A new coordination polymer {[In（bdc）（OH）]·4H2O}n（H2bdc=1,4-benzenedi-carboxylic acid） has been synthesized through hydrothermal conditions,and was characterized by X-ray single-crystal diffraction and other...A new coordination polymer {[In（bdc）（OH）]·4H2O}n（H2bdc=1,4-benzenedi-carboxylic acid） has been synthesized through hydrothermal conditions,and was characterized by X-ray single-crystal diffraction and other measurements.The complex crystallizes in the orthorhombic system,space group Imma with a=18.3621（13）,b=7.1932（5）,c=11.8278（8）,V=1562.24（19）3,Z=4.Dc=1.565g/cm3,Mr=368.00,F（000）=728,μ（MoKα）=1.542 mm–1,S=1.019,R=0.0468 and wR=0.1326 for 884 observed reflections（＆gt;2σ（Ⅰ））.The title compound represents a 3-Dframework containing four kinds of tunnels in different shapes and sizes.展开更多
A novel nickel（Ⅱ） complex Ni（Iz）2（Bdc）（H2O）2 （Iz = imidazole, Bdc = 1,4-benzenedicarboxylate） has been synthesized and structurally characterized by X-ray analysis. The crystal is of monoclinic, space group...A novel nickel（Ⅱ） complex Ni（Iz）2（Bdc）（H2O）2 （Iz = imidazole, Bdc = 1,4-benzenedicarboxylate） has been synthesized and structurally characterized by X-ray analysis. The crystal is of monoclinic, space group P2 1/n with a = 5.5079（5）, b = 15.0973, c = 9.9825（9） A, β = 90.2380（10）°, C14H16N4NiO6, Mr = 395.02, Z = 2, V = 830.08（13） A^3 Dc = 1.580 g/cm^3, μ（MoKa） = 1.208 mm^-1, F（000） = 408, R = 0.0234 and wR = 0.0603 for 1379 observed reflections （I 〉 2σ（I））. In the title complex, adjacent nickel（Ⅱ） ions are bridged through the oxygen atoms of carboxylic groups in syn-anti conformation, yielding an infinite one-dimensional chain. These chains are linked to each other to form a 3-D network structure by three kinds of hydrogen-bonding interactions.展开更多
A zinc(II) complex [Zn(bdc)(py)·H 2O] n (bdc=1,4-benzenedicarboxylate, py=pyridine) has been prepared and characterized. Single crystal X-ray diffraction analysis reveals that the complex crystallizes in the mo...A zinc(II) complex [Zn(bdc)(py)·H 2O] n (bdc=1,4-benzenedicarboxylate, py=pyridine) has been prepared and characterized. Single crystal X-ray diffraction analysis reveals that the complex crystallizes in the monoclinic space group P2 1/n with a=0.84823(3), b=0.91440(3), c=1.65141(2) nm, β=91.243(2)°, V=1.28057(6) nm 3, Z=4. The coordination geometry at each Zn(II) center is a distorted tetrahedron. Two independent bdc ligands in a herringbone pattern link alternatively four-coordinated Zn(II) centers into a one-dimensional polymeric chain. Hydrogen bonds among coordinated water molecules and uncoordinated oxygen atoms of two independent bdc ligands from different polymeric chains extend one-dimensional polymeric chains into a three-dimensional structure.展开更多
Polyethylene terephthalate (PET) as one of non-degradable wastes has become a huge threat to the environment and human health.Chemical Recycle of PET is a sustainable way to release 1,4-benzenedicarboxylic acid (BDC) ...Polyethylene terephthalate (PET) as one of non-degradable wastes has become a huge threat to the environment and human health.Chemical Recycle of PET is a sustainable way to release 1,4-benzenedicarboxylic acid (BDC) the monomer of PET as common used organiclinker for synthesis of functional Metal–organic-frameworks (PET-derived MOFs) such as UiO-66, MIL-101, etc. This sustainable and costeffective“Waste-to-MOFs” model is of great significant to be intensively investigated in the past years. Attributes of substantial porosity, specificsurface area, exposed