As part of the development work of the Chinese new regional climate model (RIEMS), the radiative process of black carbon (BC) aerosols has been introduced into the original radiative procedures of RIEMS, and the trans...As part of the development work of the Chinese new regional climate model (RIEMS), the radiative process of black carbon (BC) aerosols has been introduced into the original radiative procedures of RIEMS, and the transport model of BC aerosols has also been established and combined with the RIEMS model. Using the new model system, the distribution of black carbon aerosols and their radiative effect over the China region are investigated. The influences of BC aerosole on the atmospheric radiative transfer and on the air temperature, land surface temperature, and total rainfall are analyzed. It is found that BC aerosols induce a positive radiative forcing at the top of the atmosphere (TOA), which is dominated by shortwave radiative forcing. The maximum radiative forcing occurs in North China in July and in South China in April. At the same time, negative radiative forcing is observed on the surface. Based on the radiative forcing comparison between clear sky and cloudy sky, it is found that cloud can enforce the TOA positive radiative forcing and decrease the negative surface radiative forcing. The responses of the climate system in July to the radiative forcing due to BC aerosols are the decrease in the air temperature in the middle and lower reaches of the Changjiang River and Huaihe area and most areas of South China, and the weak increase or decrease in air temperature over North China. The total rainfall in the middle and lower reaches of the Changjiang River area is increased, but it decreased in North China in July.展开更多
This paper presents aerosol black carbon (BC) concentrations measured at deck level on board the R/V XUE LONG icebreaker. The vessel cruised the Arctic Ocean carrying an in situ aethalometer during the summers of 20...This paper presents aerosol black carbon (BC) concentrations measured at deck level on board the R/V XUE LONG icebreaker. The vessel cruised the Arctic Ocean carrying an in situ aethalometer during the summers of 2008 and 2010. The courses of the third Chinese National Arctic Research Expedition (3rd CHINARE- Arctic, August 2008) and fourth Chinese National Arctic Research Expedition (4th CHINARE-Aretic, from late July to August 2010) were bounded by 173°W-143°W and 178°E-150°W, with northernmost points 85°25′N and 88°26′N, respectively. Results show low surface BC concentrations over the ocean throughout the courses, with means (standard error) of 6.0 (:t_4.7) ng.m-a for 3rd CHINARE-Arctic, and 8.4(±7.1) ng.m^-3 for 4th CHINARE- Arctic. It is clear that these onboard BC concentrations are similar to reported data from coastal stations in the Arctic region. The latitude-average BC concentration varied from 3.0-26.2 ng.m-3 for 3rd CHINARE-Arctic, to 4.2-20.5 ng-m-a for 4th CHINARE-Arctic. At latitudes higher than 72°N for 3rd CHINARE-Arctic and 75°N for 4th CHINARE-Arctic, BC concentrations were lower and had negligible latitudinal gradients. Analysis indicates that the presence of the Arctic front isolates the lower atmosphere of the high-latitude Arctic Ocean from low-latitude terrestrial transport. This maintains the very low BC concentrations and negligible concentration gradients at high latitudes of the Arctic Ocean during summer. Calculated airmass backward trajectories for the two expeditions show that the Arctic front in 2010 was further north than in 2008, which caused different latitudinal variation of BC concentration in the two years.展开更多
Different-sized aerosols were collected by an Andersen air sampler to observe the detailed morphology of the black carbon (BC) aerosols which were separated chemically from the other accompanying aerosols, using a S...Different-sized aerosols were collected by an Andersen air sampler to observe the detailed morphology of the black carbon (BC) aerosols which were separated chemically from the other accompanying aerosols, using a Scanning Electron Microscope equipped with an Energy Dispersive X-ray Spectrometer (SEM-EDX). The results indicate that most BC aerosols are spherical particles of about 50 nm in diameter and with a homogeneous surface. Results also show that these particles aggregate with other aerosols or with themselves to form larger agglomerates in the micrometer range. The shape of these 50-nm BC spherical particles was found to be very similar to that of BC particles released from petroleum-powered vehicular internal combustion engines. These spherical BC particles were shown to be different from the previously reported fullerenes found using Matrix-Assisted Laser Desorption/Ionization Time-Of-Flight Mass Spectrometry (MALDI-TOF-MS).展开更多
The objective of this study was to determine the black carbon concentration in Beijing in 2003.The aerosol properties were measured using an Aethalometer and a tapered element oscillating microbalance(TEOM)on the roof...The objective of this study was to determine the black carbon concentration in Beijing in 2003.The aerosol properties were measured using an Aethalometer and a tapered element oscillating microbalance(TEOM)on the roof of the Physics Building of Peking University(39.99°N,116.31°E)from July to August 2003 and from November 2003 to January 2004.The average black carbon(BC)concentrations in the summer and winter were 8.80 and 11.4μg/m3,respectively.During winter,two different cyclone cut offs were installed at the inlet of an aethalometer.The BC mass concentration in TSP,PM_(10),and PM_(2.5)were obtained.The results indicated that in winter aerosol,90%of BC exited in PM_(10)and 82.6%of BC exited in PM_(2.5).The BC in PM_(10)accounted for 5.11%of the PM_(10)mass.展开更多
