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Vegetable Oil-Based Nanolubricants in Machining:From Physicochemical Properties to Application 被引量:6
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作者 Xiaotian Zhang Changhe Li +9 位作者 Zongming Zhou Bo Liu Yanbin Zhang Min Yang Teng Gao Mingzheng Liu Naiqing Zhang Zafar Said Shubham Sharma Hafiz Muhammad Ali 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2023年第4期4-42,共39页
Cutting fluid is crucial in ensuring surface quality and machining accuracy during machining.However,traditional mineral oil-based cutting fluids no longer meet modern machining’s health and environmental protection ... Cutting fluid is crucial in ensuring surface quality and machining accuracy during machining.However,traditional mineral oil-based cutting fluids no longer meet modern machining’s health and environmental protection require-ments.As a renewable,pollution-free alternative with excellent processing characteristics,vegetable oil has become an inevitable replacement.However,vegetable oil lacks oxidation stability,extreme pressure,and antiwear proper-ties,which are essential for machining requirements.The physicochemical characteristics of vegetable oils and the improved methods’application mechanism are not fully understood.This study aims to investigate the effects of viscosity,surface tension,and molecular structure of vegetable oil on cooling and lubricating properties.The mechanisms of autoxidation and high-temperature oxidation based on the molecular structure of vegetable oil are also discussed.The study further investigates the application mechanism and performance of chemical modification and antioxidant additives.The study shows that the propionic ester of methyl hydroxy-oleate obtained by epoxidation has an initial oxidation temperature of 175℃.The application mechanism and extreme pressure performance of conventional extreme pressure additives and nanoparticle additives were also investigated to solve the problem of insufficient oxidation resistance and extreme pressure performance of nanobiological lubricants.Finally,the study discusses the future prospects of vegetable oil for chemical modification and nanoparticle addition.The study provides theoretical guidance and technical support for the industrial application and scientific research of vegetable oil in the field of lubrication and cooling.It is expected to promote sustainable development in the manufacturing industry. 展开更多
关键词 Cutting fluid Vegetable oil Chemical modification ANTIOXIDANT Extreme pressure additive Minimum quality lubrication
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Molecular Mechanism and Molecular Design of Lubricating Oil Antioxidants 被引量:1
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作者 Su Shuo Long Jun +2 位作者 Duan Qinghua Zhou Han Zhao Yi 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS CSCD 2024年第2期135-145,共11页
To overcome the limitations of traditional experimental“trial and error”methods in lubricant additive design,a new molecular design method based on molecular structure parameters is established here.The molecular me... To overcome the limitations of traditional experimental“trial and error”methods in lubricant additive design,a new molecular design method based on molecular structure parameters is established here.The molecular mechanism of the antioxidant reaction of hindered phenol,diphenylamine,and alkyl sulfide are studied via molecular simulations.Calculation results show that the strong electron-donating ability and high hydrogen-donating activity of the antioxidant molecule and the low hydrogen-abstracting activity of free radicals formed after dehydrogenation are the internal molecular causes of the shielding of phenol and diphenylamine from scavenging peroxy free radicals,and the strong electron-donating ability is the internal molecular cause of the high activity of thioether in decomposing alkyl hydrogen peroxide.Based on this antioxidant molecular mechanism,a molecular design rule of antioxidant is proposed,namely“high EHOMO,large Q(S),low bond dissociation energy BDE(O—H)and BDE(N—H)”.Two new antioxidants,PAS-I and PAS-II,are designed and prepared by chemical bonding of hindered phenol,diphenylamine,and sulfur atoms.Experimental results show that these antioxidants both have excellent antioxidant effects in lubricating oil,and that PAS-II is the superior antioxidant,consistent with theoretical predictions. 展开更多
关键词 lubricating oil ANTIOXIDANT molecular mechanism molecular design antioxidant performance
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Next Generation Lubricants and Their Potential Use in Fertility Treatment
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作者 Bayley Richardson Alisa White +1 位作者 Lindsay L. Penrose Sam Prien 《Advances in Reproductive Sciences》 2023年第4期106-115,共10页
