A method for calculation of ion distribution in reaction system forming hydroxide

A formula was proposed to calculate the distribution of metal ions quantitatively in chemical reaction system forming hydroxide where precipitation and complex are formed together. The effects of some factors on formation of precipitation and complex were investigated, and the corresponding precipitation rates of zinc, iron （III）, aluminum, copper and magnesium were calculated. As a result, it shows that the proposed formula is reliable. By the proposed formula, the existence state of metal ions in hydroxides reaction system with any metal ions can be well described and the effects of some factors on the distribution of metal ions were determined.

Bioaccumulation,subcellular distribution and chemical forms of cadmium in Aster subulatus Michx.

【Objective】Through analyzing the bioaccumulation capacity,subcellular distribution and chemical forms of cadmium(Cd)in Aster subulatus Michx.,this study was to provide reference for revealing the Cd tolerance mechanism of A.subulatus Michx.【Method】After cultured for 24 d under the action of Hoagland nutrient solution and gradient Cd concentrations(0,30,60 and 90 mg/L),A.subulatus Michx.were harvested,and its leaf,stem and root were treated by differential centrifugation,chemical reagent extraction,and digested with graphite digester,respectively,then the Cd content in the root,stem and leaf were determined by atomic absorption spectroscopy.【Result】The experimental results indicated that the bioaccumulation capacity of Cd in A.subulatus Michx.was root>stem>leaf,and the maximum Cd concentration in the root,stem and leaf of A.subulatus Michx.were 130.74,78.69 and 56.62 mg/kg(fresh matter),respectively.Most of Cd stored in the cell wall and the soluble fractions of the root and leaf of A.subulatus Michx.,with only a smaller portion Cd in organelle fraction.Analysis result of subcellular Cd content showed that 52.27%-58.61%of Cd for root was mainly stored in the soluble fraction,but 42.10%-63.28%of Cd for leaf was mainly stored in the cell wall fraction.The concentration of pectates and protein integrated-Cd was higher in the root and leaf compared to other chemical forms Cd.Pectates and protein integrated-Cd was the main chemical forms Cd in the root and leaf of A.subulatus Michx.,and their percentages were 68.91%-74.80%and 57.38%-83.80%,respectively.Cd treatment could significantly increase the proportion of water-soluble organic acid Cd from 13.64%to 22.72%in root and undissolved phosphate Cd from 10.02%to 32.78%in leaf with increasing Cd concentration in the culture medium.【Conclusion】The root,stem and leaf of A.subulatus Michx.has strong bioaccumulation capacity to Cd,Cd is primarily stored in the soluble fractions of the root and cell wall fractions of the leaf,and less toxic pectates and protein integrated-Cd is the main chemical forms Cd in the root and leaf of A.subulatus Michx.,this might be the main mechanism of Cd tolerance in A.subulatus Michx.

Thickness distribution of multi-stage incremental forming with different forming stages and angle intervals

Although multi-stage incremental sheet forming has always been adopted instead of single-stage forming to form parts with a steep wall angle or to achieve a high forming performance, it is largely dependent on empirical designs. In order to research multi-stage forming further, the effect of forming stages(n) and angle interval between the two adjacent stages(Δα) on thickness distribution was investigated. Firstly, a finite element method(FEM) model of multi-stage incremental forming was established and experimentally verified. Then, based on the proposed simulation model, different strategies were adopted to form a frustum of cone with wall angle of 30° to research the thickness distribution of multi-pass forming. It is proved that the minimum thickness increases largely and the variance of sheet thickness decreases significantly as the value of n grows. Further, with the increase of Δα, the minimum thickness increases initially and then decreases, and the optimal thickness distribution is achieved with Δα of 10°.Additionally, a formula is deduced to estimate the sheet thickness after multi-stage forming and proved to be effective. And the simulation results fit well with the experimental results.

