Metallogeny of the Lannigou Sedimentary Rock-hosted Disseminated Gold Deposit in Southwestern Guizhou Province,China

The Lannigou deposit is a large-sized sedimentary rock-hosted disseminated gold （SRHDG） deposit located in the Youjiang Basin. It is hosted by the Middle Triassic turbidite. Wall rock alterations, including silicification, pyritization, arsenopyritization, carbonatization and argillization, commonly occur along fractures. PGE study demonstrates that either Permian basalts or Triassic ultrabasic intrnsives are unlikely to be the main source of gold mineralization. Coupled with the lack of other nmgmatic activity in the vicinity of the mining area, an amagmatic origin is proposed. Organic matter compositions and GC-MS analysis of the ores and host rocks show that the organics in the ores and the host rocks have a common source; the organic matter in the ores was mainly indigenous. The positive correlation between S2 and Au contents, along with the common occurrence of organic inclusions, suggest involvement of organic matter in the ore-forming process in terms of promoting Au leaching from the source rocks, making colloidal Au migration possible, as well as hydrocarbon reduction of sulphate. Geological and geochemical characteristics of the Lannigou deposit suggest that it was formed through circulation of meteoric water and probably less importantly organic bearing formation water driven by high geothermal gradient caused by late Yanshanian extension, which leached Au from the source bed, and then migrated as Au-bisnlfides and colloidal Au, culminating in deposition by reduction-adsorption and surface complexation of gold onto the growth surface of arsenlan pyrite.

Research Progress in Solderable Black Pad of Electroless Nickel/Immersion Gold

Electroless nickel/immersion gold (ENIG) technology is widely used as one of the surface final finish for electronics packaging substrate and printed circuit board (PCB), providing a protective, conductive and solderable surface. However, there is a solder joint interfacial brittle fracture (or solderability failure) of using the ENIG coating. The characteristics and the application of ENIG technology were narrated in this paper. The research progress on the solderability failure of ENIG was introduced. The mechanism of 'black pad' and the possible measure of eliminating or alleviating the 'black pad' were also introduced. The development direction and market prospects of ENIG were prospected.

Black phosphorous nanosheets−gold nanoparticles−cisplatin for photothermal/photodynamic treatment of oral squamous cell carcinoma

To improve five-year survival rate of oral squamous cell carcinoma(OSCC),the development of a novel composite material of black phosphorus nanosheets(BPNSs)and gold nanoparticles(AuNPs)for tumor treatment was carried out.The purpose of this study is to evaluate the cytostatic effects of BPNSs,AuNPs loaded with cisplatin(CDDP)on human tongue squamous cell carcinoma cells lines(SCC-9),and 7,12-dimethylbenz anthracene induced cheek squamous cell carcinoma was validated in golden hamsters animal models.The results showed that BPNSs could efficiently inhibit the metastasis and growth of OSCC compared with CDDP and AuNPs.And a combination composite of AuNPs−BPNSs loaded with CDDP could more effectively inhibit the metastasis and growth of OSCC,which might be due to the high drug-loading capacity,excellent photothermal properties and the combination of photodynamic and photothermal therapy of BPNSs and AuNPs,as well as the synergistic effects of AuNPs,BPNSs and CDDP.

Hardening and Optimizing of the Black Gold Thin Film as the Absorption Layer for Infrared Detector

This paper reports on the study of the black gold thin film as the absorption layer in the near infrared spectrum. The fabrication of the black gold thin film was achieved by a thermal evaporation technique in N2 atmosphere. Different evaporation conditions were attempted to optimize the absorbance of the black gold coating, especially the atmosphere pressure and the mass of evaporation source. The long-standing problem of black gold’s adhesion with the substrate was solved by fuming 502 superglues into the black gold layer, which had almost no impact on the absorbance performance. Layers produced at N2 atmosphere of 3×103 Pa show an absorbance exceeding0.9 inthe near infrared.