Black carbon(BC) and PM10 in the center of the Taklimakan Desert were online monitored in the whole year of 2007.In addi-tion,TSP samples were also synchronously daily collected by medium-volume samplers with Whatman4...Black carbon(BC) and PM10 in the center of the Taklimakan Desert were online monitored in the whole year of 2007.In addi-tion,TSP samples were also synchronously daily collected by medium-volume samplers with Whatman41 filters in the spring of 2007.BC in the dust aerosol was up to 1.14%of the total mass of PM10.A remarkable seasonal variation of BC in the aerosol was observed in the order of winter】spring】autumn】summer.The peak value of BC appeared at midnight while the lowest one in the evening each day,which was just the reverse of that in the urban area.The contribution of BC to the total mass of PM10 on non-dust storm days was~11 times of that in dust storm.Through back trajectory and principal component analysis,it was found that BC in the dust aerosol over Taklimakan Desert might be attributed to the emission from the anthropogenic activities,including domestic heating,cooking,combustion of oil and natural gas,and the medium-range transport from those oases located in the margins of the desert.The total BC aerosol from the Taklimakan Desert to be transported to the eastward downstream was estimated to be 6.3×104 ton yr-1.展开更多
This study characterizes the black carbon in Agra, India home to the Taj Mahal--and situated in the lndo-Gangetic basin. The mean black carbon concentration is 9.5 μg m-3 and, owing to excessive biomass/fossil fuel c...This study characterizes the black carbon in Agra, India home to the Taj Mahal--and situated in the lndo-Gangetic basin. The mean black carbon concentration is 9.5 μg m-3 and, owing to excessive biomass/fossil fuel combustion and automobile emissions, the concentration varies considerably. Seasonally, the black carbon mass concentration is highest in winter, probably due to the increased fossil fuel consumption for heating and cooking, apart from a low boundary layer. The nocturnal peak rises prominently in winter, when the use of domestic heating is excessive. Meanwhile, the concentration is lowest during the monsoon season because of the turbulent atmospheric conditions and the process of washout by precipitation. The ratio of black carbon to brown carbon is less than unity during the entire study period, except in winter (December). This may be because that biomass combustion and diesel exhaust are major black carbon contributors in this region, while a higher ratio in winter may be due to the increased consumption of fossil fuel and wood for heating purposes. ANOVA reveals significant monthly variation in the concentration of black carbon; plus, it is negatively correlated with wind speed and temperature. A high black carbon mass concentration is observed at moderate (1-2 m s-1) wind speed, as compared to calm or turbulent atmospheric conditions.展开更多
Two inter-decadal shifts in East China summer rainfall during the last three decades of the 20th century have been identified.One shift occurred in the late 1970s and featured more rainfall in the Yangtze River valley...Two inter-decadal shifts in East China summer rainfall during the last three decades of the 20th century have been identified.One shift occurred in the late 1970s and featured more rainfall in the Yangtze River valley and prolonged drought in North China.The other shift occurred in the early 1990s and featured increased rainfall in South China.The role of black carbon(BC) aerosol in the first shift event is controversial,and it has not been documented for the second event.In this study,the authors used Geophysical Fluid Dynamics Laboratory's(GFDL's) atmospheric general circulation model known as Atmosphere and Land Model(AM2.1) ,which has been shown to capture East Asian climate variability well,to investigate these issues by conducting sensitive experiments with or without historical BC in East Asia. The results suggest that the model reproduces the first shift well,including intensified rainfall in the Yangtze River and weakened monsoonal circulation.However,the model captures only a fraction of the observed variations for the second shift event.Thus,the role of BC in modulating the two shift events is different,and its impact is relatively less important for the early 1990s event.展开更多
A study of the concentration of black carbon particles and its variation in the urban atmosphere has been carried out since 1996 in the Beijing area. The measurements were done in the late autumn and early winter each...A study of the concentration of black carbon particles and its variation in the urban atmosphere has been carried out since 1996 in the Beijing area. The measurements were done in the late autumn and early winter each year, the period before and after domestic heating activities begin. The results show the presence of black carbon particles at the high level that vary over a large range in the urban atmosphere in Beijing. The mean value of daily average concentration for the whole observation period of 1996-2004 is 20.0 μgm^-3. An evident decrease of black carbon particle concentration in the Beijing area is observed after 2000, and the daily average concentration of black carbon particles is estimated to be 16.0 μgm^-3 with a variation range of 2.10-50.50 μgm^-3 for the period of 2000-2004. The observation method and main variation behavior characteristics of black carbon particles in the urban atmosphere in the Beijing area are given and discussed.展开更多