Temporal-spatial distribution and ore-forming material source of gold,copper and silver polymetallic ore deposits in the Fuping mantle structure zone

This study was conducted following research on metallogenesis in the Zhangjiajie-Xuanhua and East Hebei mantle branch structure zones. The Fuping mantle branch structure zone is one where Au, Cu and Ag poly-metallic ore resources are concentrated in North Hebei. However, there has existed a long-standing controversy on the temporal-spatial distribution of ore resources and their ore-forming material sources. In terms of age dating and the comprehensive analysis of S, Pb, O, C and Si isotopes, it is considered that the temporal-spatial distribution of ore resources in this mantle branch structure zone is obviously controlled by the Fuping mantle branch structure. In space there is developed such a metallogenic pattern as to be Ag, Pb and Zn polymetallic ore deposits with gold appearing inside and copper appearing outside. Metallogenesis is dated mainly at Yanshanian, the ore-forming materials were derived predominantly from the deep interior of the Earth, and ore-forming fluids were derived largely from Yanshanian magmatism.

Influence of viscous medium temperature distribution on sheet fracture in viscous pressure forming at warm temperature

Viscous pressure forming(VPF) of aluminum alloy AA3003 sheet metal at warm temperature was investigated by using coupled thermo-elastoplastic-viscoplastic finite element method. The influence of viscous medium temperature distribution on sheet fracture location was studied and the distributions of fracture factor at different temperatures were obtained by using ductile fracture criterion. The results show that the failure of sheet metal varies with increasing initial temperature of viscous medium. When the initial temperature of viscous medium is near that of sheet metal,the failure location occurs at dome center,and when the initial temperature of viscous medium is too low,however,the failure location occurs at die corner. The occurrence of fracture can be postponed and even prevented through controlling the temperature distribution in viscous medium.

Study of Magnetic Force Distribution for Electromagnetic V-shape Bending Forming of Small Size Flat Sheet

Electromagnetic V-shape bending of small size sheet blank is investigated numerically and experimentally. Three-dimensional electromagnetic field models are established to calculate the magnetic force distribution on the sheet by software ANSYS / EMAG. Series of electromagnetic V-shape bending forming experiments are presented,in which small size uniform pressure coil and big size round flat spiral coil are used. The results show that small size uniform pressure coil is not suitable for electromagnetic forming of small size flat sheet,and the coil is susceptible to failure such as bulging,ablation and cracking. When the plane dimension of round flat spiral coil is bigger than sheet blank sizes,the induced current crowding effect will be resulted which seriously influence the magnetic force distribution on the sheet. In this case,magnetic force distribution can be adjusted through the change of the relative position between coil and sheet,the desired deformation can be obtained finally. Therefore,big size round flat spiral coil can be well applied to electromagnetic V-shape bending forming of small size flat sheet.

Uptake, Subcellular Distribution, and Chemical Forms of Cadmium in Wild-Type and Mutant Rice

Wild-type （Zhonghua 11） and mutant rice （Oryza sativa L.） plants were used to investigate the effect of cadmium （Cd） application on biomass production, to characterize the influx of Cd from roots to shoots, and to determine the form, content, and subcellular distribution of Cd in the roots, leaf sheaths, and leaves of the rice plants. Seedlings were cultivated in a nutrient solution and were treated with 0.5 mmol L^-1 of Cd^2＋ for 14 d. The sensitivity of rice plants to Cd toxicity was tested by studying the changes in biomass production and by observing the onset of toxicity symptoms in the plants. Both the wild-type and mutant rice plants developed symptoms of Cd stress. In addition, Cd application significantly （P ≤ 0.01） decreased dry matter production of roots, leaf sheaths, and leaves of both types, especially the mutant. The Cd content in roots of the mutant was significantly （P ≤0.05） higher than that of the wild-type rice. However, there was no significant difference in the Cd content of roots, leaf sheaths, and leaves between the wild-type and mutant rice. Most of the Cd was bound to the cell wall of the roots, leaf sheaths, and leaves, and the mutant had greater Cd content in cell organelles than the wild type. The uneven subcellular distribution could be responsible for the Cd sensitivity of the mutant rice. Furthermore, different chemical forms of Cd were found to occur in the roots, leaf sheaths, and leaves of both types of rice plants. Ethanol-, water-, and NaCl-extractable Cd had greater toxicity than the other forms of Cd and induced stunted growth and chlorosis in the plants. The high Cd content of the toxic forms of Cd in the cell organelles could seriously damage the cells and the metabolic processes in mutant rice plants.

