Detection of Bisphenol A (BPA) in Plastic Bottles Using Vertical Cultivation at Various Temperatures

Polycarbonate plastics containing bisphenol A (BPA) used to manufacture drinking water bottles. Kurdistan region in northern Iraq is a developed area with increased pollution from plastic bottles. Trace amounts of BPA have been detected in bottled water samples. The absorption of BPA was measured with HPLC using a vertical cultivation system with Bulbs of the Allium Cepa plant planted in these plastic bottles with monitored growth. Vertical cultivation was found to have a low level of BPA in the plant cells, making it a safe cultivation method under specific climate conditions. The mean concentration of BPA in vertical cultivation is 0.19 ug/ml (3.8 ng for a 20 uL injection), and the Limit of Quantification (LOQ) is 0.63 ug/ml (12.7 ng for 20 uL injection). While Scanning Electron Microscope (SEM) shows that the concentrations are relatively low in water samples stored at room temperature compared to those exposed to direct sunlight (40°C) and water bottle samples stored at (-4°C), The correlation coefficients were found to be good (0.9992). SEM is used for plastic bottle samples stored at different temperatures. The images identify compound decay and explore the morphology of BPA in manufactured plastic materials.

What We Can Do to Protect Our Environment

think we can do three things to protect our environment.First,wherever we can go,we must stop using plastic bags,boxes and bottles.Factories and shops should be required to use bags,boxes and bottles that instead of plastics.

单模-多模光纤产生系列Bottle beam

提出一种利用多模光纤的多模干涉效应在自由空间中获得多个局域空心光(Bottle beam)的新方法。单模-多模光纤结构是一段多模光纤无偏心地连接到一段单模光纤上,光由单模光纤传输到多模光纤激发产生一系列的LP0,n模,由于多模干涉效应在多模光纤中相互叠加,当入射到自由空间后形成了多个Bottle beam。文中对光束传输过程进行理论分析并利用Matlab进行仿真实验,结果表明在自由空间中可以获得系列Bottle beam。当多模光纤纤芯直径分别为45μm,60μm和90μm时所选择的光场段内的Bottle beam的尺寸大小基本相同(约400μm×20μm),而第一个空间暗域沿轴向两侧相对光强差值分别为0.62,0.41和0.11,可见当多模光纤的纤芯直径越大时所得到的Bottle beam暗域的轴向两侧光强越相近,因此也越有利于囚禁微粒。

素食狮子小泰克

俗话说,大千世界无奇不有。美国漫画家罗伯特·里普利（Robert Ripley,1890-1949）曾于20世纪二、三十年代在多家报纸开辟《信不信由你》（Believe It or Not!）专栏,收集天下奇闻轶事。吃素母狮小泰克便是他挖到的奇闻之一。

Preparation, Characterization and Catalytic Behavior of 12-Molybdophosphoric Acid Encapsulated in the Supercage of Cs^＋-exchanged Y Zeolite

In order to solve the serious leaching problem of supported heteropoly acid catalysts in polar reaction media, 12-molybdophosphoric acid encapsulated in the supercage of Cs^＋-exchanged Y zeolite was prepared by the ＂ship in the bottle＂ synthesis. The influence of ion-exchange conditions and the synthesis parameters on the encaosulation of PMo12 were investigated. The obtained solid sample was characterized by X-ray diffraction （XRD）, 31p magic angle spin nuclear magnetic resonance （MAS NMR） and Fourier Transform Infrared Spectroscopy （FT-IR）, and its catalytic activity in the esterification of acetic acid and n-butanol was tested. The ion-exchange time, concentration of aqueous Cs^＋ solution, pH value, and amount of Mo added in the synthesis mixture were revealed to influence the encapsulation very remarkably. Under the optimal conditions, 12-molybdophosphoric acid could be successfully encapsulated in the supercage of CsY zeolite, and the samples showed considerable catalytic activity and excellent reusability in the esterification reaction.

