Analyses of organic carbon, nitrogen, sulfur and iron have been performed in order to understand sources and preservation of organic matter in black shale of the Buxin Formation (Early Paleogene) from the Sanshui Basi...Analyses of organic carbon, nitrogen, sulfur and iron have been performed in order to understand sources and preservation of organic matter in black shale of the Buxin Formation (Early Paleogene) from the Sanshui Basin. The C/N ratios show that the organic matter is characterized by a mixture of terrestrial and phytoplanktonic contributions. The relative importance of different sources depend on climate conditions and most of organic matter is of terrestrial origin. The relationships between C, S and Fe indicate that the brackish environment with alternation of anoxia and low-O2 developed in the bottom waters during the deposition of these organic-rich sediments as a result of a mixed setting of thermal stratification and salinity stratification, the latter being the consequence of intermittent sea water incursion. Bacterial sulfate reduction is the most effective early diagenesis affecting the preservation of organic matter. The intensity of sulfate reduction is related to the relative proportion of metabolizable organic matter supplied to sediments.展开更多
More and more evidence indicates that organic matter (OM) in immature organic-rich sediments and sedimentary rocks is chemically adsorbed onto the outer surfaces of minerals and into interlayer (inner) surfaces of sme...More and more evidence indicates that organic matter (OM) in immature organic-rich sediments and sedimentary rocks is chemically adsorbed onto the outer surfaces of minerals and into interlayer (inner) surfaces of smectitic clay minerals in the form of amorphous molecular-scale carbon. But there have been few reports about the occurrence of highly mature OM in marine black shales (petroleum source rocks). The occurrence of highly mature OM in the black shales of basal Cambrian from northern Tarim Basin is studied in this paper. Based on the comprehensive analyses of total organic carbon contents (TOC), maximum thermolysis temperatures (T-max) of OM, mineral surface areas (MSA), and scanning electronic microscopic (SEM) and transmission electronic microscopic (TEM) observations of the black shales, it is concluded that the highly mature OM in the marine black shales of the basal Cambrian from northern Tarim Basin occurs in particulates ranging in size from 1 to 5 μm in diameter. Through the contrast of the occurrence of the highly mature OM in the black shales with that of the immature ones in modern marine continental margin sediments, some scientific problems are proposed, which are worth to study further in detail.展开更多
Lower Silurian Longmaxi Shale(SLS) in southeastern Sichuan Basin, China, was analyzed for major and selected trace elements, and their provenance, intensity of palaeoweathering of the source rocks were analyzed based ...Lower Silurian Longmaxi Shale(SLS) in southeastern Sichuan Basin, China, was analyzed for major and selected trace elements, and their provenance, intensity of palaeoweathering of the source rocks were analyzed based on these elements. The results show that SiO_2, Al_2O_3 and Fe_2O_3, are dominant major elements with average contents of 60.59%, 15.91% and 5.87% in Upper Silurian Longmaxi Shale(USLS), and 65.14%, 13.24% and 4.68% in Lower Silurian Longmaxi Shale(LSLS). The TiO_2-Zr plot, Hf(ppm) versus La/Th discriminant diagram, and abundance of Cr and Ni suggest a dominantly felsic source for the Longmaxi sediments. Average chemical index of alteration(CIA), plagioclase index of alteration(PIA) values(64.05% and 72.86%, respectively) imply low-degree chemical weathering of the source material in early Longmaxi time, and average CIA, PIA values(68.44% and 80.35%, respectively) imply moderate chemical weathering of the source material in late Longmaxi time.展开更多
Black shales are usually interpreted to require anoxic bottom waters and deeper water sedimentation. There has long been a debate about whether the Devonian Cleveland Shale Member of the Ohio Shale (CSM) was deposited...Black shales are usually interpreted to require anoxic bottom waters and deeper water sedimentation. There has long been a debate about whether the Devonian Cleveland Shale Member of the Ohio Shale (CSM) was deposited in shallow- or deep-water depositional environments. This study looked at the CSM at 3 stratigraphic sections and 5 well cores in northeastern Ohio. The CSM mostly consists of sapropelite (interbedded carbonaceous black mudstones and gray calcareous claystones). The black and gray “shales” are rhythmically bedded at micro- (<1 cm thick), meso- (<10 cm thick) and macro-scales (10s of cm thick) and represent changes in organic matter content (ranging from 7% - 20% TOC). Three types of event layers are interbedded with the mudrocks: 1) tempestites, 2) proximal turbidites, and 3) hyperpycnites. Individual tempestites and turbidites are laterally continuous?