Black Gold Ⅱ 5.1 Cannon声卡

专为电脑音乐迷而设计的新一代“黑金5.1”声卡带有光纤和同轴输入／输出接口子卡．同时还引入了多项创新设计，例如使用了机械继电器、大三芯的立体声插座以及对称式的电路设计等。这是一片十分讨人喜欢的中档声卡；

Micromineralogy of ＂Black Shale＂ Disseminated- Sulphide Gold Ore Deposits of the Ayan-Yuryakh Anticlinorium （North-East of Russia）

The results of investigation of micromineralogy of disseminated-sulphide gold ore deposits of the Yana-Kolyma belt; the investigation was conducted via electron microscopy using a QEMSCAN （Quantitative Evaluation of Minerals by Scanning Electron Microscopy） hardware and software instrument equipped with a Quantax quantitative analysis system. The following micro-mineral phases have been detected： native gold and silver, selenides of Au and Ag （naumanite and fishesserite （？）, hessite, sulfoarsenides of Ni and Co （gersdorffite, cobaltite, rammelsbergite）, molibdenite and platinum group minerals. Our findings in disseminated sulfide ores selenides of Au and Ag, and molybdenite, together with the findings of platinum group minerals and Ni and Co, emphasize the ＂black shale＂ specifics character of these types of deposits.

Black Gold on the 'Roof of the World'

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The Genesis Mechanism of the Mantle Fluid Action and Evolution in the Ore-Forming Process: A Case Study of the Laowangzhai Gold Deposit in Yunnan, China

Based on petrological studies of the wall rocks, mineralizing rocks, ores and veins from the Laowangzhai gold deposit, it is discovered that along with the development of silication, carbonation and sulfidation, a kind of black opaque ultra-microlite material runs through the spaces between grains, fissures and cleavages. Under observations of the electron microprobe, scanning electronic microscopy and energy spectrum, this kind of ultra-microlite material is confirmed to consist of ultra microcrystalline quartz, silicate, sulfides and carbonates, as well as rutile, scheelite and specularite （magnetite）, showing characters of liquation by the analyses of SEM and energy spectrum. The coexistence of immiscibility and precipitating co-crystallization strongly suggests that the mineralizing fluid changed from the melt to the hydrothermal fluid. Combined with the element geochemical researches, it is realized that the ultra-microlite aggregate is the direct relics of the mantle fluid behaving like a melt and supercritical fluid, which goes along with the mantle-derived magma and will escape from the magma body at a proper time. During the alteration process, the nature of the mantle fluid changed and it is mixed with the crustal fluid, which are favorable for mineralization in the Loawangzhai gold deposit.

Gold mineralisation and orogenic metamorphism in the Lena province of Siberia as assessed from Chertovo Koryto and Sukhoi Log deposits

The Chertovo Koryto gold deposit（80 t Au at 1.84 g/t） in the Lena world-class province,Siberia,is hosted in a metamorphosed sequence of the Paleoproterozoic Mikhailovsk Formation that comprises the oldest black shale strata of the Baikal-Patom region.The mineralisation is confined to the thrust zone complicated with a conjugate anticline fold,zones of shearing and dislocation.The struaural position of the mineralisation is similar to that at the giant Sukhoi Log deposit in the neighbouring Mama-Bodaibo zone.In the latter,the isotope age data suggest that Khomolkho black shales,hosts to Sukhoi Log mineralisation,are of Ediacaran age and underwent prograde metamorphism during early Paleozoic.The geochemical composition of the terrigenous rocks that host Sukhoi Log,Chertovo Koryto,and a number of other deposits at the various stratigraphic levels throughout the Proterozoic sequence have much in common.They do not show elevated metal contents above the common black shale abundances,except for Au and As,which is at variance with the accepted view on diagenetic enrichment of black shales in the Lena province.The occurrence of sagenitic rutile in quartz and chlorite pseudomorphs after biotite and other petrographic observations provide evidence on a retrograde nature of the metamorphic mineral assemblages in the Mikhailovsk rocks.The sulphides are pyrrhotite and arsenopyrite with very minor pyrite at Chertovo Koryto,whereas pyrite is the predominant sulphide in the Sukhoi Log ore.Fluid inclusion data on both deposits emphasise a high-temperature nature of the mineralisation albeit revealing great contrast in the fluid composition.Sukhoi Log mineralisation was formed at mixing between low-salinity aqueous solutions and dense gaseous carbonic fluids,which facilitated effective gold scavenging and precipitation,as demonstrated by thermodynamic simulation.The precursory devolatilisation of the Mikhailovsk sediments at the prograde stage results in the paucity of gaseous carbonic fluid during retrograde metamorphism and mineralisation.The similarity in the styles and chemical parameters of mineralisation,and the predominant structural control of ore localisation within the same Precambrian regional tectonic unit support an idea that orogenic gold mineralisation in the Lena province was produced during a single early Paleozoic event.