Lipase inhibitory activity of Lagenaria siceraria fruit as a strategy to treat obesity

Objective:To explore pancreatic lipase inhibitory activity under different extraction conditions in order to track the most potent extract.Methods:The methanolic extract and its fractions in solvents of increasing polarity,ether,chloroform,ethyl acetate,n-butanol and water,were made through cold maceration.Extracts in ethanol,ethyl acetate,acetone and chloroform were similarly prepared.Aqueous extract was prepared through hot decoction method.A reported method was used to determine lipase inhibitory activity of extracts and fractions over wide ranges of concentrations.Results:The extracts and fractions exhibited concentration dependent activity.The IC50(μg/mL)values of methanolic,ethanolic,chloroform,ethyl acetate,acetone,ethyl acetate(after washing with water)and aqueous decoction were 293.40,266.47,157.59,182.12,352.34,257.00,and 190.00,respectively.The activity of chloroform,ethyl acetate and aqueous extracts were close to that of the drug orlistat(IC50 146μg/mL).Out of the fractions of the methanolic extract,the chloroform fraction was most active(IC50 189.6μg/mL).The order of inhibitory activity of the fractions was as follows:chloroform>ether>n-butanolic>aqueous>ethyl acetate.The GC/MS analysis of the most active chloroform faction showed the presence of hexadecanoic acid,methyl hexadecanoate,isopropyl palmitate,methyl 9,12-octadecadienate,and methyl 9,12,15-octadecatrienoate.Conclusions:The study suggests that Lagenaria siceraria has potential to inhibit pancreatic lipase activity,suppressing lipid digestion and thereby diminishing entry of lipids into the body.Regular intake of aqueous decoction of the fruit may therefore be recommended for control of obesity.Fatty acids and their esters may play role as inhibitors of lipase.

基于Bottle的Python网络应用开发

Python语言在网络应用开发中占有重要的位置。Bottle是一个Python网络应用开发微框架。本文以一个简单日志系统为例,介绍了运用Bottle开发网络应用基本方法。

Suppressing secondary reactions of coal pyrolysis by reducing pressure and mounting internals in fixed-bed reactor

Pyrolysis of Shenmu coal was performed in fixed-bed reactors indirectly heated by reducing operating pressure and mounting internals in the reactor to explore their synergetic effects on coal pyrolysis. Mounting internals particularly designed greatly improved the heat transfer inside coal bed and raised the yield of tar production.Reducing pressure further facilitated the production of tar through its suppression of secondary reactions occurring in the reactor. The absolute increase in tar yield reached 3.33 wt% in comparison with the pyrolysis in the reactor without internals under atmospheric pressure. The obtained tar yield in the reactor with internals under reduced pressure was even higher than the yield of Gray–King assay. Through experiments in a laboratory fixed bed reactor, it was also clarified that the effect of reducing pressure is related to volatile release rate in pyrolysis. It did not obviously vary tar yield at pyrolysis temperatures below 600 ℃, while the effect was evident at 650 and 700 ℃ but became limited again above 800 ℃. Under reduced pressure the produced tar contained more aliphatics and phenols but less aromatics.

Heterosis, Combining Ability and Gene Action for Yield in Bottle Gourd

The experiment was conducted at the experimental field of Olericulture Division, Horticulture Research Centre (HRC), Bangladesh Agricultural Research Institute (BARI), Gazipur, Bangladesh during the winter season of 2018-2019 to study the genetic architecture of yield in a seven parent half diallel cross of bottle gourd. The values of mean square for GCA (general combining ability) and SCA (specific combining ability) were highly significant which suggested the presence of both additive and non-additive genetic variance in the population. But the higher magnitude of GCA compared to SCA indicated predominance of additive genetic variance. In most of the cases, the cross between poor and poor parents showed positive SCA effect for fruit yield, which indicated the higher yield. The estimates of significant positive better parent heterosis ranged from 6.27 to 49.72 percent. Analysis of genetic components of variation suggested that additive components were more important in the inheritance of fruit yield. This character was observed being controlled by two to three pairs of genes or groups of genes. Narrow sense heritability was 23 percent indicating probability of selection in generations. The graphical analysis also indicated wide genetic diversity among the parents.

