Numerical Investigation on the Deformation of the Free Interface During Water Entry and Exit of a Circular Cylinder by Using the Immersed Boundary-Multiphase Lattice Boltzmann Flux Solver

In this work,the deformation of free interface during water entry and exit of a circular cylinder is investigated numerically by using the two-dimensional(2D)immersed boundary-multiphase lattice Boltzmann flux solver(IB-MLBFS).The fluid domain is discretized by finite volume discretization,and the flux on the grid interface is evaluated by lattice Boltzmann equations.Both the implicit velocity correction and the surface flux correction are implemented by using the immersed boundary-method to consider the fluid-structure interaction and the contact interface between the multiphase fluids and the structure.First,the water entry of a circular cylinder is simulated and the results are compared with the experiment,which considered the length-diameter ratio of the circular cylinder.The reliability of 2D simulation is verified and the deformation of the free interface is well investigated.Afterward,the water exit of a circular cylinder with constant velocity is simulated,which is less researched.In addition,the results show the advantage of present IB-MLBFS to some extent.Finally,the water exit and re-entry of a circular cylinder are presented,and the results present the complex deformation of the free interface and the dynamic response of the moving structure.Based on the numerical results,the free interface of the multiphase fluids is well captured,and the contact interface on the boundary of the moving structure is accurately presented by the IB-MLBFS.

Recrystallization of freezable bound water in aqueous solutions of medium concentrations

For aqueous solutions with freezable bound water, vitrification and recrystallization are mingled, which brings difficulty to application and misleads the interpretation of relevant experiments. Here, we report a quantification scheme for the freezable bound water based on the water-content dependence of glass transition temperature, by which also the concentration range for the solutions that may undergo recrystallization finds a clear definition. Furthermore, we find that depending on the amount of the freezable bound water, different temperature protocols should be devised to achieve a complete recrystallization. Our results may be helpful for understanding the dynamics of supercooled aqueous solutions and for improving their manipulation in various industries.

Identification of Free OH and its Implication on Structural Changes of Liquid Water

The molecular structure of liquid water has been an outstanding issue for many years. The identification of free -OH holds the key in differentiating structure models for liquid water. By analyzing the relative changes of the intensity and depolarization ratio in temperature dependent Raman spectra, the occurrence of free -OH in liquid water is unambiguously de- termined. Furthermore, upon the increase of temperature from 5 ~C to 85 ~C, the structure of liquid water undergoes significant change, but the relative proportion of free -OH is con- siderably small and remains almost unchanged. This implies that the breaking of hydrogen bond from the tetrahedral structure prefers to The energetic favoring of the structural change experiments. occur at the site of the hydrogen acceptor. for liquid water is thus clearly revealed from

The Influence of Free Water Content on Dielectric Properties of Alkali Active Slag Cement Paste

The dielectric performance of alkali activated slag （AAS） cement paste was investigated in the frequency range of 1 to 1000 MHz. The experimental results showed the unstable dielectric properties of harden paste were mostly influenced by the fraction of free water in paste or absorbed water from ambient, but not including hydration water and microstructure. The free water was completely eliminated by heat treatment at 105 ℃ about 4 hours, and then its dielectric loss was depressed; but with the exposure time in air increasing, the free water adsorption in ambient air made the dielectric property of harden cement paste to be bad. The temperature and relative humidity of environment was the key factors of free water adsorption; hence, if the influence of free water on dielectric constant was measured or eliminated, the cement-based materials may be applied in humidity sensitive materials or dielectric materials domains.