Multistage mineralization in the Haoyaoerhudong gold deposit, Central Asian Orogenic Belt: Constraints from the sedimentary-diagenetic and hydrothermal sulfides and gold

The Central Asian Orogenic Belt,as one of world-class gold economic belts,preserves a number of giant,large black shale-hosted gold deposits,while it is still debated for origin of sulfides and gold mainly due to lack of identification for multiple stages of sulfides.The Haoyaoerhudong gold deposit is hosted in a sequence of Mesoproterozoic carbonaceous and pyritic slate,phyllite,and schist that form a tight syncline along the north margin of the North China Craton.Detailed petrography of the host rocks and mineralization have defined five stages of pyrites.The earliest form of pyrite(Py_(1))occurs as fine-grained dispersed pyrite in black carbonaceous slate and medium-to coarse-grained disseminated pyrite in pyrite-rich layers,contains relative low gold and high arsenic content,indicating a syn-sedimentary or diagenetic in origin.Stage Ⅱ pyrite(Py_(2))occurs with garnet and quartz inclusions and Py_(3) occurs as pyrite veins,contains higher gold and lower As content,and are interpreted to have formed from the dissolution-reprecipitation of Py_(1) during the peak metamorphism or post-peak metamorphism.Stage Ⅳ pyrite(Py_(4))from the pyrite-quartz veins crosscut the metamorphic garnet,contains the highest gold concentrations and other trace elements,and is considered to have formed post-peak metamorphism.Abundant native gold,electrum,and maldonite occur as inclusions within Py_(4) and monazite and in fractures that crosscut garnet.While,Py_(5) with typical remobilized feature is thought to be a product of melting of former pyrites(Py_(1) to Py_(4))triggered by the large-scale Hercynian magmatism.The sedimentary/diagenetic Py_(1) have δ^(34)S values that range from +12.4‰to +16.2‰.Later generations of sulfides,including Py_(2) to Py_(5),and Ccp_(2) to Ccp_(3),have δ^(34)S values from +9.5‰to +12.7‰.Monazite with maldonite inclusions from quartz-pyrite veins yielded an intercept age of 341.3±6.6 Ma,while coarse grained monazite associated biotite along fractures in the reefs yielded an intercept age of 254.6±8.2 Ma.The paragenetic,textural,chemical,and isotopic data suggest three distinct gold producing episodes at Haoyaoerhudong gold deposit.Gold and arsenic were clearly initially concentrated in organic muds,and enriched along the structures of diagenetic arsenic-rich pyrite.Subsequently,accompanying metamorphism and deformation,gold was liberated from the dissolution of diagenetic pyrites to form the pyrite veins.Finally,accompanying transformation of pyrite into pyrrhotite,gold was released into the metamorphic fluids to become concentrated as native gold,electrum,and maldonite in pyrite-quart veins.Monazite with age of 341 Ma from quartz-pyrite veins suggests that the third major gold mineralizing event in Haoyaoerhudong occurred before the Hercynian magmatism,suggesting that the Haoyaoerhudong deposit is a typical orogenic gold deposit rather than intrusion-related deposit.

Comparative Study of Gold Concentration by Elutriation from Different Precious Metal Bearing Ores

Conventional methods for precious metals gravimetric concentration involve equipment such as shaking tables, centrifuging concentrators, jigs, trommels, or a combination of those. A less commonly used technique is elutriation, which represents an efficient, safe and low-cost method of separation. The goal of the present investigation was to make a comparative study of gold concentration by elutriation from different precious metal bearing ores: an oxide ore, a mineral consisting of a sulfide matrix, a mineral in which the precious metals are free and disseminated and a slimy and clayey black sand material. The best recoveries of precious metals by elutriation were attained for the free disseminated ore and for the black sands, obtaining gold recoveries of 70% and 96% respectively, with appreciable ratios of concentration as well.