While generally recognized as a potential source of contamination during the collection process, lubricants are often used at the preference of the male partner to prevent irritation. While older lubricants have been ... While generally recognized as a potential source of contamination during the collection process, lubricants are often used at the preference of the male partner to prevent irritation. While older lubricants have been studied, there is currently no conscience within programs as to what constitutes a “safe” lubricant. The object of the current study was designed to evaluate chemically unique “next generation” lubricants in comparison to lubricants currently in use in fertility treatment and/or recognized as fertility safe;the first was a silicone-based lubricant, the second is a water-based, plant-based organic compound, in comparison to two established medical lubricants and a control. Twelve deidentified semen samples from the clinical andrology laboratory were used to test the lubricants following semen analysis. In order to enter the study, the sample had to have a minimum of 30 × 10<sup>6</sup> motile cells. Samples were then processed using a simple sperm wash modified to reconstitute the pellet into a final volume of 7 mL. Half-milliliter aliquots were then transferred into 13 wells of a standard 24-well culture plate. One well was used as a control. The remaining wells received one of the four lubricants at one of three volumes (10, 50, or 100 uL), producing 12 treatment combinations (four lubricants + 3 concentration levels) and the control. The samples were then cultured at room temperature for 24 hours. At times 0, 1, 3, 12, and 24 hrs, the plate was agitated to remix the sample, and a 4 uL aliquot of each well was analyzed for standard semen parameters using a computer-assisted semen analyzer. Results indicated the expected decrease in semen parameters over time in all treatments (P < 0.001). There was also a dose-dependent drop in most of the lubricants. However, samples contaminated with the newer lubricants appeared to maintain semen parameters similar to the controls at all but the 100 ul level of contamination, while the older lubricants caused decreases in sperm function at much lower concentrations. While semen parameters alone should not be the only criteria for the selection of a lubricant, the present study suggests newer formulations of lubricant are less likely to interfere with sperm function. 展开更多
关键词 lubricants FERTILITY CONTAMINATION Next-Generation
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Synthesis and mechanism of environmentally friendly high temperature and high salt resistant lubricants
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作者 Zong-Lun Wang Jin-Sheng Sun +6 位作者 Jing-Ping Liu Kai-He Lv Zi-Hua Shao Xian-Fa Zhang Zhe Xu Zhi-Wen Dai Ning Huang 《Petroleum Science》 SCIE EI CSCD 2023年第5期3110-3118,共9页
With the exploration and development of deep and ultra-deep oil and gas,high torque and high friction during the drilling of deep and ultra-deep wells become one of the key issues affecting drilling safety and drillin... With the exploration and development of deep and ultra-deep oil and gas,high torque and high friction during the drilling of deep and ultra-deep wells become one of the key issues affecting drilling safety and drilling speed.Meanwhile,the high temperature and high salt problem in deep formations is prominent,which poses a major challenge to the lubricity of drilling fluids under high temperature and high salt.This paper reports an organic borate ester SOP as an environmentally friendly drilling fluid lubricant.The performance evaluation results show that when 1%lubricant SOP is added to the fresh water-based mud,the lubrication coefficient decreases from 0.631 to 0.046,and the reduction rate of lubrication coefficient is 92.7%.Under the conditions of 210℃ and 30%NaCl,the reduction rate of lubricating coefficient of the base slurry with 1%SOP was still remain 81.5%.After adding 1%SOP,the wear volume decreased by 94.11%compared with the base slurry.The contact resistance experiment during the friction process shows that SOP can form a thick adsorption film on the friction surface under high temperature and high salt conditions,thus effectively reducing the friction resistance.Molecular dynamics simulation shows that lubricant SOP can be physically adsorbed on the surface of drilling tool and borehole wall through hydrogen bond and van der Waals force.XPS analysis further shows that SOP adsorbs on the friction surface and reacts with metal atoms on the friction surface to form a chemically reactive film.Therefore,under high temperature and high salt conditions,the synergistic effect of physical adsorption film and chemical reaction film effectively reduces the frictional resistance and wear of the friction surface.In addition,SOP is non-toxic and easy to degrade.Therefore,SOP is a highly effective and environmentally friendly lubricant in high temperature and high salt drilling fluid. 展开更多