≥35 km, while hyperpycnites are too thin (<1 cm) to trace laterally. Tempestites consist of hummocky stratified sandstones with groove casts and escape burrows overlain by planar laminated sandstones with wave ripples at the top. Tempestites average 13 cm thick, but can be amalgamated up to 45 cm thick, and are more common in the lower half of the unit. Turbidites are incomplete Bouma sequences that average 6 cm thick, show evidence of combined flow (“wave-modified turbidites”), and are more common toward the top of the unit. Hyperpycnites (density underflows from river discharge) consist of inverse-to-normal graded sandy or silty microlaminae that have been studied primarily by using petrography and SEM. Condensed sections in the CSM are probable firmgrounds with carbonate concretions, and indicate intervals of low sedimentation rates. The evidence shows that the CSM depositional environment was receiving siliciclastics from the northeast (e.g., Catskill delta), and that the coarser-grained clastic sediment was primarily transported as density underflows (turbidites and hyperpycnites). However, significant storm deposits (tempestites) within the CSM indicate erosion and redeposition occurred on a muddy clastic marine shelf at paleo-water depths less than storm-weather wave base (probably?≤50 m depth).展开更多
In recent years, natural gas exploration in the Sinian Dengying Formation and shale gas exploration in Doushantuo Formation have made major breakthroughs in the Sichuan Basin and its adjacent areas. However, the sedim...In recent years, natural gas exploration in the Sinian Dengying Formation and shale gas exploration in Doushantuo Formation have made major breakthroughs in the Sichuan Basin and its adjacent areas. However, the sedimentary background of the Doushantuo Formation hasn't been studied systematically. The lithofacies paleogeographic pattern, sedimentary environment, sedimentary evolution and distribution of source rocks during the depositional stage of Doushantuo Formation were systematically analyzed by using a large amount of outcrop data, and a small amount of drilling and seismic data.(1) The sedimentary sequence and stratigraphic distribution of the Sinian Doushantuo Formation in the middle-upper Yangtze region were controlled by paleouplifts and marginal sags. The Doushantuo Formation in the paleouplift region was overlayed with thin thickness, including shore facies, mixed continental shelf facies and atypical carbonate platform facies. The marginal sag had complete strata and large thickness, and developed deep water shelf facies and restricted basin facies.(2) The Doushantuo Formation is divided into four members from bottom to top, and the sedimentary sequence is a complete sedimentary cycle of transgression–high position–regression. The first member is atypical carbonate gentle slope deposit in the early stage of the transgression, the second member is shore-mixed shelf deposit in the extensive transgression period, and the third member is atypical restricted–open sea platform deposit of the high position of the transgression.(3) The second member has organic-rich black shale developed with stable distribution and large thickness, which is an important source rock interval and major shale gas interval. The third member is characterized by microbial carbonate rock and has good storage conditions which is conducive to the accumulation of natural gas, phosphate and other mineral resources, so it is a new area worthy of attention. The Qinling trough and western Hubei trough are favorable areas for exploration of natural gas(including shale gas) and mineral resources such as phosphate and manganese ore.展开更多
Ordovician black shales are widely distributed in the Tarim Basin and its peripheral regions,and some of them may serve as potential hydrocarbon source rocks.The present study of the Ordovician graptolite fauna from t...Ordovician black shales are widely distributed in the Tarim Basin and its peripheral regions,and some of them may serve as potential hydrocarbon source rocks.The present study of the Ordovician graptolite fauna from these shales,together with the yielded conodonts and chitinozoans etc.,permits a refined correlation of the rocks.Based mainly on a new collecting of the graptolites and a study of the faunas in Kalpin and Kuruktag regions,and the successful identification of the new graptolite material from a few drill cores within the basin,we are able to update our knowledge of the Ordovician in the regions,and draw some conclusions:(1) The most widespread distribution of the black shales in the Tarim Basin and its peripheral regions,which correspond to the Nemagraptus gracilis Zone,may be related to a global sea-level rise during this time interval.