Experiment and Numerical Simulation of Free Water Jet by a Central-body Nozzle

The recent research about cavitation jet mainly focuses on the organ-pipe nozzle and triangular nozzle. The research content mainly includes the optimized design about the structure of nozzles, the observation and flow analysis about the cavitation jet in the water, and the theory of rock attacked by the cavitation jet, while the energy characteristic of the free jet is not studied yet. In China, the research about the central-body nozzle is almost empty. For the purpose of studying the energy characteristic and the structure of free water jet discharged from central-body nozzle, an experiment with phase Doppler particle anemometry（PDPA） technology is carried out to measure the free water jet flow, which is produced by a central-body nozzle under the jet pressure of 15 MPa. While five sections with different axial distances from the nozzle outlet are selected for data process and analysis, the axial and radial velocity and the droplets of the particle size are studied. Meanwhile, numerical calculation of corresponding flow field is conducted by using volume of fluid（VOF） multiphase model, and the jet flow feature is discussed. The experimental and calculating results show that the axial velocity of high speed jet flow dissipates slowly in the air, and the core area and diffused area are discovered. The diameter of droplet in the core area is small, and jet energy is concentrated, while in the diffusion area, water is mingled with ambient air and radial velocity is relatively large. Obvious low-pressure area exists behind the central body and potential cavitation may occur in that area. The proposed research reveals the energy characteristic of free jet discharged from central-body nozzle, provides the theoretical basis for preestimating erosion feature of the central-body nozzle and also the theoretical foundation for revealing the mechanism of erosion.

Numerical Simulation of the Water Entry of a Structure in Free Fall Motion

To solve the problems concerning water entry of a structure, the RANS equations and volume of fluid （VOF） method are used. Combining the user-defined function （UDF） procedure with dynamic grids, the water impact on a structure in free fall is simulated, and the velocity, displacement and the pressure distribution on the structure are investigated. The results of the numerical simulation were compared with the experimental data, and solidly consistent results have been achieved, which validates the numerical model. Therefore, this method can be used to study the water impact problems of a structure.

Effects of a Free Water Protocol on Inpatients in a Neuro-Rehabilitation Setting

Background: Dysphagia is common among stroke and acquired brain injury (ABI) patients and may result in aspiration. To reduce the risk of thin liquid aspiration, patients are often restricted to thickened fluids. There is considerable clinical interest in the risks and benefits of offering oral water intake, in the form of water protocols, to patients with thin-liquid dysphagia. Objectives: A controlled pilot study of a free water protocol was undertaken at Riverview Health Centre, in Winnipeg, Manitoba to assess benefits, feasibility and possible complications of free water protocol. Methods: The study examined 16 individuals with stroke or ABI who were randomly assigned to either a control group on thickened fluids (six subjects) or a treatment group (ten subjects) that followed a free water protocol. The average length of time in the study was 4.3 weeks with a range of 1 - 17 weeks among all participants. Results: Throughout the study, there was no incidence of pneumonia in any of the sixteen participants. No statistically significant difference was noted in the weekly total liquid intake between the treatment group and the control group. Perceived swallowing related care results suggest statistically significant improvements from initial to final measures for both the treatment group (p = 0.004) and the control group (p = 0.02). However, a comparison of the change in both measures, between the treatment and control groups, shows no statistically significant differences. Conclusion: This pilot study suggests the need for larger scale work in order to more accurately identify the effects of free water protocols.

THE FREE BENDING VIBRATION OF CYLINDRICAL TANK PARTIALLY FILLED WITH-LIQUID AND SUBMERGED IN WATER

This paper studies the free bending vibration of cylindrical tank partially filled with liquid and submerged in water. The depths of liquid and water may be completely arbitrary. The exact calculating formulae of mode shape functions and inherent frequencies are deduced. The results can be gained by means of computer. The analysis shows that the effect of liquid and water on vibration of cylindrical tank is respectively equivalent to a generalized distributive mass attached to the tank.

Development and applications of solids-free oil-in-water drilling fluids

The increasing application of near balanced drilling technology to low-pressure and depleted fractured reservoirs requires the use of low-density drilling fluids to avoid formation damage. Solidsfree oil-in-water （O/W） emulsion drilling fluid is one type of low-density drilling fluid suitable for depleted fractured reservoirs. In this paper, the solids-free O/W drilling fluid was developed and has been successfully used in the Bozhong 28-1 oil and gas field, by which lost circulation, a severe problem occurred previously when drilling into fractured reservoir beds, was controlled, thereby minimizing formation damage. The O/W emulsion drilling fluid was prepared by adding 20% （by volume） No. 5 mineral oil （with high flash point, as dispersed phase） into seawater （as continuous phase）. Surfactant HTO-1 （as a primary emulsifier） and non-ionic surfactant HTO-2 （as a secondary emulsifier） were added into the drilling fluid system to stabilize the emulsion; and YJD polymer was also added to seawater to improve the viscosity of the continuous phase （seawater）. The drilling fluid was characterized by high flash point, good thermal stability and high stability to crude oil contamination.

