The binding conformations of bidentate ligand DABCO(1,4-diazobicyclo [2,2,2]octane) to a series of p'p type zinc porphyrin dimers covalently linked with flexible alkoxy chain - O(CH2)(n)O- (n=2-10) are described b...The binding conformations of bidentate ligand DABCO(1,4-diazobicyclo [2,2,2]octane) to a series of p'p type zinc porphyrin dimers covalently linked with flexible alkoxy chain - O(CH2)(n)O- (n=2-10) are described by H-1 NMR and UV-vis spectroscopy. DABCO can bind inside the cavities of porphyrin dimers and form a ternary sandwich complex as the alkoxy chain length is long enough. The thermodynamic parameters which control the binding behavior are investigated.展开更多
基金the National Natural Science Foundation (29871018) and Tianjin Science and Technology Committee Foundation (983602611) of China
文摘The binding conformations of bidentate ligand DABCO(1,4-diazobicyclo [2,2,2]octane) to a series of p'p type zinc porphyrin dimers covalently linked with flexible alkoxy chain - O(CH2)(n)O- (n=2-10) are described by H-1 NMR and UV-vis spectroscopy. DABCO can bind inside the cavities of porphyrin dimers and form a ternary sandwich complex as the alkoxy chain length is long enough. The thermodynamic parameters which control the binding behavior are investigated.