In this paper, the RIEMS 2.0 model is used to simulate the distribution of sulfate, black carbon, and organic carbon aerosols over China (16.2°-44.1°N, 93.4°-132.4°E) in 1998. The climate effects...In this paper, the RIEMS 2.0 model is used to simulate the distribution of sulfate, black carbon, and organic carbon aerosols over China (16.2°-44.1°N, 93.4°-132.4°E) in 1998. The climate effects of these three anthropogenic aerosols are also simulated. The results are summarized as follows: (1) The regional average column burdens of sulfate, BC, OC, and SOC were 5.9, 0.24, 2.4, and 0.49 mg m-2, with maxima of 33.9, 1.48, 7.3, and 1.1 mg m-2, respectively. The column burden and surface concentration of secondary organic carbon accounted for about 20% and 7%, respectively, of the total organic carbon in eastern China. (2) The radiative forcings of sulfate, organic carbon, and black carbon at the top of the atmosphere were -1.24, -0.6, and 0.16 W m 2 respectively, with extremes of -5.25, -2.6, and 0.91 W m-2. (3) The surface air temperature changes caused by sulfate, organic carbon, and black carbon were -0.07, -0.04, and 0.01 K, respectively. The air temperature increase caused by black carbon at 850 hPa was higher than that at the surface. The net effect of the three kinds of anthropogenic aerosols together decreased the annual average temperature by -0.075 K; the maximum value was -0.3 K. (4) Black carbon can reduce the precipitation in arid and semi-arid areas of northern China and increase the precipitation in wet and semi-wet areas of southern China. The average precipitation increase caused by black carbon in China was 0.003 mm d^-1. The net effect of the three kinds of anthropogenic aerosols was to decrease the precipitation over China by 0.008 mmd ^-1.展开更多
The authors present spatial and temporal characteristics of anthropogenic sulfate and carbonaceous aerosols over East Asia using a 3-D coupled regional climate-chemistry-aerosol model, and compare the simulation with ...The authors present spatial and temporal characteristics of anthropogenic sulfate and carbonaceous aerosols over East Asia using a 3-D coupled regional climate-chemistry-aerosol model, and compare the simulation with the limited aerosol observations over the region. The aerosol module consists of SO2, SO4^2-, hydrophobic and hydrophilic black carbon (BC) and organic carbon compounds (OC), including emission, advections, dry and wet deposition, and chemical production and conversion. The simulated patterns of SO2 are closely tied to its emission rate, with sharp gradients between the highly polluted regions and more rural areas. Chemical conversion (especially in the aqueous phase) and dry deposition remove 60% and 30% of the total SO2 emission, respectively. The SO4^2- shows less horizontal gradient and seasonality than SO2, with wet deposition (60%) and export (27%) being two major sinks. Carbonaceous aerosols are spatially smoother than sulfur species. The aging process transforms more than 80% of hydrophobic BC and OC to hydrophilic components, which are removed by wet deposition (60%) and export (30%). The simulated spatial and seasonal SO4^2-, BC and OC aerosol concentrations and total aerosol optical depth are generally consistent with the observations in rural areas over East Asia, with lower bias in simulated OC aerosols, likely due to the underestimation of anthropogenic OC emissions and missing treatment of secondary organic carbon. The results suggest that our model is a useful tool for characterizing the anthropogenic aerosol cycle and for assessing its potential climatic and environmental effects in future studies.展开更多
Black carbon is one of the primary aerosols directly emitted from biomass known to have strong absorbing properties. The INDAAF and PASMU observational field campaigns which took place (2018) in Abidjan (urban area) a...Black carbon is one of the primary aerosols directly emitted from biomass known to have strong absorbing properties. The INDAAF and PASMU observational field campaigns which took place (2018) in Abidjan (urban area) and Lamto (rural area) allow the analysis of Black carbon concentration at different time scales through real-time measurements using an analyzer named Aethalometer AE-33. Results presented here show at Lamto: 1) for the diurnal scale an average of 1.71 ± 0.3 μg⋅m<sup>-3</sup> (0.34 ± 0.09 μg⋅m<sup>-3</sup>) in the dry (wet) season;2) for the monthly scale an average of 1.14 ± 0.84 μg⋅m<sup>-3</sup>;3) on the seasonal scale, an average of 2.2 ± 0.02 μg⋅m<sup>-3</sup> (0.6 ± 0.19 μg⋅m<sup>-3</sup>) in the dry (wet) season. The black carbon variation at Lamto is seasonal with an amplification factor of 85.6. Regarding the urban area of Abidjan, due to sampling issues, our analyses were limited to daily, diurnal and weekly time scales. We observed: a) at a daily scale an average of 5.31.± 2.5 μg⋅m<sup>-3</sup>, b) diurnal scale, an average ranging from 6.87 to 13.92 μg⋅m<sup>-3</sup>. The analysis indicated that emissions from urban areas are more related to social and economic activities, with weekday concentrations (7.24 μg⋅m<sup>-3</sup>) higher than concentrations over the weekend (e.g. Saturday 6.59 μg⋅m<sup>-3</sup> and Sunday 6.00 μg⋅m<sup>-3</sup>). Moreover, BC concentration in Abidjan is quite noticeable compared to that of rural areas (Lamto). The ratio between the maximum values of the two areas is of the order of 5.86. In addition, concentrations in some urban areas are slightly above the daily threshold set by the WHO (10 μg⋅m<sup>-3</sup>). Therefore, the levels of urban BC concentrations are alarming whilst rural BC concentrations remain below daily WHO thresholds and are of the same magnitude as those of West African megacities. This study underlies that BC concentrations at Lamto are mainly related to biomass combustion sources while those from urban areas are related to traffic sources. The latter is permanently active, unlike those in rural Lamto, which is seasonal.展开更多