Detection of Cyanide in Pollution-free Livestock Product Breeding Water by Ion Chromatography

In order to verify the accuracy of ion chromatography for cyanide detection,optimization conditions were studied,and comparison was made for the detection results of cyanide between titration and isonicotinic acid pyrazolone spectrophotometry. The results showed that ion chromatography has good linearity and reproducibility,with the recovery rate of 95%-105% and the limit of detection of 0. 001 mg/L. This method is simple,rapid,safe,selective,and suitable for the determination of cyanide in pollution-free livestock product breeding water.

Using Double-Bounded Dichotomous-Choice to Estimate Households’ Willingness to Pay for Improved Water Quality in Bac Ninh Province of Vietnam

This study used double-bounded dichotomous-choice to estimate and analyze the factors affecting households’ willingness to pay (WTP) for water quality improvement. This study notes that households with higher income, living near a polluted water source, using tap water instead of natural water, who are handicraft producers, and who have more members, are willing to pay more. However, households who rarely hear about environmental pollution issues and who are offered a higher bid are more likely to refuse to pay. Solutions to improve water quality are suggested such as to raise people’s awareness through communication channels and social organizations;to increase income associated with environmental protection policies;to construct wastewater treatment plants;to encourage the relocation of production establishments to industrial parks and industrial complexes;to put regulations on collection, payment and sanctions in case of not declaring and paying fees into village conventions;to promulgate circulars, and bylaws to concretize and simplify regulations and policies of the Government and the Ministry of Natural Resources and Environment.

MHD Free Convective Flow of Water near 4℃ past a Vertical Moving Plate with Constant Suction

The aim of this work is the study of the magnetohydrodynamic (MHD) unsteady free convective flow of water near 4℃ past an infinitely vertical plate moving with constant velocity. The influence of constant uniform suction was also considered. The partial differential equations (PDEs) and their initial and boundary conditions, describing the problem under consideration, are dimensionalized and the numerical solution is obtained by using the finite volume discretization methodology which is suitable for Fluid Mechanics applications. The numerical results for the velocity and temperature fields are shown in figures for different dimensionless parameters entering in the problem under consideration, such as the magnetic parameter, M and the Grashof number, Gr. This study predicts the effects of a constant magnetic field and uniform suction on the free convective flow of water near 4℃, when the water is electrically conductive. Analysis of the results showed that the velocity and temperature profiles are noticeably influenced by these parameters.

Oblique Wave-free Potentials for Water Waves in Constant Finite Depth

In this paper, a method to construct oblique wave-free potentials in the linearised theory of water waves for water with uniform finite depth is presented in a systematic manner. The water has either a free surface or an ice-cover modelled as a thin elastic plate. For the case of free surface, the effect of surface tension may be neglected or taken into account. Here, the wave-free potentials are singular solutions of the modified Helmholtz equation, having singularity at a point in the fluid region and they satisfy the conditions at the upper surface and the bottom of water region and decay rapidly away from the point of singularity. These are useful in obtaining solutions to oblique water wave problems involving bodies with circular cross-sections such as long horizontal cylinders submerged or half-immersed in water of uniform fmite depth with a free surface or an ice-cover modelled as a floating elastic plate. Finally, the forms of the upper surface related to the wave-free potentials constructed here are depicted graphically in a number of figures to visualize the wave motion. The results for non-oblique wave-free potentials and the upper surface wave-free potentials are obtained. The wave-free potentials constructed here will be useful in the mathematical study of water wave problems involving infinitely long horizontal cylinders, either half-immersed or completely immersed in water.

