Generating highly active oxide-phosphide heterostructure through interfacial engineering to break the energy scaling relation toward urea-assisted natural seawater electrolysis

Urea-assisted natural seawater electrolysis is an emerging technology that is effective for grid-scale carbon-neutral hydrogen mass production yet challenging.Circumventing scaling relations is an effective strategy to break through the bottleneck of natural seawater splitting.Herein,by DFT calculation,we demonstrated that the interface boundaries between Ni_(2)P and MoO_(2) play an essential role in the selfrelaxation of the Ni-O interfacial bond,effectively modulating a coordination number of intermediates to control independently their adsorption-free energy,thus circumventing the adsorption-energy scaling relation.Following this conceptual model,a well-defined 3D F-doped Ni_(2)P-MoO_(2) heterostructure microrod array was rationally designed via an interfacial engineering strategy toward urea-assisted natural seawater electrolysis.As a result,the F-Ni_(2)P-MoO_(2) exhibits eminently active and durable bifunctional catalysts for both HER and OER in acid,alkaline,and alkaline sea water-based electrolytes.By in-situ analysis,we found that a thin amorphous layer of NiOOH,which is evolved from the Ni_(2)P during anodic reaction,is real catalytic active sites for the OER and UOR processes.Remarkable,such electrode-assembled urea-assisted natural seawater electrolyzer requires low voltages of 1.29 and 1.75 V to drive 10 and600 mA cm^(-2)and demonstrates superior durability by operating continuously for 100 h at 100 mA cm^(-2),beyond commercial Pt/C||RuO_(2) and most previous reports.

Stress environment of entry driven along gob-side through numerical simulation incorporating the angle of break

Angle of break(AOB)is the acute angle created by the coal seam bedding plane and caving line formed by roof strata movement after extraction of a longwall panel.It has a significant influence on stress redistribution both in the gob and abutment.Throughout numerical simulation investigations up to now,little attention has been paid to it or an AOB of 90°was used,which however,is not realistic.This paper presents a detailed numerical modelling incorporating the AOB against Zhenchengdi Coal Mine.The AOB was obtained through cross-measure boreholes.Hoek-Brown constitutive model was used to simulate the rock masses.Double-yield constitutive model,which was best fitted by Salamon's model,was used to simulate the gob.The results show that a‘‘/\shape"shear failure zone develops around the gob.The shear failure in the floor along the panel edge is due to opposite shear of rock mass on two sides of the caving line,and the number of yielded zones within the gob floor close to the gob edge is smaller.According to the research,the entry was determined to be driven under the gob edge employing splitlevel longwall panel layout(SLPL).The other numerical simulation for SLPL shows that stress around the god-side entry is much smaller than pre-mining stress,and the area of intact rock mass at the elevating section is larger than conventional layout.Numerical modelling was then validated by field observation.

Energy dissipation through wind-generated breaking waves

Wave breaking is an important process that controls turbulence properties and fluxes of heat and mass in the upper oceanic layer.A model is described for energy dissipation per unit area at the ocean surface attributed to wind-generated breaking waves,in terms of ratio of energy dissipation to energy input,windgenerated wave spectrum,and wave growth rate.Also advanced is a vertical distribution model of turbulent kinetic energy,based on an exponential distribution method.The result shows that energy dissipation rate depends heavily on wind speed and sea state.Our results agree well with predictions of previous works.

Numerical Study of the Ice Breaking Resistance of the Icebreaker in the Yellow River Through Smoothed-Particle Hydrodynamics

A ship-ice-water interaction model is established using smoothed-particle hydrodynamics(SPH)to predict the ice breaking resistance of the icebreaker in the Yellow River effectively.This method includes the numerical process of the constitutive equation,yield criterion,and the coupling model in SPH.The ice breaking resistance is determined under different conditions.The numerical results of the ice breaking resistance agree with the empirical formula results.Results show that the prediction accuracy of ice resistance is less than 17.6%compared with the empirical formula in the level ice.The method can also be extended to predict the floe motion and ice breaking resistance in actual river channels.The validation against the empirical formula indicates that the proposed ship-ice-water SPH method can predict the ice breaking resistance of icebreakers in actual rivers effectively.The predicted ice breaking resistance is analyzed under different conditions.The ice breaking resistance increases with increasing bending strength and ice thickness,and the latter is the most important factor influencing ice resistance.

Effects of Break-through State and System Rigidity on Vibration and Noise in Blanking

This paper studies the effects of break through state and system rigidity on vibration and noise in blanking, suggests the describtion of the generation state of breakthrough by the unloading gradient obtained from the force stroke curve, discusses the effect of the relation between the unloading gradient and the vibration system rigidity on vibration, and gives the optimal relationship between these two factors to efficiently reduce the vibration, and this conclusion is verified by noise experiments done by using two presses of unequal rigidity to carry out the same blanking.