The Adsorption of Pb(II)Using Silica Gel Synthesized from Chemical Bottle Waste:Optimization Using Box-Behnken Design

The adsorption of Pb(II)on silica gel synthesized from chemical glass bottle waste has been studied.The effect of independent variables(adsorbent dose,initial concentration of Pb(II),contact time,and pH)on the Pb(II)removal from water was evaluated and optimized using the Response Surface Methodology(RSM).Under optimized conditions(adsorbent dose:20 mg;contact time:30 min;initial Pb(II)concentration:120 mg.L^(−1);and pH:8),the removal of Pb(II)was 99.77%.The adsorption equilibrium data obtained from the batch experiment were investigated using different isotherm models.The Langmuir isotherm model fits the experimental data.This shows that the surface of the silica gel synthesized from chemical bottles waste was covered by a Pb(II)monolayer.XRF analysis showed that the synthesized silica gel had a SiO_(2) content of 75.63%.Amorphous silica was observed from XRD analysis.SEM-EDX characterization showed that Pb was adsorbed on the silica gel surface.SEM analysis showed that silica gel has irregular particles with a surface area of 297.08 m2.g^(−1) with a pore radius of 15.74 nm calculated from BET analysis.

Silica Gel from Chemical Glass Bottle Waste as Adsorbent for Methylene Blue:Optimization Using BBD

This research focuses on the effective removal of methylene blue dye using silica gel synthesized from chemical glass bottle waste as an environmentally friendly and cost-effective adsorbent.The adsorption process was optimized using Box-Behnken Design(BBD)and Response Surface Methodology(RSM)to investigate the influence of pH(6;8 and 10),contact time(15;30 and 45 min),adsorbent mass(30;50 and 70 mg),and initial concentration(20;50 and 80 mg/L)of the adsorbate on the adsorption efficiency.The BBD was conducted using Google Colaboratory software,which encompassed 27 experiments with randomly assigned combinations.The silica gel synthesized from chemical glass bottle was characterized by XRD,FTIR,SEM-EDX and TEM.The adsorption result was measured by spectrophotometer UV-Vis.The optimized conditions resulted in a remarkable methylene blue removal efficiency of 99.41%.Characterization of the silica gel demonstrated amorphous morphology and prominent absorption bands characteristic of silica.The Langmuir isotherm model best described the adsorption behavior,revealing chemisorption with a monolayer coverage of methylene blue on the adsorbent surface,and a maximum adsorption capacity of 82.02 mg/g.Additionally,the pseudo-second-order kinetics model indicated a chemisorption mechanism during the adsorption process.The findings highlight the potential of silica gel from chemical glass bottle waste as a promising adsorbent for wastewater treatment,offering economic and environmental benefits.Further investigations can explore its scalability,regenerability,and reusability for industrial-scale applications.

Water and Energy Footprint Assessment of Bottled Water Industries in India

Assessment of water and energy footprint for eight bottled water industries was carried out. The investigation showed that one litre of bottled water has a water footprint of 17.41 litres and energy footprint of 7.08 MJ. Water consumption by the industry comprises 61% during material production, 17% in processes, 16% in energy and only 6% in the actual product. Hence, maximum consumption of water is in material production, while the processes required a smaller fraction of the total water and energy consumed. Therefore, water footprint can be reduced through optimization of water consumption in material production.

News about Tap and Bottled Water: Can This Influence People’s Choices?