Antimicrobial Resistant Coliforms in Tap Water with Low Free Residual Chlorine Levels in Two Hospitals: Case Study in Gaza, Palestine

Universal access to safe water, whether at households or health centres, is central to achieving the sixth sustainable development goal by 2030. A hospital-based survey was conducted to screen for antimicrobial resistance among coliforms in samples collected from tap water (n = 54) at surgical wards in Gaza and to investigate the association with free residual chlorine and pH levels. Total coliforms (TC) were detected in 48.1% (26/54) of tested samples and FCs were detected in 25.9% (14/54). Free residual chlorine test ranged from zero to 0.2 mg/l (average: 0.08 mg/l), of which more than half of the samples (53.7%) 29/54 showed no free residual chlorine. The mean value of free residual chlorine in samples tested positive for growth on m-Endo (0.03) was lower than the mean for negative samples (0.14). The pH values were within the acceptable range (average: 7.6) and there was a statistically significant variation between the mean of pH values for samples tested positive on m-Endo (7.29) and that tested negative (7.84). Among coliform positive samples, 23.1% (6/26) had coliform isolates with resistance patterns. More than two-thirds of antimicrobial resistant (AMR) isolates were resistant to amikacin, ceftazidime, ceftriaxone, and imipenem. Moreover, 50% of the isolates were resistant to piperacillin-tazobactam. One-third (33.3%) of isolates were resistant to cefoxitin, and fosfomycin, 16.7% were resistant to ciprofloxacin, and nitrofurantoin. Intermediate resistance was shown in 16.7% of the isolates to cefoxitin and ciprofloxacin. The ESBL and carbapenem resistance genes detected in isolates were TEM (66.7%), NDM (33.3%), OXA (25%), blaCTXM (16.7%), and blaCTXM-3 (16.7%). The finding highlighted the level of contamination with AMR coliform in samples collected from tap water and pointed out the importance of managing water safety through identifying the main source of contamination, in addition to maintaining proper water disinfection at healthcare facilities for the patient, staff and environmental safety.

Free proline accumulation in rice plants under different leaf water potential

Seedlings of drought-tolerance rice varieties Han 501and Han A03,and the drought sensitive varietiesNanjing 11 and Yanjing 2 were raised in a paddyfield and transplanted into pots at the age of 8leaves.Water stress started at the tillering stage byholding water from 0 MPa of the soil water potentialin pots till the leaves showed seriously wilting.

Calculation of the Heat Energy Needed for Melting of the Ice Formed from Bounded Water in the Wood

An engineering approach for the calculation of the specific heat energy needed for melting of the ice, which is created from the freezing of hygroscopically bounded water in the wood, qbw, has been suggested. The approach, together with the equation that presents it, includes mathematical descriptions of the density of frozen wood in the hygroscopic diapason, Pw, and of the specific heat capacity of the ice formed from the bounded water in the wood, cbw for the calculation of Pw, cbw and qbw according to the suggested approach a software program has been prepared in the calculation environment of Visual Fortran. Using the program computations have been carried out for the determination ofpw, cbw and qbw, of oak, pine, beech and poplar frozen wood with initial temperature in the range from -20℃ to -2℃, at which the thawing of the ice from the bounded water is completed, and with moisture content in the hygroscopic range during wood defrosting. Based on the obtained results, a very simple and easy for use equation for the calculation of qbw depending only on the wood moisture content and on the content of non-frozen water in the wood at given initial wood temperature has been suggested.

Modulating the properties of monolayer C2N:A promising metal-free photocatalyst for water splitting

Photocatalytic water splitting has gained increasing attention, since it utilizes renewable resources, such as water and solar energy, to produce hydrogen. Using the first-principles density functional theory, we investigate the properties of the single layer C_2N which was successfully synthesized. We reveal that monolayer C_2N has a substantial direct band gap of 2.45 eV. To regulate its band gap, four different nonmetal elements（B, O, P, and S） on the cation and anion sites are considered. Among them, B-doped N site is the most effective one, with the lowest formation energy and a band gap of 2.01 eV. P-doped N site is the next, with a band gap of 2.08 eV, though its formation energy is higher. The band alignments with respect to the water redox levels show that, for these two dopings, the thermodynamic criterion for the overall water splitting is satisfied. We therefore predict that B-or P-doped C_2N, with an appropriate band gap and an optimal band-edge position, would be a promising photocatalyst for visible-light water splitting.