(2) Black shales of Ordovician occur most frequently and extensively in the Kuruktag(also spelled as Quruq Tagh) region in east-ern Tianshan Mountains,spanning Tremadocian to mid-Katian(D.spiniferus Zone) temporally and extending southeastwards into Manjiaer Depression.The black shales of the D.spiniferus Zone may even extend into the central Tarim Basin.(3) Three different bio-and litho-facies belts(Bachu:carbonate platform and reef belt;Kalpin-Aksu:marginal platform and upper slope belt;Wushi:slope belt) are recognized in the northwestern Tarim Basin.(4) The internationally well-correlated Saergan black shale,which has been considered to possess high potential for hydrocarbon source rock,may possess a restricted distribution in the Kalpin and Aksu areas.展开更多
The systematic analyses of trace elements, REEs and PGEs of black shale at the bot-tom of the Lower Cambrian in Tarim Basin have been made for the first time in this work. The basic geochemical features are that some ...The systematic analyses of trace elements, REEs and PGEs of black shale at the bot-tom of the Lower Cambrian in Tarim Basin have been made for the first time in this work. The basic geochemical features are that some trace elements having something to do with the deep-level fluids are highly enriched, including V, Cr, Ni, Cu, Zn, Ge, As, Sr, Y, Mo, Ag, Cd, Sb, Ba, Pb and U, and the Th/U and Th/Sc ratios decreased compared with those in the same kind of rocks in the crust, that the enriched degrees of LREEs are reduced, Eu and Ce depleted distinctly in the chon-drite-normalized REE patterns, and that the contents of PGEs and Au are increased. These char-acteristics indicate that there were more mafic interior sources in the basin when the black shale was deposited. Generally, the interior sources show an extensional tectonic setting of lithosphere. It can be seen from the change of the characteristics of trace elements, REEs and PGEs along the black shale section that the quantity of interior source from inner earth is gradually increased upwards in the lower part of the section, reaches the peak value as shown by sample No. 4 (XCM7-1), and then decreased, which might indicate the episodic extension of lithosphere in the beginning of the Lower Cambrian.展开更多
基金A financial support for this research was provided by the Natural Science Foundation of China under Grant No.4027201 1the Natural Science Foundation of Guangdong Province under Grant No.001203.
文摘Analyses of organic carbon, nitrogen, sulfur and iron have been performed in order to understand sources and preservation of organic matter in black shale of the Buxin Formation (Early Paleogene) from the Sanshui Basin. The C/N ratios show that the organic matter is characterized by a mixture of terrestrial and phytoplanktonic contributions. The relative importance of different sources depend on climate conditions and most of organic matter is of terrestrial origin. The relationships between C, S and Fe indicate that the brackish environment with alternation of anoxia and low-O2 developed in the bottom waters during the deposition of these organic-rich sediments as a result of a mixed setting of thermal stratification and salinity stratification, the latter being the consequence of intermittent sea water incursion. Bacterial sulfate reduction is the most effective early diagenesis affecting the preservation of organic matter. The intensity of sulfate reduction is related to the relative proportion of metabolizable organic matter supplied to sediments.
文摘More and more evidence indicates that organic matter (OM) in immature organic-rich sediments and sedimentary rocks is chemically adsorbed onto the outer surfaces of minerals and into interlayer (inner) surfaces of smectitic clay minerals in the form of amorphous molecular-scale carbon. But there have been few reports about the occurrence of highly mature OM in marine black shales (petroleum source rocks). The occurrence of highly mature OM in the black shales of basal Cambrian from northern Tarim Basin is studied in this paper. Based on the comprehensive analyses of total organic carbon contents (TOC), maximum thermolysis temperatures (T-max) of OM, mineral surface areas (MSA), and scanning electronic microscopic (SEM) and transmission electronic microscopic (TEM) observations of the black shales, it is concluded that the highly mature OM in the marine black shales of the basal Cambrian from northern Tarim Basin occurs in particulates ranging in size from 1 to 5 μm in diameter. Through the contrast of the occurrence of the highly mature OM in the black shales with that of the immature ones in modern marine continental margin sediments, some scientific problems are proposed, which are worth to study further in detail.