Using the CAM3.0 model, we investigated the respective effects of aerosol concentration increasing and decadal variation of global sea surface temperature(SST) around year 1976/77 on the East Asian precipitation in bo...Using the CAM3.0 model, we investigated the respective effects of aerosol concentration increasing and decadal variation of global sea surface temperature(SST) around year 1976/77 on the East Asian precipitation in boreal summer. By doubling the concentration of the sulfate aerosol and black carbon aerosol separately and synchronously in East Asia(100-150 °E, 20-50 °N), the climate effects of these aerosols are specifically investigated. The results show that both the decadal SST changing and aerosol concentration increasing could lead to rainfall decreasing in the center of East Asia, but increasing in the regions along southeast coast areas of China. However, the different patterns of rainfall over ocean and lower wind field over Asian continent between aerosol experiments and SST experiments in CAM3.0 indicate the presence of different mechanisms. In the increased aerosol concentration experiments, scattering effect is the main climate effect for both sulfate and black carbon aerosols in the Eastern Asian summer. Especially in the increased sulfate aerosol concentration experiment, the climate scattering effect of aerosol leads to the most significant temperature decreasing, sinking convection anomalies and decreased rainfall in the troposphere over the central part of East Asia. However, in an increased black carbon aerosol concentration experiment, weakened sinking convection anomalies exist at the southerly position. This weakened sinking and its compensating rising convection anomalies in the south lead to the heavy rainfall over southeast coast areas of China. When concentrations of both sulfate and black carbon aerosols increase synchronously, the anomalous rainfall distribution is somewhat like that in the increased black carbon concentration aerosol experiment but with less intensity.展开更多
The first ever land campaign to study the spatial variability of the aerosol characteristics along the Brahmaputra river valley (BRV) in Assam, North-Eastern India, was conducted during 2011. Measurements were made ov...The first ever land campaign to study the spatial variability of the aerosol characteristics along the Brahmaputra river valley (BRV) in Assam, North-Eastern India, was conducted during 2011. Measurements were made over 13 locations for Aerosol Optical Depth (AOD), scattering coefficient, particulate matter, black carbon (BC) concentration and meteorological parameters. The BRV is divided into three sectors longitudinally viz western sector (WS), central sector (CS), and eastern sector (ES). Significant Spatial heterogeneity in AOD and BC concentration was observed (p < 0.05) with the highest values over WS and a continual decrease from WS to ES with aerosol dominance in PM2.5 category along the entire valley. The Angstrom coefficient measured using different wavelength pairs showed spatial variability indicating dominance of fine particles over WS and coarse particles in ES with a probable bimodal distribution. The scattering and absorption coefficient shows dominance of both types of aerosol over WS than other areas. The shortwave radiative forcing was higher over the WS than CS and ES of the valley. The campaign revealed that under favorable wind conditions, the BRV is loaded with significant amount of natural and anthropogenic aerosol during local winter and is influenced by the long-range transport of aerosols from the Indo-Gangetic plain.展开更多
Continuous and near-real-time measurements of the mass concentration of Aerosol Black Carbon (BC) were carried out 1st to 31st July 2010 of rainy season and compare with data of July-2010 to March-2011 using an Aethal...Continuous and near-real-time measurements of the mass concentration of Aerosol Black Carbon (BC) were carried out 1st to 31st July 2010 of rainy season and compare with data of July-2010 to March-2011 using an Aethalometer (model AE-31 of Magee Scientific, USA). The principle of the Aethalometer is to measure the attenuation of a beam of light transmitted through a filter, while the filter is continuously collecting an aero-sol sample. This measurement is made at successive regular intervals of a time base period has been. the BC mass concentration is estimated by measuring the change in the transmittance of a quartz filter tape, on to which the particles impinge. The instrument was operated at a time base of 5 min, round the clock with a flow rate of 4-liter min–1, to study the impact of rainy season on black carbon concentrations over a typical urban environment namely Ranchi, India. BC concentrations were high during morning (0600 to 0900 h) and evening hours (1900 to 2300 h) compared to afternoon hours. During early morning hours, high values of BC are attributed to the turbulence set-in by the solar heating which breaks the night-time stable layer and aero-sols in the nocturnal residual layer are mixed up with those near the surface.展开更多
黑碳(BC)气溶胶(简称黑碳)对区域和全球气候变化具有重要影响。为了进一步认识亚洲地区黑碳的区域气候效应,本文使用新一代的区域气候—化学模式RegCM4,研究了来自印度和中国内地的黑碳排放对东亚冬季气候的影响。结果表明:来自中国内...黑碳(BC)气溶胶(简称黑碳)对区域和全球气候变化具有重要影响。为了进一步认识亚洲地区黑碳的区域气候效应,本文使用新一代的区域气候—化学模式RegCM4,研究了来自印度和中国内地的黑碳排放对东亚冬季气候的影响。结果表明:来自中国内地和印度的黑碳排放可导致东亚地区黑碳的区域平均柱含量、大气顶和地表有效辐射强迫分别变化了+1.78 mg m^(−2)、+1.98 W m^(−2)和−2.17 W m^(−2)。中国内地和印度黑碳对东亚气候的影响机制相同。印度黑碳对东亚冬季气候的影响主要通过对大气动力过程的调整来实现,由此造成的散射气溶胶浓度增加可导致该区域850 hPa附近和地表气温降低,而中国内地的黑碳还可直接影响东亚气候,其加热效应可导致该区域大部分地区850 hPa附近的气层变暖。由于中国内地黑碳在东亚地区占主导,其在影响东亚区域气候变化方面发挥着更重要的作用。总体而言,两地总的黑碳会造成850 hPa高度附近云量减少和气温升高;地表日照时数减少,气温、感热通量和地表蒸发量下降;边界层高度降低和散射气溶胶的柱含量上升。研究结果还进一步反映了东亚冬季气候对不同排放黑碳的响应表现出了一定的非线性。展开更多
基金This research was sponsored by the National Key Program for Developing Basic Sciences of China(No.G1999043400)the National Natural Science Foundation of China(Grant Nos.40205016 and 40165001).