metal centers, uniform structure, and flexible morphology render PET-derived MOFs are well-suited for applications inadsorption, energy storage, catalysis, among others. Herein, in the present work, we have summarized recent advances in synthesis of PETderived MOFs using ex-situ and in-situ methods for typical applications of adsorption, catalysis and energy storage. Despite those improvementsin synthesis methods and potential applications, challenges still remain in development of green and economical routes to fully utilize waste PETfor massive manufacture of valuable MOF materials and chemicals. This review provides insights into the conversion of non-degradable PETwaste to value-added MOF materials, and further suggests promising perspectives to develop the sustainable “Waste-to-MOFs” model inaddressing environmental pollution and energy crises.展开更多
A new cadmium-organic framework, [Cd2（TBDC）2（DMF）2（H2O）]n （1）, was synthesized by solvothermal reaction of rigid carboxylate ligand 2,3,5,6-tetramethyl-l,4-ben- zenedicarboxylate （H2TBDC） and cadmium nitrate...A new cadmium-organic framework, [Cd2（TBDC）2（DMF）2（H2O）]n （1）, was synthesized by solvothermal reaction of rigid carboxylate ligand 2,3,5,6-tetramethyl-l,4-ben- zenedicarboxylate （H2TBDC） and cadmium nitrate and characterized by elemental analysis, infrared spectrum, thermal analysis, PXRD, single-crystal X-ray diffraction and photoluminescence in the solid state. Compound 1 crystallizes in orthorhombic, space group Pca21 with a = 21.487（6）, b = 7.790（2）, c = 20.666（6） A, C30H40Cd2N2O11, Mr = 829.44, V= 3459.3（16） A3, Z = 4, Dc = 1.593 g.cm-3,μ = 1.29 mm-1, F（000） = 1672, 2.7〈θ〈27.2°, λ（MoKa） = 0.71073 A, T= 293（2） K, the final R = 0.026, wR = 0.0548 and S = 1.027. X-ray diffraction analysis reveals that complex 1 possesses a 3D framework and exhibits rnsw net. Thus, the solid-state luminescent spectrum of 1 displays that the emission of cadmium（lI） complex shows a peak at 317 nm upon 250 nm excitation at room temperature.展开更多
基金supported by 973 Program (2006CB932900)NNSFC (20571074)NSF of Fujian (2007J172)
文摘A new coordination polymer {[In（bdc）（OH）]·4H2O}n（H2bdc=1,4-benzenedi-carboxylic acid） has been synthesized through hydrothermal conditions,and was characterized by X-ray single-crystal diffraction and other measurements.The complex crystallizes in the orthorhombic system,space group Imma with a=18.3621（13）,b=7.1932（5）,c=11.8278（8）,V=1562.24（19）3,Z=4.Dc=1.565g/cm3,Mr=368.00,F（000）=728,μ（MoKα）=1.542 mm–1,S=1.019,R=0.0468 and wR=0.1326 for 884 observed reflections（＆gt;2σ（Ⅰ））.The title compound represents a 3-Dframework containing four kinds of tunnels in different shapes and sizes.
基金This work was supported by the National Natural Science Foundation of China (No. 50572040)
文摘A novel nickel（Ⅱ） complex Ni（Iz）2（Bdc）（H2O）2 （Iz = imidazole, Bdc = 1,4-benzenedicarboxylate） has been synthesized and structurally characterized by X-ray analysis. The crystal is of monoclinic, space group P2 1/n with a = 5.5079（5）, b = 15.0973, c = 9.9825（9） A, β = 90.2380（10）°, C14H16N4NiO6, Mr = 395.02, Z = 2, V = 830.08（13） A^3 Dc = 1.580 g/cm^3, μ（MoKa） = 1.208 mm^-1, F（000） = 408, R = 0.0234 and wR = 0.0603 for 1379 observed reflections （I 〉 2σ（I））. In the title complex, adjacent nickel（Ⅱ） ions are bridged through the oxygen atoms of carboxylic groups in syn-anti conformation, yielding an infinite one-dimensional chain. These chains are linked to each other to form a 3-D network structure by three kinds of hydrogen-bonding interactions.
