A new mathematical approach to the treatment of spectrophotometric data for differentiation between mononuclear and polynuclear in solution is presented.The improvable fixed logarithm method is for complexes of the type MmBn(m=n) or MmBn(m=n).We report that La(Ⅲ) combines with AFB at pH 4.5 to form a single complex,withm=n=2,La2(AFB)2. 展开更多
关键词 AFB La SPECTROPHOTOMETRIC STUDY OF bimetalLIC TERNARY COMPLEX OF LANTHANUM COPPER WITH ALIZARIN FLUORINE BLUE
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Synthesis and Crystal Structure of Tetra((8-quinolyl)-amido-N)ytterbium Bi(tetrahydrofuran-O)lithium
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作者 李邦玉 姚英明 +2 位作者 王耀荣 张勇 沈琪 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2011年第10期1459-1463,共5页
The treatment of the mixture of n-BuLi with 1 equiv.8-aminoquinoline in THF in situ,which reacted further with 1/3 equiv.of YbCl3 in THF,to give the homoleptic lanthanide amide ate complex Yb(NH-C9H6N)4Li(C4H8O)2... The treatment of the mixture of n-BuLi with 1 equiv.8-aminoquinoline in THF in situ,which reacted further with 1/3 equiv.of YbCl3 in THF,to give the homoleptic lanthanide amide ate complex Yb(NH-C9H6N)4Li(C4H8O)2(1).The crystal structure was determined by X-ray diffraction and the following crystallographic data were obtained:C44H44N8O2YbLi,Mr = 896.85,monoclinic,space group C2/c,a = 7.8384(16),b = 22.294(5),c = 22.668(5),β = 97.614(5)°,V = 3926.3(14)3,Z = 4,Dc = 1.517 g/cm3,F(000)= 1812,μ(MoKα)= 2.431 mm-1,R = 0.0542 and wR = 0.1523 for 3372 observed reflections with I 2σ(I).The structure of molecule 1 consists of one ytterbium atom,one lithium atom,four 8-aminoquinoline ligands and two THF molecules.The ytterbium atom is coordinated by eight nitrogen atoms of four 8-aminoquinoline ligands,forming a distorted dodecahedral geometry. 展开更多
关键词 YTTERBIUM 8-AMINOQUINOLINE crystal structure bimetallic complex
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Syntheses of bimetallic lanthanide bis(amido) complexes stabilized by bridged bis(guanidinate) ligands and their catalytic activity toward the hydrophosphonylation reaction of aldehydes and ketones
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作者 Kun Nie Chengwei Liu +1 位作者 Yong Zhang Yingming Yao 《Science China Chemistry》 SCIE EI CAS CSCD 2015年第9期1451-1460,共10页
A series of bimetallic lanthanide bis(amido) complexes stabilized by bridged bis(guanidinate) ligands {[(Me3Si)2N]2Ln[(RN)2-CN(CH2)2]}2 [R=iPr, Ln=Sm(1), Yb(2), Y(3); R=cyclohexyl(Cy), Ln=Sm(4), and Yb(5)] were synthe... A series of bimetallic lanthanide bis(amido) complexes stabilized by bridged bis(guanidinate) ligands {[(Me3Si)2N]2Ln[(RN)2-CN(CH2)2]}2 [R=iPr, Ln=Sm(1), Yb(2), Y(3); R=cyclohexyl(Cy), Ln=Sm(4), and Yb(5)] were synthesized through the metathesis reactions of {Ln(μ-Cl)[N(Si Me3)2]2(THF)}2(Ln=Sm, Yb, Y) with lithium guanidinate {Li[(RN)2CN(CH2)2]}2(R=iPr, Cy), the latter of which was generated in situ by the reaction of carbodiimides with lithium amides. Complexes 1–5 were well characterized by elemental analyses, IR spectra, and(for Complex 3) NMR spectroscopy. The solid-state molecular structures of all of the complexes were determined by single-crystal X-ray analyses with the exception of Complex 3, which showed similar unsolvated centrosymmetric dinuclear structures. Each of the lanthanide centers is four-coordinated with two nitrogen atoms from a guanidinate ligand and two nitrogen atoms from two amido groups. The piperazidine rings adopt chair conformations in all cases. These organolanthanide complexes were found to be efficient catalysts for the hydrophosphonylation reaction of various aldehydes and unactivated ketones and to afford ?-hydroxyphosphonates in high yields under low catalyst loading(0.1 mol%) in a short reaction time. 展开更多
关键词 bimetallic lanthanide complex bridged bis(guanidinate) ligand hydrophosphonylation reaction aldehyde ketone
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Synthesis and Crystal Structure of Cu_2(pba)(bpy)_2Cl_2·4H_2O
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作者 朱志成 黄小平 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2000年第5期322-325,共4页
A new copper complex, Cu2(pba)(bpy)2Cl2·4H2O (here pba was propylenebis (oxamic acid), bpy was bipyridine), was synthesized. Crystal structure of the title complex was determined. It belongs to the tetrag... A new copper complex, Cu2(pba)(bpy)2Cl2·4H2O (here pba was propylenebis (oxamic acid), bpy was bipyridine), was synthesized. Crystal structure of the title complex was determined. It belongs to the tetragonal system, molecular formula Cu2Cl2O 10N6C 27H 32, Mr=798.58, space group P41212, a=b=9.484(4), c=35\^918(9), V=3235(2)3, Dx=1.64gcm -3 and F(000)=1568, μ=1\^546mm -1 for Z=4. The crystal structure was solved by direct methods for final R=0\^048 and Rw=0.060 for 1992 observed reflections with I>3σ(I). The complex has a C2 symmetry. A chloride anion, two nitrogen atoms from bipyridine and two oxygen atoms from the oxamide carbonyl and carboxyl coordinated to the Cu II ion forming a square pyramidal geometry. In each molecule, two bpy are almost parallel. 展开更多