The pursuit of alternative safe water has increased dramatically the world trade in bottled water. Events happened in Canada which changed the population’s perception about the quality of tap water, despite all government efforts. Media has an important role to pass on information because there is value judgment in its reports. As a result, this study aims to present recent data from two Canadian newspapers of national circulation, which refer to tap water and bottled water. It used quantitative and qualitative data for this analysis. The study concludes that the media, taken into consideration, provides its readers with important information, but the information can also be ambiguous. Nevertheless, it arouses interest in further research about this subject matter and about protecting water resources.

Classification of Various Bottled Mineral Waters Marketed in Djibouti

In this study, nineteen different brands of bottled mineral waters (7 brands local and 12 brands imported) were collected from supermarkets and independent food stores throughout Djibouti. The chemical composition mentioned on the labels of the nineteen bottled mineral waters has made the subject of a first verification by Ionic Balance Error (IBE). It was found out of the nineteen brands selected, 12 brands (2 brands local and 10 brands imported) had acceptable charge balance error. Correlation Analysis (CA), Principal Component Analysis (PCA) and Hierarchical Cluster Analysis (HCA) were used to analyze the data collected from the labels of bottled water. The obtained results showed that the 12 brands of studied waters can be grouped in 4 distinct classes with similar chemical characteristics. Two local and one imported brands have the same chemical composition but marketed under different names. It was observed that the chemical content local water brands were within the normal range prescribed by both WHO and USEPA except five imported water brands that have concentration values Ca, HCO3, Mg and SO4 beyond acceptable standards. Total hardness values classified most of the studied brands from moderate to very hard water.

Bottle gourd(Lagenaria siceraria) juice poisoning

BACKGROUND: Bottle gourd(Lagenaria siceraria) is popularly known as lauki, ghia or dudhi in India. Its consumption is advocated by traditional medicine healers for controlling diabetes mellitus, hypertension, liver diseases, weight loss and other diseases. However, in last few years there have been reports of suspected toxicity due to consumption of its juice leading to severe vomiting and upper gastrointestinal bleeding. As emergency physicians we need to be aware of this very rare poisoning specially in India.METHODS: We present a case of a 52-year-old woman who presented with multiple episodes of hematemesis and shock to the emergency department(ED) after consuming bottle gourd juice. The patient was resuscitated and stabilized with fl uids, proton pump inhibitors and antiemetics and shifted to the intensive care unit(ICU) under the care of a gastroenterology team for urgent endoscopy and further management.RESULTS: The patient received intravenous fluids, antibiotics, antiemetics, and antacids and underwent upper gastroenterologic endoscopy during the hospitalization. She was discharged in a stable condition 4 days later.CONCLUSIONS: As a member of the Cucurbitaceae family, bottle gourd contains toxic tetracyclic triterpenoid compounds called cucurbitacins which are responsible for the bitter taste and toxicity. There is no known antidote for this toxicity, and clinicians treat such patients symptomatically only. It is important to educate the public about the harmful effects of this potentially life-threatening toxicity.

Exploiting Virtual Elasticity of Production Systems for Respecting OTD-Part 1: Post-Optimality Conditions for Ergodic Order Arrivals in Fixed Capacity Regimes

Respecting the on-time-delivery (OTD) for manufacturing orders is mandatory. This depends, however, on the probability distribution of incoming order rate. The case of non-equal distribution, such as aggregated arrivals, may compromise the observance of on-time supplies for some orders. The purpose of this paper is to evaluate the conditions of post-optimality for stochastic order rate governed production systems in order to observe OTD. Instead of a heuristic or a simulative exploration, a Cartesian-based approach is applied to developing the necessary and sufficient mathematical condition to solve the problem statement. The research result demonstrates that increasing speed of throughput reveals a latent capacity, which allows arrival orders above capacity limits to be backlog-buffered and rescheduled for OTD, exploiting the virtual manufacturing elasticity inherent to all production systems to increase OTD reliability of non JIT-based production systems.

