MISCIBILITY AND MORPHOLOGICAL STRUCTURE OF BIODEGRADABLE BLEND OF POLY(β—HYDROXYBUTYRATE)AND POLY(D,L—LACTIDE)

The poly(β-hydroxybutyrate)/poly(d,1-lactide)(PHB/PLA)blend was found to be immiscible,the melting point and the phase crystallinity of PHB were independent of the blend composition.Comparing with plain PHB,the blend exhibited the crystallization change and a certain improvement of the mechanical property.

PARACRYSTAL STRUCTURE PARAMETERS STUDIES IN LDPE/EPO BLENDS WITH VARIANCE-RANGE FUNCTION METHOD

X-ray diffraction line profiles of low density polyethylene(LDPE)/ (ethylene-propylene-octene-1)copolymer(EPO)blends have been analyzed with variance range function method.Theories for determining the microparacrystallite size and the distortion parameter from single reflection have been described,and the value of these two parameters at (110)and(200)directions have been determined.

A single-level composite structure optimization method based on a blending tapered model

In order to decrease the number of design variables and improve the efficiency of com- posite structure optimal design, a single-level composite structure optimization method based on a tapered model is presented. Compared with the conventional multi-level composite structure opti- mization method, this single-level method has many advantages. First, by using a distance variable and a ply group variable, the number of design variables is decreased evidently and independent with the density of sub-regions, which makes the single-level method very suitable for large-scale composite structures. Second, it is very convenient to optimize laminate thickness and stacking sequence in the same level, which probably improves the quality of optimal result. Third, ply con-tinuity can be guaranteed between sub-regions in the single-level method, which could reduce stress concentration and manufacturing difficulty. An example of a composite wing is used to demonstrate the advantages and competence of the single-level method proposed.

Additivity of pore structural parameters of granular activated carbons derived from different coals and their blends

A series of granular activated carbons （GACs） were prepared by briquetting method from Chinese coals of different ranks and their blends, with coal pitch as the binder. Pore structural parameters including BET specific surface area （SBEr）, total pore volume （Vr） and average pore diameter （da） were measured and cal- culated as well as process parameters such as yield of char （CY） and burn-off （B）. The relationship between the pore structural parameters of the GAC from coal blend （BC-GAC） and the ones of the GACs from corresponding single coals （SC-GACs） was analyzed, in which an index, the relative error （δ）, was presented to define the bias between fitted values and experimental values of these parameters of the BC-GACs. The results show that the BC-GAC keeps qualitatively the pore structural features of the SC-GACs; as concerned as the quantitative relationship, the pore structural parameters of the BC-GAC from coal blend consisting of non-caking coals can be obtained by adding proportionally the pore structural parameters of the SC-GACs with a less than 10%. Meanwhile, for the BC-GAC from coal blend containing weak caking bituminous coal, the δ increases up to 25% and the experimental pore size distribution differs greatly from the fitted one.

Effect of Konjac Glucomannan on Sodium Alginate Membrane

This paper introduces a blended membrane which is prepared by coagulation of sodium alginate and konjac glucomannan（KGM） in an aqueous solution, and studies the effect of different concentrations of KGM on sodium alginate films. The structural characterization of prepared blend film was implemented by scanning electron microscopy（SEM） and Fourier transform infrared spectroscopy（FT-IR）, and the optimum ratio was determined by comparing fracture elongation, moisture absorption and moisture retention. The results indicate that the two polysaccharide molecules, sodium alginate and KGM, in the blend membrane have a good compatibility. The surface of blend film is smooth and uniform. The addition of KGM can significantly improve the moisture absorption and moisture retention performance of sodium alginate film, and its mechanical performance is also improved to some extent. The ratio of sodium alginate and KGM is 3.2∶1.5.

Growth and properties of GaAs nanowires on fused quartz substrate

The growth of GaAs nanowires directly on fused quartz substrates using molecular beam epitaxy via a vapor-liquid-solid mechanism with gold as catalyst is reported. Unlike conventional Au-catalyst MBE growth of nanowires （NWs） on GaAs substrates, zinc blende is found to be the dominant crystal structure for NWs grown on fused-quartz substrates by MBE. Further transmission electron microscopy measurements show that the prepared ZB NWs have the growth direction of [112] and lamellar { 111 } twins extend through the length of NWs. Although there are longitudinal planar defects that extend through NWs, the narrow full width at half maximum of PL implies high crystal quality of NWs grown on fused-quartz substrates.

Size-independent growth of pure zinc blende GaAs nanowires

Pure zinc blende GaAs nanowires were grown by metal organic chemical vapor deposition on GaAs（111） B substrates via Au catalyzed vapor-liquid-solid mechanism.We found that the grown nanowires are rod-like in shape and have a pure zinc blende structure;moreover,the growth rate is independent on its diameters.It can be concluded that, direct impingement of vapor species onto the Au-Ga droplets contributes to the growth of the nanowire;in contrast,the adatom diffusion makes little contribution.The results indicate that the droplet acts as a catalyst rather than an adatom collector,larger diameter and high supersatuation in the droplet leads to the pure zinc blende structure of the nanowire.