Calcium Forms, Subcelluar Distribution and Ultrastructure of Pulp Cells as Influenced by Calcium Deficiency in Apple (Malus pumila) Fruits

Calcium in Red Fuji and Starkrimson apples during storage were fractionated by sequentextracting. Localization and distribution of calcium and influence of calcium nutritionon cell ultrastructure were observed by transmission electron microscopy combined within situ precipitation of calcium with an improved method of potassium pyroantimonatetechnique. Results indicated that spraying calcium solution on surface of young fruitsincreased contents of calcium in all forms. During storage, contents of soluble calciumand pectic calcium declined and those in calcium phosphate, calcium oxalate and calciumsilicate increased. Calcium contents of Red Fuji in all forms were higher than those ofStarkrimson, indicating that calcium accumulating capability of Red Fuji fruits precededthat of Starkrimson. Under transmission electron microscopy, calcium antimonite precipitates(CaAP) was mainly distributed in cell wall, tonoplast, nuclear membrane and nucleoplasm,much more CaAP deposited in vacuole. Calcium deficiency during storage leads to decreaseof CaAP in locations mentioned above, disappearance of compartmentation, and entrance ofCaAP to cytoplasm. Transformation from soluble calcium and pectic calcium to calciumphosphate, oxalate and damages of biomembranes structuraly and functionally resultedfrom calcium deficiency during storage were the crucial causation of physiologicaldisorder.

Forms of Rare Earth Elements in Soils: Ⅰ. Distribution

The distribution of rare earth element (REE) forms in soils is given in the present paper on the basis of sequential fractionation and determination of 34 representative surface soils collected from all parts of China.Results obtained show that the extraction rate of water soluble and exchangeable REE had the odd-even phenomenon and that of organically bound REE from La to Lu tended to reduce gradually with the increase of atomic number.The stability of Sc and the activity and enrichment of Tm in soils are proposed.Furthermore,the paper makes a preliminary discussion on the differences in the concentration distribution of various forms of individual REE in some soils.

How elevation and soil properties affect plant distribution patterns and species diversity in the Mediterranean mountain ecosystem of Al-Jabal Al- Akhdar, Libya

The objectives of this study were to assess distribution patterns of plant species richness,plant diversity and vegetation structure in relation to environmental factors along elevation gradient in Al-Jabal Al-Akhdar,Libya.For each species,its growth form,chorological affinities,degree of occurrence,endemism status and originality were provided.A total of 534 taxa were generated from 70 families of the flowering plants,and 3 of the non-flowering plants were identified.The native flora of the study area was counted for 80.2%of the total indigenous taxa(465).The hump-shaped pattern of plant species richness was obtained,with the highest species richness at the mid-elevations,and both ends of the gradient have the lowest.The annuals(300 species,56.2%)and non-succulent perennial herbs(165 species,30.9%)were the most dominant growth forms of the total species composition.Along the elevation gradient,Asteraceae,Fabaceae,Poaceae,Lamiaceae and Apiaceae were the dominant families with the highest numbers of species.This investigation recorded 31 endemic taxa,comprising 25 dicots and 6 monocots,primarily of Mediterranean origin,with most belonging to the Asteraceae and Lamiaceae families.Mediterranean chorotype was the dominant,whether pure(mono-),or combined with one(bi-and pluri-regional)or more(pluri-regional).Application of cluster analysis on the vegetation data yielded four cluster groups;each was linked to an elevation level.It emphasized the importance of establishing conservation strategies to minimize human disturbance and safeguard relic habitats of Juniperus phoenicea L.at its southern distribution limits in Africa,underlining the proactive management required for species preservation.The application of Redundancy Analysis revealed that Shannon diversity index(H'),pH and Fe were the determinant soil factor in the mid-elevation levels(L2 and L3)whereas altitude,fine sand,HCO3,OM,and soil contents of Na,SO4 and Cl for the extreme levels(L1 and L4).