SIMULATION OF EXTRA LIGHT-THIN COMPONENT DEFORMATION WITH ABNORMAL SHAPE

Based on the analyses of the structural feature and the function requirements of newstyle bottle cap, the two fundamental components, the lining washer and the outer body, are abstracted as a plate and a cylinder with thin wall respectively. For simulating the deformation of the lining washer under equiaxial pressure, the modified Lagrangian finite element analysis is applied on the 228 triangular elements. Under assembly pressure, the plastoelastic deformation of both the lining washer and the outer body are studied in terms of Tresca＇s yield criterion and the limitation of the plastic deformation is presented when the two components are assembled into one unit. For the production of this kind of bottle cover, experiments are carried out by carefully measuring the changes of the diameter of lining washer as well as that of the outer body. It is shown that results from the experiments have a good agreement with the theoretical calculation and the maximum value of the allowable pressure has successfully been used in the design of newly developed bottle cap production system.

Experimental Evidence of Capillary Interruption of a Liquid Jet

We observe the gravity discharge of liquid through the short cylindrical tube of diameter of 2 mm and aspect ratio 2.5 and 10 attached to the underside of Mariotte bottle. When the hydrostatic head is reduced and approaches to a certain value, a laminar jet escaped from the nozzle is interrupted and the discharge is drop wise. The plot of the discharge rate as a function of hydrostatic head does not pass through the origin as predicted by Torricelli law for an ideal liquid. We attribute this feature to the energy losses related with creating a new free surface area of the jet. The measurements for water and aqueous ethanol solution are compared with theoretical predictions based on the modified Bernoulli equation with the interfacial energy density correction and good agreement is observed.

Decision Making in Sustainable Development: Some Methods to Evaluate Energy and Nonrenewable Resources Waste When Using Some Plastics

This paper explores a decision making model for a multidisciplinary problem in nature. This problem considers the role of energy use in sustainable development and the potential sources to increase energy efficiency during its whole life cycle;it also deals with multicriteria decision making of plastic materials used in a day to day basis. Exergy analysis of plastic materials used to the manufacture of disposable polyethylene bags comparing them with other materials that can be used for substitution will be important to take decisions. We are also interested in plastic poly (ethylene Terephthalate or PET) bottles. The calculation of the incoming and outgoing Exergy flows during the production processes are carried out. The Exergy loss considering the sustainability concept, Green House Gases emissions, real energy flows needed to the chain of processes, material balances in the productions chains and value added, are presented as a set of criteria to make decisions of alternative materials including the actual ones. A case study for Mexico’s market will be developed in order to prove the methodology. It offers some interesting data about consumption and production of bags and bottles.

Study of the efficacy of a Wheaton coated bottle with permethrin and deltamethrin in laboratory conditions and a WHO impregnated paper with bendiocarb in field conditions

Objective:To determine the efficacy of WHO impregnated paper and CDC coated bottle based on number of storage days and number of limes of consecutive use,in the assessment of insecticide vector susceptibility tests in laboratory and field conditions.Methods:Larvae and pupae of Anopheles gambiae s.l.mosquitoes were collected from the breeding sites in Seme-Kpodji and Cotonou districts in Southern Benin in April 2013 during the first rainy season.Anopheles gambiae s.l.mosquitoes were also collected from the breeding sites in Parakou district in Northern Benin in May 2013 at the beginning of the rainy season.Susceptibility tests were done using impregnated paper with bendiocarb(0.1%)following WHO protocol and stock solutions of permethrin(21.5 ug per bottle)and deltamethrin(12.5 ug per bottle)following CDC protocol on unfed female mosquitoes aged 2-5 days old.These bioassays were repeated a certain number of times.The temperature and relative humidity were monitored and recorded during the susceptibility tests.Results:This study showed that a WHO impregnated paper with bendiocarb could be used four times during four consecutive days in field conditions.Regarding a Wheaton coated bottle with permethrin or deltamethrin,they could be used at least three limes during four consecutive days in laboratory conditions.Conclusions:The day storage and the number of times that a WHO impregnated paper and a CDC coated bottle maintained their efficacy are useful in the assessment of insecticide vectors susceptibility tests.