文摘As part of the development work of the Chinese new regional climate model (RIEMS), the radiative process of black carbon (BC) aerosols has been introduced into the original radiative procedures of RIEMS, and the transport model of BC aerosols has also been established and combined with the RIEMS model. Using the new model system, the distribution of black carbon aerosols and their radiative effect over the China region are investigated. The influences of BC aerosole on the atmospheric radiative transfer and on the air temperature, land surface temperature, and total rainfall are analyzed. It is found that BC aerosols induce a positive radiative forcing at the top of the atmosphere (TOA), which is dominated by shortwave radiative forcing. The maximum radiative forcing occurs in North China in July and in South China in April. At the same time, negative radiative forcing is observed on the surface. Based on the radiative forcing comparison between clear sky and cloudy sky, it is found that cloud can enforce the TOA positive radiative forcing and decrease the negative surface radiative forcing. The responses of the climate system in July to the radiative forcing due to BC aerosols are the decrease in the air temperature in the middle and lower reaches of the Changjiang River and Huaihe area and most areas of South China, and the weak increase or decrease in air temperature over North China. The total rainfall in the middle and lower reaches of the Changjiang River area is increased, but it decreased in North China in July.
基金supported by the project of the third and fourth Chinese National Arctic Research Expedtions
文摘This paper presents aerosol black carbon (BC) concentrations measured at deck level on board the R/V XUE LONG icebreaker. The vessel cruised the Arctic Ocean carrying an in situ aethalometer during the summers of 2008 and 2010. The courses of the third Chinese National Arctic Research Expedition (3rd CHINARE- Arctic, August 2008) and fourth Chinese National Arctic Research Expedition (4th CHINARE-Aretic, from late July to August 2010) were bounded by 173°W-143°W and 178°E-150°W, with northernmost points 85°25′N and 88°26′N, respectively. Results show low surface BC concentrations over the ocean throughout the courses, with means (standard error) of 6.0 (:t_4.7) ng.m-a for 3rd CHINARE-Arctic, and 8.4(±7.1) ng.m^-3 for 4th CHINARE- Arctic. It is clear that these onboard BC concentrations are similar to reported data from coastal stations in the Arctic region. The latitude-average BC concentration varied from 3.0-26.2 ng.m-3 for 3rd CHINARE-Arctic, to 4.2-20.5 ng-m-a for 4th CHINARE-Arctic. At latitudes higher than 72°N for 3rd CHINARE-Arctic and 75°N for 4th CHINARE-Arctic, BC concentrations were lower and had negligible latitudinal gradients. Analysis indicates that the presence of the Arctic front isolates the lower atmosphere of the high-latitude Arctic Ocean from low-latitude terrestrial transport. This maintains the very low BC concentrations and negligible concentration gradients at high latitudes of the Arctic Ocean during summer. Calculated airmass backward trajectories for the two expeditions show that the Arctic front in 2010 was further north than in 2008, which caused different latitudinal variation of BC concentration in the two years.
基金This work was partly supported by National Natural Science Foundation of China (NSFC, 40575066) Japan Society for the Promotion of Science (JSPS).
文摘Different-sized aerosols were collected by an Andersen air sampler to observe the detailed morphology of the black carbon (BC) aerosols which were separated chemically from the other accompanying aerosols, using a Scanning Electron Microscope equipped with an Energy Dispersive X-ray Spectrometer (SEM-EDX). The results indicate that most BC aerosols are spherical particles of about 50 nm in diameter and with a homogeneous surface. Results also show that these particles aggregate with other aerosols or with themselves to form larger agglomerates in the micrometer range. The shape of these 50-nm BC spherical particles was found to be very similar to that of BC particles released from petroleum-powered vehicular internal combustion engines. These spherical BC particles were shown to be different from the previously reported fullerenes found using Matrix-Assisted Laser Desorption/Ionization Time-Of-Flight Mass Spectrometry (MALDI-TOF-MS).
基金This work was supported by the National Key Basic Research and Development(973)Program of China(Grant No.G1999045700).
文摘The objective of this study was to determine the black carbon concentration in Beijing in 2003.The aerosol properties were measured using an Aethalometer and a tapered element oscillating microbalance(TEOM)on the roof of the Physics Building of Peking University(39.99°N,116.31°E)from July to August 2003 and from November 2003 to January 2004.The average black carbon(BC)concentrations in the summer and winter were 8.80 and 11.4μg/m3,respectively.During winter,two different cyclone cut offs were installed at the inlet of an aethalometer.The BC mass concentration in TSP,PM_(10),and PM_(2.5)were obtained.The results indicated that in winter aerosol,90%of BC exited in PM_(10)and 82.6%of BC exited in PM_(2.5).The BC in PM_(10)accounted for 5.11%of the PM_(10)mass.