Graphite and Graphite-like Materials from Black Shale and Magmatic Ores: Raman Spectroscopy Data

Graphite and graphite-like materials widely are present at black shale and magmatic ores. The nature of these carbon materials (CM) is multifarious. In what cause connects a mineralization with carbon. The great numbers of parameters, namely, the temperature, the pressure, the shear stress, the catalytic species, the host-rock lithology, the time and etc., have an influence on the graphitization process. Accumulations of gold and platinum group elements in black graphite shale and extraction of these metals from rocks depend in considerable degree from structural properties of CM. Raman spectroscopy has wide applied for various carbon modifications, including nano-structuring materials. The first and second-order Raman spectrum have been correlated with changes in the structure of graphite. There is a linear relationship between temperature and Raman R2 and R1 parameters (derived from the area and intensity of the defect band (D) relative to the ordered graphite band (G), respectively). The purpose of the present study is to characterize the rocks and CM from carbon-rich rocks of gold-ore deposits of the black-shale formation and magmatic ores using micro-Raman spectroscopy technique (Horiba Jobin Ivon LabRam spectrometer). Exciting was performed with 325 nm line of He-Cd laser. The graphite and graphite-like samples from many ore deposits of Russia and Kazahstan are investigations. R1 and R2 ratio indicate variable degree of organisation CM in the samples. The results show different spectral variations of CM with metamorphic grade: the well-ordered graphite from magmatic rocks, more - ordered and the disordered less graphitized CM from black-shale ores. For the first time in the world practice the Raman spectroscopy technique has been applied to determine the temperature of graphitizing for CM at gold-ore deposits of the black-shale formation. The temperatures obtained on carboniferous substance for the gold deposits range from 405°С to 280°С. Temperature of CM formation from Pt-low sulphide ores of the Talnakh deposit ranges from 4700C to 6500C. It has been shown that the carbon-rich phases from black-shale and magmatic rocks have various degrees of graphitization and different carbon forms.

激电测深法在南秦岭苏岭沟金矿区的勘查应用

南秦岭夏家店金矿床由夏家店、苏岭沟和刘家峡3个矿区组成,是一处典型的具有重要经济价值的黑色岩系容矿的金矿床。在苏岭沟金矿区利用激电测深(IP)方法,探测了泥盆系地层覆盖地段Ⅰ号构造带和黑色含矿岩系在深部向西延伸及其倾向埋深展布情况。根据激电测深数据获得“低阻-高极化”特征的断面激电异常曲线图并结合地质资料,解译推测了深部含矿目标层及含矿构造空间赋存状况。经钻探验证,金矿化体位置与激电测深推断的极化率异常中心埋深基本吻合。同时,建立了矿区岩(矿)石电性参数的数据库。本次研究为本矿区及矿区外围开展激电测深法探寻同类型、同特征的矿床积累了数据支撑。

黑捕收剂在硫化铜矿中的浮选实验研究

硫化矿是较为重要的矿产资源,也是贵金属的主要来源,浮选是一种常用的矿石选矿方法,是目前硫化矿综合回收的首选方法。此次研究针对黑药捕收剂的特性,将其运用于硫化铜矿的浮选实验,通过对硫化铜矿和毒矿的性质进行分析,选择不同的磨矿细度和pH值调整来对硫化铜矿和毒砂进行实验最后在合适的指标下,对两种矿物进行闭路实验。实验结果表明,丁铵黑药与硫化铜矿的组合,可以获得金品位24.97g/t,其金回收率为87.92%。丁铵黑药对硫化铜矿的回收率高于毒矿3.65个百分点。研究表明,黑药捕收剂对硫化铜矿的浮选效果较高,能够给矿物加工行业提供一定的参考。

贵州遵义中南村黑色岩系黄铁矿的成分标型与成因探讨

对贵州遵义中南村黑色岩系多元素矿床黄铁矿中的Co、Ni、As、Se、Te、n(S)/n(Fe)、w(Co)/w(Ni)、w(S)/w(Se)、w(Se)/w(Te)等标型进行了研究,并将其与4个胶东热液型金矿的黄铁矿的相应数据进行了对比。通过成分标型分析,并结合黄铁矿的形态、内部结构和同位素特征以及前人的研究成果,认为此黑色岩系多元素矿床应为海底热水沉积和生物沉积混合成因。该黑色岩系黄铁矿同胶东界河金矿的黄铁矿、胶东金青顶金矿中的黄铁矿、胶东玲珑金矿西山矿区中的黄铁矿和胶东三山岛金矿床中的黄铁矿等热液金矿型黄铁矿在10000×w(Co+Ni)/w(Fe)—10000×w(As+Se+Te)/w(S)—100×(n(S)/n(Fe)-1 8)三角图上的投点明显不同,前者投点甚为分散,后者投点较集中。从成因角度分析认为:后者的物质来自花岗岩,主成矿过程受单一的温度变化范围不大的岩浆热液控制;前者物质来源复杂,受高温阶段的深部循环热水和低温阶段的海水—热水混合流体甚至生物作用的制约。由此可以初步提出以下一般判据:在10000×w(Co+Ni)/w(Fe)—10000×w(As+Se+Te)/w(S)—100×(n(S)/n(Fe)-1 8)三角图上,成因简单的黄铁矿的投点较集中,成因复杂的黄铁矿的投点较分散。