Life form and geographical distribution of plants in Posthband region,Khonj,Fars Province,Iran

A study was conducted to identify plant species,diversity,life form and relevant species to Mediterranean climate,Irano-Torunian and Sahara-Sindian in Postband region（N 27°58＇4＂-28°2＇16＂,E 53°17＇34＂-53°22＇30＂）.In total,95 species belonging to 29 families and 69 genera of flora were surveyed and identified from December 2006 to June 2008.Composite and Gramineae were important families in terms of species frequency.According to Raunkiaer＇s system and using X^2 tests,the life-form spectrum showed that therophytes accounted for 47% of all species,and hemicryptophytes for 31%,phanerophytes for 12%,chamaeophyte for 7%,and cryptophytes for 3%.In geographical distribution,29% species with the most frequency belonged to Irano-Torunian region.Results show that therophytes were more than normal spectrum and phaneropytes were less than normal spectrum,which was in agreement with data obtained in arid climate.

Distribution of Chemical Forms for Co, Cr, Ni and V in Typical Soils of China

Co, Ni, Cr and V in 25 typical soils of China were fractionated into exchangeable, carbonate bound (calcareous soils), Mn oxide bound, organically bound, amorphous Fe oxide bound, crystalline Fe oxide bound and residual forms using a seven-step sequential extraction procedure, so as to study the distribution of chemical forms of these metals as well as the effects of soil properties on the distribution. The results showed that most of soil Co, Ni, Cr and V were present in residual forms, and the distribution ratio averaged 48.2% for Co, 53.0% for Ni, 81.5% for Cr and 68.7% for V. The speciation of heavy metals was greatly influenced by soil physico-chemical properties and the chemistry of elements. The results also indicated that the recovery of metal elements by the sequential extraction procedure was satisfactory, with the relative difference between the sum of seven forms and the total content in soils averaging 9.5% for Co, 12.8% for Ni, 6.6% for Cr and 7.2% for V.

Phosphorous Forms in Sediments and Their Distribution in the Yangtze Estuary and Coastal Areas

Based on analyses of surface and core sediments in the tidal flats of the Yangtze Estuary and coastal areas, the present study reveals phosphorous forms existing in sediments and their distributions. The results show that phosphorus in tidal flat sediments in the study area mainly consists of inorganic phosphorous forms, involving DP, Fe-P, Al-P, and Ca-P and organic phosphorous forms, in which Ca-P and OP are dominant compositions. This finding indicates that spatial distributions of various phosphorous forms are related to sedimentary environments in water and grain sizes of sediments, and are influenced by sewage discharges and effluents from aquacultivation in the coastal areas.

Analysis of the Stress Distribution Pattern of Anatomic and Non-Anatomic Tooth Forms on Maxillary and Mandibular Edentulous Ridges—A Photoelastic Study

Aim: To compare the type of stress distribution pattern occurring with anatomic and non-anatomic tooth forms beneath a complete denture in both maxillary and mandibular arch. Methodology: A photoelastic model of the edentulous maxillary and mandibular ridge was prepared meticulously to simulate the human mandible and maxilla. Two sets of acrylic teeth with anatomic and non-anatomic occlusal forms were used to fabricate upper and lower dentures. A vertical static load of 100 N was applied through the mandibular model to the maxillary model. After load application on the dentures the photoelastic model as well as the upper and lower complete dentures were sectioned in the midline. The sectioned photoelastic model was viewed through a polariscope to observe the fringe pattern indicating varying amounts of stress distribution. In this study, a two-dimensional photoelastic stress analysis technique was utilized. Results: Force per unit area was observed more in anatomic teeth than the non-anatomic counterpart. Hence anatomic tooth forms may increase the possibility of bone resorption rate over a period of time. However, in non-anatomic lower teeth, a decrease in value was observed from posterior to anterior region. Conclusion: Stress of greater magnitude was observed with cuspal teeth whereas non-anatomic (0°) showed slightly less magnitude of stress. Depending upon the clinical situation the clinician needs to choose the type of occlusal tooth forms for edentulous patients.

