Cordierite precursor was obtained through a process, which involved the decomposition of metal nitrates on the surface of ultrafine carbon black powder between 100-300℃ and the gasification of the carbon black at hig...Cordierite precursor was obtained through a process, which involved the decomposition of metal nitrates on the surface of ultrafine carbon black powder between 100-300℃ and the gasification of the carbon black at higher temperature in air. The average size of the particles, which were heat-treated at 700℃ for 10h, is about 1020nm, and the specific surface area is about 129m 2/g. The experimental results show that the ultrafine particles of cordierite precursor can be produced by this process. The precursor powder was calcined at different temperatures. X-ray diffraction examination indicates that β-quartz is crystallized from the amorphous matrix around 850℃ firstly and then MgO-Al 2O 3 spinel and α-cordierite appears. Above 1000℃, MgO-Al 2O 3 spinel and cristobalite disappear gradually and form an intermediate phase (sapphirine). At around 1300℃, the main phase is α-cordierite, and no other phase is detected.展开更多
One of the most severe problems affecting the efficient operations of gas pipelines is corrosion caused by black powder. According to the literature, the primary source for the existence of black powder is condensed w...One of the most severe problems affecting the efficient operations of gas pipelines is corrosion caused by black powder. According to the literature, the primary source for the existence of black powder is condensed water. In this case study, the temperature (40°C) of the sales gas is much higher than its dew point (9.24°C). The water is therefore in vapor phase. It is then proposed to remove water vapor from the gas at the entrance of the plant using an adsorption process. The recommended technology is the Layered Bed Temperature-Swing Adsorption (LBTSA) with micro-channels with molecular sieve zeolite 4A and activated alumina as adsorbents. In the case of presence of aerosols that could condense water, it is suggested to utilize a RED (Rare Earth Drum) magnetic separator in order to remove black powder from the gaseous feed.展开更多
文摘Cordierite precursor was obtained through a process, which involved the decomposition of metal nitrates on the surface of ultrafine carbon black powder between 100-300℃ and the gasification of the carbon black at higher temperature in air. The average size of the particles, which were heat-treated at 700℃ for 10h, is about 1020nm, and the specific surface area is about 129m 2/g. The experimental results show that the ultrafine particles of cordierite precursor can be produced by this process. The precursor powder was calcined at different temperatures. X-ray diffraction examination indicates that β-quartz is crystallized from the amorphous matrix around 850℃ firstly and then MgO-Al 2O 3 spinel and α-cordierite appears. Above 1000℃, MgO-Al 2O 3 spinel and cristobalite disappear gradually and form an intermediate phase (sapphirine). At around 1300℃, the main phase is α-cordierite, and no other phase is detected.
文摘One of the most severe problems affecting the efficient operations of gas pipelines is corrosion caused by black powder. According to the literature, the primary source for the existence of black powder is condensed water. In this case study, the temperature (40°C) of the sales gas is much higher than its dew point (9.24°C). The water is therefore in vapor phase. It is then proposed to remove water vapor from the gas at the entrance of the plant using an adsorption process. The recommended technology is the Layered Bed Temperature-Swing Adsorption (LBTSA) with micro-channels with molecular sieve zeolite 4A and activated alumina as adsorbents. In the case of presence of aerosols that could condense water, it is suggested to utilize a RED (Rare Earth Drum) magnetic separator in order to remove black powder from the gaseous feed.