关键词 Deep oil and gas lubricANT Environmentally friendly Water-based drilling fluid Molecular dynamics simulations
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Grindability Evaluation of Ultrasonic Assisted Grinding of Silicon Nitride Ceramic Using Minimum Quantity Lubrication Based SiO_(2)Nanofluid
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作者 Yusuf Suleiman Dambatta Changhe Li +8 位作者 Mohd Sayuti Ahmed A D Sarhan Min Yang Benkai Li Anxue Chu Mingzheng Liu Yanbin Zhang Zafar Said Zongming Zhou 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2024年第2期115-136,共22页
Minimum quantity Lubrication(MQL)is a sustainable lubrication system that is famous in many machining systems.It involve the spray of an infinitesimal amount of mist-like lubricants during machining processes.The MQL ... Minimum quantity Lubrication(MQL)is a sustainable lubrication system that is famous in many machining systems.It involve the spray of an infinitesimal amount of mist-like lubricants during machining processes.The MQL system is affirmed to exhibit an excellent machining performance,and it is highly economical.The nanofluids are understood to exhibit excellent lubricity and heat evacuation capability,compared to pure oil-based MQL system.Studies have shown that the surface quality and amount of energy expended in the grinding operations can be reduced considerably due to the positive effect of these nanofluids.This work presents an experimental study on the tribological performance of SiO_(2)nanofluid during grinding of Si_(3)N_(4)ceramic.The effect different grinding modes and lubrication systems during the grinding operation was also analyzed.Different concentrations of the SiO_(2)nanofluid was manufactured using canola,corn and sunflower oils.The quantitative evaluation of the grinding process was done based on the amount of grinding forces,specific grinding energy,frictional coefficient,and surface integrity.It was found that the canola oil exhibits optimal lubrication performance compared to corn oil,sunflower oil,and traditional lubrication systems.Additionally,the introduction of ultrasonic vibrations with the SiO_(2)nanofluid in MQL system was found to reduce the specific grinding energy,normal grinding forces,tangential grinding forces,and surface roughness by 65%,57%,65%,and 18%respectively.Finally,regression analysis was used to obtain an optimum parameter combinations.The observations from this work will aid the smooth transition towards ecofriendly and sustainable machining of engineering ceramics. 展开更多
关键词 Minimum quantity lubrication(MQL) Ultrasonic assisted grinding(UAG) Eco-friendly lubricants NANOFLUID GRINDING CERAMIC
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Silicone oil as a corneal lubricant to reduce corneal edema and improve visualization during
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作者 Dan-Yang Che Zhu-Lin Chan +1 位作者 Ji-Bo Zhou Dong-Qing Zhu 《International Journal of Ophthalmology(English edition)》 SCIE CAS 2024年第1期92-96,共5页
AIM:To evaluate the efficacy and safety of silicone oil(SO)as a corneal lubricant to improve visualization during vitrectomy.METHODS:Patients who underwent vitreoretinal surgery were divided into two groups.Group 1 wa... AIM:To evaluate the efficacy and safety of silicone oil(SO)as a corneal lubricant to improve visualization during vitrectomy.METHODS:Patients who underwent vitreoretinal surgery were divided into two groups.Group 1 was operated on with initial SO(Oxane 5700)as a corneal lubricant.Group 2 was operated on with initial lactated ringer’s solution(LRS)and then replaced with SO as required.Fundus clarity was scored during the surgery.Fluorescein staining was performed to determine the damage to corneal epithelium.RESULTS:Totally 114 eyes of 114 patients were included.Single SO use maintained a clear cornea and provided excellent visualization of surgical image.In group 1,the fundus clarity was grade 3 in 41/45 eyes and grade 2 in 4/45 eyes.In group 2,corneal edema frequently occurred after initial LRS use.The fundus clarity was grade 3 in 19/69 eyes,2 in 37/69 eyes and 1 in 13/69 eyes(P<0.05).SO was applied in 29 eyes of initial LRS use with subsequent corneal edema,which eliminated the corneal edema in 26 eyes.Corneal fluorescein staining score in group 1 was 0 in 28 eyes,1 in 11 eyes and 2 in 6 eyes,and 40,20 and 9,respectively,in group 2(all P>0.05).CONCLUSION:The use of SO as a corneal lubricant is effective and safe for preserving and improving corneal clarity and providing clear surgical field during vitrectomy. 展开更多