基金ProjectsupportedbytheNationalNaturalScienceFoundationofChina (No .2 982 5 10 3) ,theNaturalScienceFoundation (No .8982 0 0 3)ofFujianProvinceandChineseAcademyofSciences
文摘A zinc(II) complex [Zn(bdc)(py)·H 2O] n (bdc=1,4-benzenedicarboxylate, py=pyridine) has been prepared and characterized. Single crystal X-ray diffraction analysis reveals that the complex crystallizes in the monoclinic space group P2 1/n with a=0.84823(3), b=0.91440(3), c=1.65141(2) nm, β=91.243(2)°, V=1.28057(6) nm 3, Z=4. The coordination geometry at each Zn(II) center is a distorted tetrahedron. Two independent bdc ligands in a herringbone pattern link alternatively four-coordinated Zn(II) centers into a one-dimensional polymeric chain. Hydrogen bonds among coordinated water molecules and uncoordinated oxygen atoms of two independent bdc ligands from different polymeric chains extend one-dimensional polymeric chains into a three-dimensional structure.
基金supported by the National Natural Science Foundation of China(21902105,52274172)Shenzhen Science and Technology Program(JCYJ20210324094000001)Guangdong Basic and Applied Basic Research Foundation(2020A1515010471).
文摘Polyethylene terephthalate (PET) as one of non-degradable wastes has become a huge threat to the environment and human health.Chemical Recycle of PET is a sustainable way to release 1,4-benzenedicarboxylic acid (BDC) the monomer of PET as common used organiclinker for synthesis of functional Metal–organic-frameworks (PET-derived MOFs) such as UiO-66, MIL-101, etc. This sustainable and costeffective“Waste-to-MOFs” model is of great significant to be intensively investigated in the past years. Attributes of substantial porosity, specificsurface area, exposed metal centers, uniform structure, and flexible morphology render PET-derived MOFs are well-suited for applications inadsorption, energy storage, catalysis, among others. Herein, in the present work, we have summarized recent advances in synthesis of PETderived MOFs using ex-situ and in-situ methods for typical applications of adsorption, catalysis and energy storage. Despite those improvementsin synthesis methods and potential applications, challenges still remain in development of green and economical routes to fully utilize waste PETfor massive manufacture of valuable MOF materials and chemicals. This review provides insights into the conversion of non-degradable PETwaste to value-added MOF materials, and further suggests promising perspectives to develop the sustainable “Waste-to-MOFs” model inaddressing environmental pollution and energy crises.
基金Supported by the NNSFC(Nos.90922014,21271117)NCET-11-0309+2 种基金the Shandong Natural Science Fund for Distinguished Young Scholars(JQ201003)Independent Innovation Foundation of Shandong University(2010JQ011)Fundamental Research Funds for the Central Universities(13CX05010A)
文摘A new cadmium-organic framework, [Cd2（TBDC）2（DMF）2（H2O）]n （1）, was synthesized by solvothermal reaction of rigid carboxylate ligand 2,3,5,6-tetramethyl-l,4-ben- zenedicarboxylate （H2TBDC） and cadmium nitrate and characterized by elemental analysis, infrared spectrum, thermal analysis, PXRD, single-crystal X-ray diffraction and photoluminescence in the solid state. Compound 1 crystallizes in orthorhombic, space group Pca21 with a = 21.487（6）, b = 7.790（2）, c = 20.666（6） A, C30H40Cd2N2O11, Mr = 829.44, V= 3459.3（16） A3, Z = 4, Dc = 1.593 g.cm-3,μ = 1.29 mm-1, F（000） = 1672, 2.7〈θ〈27.2°, λ（MoKa） = 0.71073 A, T= 293（2） K, the final R = 0.026, wR = 0.0548 and S = 1.027. X-ray diffraction analysis reveals that complex 1 possesses a 3D framework and exhibits rnsw net. Thus, the solid-state luminescent spectrum of 1 displays that the emission of cadmium（lI） complex shows a peak at 317 nm upon 250 nm excitation at room temperature.