A Study on the Structure and Behavior of Sinter-free Material for Phosphorous Removal from Waste Water

Oyster shell and cement were taken as the major raw materials to fabricate hollow, tubular and recoverable material for phosphorous removal （P removal） from waste water without sintering. In this paper, the effects of different affecting factors on the sample P removal ratio were discussed to select optimal P removal process conditions. SEM and XRD were used to characterize the microscopic structures and composition of samples, and molybdenum blue spectrophotometry was applied to determine the P content in waste water. Results showed that at 30 ℃ for 2 d, the P removal ratio reached 93.3% when the cement content was 10 wt% and oyster shell powder was 90 wt%. SEM analysis revealed a flaky structure consisting of phosphorus-containing compound in the samples after P removal, and it piled on and maintained the porous structure. In addition, the results also suggested that raising the ambient temperature was benefit to the P removal. The P removal ratio of the material was optimal under neutral and alkali conditions.

Quantitative evaluation of adsorbed and free water in deep shales:a case study on the Wufeng-Longmaxi Formations from the Luzhou area,southern Sichuan Basin,China

Deep shale gas reservoirs commonly contain connate water, which affects the enrichment and migration of shale gas and has attracted the attention of many scholars. It is significant to quantitatively estimate the amounts of adsorbed and free water in shale matrix pores, considering the different impacts of pore water (adsorbed water and free water) on shale gas. In this paper, pore water in six deep shale samples from the Wufeng-Longmaxi Formations in the Luzhou area, southern Sichuan Basin, China, was quantitatively evaluated by saturation-centrifugation experiments. Further, the impact of shale material composition and microstructure on the pore water occurrence was analyzed. The results show that amounts of adsorbed and free water are respectively 1.7967–9.8218 mg/g (mean 6.4501 mg/g) and 9.5511–19.802 mg/g (mean 13.9541 mg/g) under the experimental conditions (30℃, distilled water). The ratio of adsorbed water to total water is 15.83%–42.61% (mean 30.45%). The amounts of adsorbed and free water are related to the pore microstructure and material compositions of shale. The specific surface area of shale controls the amount of adsorbed water, and the pore volume controls the amount of free water;organic pores developed in shale solid asphalt contribute specific surface area and pore volume, and inorganic pores developed in clay mineral contribute pore volume. Therefore, the pores of shale solid asphalt accumulate the adsorbed water and free water, and the pores of clay minerals mainly accumulate the free water.

Formation and Water Stability of Aggregates in Red Soils as Affected by Organic Matter

The water stability of aggregates in various size classes separated from 18 samples of red soils under different managements, and the mechanisms responsible for the formation of water-stable soil aggregates were studied. The results showed that the water stability of soil aggregates declined with increasing size, especially for the low organic matter soils. Organic matter plays a key role in the formation of water-stable soil aggregates. The larger the soil aggregate size, the greater the impact of organic matter on the water stability of soil aggregates. Removal of organic matter markedly disintegrated the large water-stable aggregates (> 2.0 mm) and increased the small ones (< 0.25-0.smm) to some extent, whereas removal of free iron(aluminium) oxides considerably destroyed aggregates of all sizes, especially the < 0.25-0.5 mm classes. The contents of organic matter in water-stable aggregates increased with aggregate sizes. It is concluded from this study that small water-stable aggregates (< 0.25-0.5 mm) were chiefly cemented by Fe and Al oxides whilst the large ones (> 2.0 mm) were mainly glued up by organic matter. Both free oxides and organic matter contribute to the formation and water stability of aggregates in red soils.