关键词 silicone oil corneal lubricant corneal edema VITRECTOMY
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Fluorographene with Narrow Lateral Size and Thickness Distributions Prepared for Enhancing Lubrication Performance of Bentonite Grease
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作者 XIANG Shuo LU Peng +6 位作者 ZHANG Qinhui XIAO Bowen YANG Xin* ZHANG Peili MA Pengfei HE Yan LI Xuebin 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第5期1294-1302,共9页
Fluorographene(FG)with narrow lateral size and thickness distributions was prepared by a liquid-phase exfoliation method,based on liquid cascade centrifugation.The Rtec MFT-5000 tribo-meter was used to investigate the... Fluorographene(FG)with narrow lateral size and thickness distributions was prepared by a liquid-phase exfoliation method,based on liquid cascade centrifugation.The Rtec MFT-5000 tribo-meter was used to investigate the lubricating performance of bentonite grease enhanced by the as-prepared FG.The results showed that the coefficient of friction and the wear volume of bentonite grease with 0.3 wt%FG were decreased by 20.4%and 44.9%,respectively,as compared to those of the base grease.The main reason is that FG can promote the formation of the tribo-chemical reaction film consisting of complex carbon oxide,Fe_(2)O_(3)and FeF_(3)on the friction surface,which can remarkably improve the performance of friction reduction and prevent the appearance of severe wear. 展开更多
关键词 fluorographene liquid-phase exfoliation bentonite grease lubrication performance
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Design and optimization of fluid lubricated bearings operated with extreme working performances——a comprehensive review
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作者 Guohua Zhang Ming Huang +6 位作者 Gangli Chen Jiasheng Li Yang Liu Jianguo He Yueqing Zheng Siwei Tang Hailong Cui 《International Journal of Extreme Manufacturing》 SCIE EI CAS CSCD 2024年第2期325-376,共52页
Fluid lubricated bearings have been widely adopted as support components for high-end equipment in metrology,semiconductor devices,aviation,strategic defense,ultraprecision manufacturing,medical treatment,and power ge... Fluid lubricated bearings have been widely adopted as support components for high-end equipment in metrology,semiconductor devices,aviation,strategic defense,ultraprecision manufacturing,medical treatment,and power generation.In all these applications,the equipment must deliver extreme working performances such as ultraprecise movement,ultrahigh rotation speed,ultraheavy bearing loads,ultrahigh environmental temperatures,strong radiation resistance,and high vacuum operation,which have challenged the design and optimization of reliable fluid lubricated bearings.Breakthrough of any related bottlenecks will promote the development course of high-end equipment.To promote the advancement of high-end equipment,this paper reviews the design and optimization of fluid lubricated bearings operated at typical extreme working performances,targeting the realization of extreme working performances,current challenges and solutions,underlying deficiencies,and promising developmental directions.This paper can guide the selection of suitable fluid lubricated bearings and optimize their structures to meet their required working performances. 展开更多
关键词 fluid lubricated bearings structural design performance optimization extreme working performances
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FlowBreakdown of Hybrid Nanofluid on a Rigid Surface with Power Law Fluid as Lubricated Layers
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作者 Mirza Naveed Jahangeer Baig NadeemSalamat +5 位作者 Sohail Nadeem NaeemUllah Mohamed Bechir Ben Hamida Hassan Ali Ghazwani Sayed M.Eldin A.S.Al-Shafay 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第2期1485-1499,共15页
Thiswork investigates an oblique stagnation point flowof hybrid nanofluid over a rigid surface with power lawfluidas lubricated layers. Copper (Cu) and Silver (Ag) solid particles are used as hybrid particles acting i... Thiswork investigates an oblique stagnation point flowof hybrid nanofluid over a rigid surface with power lawfluidas lubricated layers. Copper (Cu) and Silver (Ag) solid particles are used as hybrid particles acting in water H2O asa base fluid. The mathematical formulation of flow configuration is presented in terms of differential systemthat isnonlinear in nature. The thermal aspects of the flow field are also investigated by assuming the surface is a heatedsurface with a constant temperature T. Numerical solutions to the governing mathematical model are calculatedby the RK45 algorithm. The results based on the numerical solution against various flow and thermal controllingparameters are presented in terms of line graphs. The specific results depict that the heat flux increases over thelubricated-indexed parameter. 展开更多