基金Project(41302076)supported by the National Natural Science Foundation of ChinaProject(BJ14266)supported by MOST Special Fund from the State Key Laboratory of Continental Dynamics,Northwest University,ChinaProject(2014JQ5191)supported by Natural Science Basic Research Plan of Shaanxi Province,China
文摘Lower Silurian Longmaxi Shale(SLS) in southeastern Sichuan Basin, China, was analyzed for major and selected trace elements, and their provenance, intensity of palaeoweathering of the source rocks were analyzed based on these elements. The results show that SiO_2, Al_2O_3 and Fe_2O_3, are dominant major elements with average contents of 60.59%, 15.91% and 5.87% in Upper Silurian Longmaxi Shale(USLS), and 65.14%, 13.24% and 4.68% in Lower Silurian Longmaxi Shale(LSLS). The TiO_2-Zr plot, Hf(ppm) versus La/Th discriminant diagram, and abundance of Cr and Ni suggest a dominantly felsic source for the Longmaxi sediments. Average chemical index of alteration(CIA), plagioclase index of alteration(PIA) values(64.05% and 72.86%, respectively) imply low-degree chemical weathering of the source material in early Longmaxi time, and average CIA, PIA values(68.44% and 80.35%, respectively) imply moderate chemical weathering of the source material in late Longmaxi time.
文摘Black shales are usually interpreted to require anoxic bottom waters and deeper water sedimentation. There has long been a debate about whether the Devonian Cleveland Shale Member of the Ohio Shale (CSM) was deposited in shallow- or deep-water depositional environments. This study looked at the CSM at 3 stratigraphic sections and 5 well cores in northeastern Ohio. The CSM mostly consists of sapropelite (interbedded carbonaceous black mudstones and gray calcareous claystones). The black and gray “shales” are rhythmically bedded at micro- (<1 cm thick), meso- (<10 cm thick) and macro-scales (10s of cm thick) and represent changes in organic matter content (ranging from 7% - 20% TOC). Three types of event layers are interbedded with the mudrocks: 1) tempestites, 2) proximal turbidites, and 3) hyperpycnites. Individual tempestites and turbidites are laterally continuous?≥35 km, while hyperpycnites are too thin (<1 cm) to trace laterally. Tempestites consist of hummocky stratified sandstones with groove casts and escape burrows overlain by planar laminated sandstones with wave ripples at the top. Tempestites average 13 cm thick, but can be amalgamated up to 45 cm thick, and are more common in the lower half of the unit. Turbidites are incomplete Bouma sequences that average 6 cm thick, show evidence of combined flow (“wave-modified turbidites”), and are more common toward the top of the unit. Hyperpycnites (density underflows from river discharge) consist of inverse-to-normal graded sandy or silty microlaminae that have been studied primarily by using petrography and SEM. Condensed sections in the CSM are probable firmgrounds with carbonate concretions, and indicate intervals of low sedimentation rates. The evidence shows that the CSM depositional environment was receiving siliciclastics from the northeast (e.g., Catskill delta), and that the coarser-grained clastic sediment was primarily transported as density underflows (turbidites and hyperpycnites). However, significant storm deposits (tempestites) within the CSM indicate erosion and redeposition occurred on a muddy clastic marine shelf at paleo-water depths less than storm-weather wave base (probably?≤50 m depth).