Exogenous Nitric Oxide Involved in Subcellular Distribution and Chemical Forms of Cu^(2+) Under Copper Stress in Tomato Seedlings

Nitric oxide（NO）,a bioactive signaling molecule,serves as an antioxidant and anti-stress agent under abiotic stress.A hydroponics experiment was conducted to investigate the effects of sodium nitroprusside（SNP）,a NO donor,on tomato seedlings exposed to 50 μmol L-1CuCl 2.The results show that copper is primarily stored in the soluble cell sap fraction in the roots,especially after treatment with Cu＋SNP treatment,which accounted for 66.2% of the total copper content.The copper concentration gradually decreased from the roots to the leaves.In the leaves,exogenous NO induces the storage of excess copper in the cell walls.Copper stress decreases the proportion of copper integrated with pectates and proteins,but exogenous NO remarkably reverses this trend.The alleviating effect of NO is blocked by hemoglobin.Thus,exogenous NO is likely involved in the regulation of the subcellular copper concentrations and its chemical forms under copper stress.Although exogenous NO inhibited the absorption and transport of excess copper to some extent,the copper accumulation in tomato seedlings significantly increased under copper stress.The use of exogenous NO to enhance copper tolerance in some plants is a promising method for copper remediation.

CHEMICAL CHARACTERISTICS OF AEROSOLS IN THE KUROSHIO AREA——II.CHEMICAL FORMS AND SIZE DISTRIBUTIONS OF TRACE METALS

Aerosol samples were collected with a Sierrer Model 235 cascade impactor in the marine atmosphere over the Kuroshio area in consecutive four seasons from 1987 to 1988. Na, G, Al, V, and water soluble and acid soluble Mn, Fe, Pb, Cu, V, Cd were determined by neutron activation analysis and atomic absorption spectrophotometry, respectively. Seawater source chemical species in the aerosols appeared in high content in large over 3.6um diameter particles, and crustal source vanadium appeared in 3.6um diameter particles, but pollution source vanadium appeared in less than 0.52um diameter particles. Trace metals in the aerosols mostly had the highest concentration of water soluble metals on fine particles, and acid soluble metals on large particles. The concentrations of trace metals in the aerosols were higher in autumn and winter, lower in spring and summer.

Distribution Characteristics and Accumulation Model for the Coal-formed Gas Generated from Permo-Carboniferous Coal Measures in Bohai Bay Basin, China: A Review

Coal-formed gas generated from the Permo-Carboniferous coal measures has become one of the most important targets for deep hydrocarbon exploration in the Bohai Bay Basin,offshore eastern China.However,the proven gas reserves from this source rock remain low to date,and the distribution characteristics and accumulation model for the coal-formed gas are not clear.Here we review the coal-formed gas deposits formed from the Permo-Carboniferous coal measures in the Bohai Bay Basin.The accumulations are scattered,and dominated by middle-small sized gas fields,of which the proven reserves ranging from 0.002 to 149.4×108 m3 with an average of 44.30×108 m3 and a mid-point of 8.16×108 m3.The commercially valuable gas fields are mainly found in the central and southern parts of the basin.Vertically,the coal-formed gas is accumulated at multiple stratigraphic levels from Paleogene to Archaeozoic,among which the Paleogene and PermoCarboniferous are the main reservoir strata.According to the transporting pathway,filling mechanism and the relationship between source rocks and reservoir,the coal-formed gas accumulation model can be defined into three types:"Upward migrated,fault transported gas"accumulation model,"Laterally migrated,sandbody transported gas"accumulation model,and"Downward migrated,sub-source,fracture transported gas"accumulation model.Source rock distribution,thermal evolution and hydrocarbon generation capacity are the fundamental controlling factors for the macro distribution and enrichment of the coal-formed gas.The fault activity and the configuration of fault and caprock control the vertical enrichment pattern.