基金support from the National Key Project of Basic Research of China(2006CB403704)National Natural Science Foundation of China(20877020,20977017 & 40599420)
文摘Black carbon(BC) and PM10 in the center of the Taklimakan Desert were online monitored in the whole year of 2007.In addi-tion,TSP samples were also synchronously daily collected by medium-volume samplers with Whatman41 filters in the spring of 2007.BC in the dust aerosol was up to 1.14%of the total mass of PM10.A remarkable seasonal variation of BC in the aerosol was observed in the order of winter】spring】autumn】summer.The peak value of BC appeared at midnight while the lowest one in the evening each day,which was just the reverse of that in the urban area.The contribution of BC to the total mass of PM10 on non-dust storm days was~11 times of that in dust storm.Through back trajectory and principal component analysis,it was found that BC in the dust aerosol over Taklimakan Desert might be attributed to the emission from the anthropogenic activities,including domestic heating,cooking,combustion of oil and natural gas,and the medium-range transport from those oases located in the margins of the desert.The total BC aerosol from the Taklimakan Desert to be transported to the eastward downstream was estimated to be 6.3×104 ton yr-1.
基金a part of the Aerosol Radiative Forcing over India project of the Indian Space Research Organization’s Geosphere Biosphere Programme
文摘This study characterizes the black carbon in Agra, India home to the Taj Mahal--and situated in the lndo-Gangetic basin. The mean black carbon concentration is 9.5 μg m-3 and, owing to excessive biomass/fossil fuel combustion and automobile emissions, the concentration varies considerably. Seasonally, the black carbon mass concentration is highest in winter, probably due to the increased fossil fuel consumption for heating and cooking, apart from a low boundary layer. The nocturnal peak rises prominently in winter, when the use of domestic heating is excessive. Meanwhile, the concentration is lowest during the monsoon season because of the turbulent atmospheric conditions and the process of washout by precipitation. The ratio of black carbon to brown carbon is less than unity during the entire study period, except in winter (December). This may be because that biomass combustion and diesel exhaust are major black carbon contributors in this region, while a higher ratio in winter may be due to the increased consumption of fossil fuel and wood for heating purposes. ANOVA reveals significant monthly variation in the concentration of black carbon; plus, it is negatively correlated with wind speed and temperature. A high black carbon mass concentration is observed at moderate (1-2 m s-1) wind speed, as compared to calm or turbulent atmospheric conditions.
基金supported by the Knowledge Innovation Program of the Chinese Academy of Sciences(Grant No.KZCX2-YW-Q11-03)
文摘Two inter-decadal shifts in East China summer rainfall during the last three decades of the 20th century have been identified.One shift occurred in the late 1970s and featured more rainfall in the Yangtze River valley and prolonged drought in North China.The other shift occurred in the early 1990s and featured increased rainfall in South China.The role of black carbon(BC) aerosol in the first shift event is controversial,and it has not been documented for the second event.In this study,the authors used Geophysical Fluid Dynamics Laboratory's(GFDL's) atmospheric general circulation model known as Atmosphere and Land Model(AM2.1) ,which has been shown to capture East Asian climate variability well,to investigate these issues by conducting sensitive experiments with or without historical BC in East Asia. The results suggest that the model reproduces the first shift well,including intensified rainfall in the Yangtze River and weakened monsoonal circulation.However,the model captures only a fraction of the observed variations for the second shift event.Thus,the role of BC in modulating the two shift events is different,and its impact is relatively less important for the early 1990s event.
基金This work was supported by the Bureau of International Cooperation of the National Science Foundation of China(No.40311120114)the Bureau of International Cooperation of the Chinese Academy of Sciences(No.980491002)
文摘A study of the concentration of black carbon particles and its variation in the urban atmosphere has been carried out since 1996 in the Beijing area. The measurements were done in the late autumn and early winter each year, the period before and after domestic heating activities begin. The results show the presence of black carbon particles at the high level that vary over a large range in the urban atmosphere in Beijing. The mean value of daily average concentration for the whole observation period of 1996-2004 is 20.0 μgm^-3. An evident decrease of black carbon particle concentration in the Beijing area is observed after 2000, and the daily average concentration of black carbon particles is estimated to be 16.0 μgm^-3 with a variation range of 2.10-50.50 μgm^-3 for the period of 2000-2004. The observation method and main variation behavior characteristics of black carbon particles in the urban atmosphere in the Beijing area are given and discussed.