关键词 Oblique stagnation point flow hybrid nanofluid lubricated layer MAGNETOHYDRODYNAMICS
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Identification of Lubricating Oil Additives Using XGBoost and Ant Colony Optimization Algorithms
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作者 Xia Yanqiu Cui Jinwei +2 位作者 Xie Peiyuan Zou Shaode Feng Xin 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS CSCD 2024年第2期158-167,共10页
To address the problem of identifying multiple types of additives in lubricating oil,a method based on midinfrared spectral band selection using the eXtreme Gradient Boosting(XGBoost)algorithm combined with the ant co... To address the problem of identifying multiple types of additives in lubricating oil,a method based on midinfrared spectral band selection using the eXtreme Gradient Boosting(XGBoost)algorithm combined with the ant colony optimization(ACO)algorithm is proposed.The XGBoost algorithm was used to train and test three additives,T534(alkyl diphenylamine),T308(isooctyl acid thiophospholipid octadecylamine),and T306(trimethylphenol phosphate),separately,in order to screen for the optimal combination of spectral bands for each additive.The ACO algorithm was used to optimize the parameters of the XGBoost algorithm to improve the identification accuracy.During this process,the support vector machine(SVM)and hybrid bat algorithms(HBA)were included as a comparison,generating four models:ACO-XGBoost,ACO-SVM,HBA-XGboost,and HBA-SVM.The results showed that all four models could identify the three additives efficiently,with the ACO-XGBoost model achieving 100%recognition of all three additives.In addition,the generalizability of the ACO-XGBoost model was further demonstrated by predicting a lubricating oil containing the three additives prepared in our laboratory and a collected sample of commercial oil currently in use。 展开更多
关键词 lubricant oil additives fourier transform infrared spectroscopy type identification ACO-XGBoost combinatorial algorithm
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EVALUATION OF LUBRICANTS FOR COLD ROLLING ALUMINUM STRIPS 被引量:6
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作者 Sun Jianlin Zhang Xinming(Department of Materials Science and Engineering, Central South University ofTechnology, Changsha 410083, China) 《Journal of Central South University》 SCIE EI CAS 1997年第1期65-68,共4页
Various kinds of base oils were applied to cold rolling aluminum strips on a test mill for evaluationof the influences of these base oils,aromatics contents and viscosity of base oils on their lubricating performances... Various kinds of base oils were applied to cold rolling aluminum strips on a test mill for evaluationof the influences of these base oils,aromatics contents and viscosity of base oils on their lubricating performances and surface reflectivity of rolled strips at annealing. Results showed that low friction coefficient androlling force were obtained by using the normal paraffins,whereas their contaminations on the annealed stripsurface were the same as those of other saturated hydrocarbons. Aromatics in base oil affected the stir face reflectivity of annealed strips, but the decrease of aromatics in base oil was ineffective to improve rolled stripssurface quality when it is less than 1 %. Base oil viscosity has the great influences on the lubricating performances and surface reflectivity of annealed strips just in this condition. 展开更多
关键词 COLD ROLLING lubricants ALUMINUM STRIP
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SWOT-AHP hybrid model for vehicle lubricants from CNPCLC,China 被引量:6
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作者 Jiang Qingzhe XuYanming +3 位作者 Xin Wenju Song Zhaozheng Song Qianqian Ke Ming 《Petroleum Science》 SCIE CAS CSCD 2012年第4期558-564,共7页
In recent years, owing to the strong increase in demand for lubricants, China is ranked second in the global lubricant market. With the rapid development of China's automobile industry, there is an increasing demand ... In recent years, owing to the strong increase in demand for lubricants, China is ranked second in the global lubricant market. With the rapid development of China's automobile industry, there is an increasing demand for vehicle lubricants and an increasing requirement for higher quality lubricants. While the demands for vehicle lubricants are increasing year by year in China, the quality grade of vehicle lubricant will be improved by leaps and bounds, and the high standard lubricant for automobile will be directly brought in line with international practice. At present, the market share of most high-end vehicle lubricant has been occupied by foreign lubricant brands. So for China National Petroleum Corporation Lubricant Company (CNPCLC), the urgent issue is that strategies must be made to respond to the stern challenges and to occupy more market share. In this paper, by using the analytic hierarchy process (AHP) technique that has the advantage of combining quantitative with qualitative analysis, a SWOT-AHP model for CNPCLC vehicle lubricants is developed, presenting a good tool for studying the competitive factors domestic and overseas for vehicle lubricants. Finally a strategic plan for CNPCLC vehicle lubricants is suggested. 展开更多