基金Supportd by the China National Science and Technology Major Project(2016ZX05004-001)
文摘In recent years, natural gas exploration in the Sinian Dengying Formation and shale gas exploration in Doushantuo Formation have made major breakthroughs in the Sichuan Basin and its adjacent areas. However, the sedimentary background of the Doushantuo Formation hasn't been studied systematically. The lithofacies paleogeographic pattern, sedimentary environment, sedimentary evolution and distribution of source rocks during the depositional stage of Doushantuo Formation were systematically analyzed by using a large amount of outcrop data, and a small amount of drilling and seismic data.(1) The sedimentary sequence and stratigraphic distribution of the Sinian Doushantuo Formation in the middle-upper Yangtze region were controlled by paleouplifts and marginal sags. The Doushantuo Formation in the paleouplift region was overlayed with thin thickness, including shore facies, mixed continental shelf facies and atypical carbonate platform facies. The marginal sag had complete strata and large thickness, and developed deep water shelf facies and restricted basin facies.(2) The Doushantuo Formation is divided into four members from bottom to top, and the sedimentary sequence is a complete sedimentary cycle of transgression–high position–regression. The first member is atypical carbonate gentle slope deposit in the early stage of the transgression, the second member is shore-mixed shelf deposit in the extensive transgression period, and the third member is atypical restricted–open sea platform deposit of the high position of the transgression.(3) The second member has organic-rich black shale developed with stable distribution and large thickness, which is an important source rock interval and major shale gas interval. The third member is characterized by microbial carbonate rock and has good storage conditions which is conducive to the accumulation of natural gas, phosphate and other mineral resources, so it is a new area worthy of attention. The Qinling trough and western Hubei trough are favorable areas for exploration of natural gas(including shale gas) and mineral resources such as phosphate and manganese ore.
基金supported by Chinese Academy of Sci-ences (Grant Nos. KZCX2-EW-111 and KZCX2-YW-Q05-01)China Geological Survey (Grant No.1212011120116)
文摘Ordovician black shales are widely distributed in the Tarim Basin and its peripheral regions,and some of them may serve as potential hydrocarbon source rocks.The present study of the Ordovician graptolite fauna from these shales,together with the yielded conodonts and chitinozoans etc.,permits a refined correlation of the rocks.Based mainly on a new collecting of the graptolites and a study of the faunas in Kalpin and Kuruktag regions,and the successful identification of the new graptolite material from a few drill cores within the basin,we are able to update our knowledge of the Ordovician in the regions,and draw some conclusions:(1) The most widespread distribution of the black shales in the Tarim Basin and its peripheral regions,which correspond to the Nemagraptus gracilis Zone,may be related to a global sea-level rise during this time interval.(2) Black shales of Ordovician occur most frequently and extensively in the Kuruktag(also spelled as Quruq Tagh) region in east-ern Tianshan Mountains,spanning Tremadocian to mid-Katian(D.spiniferus Zone) temporally and extending southeastwards into Manjiaer Depression.The black shales of the D.spiniferus Zone may even extend into the central Tarim Basin.(3) Three different bio-and litho-facies belts(Bachu:carbonate platform and reef belt;Kalpin-Aksu:marginal platform and upper slope belt;Wushi:slope belt) are recognized in the northwestern Tarim Basin.(4) The internationally well-correlated Saergan black shale,which has been considered to possess high potential for hydrocarbon source rock,may possess a restricted distribution in the Kalpin and Aksu areas.
基金This work was jointly supported by the Ministry of Science and Technology of China (Grant No. G1999043304) the National Natural Science Foundation of China (Grant No. 40172042) and the Special Foundation for Doctoral Subjects in China (Grant No. 2000
文摘The systematic analyses of trace elements, REEs and PGEs of black shale at the bot-tom of the Lower Cambrian in Tarim Basin have been made for the first time in this work. The basic geochemical features are that some trace elements having something to do with the deep-level fluids are highly enriched, including V, Cr, Ni, Cu, Zn, Ge, As, Sr, Y, Mo, Ag, Cd, Sb, Ba, Pb and U, and the Th/U and Th/Sc ratios decreased compared with those in the same kind of rocks in the crust, that the enriched degrees of LREEs are reduced, Eu and Ce depleted distinctly in the chon-drite-normalized REE patterns, and that the contents of PGEs and Au are increased. These char-acteristics indicate that there were more mafic interior sources in the basin when the black shale was deposited. Generally, the interior sources show an extensional tectonic setting of lithosphere. It can be seen from the change of the characteristics of trace elements, REEs and PGEs along the black shale section that the quantity of interior source from inner earth is gradually increased upwards in the lower part of the section, reaches the peak value as shown by sample No. 4 (XCM7-1), and then decreased, which might indicate the episodic extension of lithosphere in the beginning of the Lower Cambrian.