基金supported by the National Program on Key Basic Research Project of China (973) under Grant Nos.2006CB400506 and 2010CB428501the National Natural Science Foundation of China (Grant No.40775014)
文摘In this paper, the RIEMS 2.0 model is used to simulate the distribution of sulfate, black carbon, and organic carbon aerosols over China (16.2°-44.1°N, 93.4°-132.4°E) in 1998. The climate effects of these three anthropogenic aerosols are also simulated. The results are summarized as follows: (1) The regional average column burdens of sulfate, BC, OC, and SOC were 5.9, 0.24, 2.4, and 0.49 mg m-2, with maxima of 33.9, 1.48, 7.3, and 1.1 mg m-2, respectively. The column burden and surface concentration of secondary organic carbon accounted for about 20% and 7%, respectively, of the total organic carbon in eastern China. (2) The radiative forcings of sulfate, organic carbon, and black carbon at the top of the atmosphere were -1.24, -0.6, and 0.16 W m 2 respectively, with extremes of -5.25, -2.6, and 0.91 W m-2. (3) The surface air temperature changes caused by sulfate, organic carbon, and black carbon were -0.07, -0.04, and 0.01 K, respectively. The air temperature increase caused by black carbon at 850 hPa was higher than that at the surface. The net effect of the three kinds of anthropogenic aerosols together decreased the annual average temperature by -0.075 K; the maximum value was -0.3 K. (4) Black carbon can reduce the precipitation in arid and semi-arid areas of northern China and increase the precipitation in wet and semi-wet areas of southern China. The average precipitation increase caused by black carbon in China was 0.003 mm d^-1. The net effect of the three kinds of anthropogenic aerosols was to decrease the precipitation over China by 0.008 mmd ^-1.
基金funds from the U. S. Na- tional Aeronautics and Space Administration under Grant NNG04GB89G the U. S. National Science Foundation under grant ATM-0129495
文摘The authors present spatial and temporal characteristics of anthropogenic sulfate and carbonaceous aerosols over East Asia using a 3-D coupled regional climate-chemistry-aerosol model, and compare the simulation with the limited aerosol observations over the region. The aerosol module consists of SO2, SO4^2-, hydrophobic and hydrophilic black carbon (BC) and organic carbon compounds (OC), including emission, advections, dry and wet deposition, and chemical production and conversion. The simulated patterns of SO2 are closely tied to its emission rate, with sharp gradients between the highly polluted regions and more rural areas. Chemical conversion (especially in the aqueous phase) and dry deposition remove 60% and 30% of the total SO2 emission, respectively. The SO4^2- shows less horizontal gradient and seasonality than SO2, with wet deposition (60%) and export (27%) being two major sinks. Carbonaceous aerosols are spatially smoother than sulfur species. The aging process transforms more than 80% of hydrophobic BC and OC to hydrophilic components, which are removed by wet deposition (60%) and export (30%). The simulated spatial and seasonal SO4^2-, BC and OC aerosol concentrations and total aerosol optical depth are generally consistent with the observations in rural areas over East Asia, with lower bias in simulated OC aerosols, likely due to the underestimation of anthropogenic OC emissions and missing treatment of secondary organic carbon. The results suggest that our model is a useful tool for characterizing the anthropogenic aerosol cycle and for assessing its potential climatic and environmental effects in future studies.
文摘Black carbon is one of the primary aerosols directly emitted from biomass known to have strong absorbing properties. The INDAAF and PASMU observational field campaigns which took place (2018) in Abidjan (urban area) and Lamto (rural area) allow the analysis of Black carbon concentration at different time scales through real-time measurements using an analyzer named Aethalometer AE-33. Results presented here show at Lamto: 1) for the diurnal scale an average of 1.71 ± 0.3 μg⋅m<sup>-3</sup> (0.34 ± 0.09 μg⋅m<sup>-3</sup>) in the dry (wet) season;2) for the monthly scale an average of 1.14 ± 0.84 μg⋅m<sup>-3</sup>;3) on the seasonal scale, an average of 2.2 ± 0.02 μg⋅m<sup>-3</sup> (0.6 ± 0.19 μg⋅m<sup>-3</sup>) in the dry (wet) season. The black carbon variation at Lamto is seasonal with an amplification factor of 85.6. Regarding the urban area of Abidjan, due to sampling issues, our analyses were limited to daily, diurnal and weekly time scales. We observed: a) at a daily scale an average of 5.31.± 2.5 μg⋅m<sup>-3</sup>, b) diurnal scale, an average ranging from 6.87 to 13.92 μg⋅m<sup>-3</sup>. The analysis indicated that emissions from urban areas are more related to social and economic activities, with weekday concentrations (7.24 μg⋅m<sup>-3</sup>) higher than concentrations over the weekend (e.g. Saturday 6.59 μg⋅m<sup>-3</sup> and Sunday 6.00 μg⋅m<sup>-3</sup>). Moreover, BC concentration in Abidjan is quite noticeable compared to that of rural areas (Lamto). The ratio between the maximum values of the two areas is of the order of 5.86. In addition, concentrations in some urban areas are slightly above the daily threshold set by the WHO (10 μg⋅m<sup>-3</sup>). Therefore, the levels of urban BC concentrations are alarming whilst rural BC concentrations remain below daily WHO thresholds and are of the same magnitude as those of West African megacities. This study underlies that BC concentrations at Lamto are mainly related to biomass combustion sources while those from urban areas are related to traffic sources. The latter is permanently active, unlike those in rural Lamto, which is seasonal.