关键词 SWOT AHP CNPCLC vehicle lubricant strategic planning
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Size effects on flow stress of C3602 in cylinder compression with different lubricants 被引量:3
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作者 GONG Feng GUO Bin ZHOU Jian SHAN Debin 《Rare Metals》 SCIE EI CAS CSCD 2009年第5期528-532,共5页
Micro parts are more difficult to be formed than macro parts because of size effects. The size effects on the flow stress of copper alloy C3602 with different lubricants were studied. Specimens were heat treated at 35... Micro parts are more difficult to be formed than macro parts because of size effects. The size effects on the flow stress of copper alloy C3602 with different lubricants were studied. Specimens were heat treated at 350℃ for 1 h and 700℃ for 3 h in nitrogen atmosphere, respectively. The initial diameters of the specimens were varied from 5 to 1 mm with a height-to-diameter ratio h0/D0 = 1.5. Cylinder compression was carried out in the lubrication condition with talc powder, without lubricant, with petroleum jelly, and with vegetable oil. The experiment was carried out at room temperature on a universal testing machine INSTRON 5569 with a strain rate of ε = 0.0025 A. The results show that with the same lubricant, the yield strength decreases with a decrease in specimen size for the specimens annealed at 350℃ for 1 b; however, it increases with a decrease in specimen size for the specimens annealed at 700℃ for 3 h. The yield strength decreases with an increase in grain size. The influences of lubricants on yield strength become larger with miniaturization of the specimens. 展开更多
关键词 MICROFORMING size effects cylinder compression flow stress lubricANT
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The Friction and Wear of Sleeve-ring Pair Lubricated by Active Lubricants in the Presence of Magnetic Field 被引量:2
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作者 周强 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2004年第B10期69-71,共3页
The effect of magnetic field on the tribological process of sleeve-ring pair lubricated by WRL lubricants was investigated by means of a NG-x wear tester and a PS5013 video microscope. The friction coefficient(f) and ... The effect of magnetic field on the tribological process of sleeve-ring pair lubricated by WRL lubricants was investigated by means of a NG-x wear tester and a PS5013 video microscope. The friction coefficient(f) and the wear weight(W) in lubricating test with WRL lubricant were decreased with the increase in the magnetic field vertical to the rubbing surface, and an almost zero wear lubricating situation was gained in a magnetic field of 1000A/m. The captured wear micro particles on the rubbing surface were observed in the testing process, and the theoretical analysis of magnetic effects was completed. It is indicated that the magnetic field has not only a capturing action of wear micro particles on the worn surface, but also a inducing polarization of magnetic anisotropy of lubricant molecular. The actions promote the absorption of WRL lubricant into the wear surface as well as wear micro-particles, so that a good tribological effect is obtained when both magnetic field and WRL present. 展开更多
关键词 magnetic field sleeve-ring pair friction and wear WRL lubricant tribological property
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Lubrication effectiveness of composite lubricants during P/M electrostatic die wall lubrication and warm compaction 被引量:1
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作者 Farid Akhtar 《Journal of University of Science and Technology Beijing》 CSCD 2006年第6期528-531,共4页
The lubrication effectiveness of the composite lubricants, 50wt% ethylene bis-stearamide (EBS) wax +50wt% graphite and 50wt% EBS wax + 50wt% BN, during the powder metallurgy (P/M) electrostatic die wall lubricat... The lubrication effectiveness of the composite lubricants, 50wt% ethylene bis-stearamide (EBS) wax +50wt% graphite and 50wt% EBS wax + 50wt% BN, during the powder metallurgy (P/M) electrostatic die wall lubrication and warm compaction was studied. The results show that the combination of 50wt% EBS wax and 50wt% graphite has excellent lubrication performance, resulting in fairly high green densities, but the mixture of 50wt% EBS wax and 50wt% BN has less beneficial effect. In addition, corresponding die temperatures should be applied when different die wall lubricants are used to achieve the highest green densities. 展开更多
