High density polyethylene （HDPE）/polyethylene-block-poly（ethylene glycol） （PE-b-PEG） blend porous membranes were prepared via thermally induced phase separation （TIPS） process using diphenyl ether （DPE） as d...High density polyethylene （HDPE）/polyethylene-block-poly（ethylene glycol） （PE-b-PEG） blend porous membranes were prepared via thermally induced phase separation （TIPS） process using diphenyl ether （DPE） as diluent. The phase diagrams of HDPE/PE-b-PEG/DPE systems were determined by optical microscopy and differential scanning calorimetry （DSC）. By varying the content of PE-b-PEG, the effects of PE-b-PEG copolymer on morphology and crystalline structure of membranes were studied by scanning electron microscopy （SEM） and wide angle X-ray diffraction （WAXD）. The chemical compositions of whole membranes and surface layers were characterized by elementary analysis, Fourier transform infrared spectroscopy-attenuated total reflection （FTIR-ATR） and X-ray photoelectron spectroscopy （XPS）. Water contact angle, static protein adsorption and water flux experiments were used to evaluate the hydrophilicity, antifouling and water permeation properties of the membranes. It was found that the addition of PE-b-PEG increased the pore size of the obtained blend membranes. In the investigated range of PE-b-PEG content, the PEG blocks could not aggregate into obviously separated domains in membrane matrix. More importantly, PE-b-PEG could not only be retained stably in the membrane matrix during membrane formation, but also enrich at the membrane surface layer. Such stability and surface enrichment of PE-b-PEG endowed the blend membranes with improved hydrophilicity, protein absorption resistance and water permeation properties, which would be substantially beneficial to HDPE membranes for water treatment application.展开更多
To improve the performances of HDPE-based separators, polyether chains were incorporated into HDPE membranes by blending with poly（ethylene-block-ethylene glycol） （PE-b-PEG） via thermally induced phase separation ...To improve the performances of HDPE-based separators, polyether chains were incorporated into HDPE membranes by blending with poly（ethylene-block-ethylene glycol） （PE-b-PEG） via thermally induced phase separation （TIPS） process. By measuring the composition, morphology, crystallinity, ion conductivity, etc, the influence of PE-b-PEG on structures and properties of the blend separator were investigated. It was found that the incorporated PEG chains yielded higher surface energy for HDPE separator and improved affinity to liquid electrolyte. Thus, the stability of liquid electrolyte trapped in separator was increased while the interfacial resistance between separator and electrode was reduced effectively. The ionic conductivity of liquid electrolyte soaked separator could reach 1.28 ×10^-3 S.cm^-1 at 25℃, and the electrochemical stability window was up to 4.5 V （versus Li^＋/Li）. These results revealed that blending PE-b-PEG into porous HDPE membranes could efficiently improve the performances of PE separators for lithium batteries.展开更多
以聚乙二醇单甲醚、丁二酸酐、4-氨基苯乙酮、5-乙酰基-2-氨基二苯甲酮为原料合成了以聚苯基喹啉(PPQ)为硬段、聚乙二醇(PEG)为软段的"刚棒—线团"两嵌段共聚物PPQ b PEG,通过IR、1HNMR对其结构进行了表征,并对PPQ b PEG嵌段...以聚乙二醇单甲醚、丁二酸酐、4-氨基苯乙酮、5-乙酰基-2-氨基二苯甲酮为原料合成了以聚苯基喹啉(PPQ)为硬段、聚乙二醇(PEG)为软段的"刚棒—线团"两嵌段共聚物PPQ b PEG,通过IR、1HNMR对其结构进行了表征,并对PPQ b PEG嵌段共聚物的热稳定性进行研究,结果表明:PPQ b PEG(d)的热稳定性高,PPQ b PEG起始的分解温度为250℃,在250～400℃失重很少,其失重率小于5%,在400～600℃才迅速失重,到620℃时彻底分解。展开更多
基金supported by the 863 program(No.2006AA03Z233)973 program(No.2009CB623402) of China
文摘High density polyethylene （HDPE）/polyethylene-block-poly（ethylene glycol） （PE-b-PEG） blend porous membranes were prepared via thermally induced phase separation （TIPS） process using diphenyl ether （DPE） as diluent. The phase diagrams of HDPE/PE-b-PEG/DPE systems were determined by optical microscopy and differential scanning calorimetry （DSC）. By varying the content of PE-b-PEG, the effects of PE-b-PEG copolymer on morphology and crystalline structure of membranes were studied by scanning electron microscopy （SEM） and wide angle X-ray diffraction （WAXD）. The chemical compositions of whole membranes and surface layers were characterized by elementary analysis, Fourier transform infrared spectroscopy-attenuated total reflection （FTIR-ATR） and X-ray photoelectron spectroscopy （XPS）. Water contact angle, static protein adsorption and water flux experiments were used to evaluate the hydrophilicity, antifouling and water permeation properties of the membranes. It was found that the addition of PE-b-PEG increased the pore size of the obtained blend membranes. In the investigated range of PE-b-PEG content, the PEG blocks could not aggregate into obviously separated domains in membrane matrix. More importantly, PE-b-PEG could not only be retained stably in the membrane matrix during membrane formation, but also enrich at the membrane surface layer. Such stability and surface enrichment of PE-b-PEG endowed the blend membranes with improved hydrophilicity, protein absorption resistance and water permeation properties, which would be substantially beneficial to HDPE membranes for water treatment application.
基金financially supported by the National Natural Science Foundation of China (Nos. 20974094, U1134002)
文摘To improve the performances of HDPE-based separators, polyether chains were incorporated into HDPE membranes by blending with poly（ethylene-block-ethylene glycol） （PE-b-PEG） via thermally induced phase separation （TIPS） process. By measuring the composition, morphology, crystallinity, ion conductivity, etc, the influence of PE-b-PEG on structures and properties of the blend separator were investigated. It was found that the incorporated PEG chains yielded higher surface energy for HDPE separator and improved affinity to liquid electrolyte. Thus, the stability of liquid electrolyte trapped in separator was increased while the interfacial resistance between separator and electrode was reduced effectively. The ionic conductivity of liquid electrolyte soaked separator could reach 1.28 ×10^-3 S.cm^-1 at 25℃, and the electrochemical stability window was up to 4.5 V （versus Li^＋/Li）. These results revealed that blending PE-b-PEG into porous HDPE membranes could efficiently improve the performances of PE separators for lithium batteries.
文摘以聚乙二醇单甲醚、丁二酸酐、4-氨基苯乙酮、5-乙酰基-2-氨基二苯甲酮为原料合成了以聚苯基喹啉(PPQ)为硬段、聚乙二醇(PEG)为软段的"刚棒—线团"两嵌段共聚物PPQ b PEG,通过IR、1HNMR对其结构进行了表征,并对PPQ b PEG嵌段共聚物的热稳定性进行研究,结果表明:PPQ b PEG(d)的热稳定性高,PPQ b PEG起始的分解温度为250℃,在250～400℃失重很少,其失重率小于5%,在400～600℃才迅速失重,到620℃时彻底分解。