Study on Distribution Characteristics and Occurrence Form of Soil Fluorine in Sorghum Base of Renhuai City

In order to find out the effects of soil fluorine on ecological environment and crop safety in the sorghum cultivation base of Renhuai City, Guizhou Province, the content and the occurrence forms of soil fluorine and its influencing factors of Maoba Town were investigated and studied. The results showed that the total fluorine content in the soil of the sorghum base ranged from 668.60 to 2 596.80 mg/kg, with an average of 1 483.25 mg/kg, which was 3.10 and 1.85 times of the national soil background value and the average value of the soil in endemic areas, respectively. The spatial distribution of fluorine in the soil of the study area was uneven, and the fluorine content was in the order of Anliang Village>Yangliu Village>Houba Village>Xiongfeng Village. The soil fluorine contents of various forms varied greatly, and the distribution law was as follows: residual state>water soluble state>organically bound state>exchangeable state>Fe/Mn-F state. The residual fluorine content was the highest, accounting for more than 99% of total fluorine content, while the sum of other four forms was less than 1%, with their respective proportions ranging from 0.10% to 0.30%. The content and proportion of available fluorine in water-soluble and exchangeable states were relatively low, which had limited influence on the surrounding water environment and crop safety. The physicochemical properties of soil, such as pH, organic matter, cation exchange capacity and clay particles had a certain influence on the occurrence forms of soil fluorine, thus changing the availability and migration of soil fluorine, which might endanger the ecological environment safety, food safety and human health.

Subcellular Distribution and Chemical Forms of Cadmium in the Medicine Food Homology Plant Platycodon grandiflorum(Jacq.)A.DC.

Although Platycodon grandiflorum(Jacq.)A.DC.is a renowned medicine food homology plant,reports of excessive cadmium(Cd)levels are common,which affects its safety for clinical use and food consumption.To enable its Cd levels to be regulated or reduced,it is necessary to first elucidate the mechanism of Cd uptake and accumulation in the plant,in addition to its detoxification mechanisms.This present study used inductively couple plasma-mass-spectrometry to analyze the subcellular distribution and chemical forms of Cd in different tissues of P.grandiflorum.The experimental results showed that Cd was mainly accumulated in the roots[predominantly in the cell wall(50.96%-61.42%)],and it was found primarily in hypomobile and hypotoxic forms.The proportion of Cd in the soluble fraction increased after Cd exposure,and the proportion of insoluble phosphate Cd and oxalate Cd increased in roots and leaves,with a higher increase in oxalate Cd.Therefore,it is likely that root retention mechanisms,cell wall deposition,vacuole sequestration,and the formation of low mobility and low toxicity forms are tolerance strategies for Cd detoxification used by P.grandiflorum.The results of this study provide a theoretical grounding for the study of Cd accumulation and detoxification mechanisms in P.grandiflorum,and they can be used as a reference for developing Cd limits and standards for other medicine food homology plants.

Modeling Regional and Local-scale Permafrost Distribution in Qinghai-Tibet Plateau Using Equivalent-elevation Method

This study proposes an equivalent-elevation method to evaluate the integrated effects of latitude and elevation on regional and local-scale permafrost distribution in the Qinghai-Tibet Plateau,and to model the general permafrost-distribution patterns in regional and local-scale area.It is found that the Gaussian curve―an empirical model describing the relation between variations of altitudinal permafrost lower limit (PLL) and latitude in the Northern Hemisphere―could be applied in regional-and local-scale areas in the Qinghai-Tibet Plateau in a latitude-sensitive interval of 30°-50°N.The curve was then used to evaluate the latitudinal effect on permafrost distribution through transforming the latitudinal effect into a kind of altitudinal difference of PLL.This study then calculated the local equivalent-elevation value by overlaying the altitudinal difference of PLL onto real elevation at a certain location.The equivalent-elevation method was verified in an experimental subwatershed of the Qinghai-Tibet Plateau.However,feasibility of the method should be further tested in order to extend for future studies.The use of equivalent-elevation values can build a platform for comparing the regional general permafrost distribution in the plateau,and for basing further evaluations of local factors' effects on regional permafrost distribution.