关键词 powder metallurgy composite lubricant ELECTROSTATIC die wall lubrication warm compaction
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Research on Friction Properties of Mineral Lubricants in Thin-Film-Lubricating Regime 被引量:1
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作者 Zhang Jie Guan Tingting Piao Jicheng 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2014年第1期90-95,共6页
On the basis of thin film lubrication theory, the influence of fluid film(disordered film), ordered film and adsorbed film on tribological behavior of lubricating oil in thin-film lubrication(TFL) regime was studied. ... On the basis of thin film lubrication theory, the influence of fluid film(disordered film), ordered film and adsorbed film on tribological behavior of lubricating oil in thin-film lubrication(TFL) regime was studied. The μ-L(friction coefficient versus load) curves of different oil viscosity and additive dosage were obtained by a high frequency reciprocating test rig and the adsorption capacity of additive on steel surface were measured by QCM-D. Based on the Stribeck curve and thin film lubrication theory model, some conclusions can be drawn up, namely:(1) The μ-L curves and the parameters of L0 and μ0, obtained from the high frequency reciprocating test rig with ball-disc contact, can be used to study tribological behaviors of lubricating oil under TFL conditions.(2) In comparison with the high viscosity base fluid, the lower one can enter into TFL regime under lower load and keeps a lower friction coefficient in TFL regime.(3) The polar molecules in additive formulation produce ordered adsorbed layer on steel surface to reduce friction coefficient. And in TFL regime, the molecule's polarity, layer thickness and saturation degree on steel surface probably can influence lubricant's tribological behaviors between the moving interfaces. Moreover, the further study would be focused on the competitive adsorption of different additives, the formation of dual- and/or tri-molecular adsorption layers, and other aspects. 展开更多
关键词 thin film lubrication(TFL) adsorption film quartz crystal microbalance with dissipation monitoring(QCM-D) Stribeck curve mineral lubricants
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Test on Evaluation Method for Biodegradability of Lubricants 被引量:2
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作者 杨礼河 朱勇 +2 位作者 范国琛 孙玉德 解世文 《Transactions of Tianjin University》 EI CAS 2008年第1期61-65,共5页
Using carbon tetrachloride (CCl4) as extraction agent, the activated sludge from Tianjin Jizhuangzi Sewage Treatment Plant as inoculum, the test study on biodegradability of lubricants was carried out. The test flas... Using carbon tetrachloride (CCl4) as extraction agent, the activated sludge from Tianjin Jizhuangzi Sewage Treatment Plant as inoculum, the test study on biodegradability of lubricants was carried out. The test flasks containing the mineral medium, the test oil and the inoculum were placed in incubation together with flasks containing poisoned blanks for periods of 0 and 21 days, respectively. Flasks containing the reference materials in place of the test oil were run in parallel. At the end of the incubation period, the contents of the flasks were subjected to sonic vibration, and were acidified and extracted by using CCI4. The extracts were then analysed by infra-red (IR) spectrometer to measure the maximum absorption of the C-H stretch of CH2-CH3 band at wavelength of 2 930 cm^-1. The absorption values were used to calculate the residual oil contents of the poisoned and test flasks. Consequently the biodegradability of the test oil was calculated. The test results indicate that the differences in the biodegradability of test materials in different tests are within 5.5%, and consistent with the data described in Coordinating European Council (CEC) L-33- A-93. The biodegradability of lubricants can be evaluated by this method effectively. 展开更多
关键词 BIODEGRADABILITY lubricANT evaluating test CEC L-33-A-93
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A Fuel Economy Study in Heavy Duty Diesel Engine Lubricants 被引量:1
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作者 Hiroshi Watanabe Wim van Dam +1 位作者 Gary Parsons Peter Kleijwegt 《润滑油》 CAS 2011年第4期12-19,共8页