基金National Key Program for Developing Basic Science(2016YFA0600303)National Natural Science Foundation of China(41675064,41621005,41330420,41275068)+2 种基金Jiangsu Province Science Foundation(SBK2015020577)Key Laboratory Project Foundation(KLME1501)Jiangsu Collaborative Innovation Center for Climate Change
文摘Using the CAM3.0 model, we investigated the respective effects of aerosol concentration increasing and decadal variation of global sea surface temperature(SST) around year 1976/77 on the East Asian precipitation in boreal summer. By doubling the concentration of the sulfate aerosol and black carbon aerosol separately and synchronously in East Asia(100-150 °E, 20-50 °N), the climate effects of these aerosols are specifically investigated. The results show that both the decadal SST changing and aerosol concentration increasing could lead to rainfall decreasing in the center of East Asia, but increasing in the regions along southeast coast areas of China. However, the different patterns of rainfall over ocean and lower wind field over Asian continent between aerosol experiments and SST experiments in CAM3.0 indicate the presence of different mechanisms. In the increased aerosol concentration experiments, scattering effect is the main climate effect for both sulfate and black carbon aerosols in the Eastern Asian summer. Especially in the increased sulfate aerosol concentration experiment, the climate scattering effect of aerosol leads to the most significant temperature decreasing, sinking convection anomalies and decreased rainfall in the troposphere over the central part of East Asia. However, in an increased black carbon aerosol concentration experiment, weakened sinking convection anomalies exist at the southerly position. This weakened sinking and its compensating rising convection anomalies in the south lead to the heavy rainfall over southeast coast areas of China. When concentrations of both sulfate and black carbon aerosols increase synchronously, the anomalous rainfall distribution is somewhat like that in the increased black carbon concentration aerosol experiment but with less intensity.
文摘The first ever land campaign to study the spatial variability of the aerosol characteristics along the Brahmaputra river valley (BRV) in Assam, North-Eastern India, was conducted during 2011. Measurements were made over 13 locations for Aerosol Optical Depth (AOD), scattering coefficient, particulate matter, black carbon (BC) concentration and meteorological parameters. The BRV is divided into three sectors longitudinally viz western sector (WS), central sector (CS), and eastern sector (ES). Significant Spatial heterogeneity in AOD and BC concentration was observed (p < 0.05) with the highest values over WS and a continual decrease from WS to ES with aerosol dominance in PM2.5 category along the entire valley. The Angstrom coefficient measured using different wavelength pairs showed spatial variability indicating dominance of fine particles over WS and coarse particles in ES with a probable bimodal distribution. The scattering and absorption coefficient shows dominance of both types of aerosol over WS than other areas. The shortwave radiative forcing was higher over the WS than CS and ES of the valley. The campaign revealed that under favorable wind conditions, the BRV is loaded with significant amount of natural and anthropogenic aerosol during local winter and is influenced by the long-range transport of aerosols from the Indo-Gangetic plain.
文摘Continuous and near-real-time measurements of the mass concentration of Aerosol Black Carbon (BC) were carried out 1st to 31st July 2010 of rainy season and compare with data of July-2010 to March-2011 using an Aethalometer (model AE-31 of Magee Scientific, USA). The principle of the Aethalometer is to measure the attenuation of a beam of light transmitted through a filter, while the filter is continuously collecting an aero-sol sample. This measurement is made at successive regular intervals of a time base period has been. the BC mass concentration is estimated by measuring the change in the transmittance of a quartz filter tape, on to which the particles impinge. The instrument was operated at a time base of 5 min, round the clock with a flow rate of 4-liter min–1, to study the impact of rainy season on black carbon concentrations over a typical urban environment namely Ranchi, India. BC concentrations were high during morning (0600 to 0900 h) and evening hours (1900 to 2300 h) compared to afternoon hours. During early morning hours, high values of BC are attributed to the turbulence set-in by the solar heating which breaks the night-time stable layer and aero-sols in the nocturnal residual layer are mixed up with those near the surface.
文摘黑碳(BC)气溶胶(简称黑碳)对区域和全球气候变化具有重要影响。为了进一步认识亚洲地区黑碳的区域气候效应,本文使用新一代的区域气候—化学模式RegCM4,研究了来自印度和中国内地的黑碳排放对东亚冬季气候的影响。结果表明:来自中国内地和印度的黑碳排放可导致东亚地区黑碳的区域平均柱含量、大气顶和地表有效辐射强迫分别变化了+1.78 mg m^(−2)、+1.98 W m^(−2)和−2.17 W m^(−2)。中国内地和印度黑碳对东亚气候的影响机制相同。印度黑碳对东亚冬季气候的影响主要通过对大气动力过程的调整来实现,由此造成的散射气溶胶浓度增加可导致该区域850 hPa附近和地表气温降低,而中国内地的黑碳还可直接影响东亚气候,其加热效应可导致该区域大部分地区850 hPa附近的气层变暖。由于中国内地黑碳在东亚地区占主导,其在影响东亚区域气候变化方面发挥着更重要的作用。总体而言,两地总的黑碳会造成850 hPa高度附近云量减少和气温升高;地表日照时数减少,气温、感热通量和地表蒸发量下降;边界层高度降低和散射气溶胶的柱含量上升。研究结果还进一步反映了东亚冬季气候对不同排放黑碳的响应表现出了一定的非线性。