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Random Binary Brush Architecture Enhances both Ionic Conductivity and Mechanical Strength at Room Temperature 被引量:1
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作者 Yu-Feng Lyu Zhi-Jie Zhang +3 位作者 Chang Liu Zhi Geng Long-Cheng Gao Quan Chen 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2018年第1期78-84,共7页
The ionic conductivity and the mechanical strength are two key factors for the performance of poly(ethylene oxide)(PEO) based polyelectrolytes. However, crystallized PEO suppresses ion conductivity at low temperat... The ionic conductivity and the mechanical strength are two key factors for the performance of poly(ethylene oxide)(PEO) based polyelectrolytes. However, crystallized PEO suppresses ion conductivity at low temperature and melted PEO has low mechanical strength at high temperature. Here, random binary brush copolymer composed of PEO-and polystyrene(PS)-based side chains is synthesized. PEO crystallinity is suppressed by the introduction of PS brushes. Doping with lithium trifluoromethanesulfonate(Li Tf) induces microphase separation. Due to a random arrangement of the brushes, the microphase segregation is incomplete even at high salt loading, which provides both high ionic conductivity and high mechanical strength at room temperature. These results provide opportunities for the design of polymeric electrolytes to be used at room temperature. 展开更多
关键词 binary brush copolymer PEO Ionic conductivity Phase separation
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