Internal combustion engines′ fuel economy is an important role for engine designers,engine manufacturers over the past 30 years,especially passenger car motor oils.In heavy duty diesel engine,over the past 20 years,f... Internal combustion engines′ fuel economy is an important role for engine designers,engine manufacturers over the past 30 years,especially passenger car motor oils.In heavy duty diesel engine,over the past 20 years,fuel economy has in some cases been sacrificed for exhaust gas emission optimizations.Now,Heavy Duty Automotive and the related industries have strong interest in fuel economy and the lubricants.It is driven by competitive market forces as well as government mandates and new emission regulations.Japan was the first country in the world to establish and implement heavy duty trucks and buses fuel economy standards.Other countries also have followed either by establishing direct fuel economy standards or greenhouse gas(GHG) emissions standards which are directly tied to fuel economy.This paper is discussing that heavy duty diesel engine lubricants can contribute on fuel economy.The contribution of various aspects of engine oil formulations on fuel economy will be discussed such as lubricant viscosity grade,lubricant additives and friction modifiers.In this paper,the evaluation discussions are based on fuel economy measurements in some bench tests,standardized laboratory engine tests and field tests. 展开更多
关键词 DIESEL fuel economy friction modifier VISCOSITY friction coefficient heavy duty diesel engine greenhouse gas(GHG) lubricant additive
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Genetic Function Approximation Based QSPR Models for Predicting the Wetting Ability of Lubricants onto Rolled Copper Foil Surface 被引量:1
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作者 Xiong Sang Sun Jianlin 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2018年第2期79-89,共11页
The contact angle phenomena and wetting behavior of fatty acids,alcohols and ester used as additives in lubricants onto the rolled copper foil(RCF)surface were studied by the static sessile drop method.Semi-empirical ... The contact angle phenomena and wetting behavior of fatty acids,alcohols and ester used as additives in lubricants onto the rolled copper foil(RCF)surface were studied by the static sessile drop method.Semi-empirical quantum-chemical method studies on the contact angle of these compounds onto surface using several structural parameters were carried out.Molecular refractivity as well as several structural parameters were adopted in the development of quantitative structure-property relationships(QSPR)using genetic function approximation(GFA)statistical analysis method.The results show that quantum parameters are a better choice when predicting the contact angle and wettability of lubricants onto the RCF surface.Contact angle of the compounds serves as a function of their viscosity,interfacial tension,and physicochemical parameters.Alog P,molecular refractivity,molecular flexibility,total molecular mass,solvent surface area,element count,total energy and dipole are the most sensitive ones among the major contributing parameters.Notably,studies of lubricants on the RCF surfaces allow wetting theories to be tested down to the microcosmic scale,which can bring about new insight to predict wettability of lubricants onto RCF surface. 展开更多
关键词 lubricants WETTING contact angle MODELLING QSPR
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Lubrication performance of rapeseed oil-based nano-lubricants in parallel tubular channel angular pressing process 被引量:1
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作者 Mehdi KASAEIAN-NAEINI Ramin HASHEMI Ali HOSSEINI 《Journal of Central South University》 SCIE EI CAS CSCD 2019年第5期1042-1049,共8页
Due to the biological risks of using the conventional lubricants,the vegetable oils have been considered nowadays.Besides,to improve the tribological properties of the vegetable oils in various applications like metal... Due to the biological risks of using the conventional lubricants,the vegetable oils have been considered nowadays.Besides,to improve the tribological properties of the vegetable oils in various applications like metal forming processes,nanoparticles have been used as additives.This research evaluated the lubrication performance of the Al2O3 and TiO2 nanoparticles dispersed in rapeseed oil during the parallel tubular channel angular pressing (PTCAP) process.The experimental PTCAP tests have been fulfilled under three lubrication conditions and the comparison between the PTCAP processed tubes has been performed in terms of the maximum forming force,surface roughness,and microhardness.The experimental results indicate that adding the mentioned nanoparticles has caused at least a 50% reduction in the maximum deformation load.Moreover,a remarkable decrement in the surface roughness of the formed tubes has been obtained. 展开更多
关键词 parallel tubular channel angular pressing nano lubricant nano-particle additives vegetable oil aluminum alloy
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