绥芬河三块鱼属鱼类和东北雅罗鱼亲缘关系的RAPD分析

利用RAPD技术对绥芬河水系三块鱼属 (Tribolodon)的金滩头、黑滩头和雅罗鱼属的东北雅罗鱼 (Leucis cuswaleckiiDybowsk)进行属间、种间遗传物质相似性分析。样品取于溯河生殖洄游期 ( 4～ 6月 )。结果表明 ,金滩头和黑滩头种间的RAPD指纹图谱带型差异显著 ,平均带纹相似系数为 0 .3 0 ,遗传距离为 0 .70。东北雅罗鱼与金滩头和黑滩头属间的平均带纹相似系数分别为 0 .13和 0 .16,遗传距离为 0 .87和 0 .84。根据绥芬河水系金滩头和黑滩头间的遗传距离 ( 0 .70 ) ,将二者划分为 2个不同物种 ,即珠星三块鱼 (TribolodonhakonensisG櫣ｎｔｈｅｒ)和三块鱼(T .brandtiDybowski)。

壳聚糖修饰炭黑负载Pt-Au催化剂对甲醇氧化的电催化性能

以炭黑及自制的壳聚糖-炭黑(CHI-C)复合材料为载体,采用溶胶负载法制备了Ptm^Au/C及Ptm^Au/CHI-C催化剂(^代表Au、Pt为分步负载,m代表Pt/Au原子比),通过紫外-可见吸收光谱、X射线衍射、透射电镜及X射线光电子能谱对催化剂进行了表征。利用循环伏安法和计时电流法分别测定了Pt-Au催化剂对甲醇电催化氧化反应的活性和稳定性,考查了Pt/Au原子比及CHI改性对电催化活性和稳定性的影响。结果表明,Pt1.0^Au/C具有最高的催化活性,炭黑中加入少量CHI能提高Pt1.0^Au/C催化剂的稳定性。

陕西石泉-汉阴北部下志留统黑色岩系中的金矿床

石泉-汉阴北部下志留统梅子垭组黑色岩系金矿带位于南秦岭造山带西部的牛山古陆北缘.该矿带东西长约100 km,南北宽10~20 km.初步查明下志留统梅子垭组为区内金矿含矿层位,并按其岩性组合特征划分为6个岩性段,4个子含矿层位.矿带内发现10余处金矿床（点.）金矿受地层、岩性、古地理和古构造条件控制,与黑色岩系具有同源性.金主要以颗粒金存在且分布极不均匀.硫同位素的变化范围说明硫来源于地层.氢氧同位素的特征说明成矿热液中的水介质是以变质热液和大气降水为主的混合水.稀土元素特征显示金矿物源与秦巴地区泥盆系沉积岩相似.韧性剪切带并不是金矿体出现的必须标志.研究认为梅子垭组中的金矿属沉积型矿床.

天山成矿带境内外地球化学特征对比——中国东天山和哈萨克斯坦楚伊犁地区

对天山成矿带中国境内的东天山地区和哈萨克斯坦境内的楚伊犁地区1∶100万比例尺的地球化学填图所揭示的信息进行了对比研究。造岩元素、铁族元素、稀有元素、稀土元素和分散元素在这2个地区的含量和富集程度都非常接近,说明天山地区具有相同的地质背景;贵金属元素Au在楚伊犁地区的含量和富集程度要显著高于东天山地区,楚伊犁地区的Au异常不仅与石英脉型金矿有关,还与黑色页岩微粒金矿化有关;有色金属元素在2个地区差别不大,不同的是Cu异常在东天山以独立或与其他有色金属元素伴生异常存在,而在楚伊犁主要以与贵金属元素伴生异常存在;铂族元素在2个地区含量比较接近,一类异常与基性和超基性岩有关,另一类与黑色岩系有关。尽管这2个地区都还未发现有经济价值的铂族元素矿床,但在楚伊犁地区已经发现与炭质硅质岩有关的微粒金、铂矿化。