关键词 bimetallic complexes crystal structure N N'\|dioxamide\|1 3\|propylenebiamine
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Crystal and Molecular Structure of Methylene-bis[benzobicyclo(diaza-diphenyl) stannoxide],[o-O■n(C_6H_5)_2]_2CH_2·1/2C_6H_6
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作者 王积涛 高生华 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 1994年第2期91-94,共4页
Methylene-bis[benzobicyclo(diaza-diphenyl) stannoxide,C_(41)H_(34)N_4O_4Sn_2·1/2C_6H_6],Mr=923.19,m.p.126-127℃,triclinic,P1,a=9.780(4),b=14.485(2),c=15.122(6),α=74. 95(3),β=72.21(3),γ=82.68(2)°,V=1967(1)... Methylene-bis[benzobicyclo(diaza-diphenyl) stannoxide,C_(41)H_(34)N_4O_4Sn_2·1/2C_6H_6],Mr=923.19,m.p.126-127℃,triclinic,P1,a=9.780(4),b=14.485(2),c=15.122(6),α=74. 95(3),β=72.21(3),γ=82.68(2)°,V=1967(1) Z=2,Dx=1.56 g/cm ̄3, MoKα(λ=0.71073),μ=13.20 cm-1,F(000)=922;final R=0.045, Rw=0.046 for 3637 observed reflections(I≥3σ(I)).The title compound is a bimetallo-heterocyclic complex prepared by condensation.Each tin atom has a trigonal bipyramidal coordination with two oxygen atoms occupying the axial positions. 展开更多
关键词 crystal structure bimetallic complex five-coordinated-tin complex
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Synthesis and Crystal Structure of a Mixed Cu - Cd Bim etallic Com plex {〔 Cu Cd(pba)( H_2 O)_3〕·2 H_2 O} _n
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作者 朱志成 黄小荥 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 1999年第5期340-343,共4页
A one dimensional bimetallic compound {〔CuCd(pba)(H 2O) 3〕·2H 2O} n in which pba was propylenebis (oxamic acid), was prepared. Crystal structure of the title compound was determined. It belongs to orthorhombi... A one dimensional bimetallic compound {〔CuCd(pba)(H 2O) 3〕·2H 2O} n in which pba was propylenebis (oxamic acid), was prepared. Crystal structure of the title compound was determined. It belongs to orthorhombic system, molecular formula CuCdC 7H 16 N 2O 11 , M r =480.17, space group Pnma(#62), a=12.953(2), b=21 626(6), c=5.253(3), V=1471(2) 3 and D x =2.17g/cm 3 for Z =4. The structure was solved by direct methods with final R =0.052 and R w =0.063 for 1055 observed reflections with I>3σ(I ). Two nitrogen atoms and two oxygen atoms from the oxamide and a water molecule coordinated to the Cu II ion forming a square pyramidal geometry. Four oxygen atoms from the oxamide and two water molecules coordinated to the Cd II ion forming an elongated octahedral geometry. 展开更多
关键词 one dimensional complex X ray structure bimetallic link complex
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Diatomic Pd catalyst with conjugated backbone for synergistic electrochemical CO_(2)reduction
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作者 Wenxuan Zhang Mengran Zhang +2 位作者 Hongjuan Wang Wen Zhang Min Zhang 《Nano Research》 SCIE EI CSCD 2024年第6期4850-4855,共6页
Double-site catalysts have attracted widespread attention in the field of electrocatalysis due to their high metal loading,adjustable active centres,and electronic valence states.However,the development of bimetallic ... Double-site catalysts have attracted widespread attention in the field of electrocatalysis due to their high metal loading,adjustable active centres,and electronic valence states.However,the development of bimetallic sites catalysts that coordinate with definite atoms is still in the exploratory stage.Here,we designed and synthesized a bimetallic palladium complex(BPB-Pd_(2))with conjugated backbone.The supported BPB-Pd_(2)was applied to electrochemical CO_(2)reduction reaction(CO_(2)RR)for the first time.The as-obtained BPB-Pd_(2)gives an exceptional Faradaic efficiency of CO(FECO)of 94.4%at−0.80 V vs.reversible hydrogen electrode(RHE),which is significantly superior to monoatomic palladium catalyst(BPB-Pd1).The density functional theory(DFT)calculations revealed that the essential reason for the outstanding activity of BPB-Pd_(2)toward CO_(2)RR was that the electronic effect between diatomic palladium reduces the free energy change for CO_(2)RR process.Thus,BPB-Pd_(2)exhibits moderate free energy change to form COOH*intermediate,which was beneficial for the generation of CO in CO_(2)RR. 展开更多
关键词 synthesis electrocatalysis CO_(2)reduction bimetallic palladium complex synergistic catalysis
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