Investigation of hydroxyl-terminated polybutadiene propellant breaking characteristics and mechanism impacted by submerged cavitation water jet

A submerged cavitation water jet(SCWJ)is an effective method to recycle solid propellant from obsolete solid engines by the breaking method.Solid propellant's breaking modes and mechanical process under SCWJ impact are unclear.This study aims to understand those impact breaking mechanisms.The hydroxyl-terminated polybutadiene(HTPB)propellant was chosen as the research material,and a self-designed test system was used to conduct impact tests at four different working pressures.The high-speed camera characterized crack propagation,and the DIC method calculated strain change during the impact process.Besides,micro and macro fracture morphologies were characterized by scanning electron microscope(SEM)and computed tomography(CT)scanning.The results reveal that the compressive strain concentration region locates right below the nozzle,and the shear strain region distributes symmetrically with the jet axis,which increases to 4% at first 16th ms,the compressive strain rises to 2% and 6% in the axial and transverse direction,respectively.The two tensile cracks formed first at the compression strain concentrate region,and there generate many shear cracks around the tensile cracks,and those shear cracks that develop and aggregate cause the cracks to become wider and cut through the tensile cracks,forming the tensile-shear cracks and the impact parts eventually fail.The HTPB propellant forms a breaking hole shaped conical after impact 10 s.The mass loss increases by 17 times at maximum,with the working pressure increasing by three times.Meanwhile,the damage value of the breaking hole remaining on the surface increases by 7.8 times while 2.9 times in the depth of the breaking hole.The breaking efficiency is closely affected by working pressures.The failure modes of HTPB impacted by SCWJ are classified as tensile crack-dominated and tensile-shear crack-dominated damage mechanisms.

China’s toy makers explore growth breakthroughs

China’s toy makers are exploring new ways to break the bottlenecks of development as the ongoing European crisis continues to impact demand,according to Xinhua.Toy makers are actively expanding industrial reaches,enriching cultural elements in products and tapping into the domestic market in their attempts to survive global headwinds,reporters from

Cavitation cloud impingement and scattering motion of jet in rock breaking process

The cavitation cloud impingement of the jet in the rock breaking process was experimentally investigated to reveal the jet erosion mechanism in drilling of petroleum exploitation. Serial erosion tests and flow visualization were performed, where the cavitation cloud motion in the erosion crater was obtained with the designed transparent specimen. Various erosion patterns were identified in the whole erosion process based on the eroded specimen topography. The shallow eroded crater with a shrinking erosion area is generated by the combination of impinging and scattering cavitation clouds. The increase of l_(d) promotes the development of cavitation cloud σ_(c) but reduces the impingement frequency f_(d), suggesting that the jet aggressive ability is enhanced when the balance between σ_(c) and f_(d) is reached. The cavitation cloud motion in the erosion crater was investigated with the transparent specimen. The erosion in the crater at shorter exposure periods T_(e) is generated by the combination of impingement and restricted scattering of cavitation clouds. With the continuous development of the erosion damage, the jet's aggressive ability is diminished due to the erosion expansion on sandstone, where the cavitation clouds impinge on the target and then collapse and vanish without restricted scattering.

Casting Technology Breakthrough for Critical Components in LM-2C

It was reported in mid May that a2.5-meter-diameter cast supporting structure was manufactured in the Capital Aerospace Machinery Corporation,a subsidiary of CALT,breaking the 2 meters’diameter technical limit of castings for launch vehicle.The supporting structure will be applied in LM-2C for launching three sat-

Across two phylogeographic breaks: Quaternary evolutionary history of a mountain aspen (Populus rotundifolia) in the Hengduan Mountains

Biogeographical barriers to gene flow are central to plant phylogeography.In East Asia,plant distribution is greatly influenced by two phylogeographic breaks,the Mekong-Salween Divide and Tanaka-Kaiyong Line,however,few studies have investigated how these barriers affect the genetic diversity of species that are distributed across both.Here we used 14 microsatellite loci and four chloroplast DNA fragments to examine genetic diversity and distribution patterns of 49 populations of Populus rotundifolia,a species that spans both the Mekong-Salween Divide and the Tanaka-Kaiyong Line in southwestern China.Demographic and migration hypotheses were tested using coalescent-based approaches.Limited historical gene flow was observed between the western and eastern groups of P.rotundifolia,but substantial flow occurred across both the Mekong-Salween Divide and Tanaka-Kaiyong Line,manifesting in clear admixture and high genetic diversity in the central group.Wind-borne pollen and seeds may have facilitated the dispersal of P.rotundifolia following prevalent northwest winds in the spring.We also found that the Hengduan Mountains,where multiple genetic barriers were detected,acted on the whole as a barrier between the western and eastern groups of P.rotundifolia.Ecological niche modeling suggested that P.rotundifolia has undergone range expansion since the last glacial maximum,and demographic reconstruction indicated an earlier population expansion around 600 Ka.The phylogeographic pattern of P.rotundifolia reflects the interplay of biological traits,wind patterns,barriers,niche differentiation,and Quaternary climate history.This study emphasizes the need for multiple lines of evidence in understanding the Quaternary evolution of plants in topographically complex areas.

Determination of the flooding zone during a dam break in a channel with a bend in the presence of several obstacles by the VOF method

This paper aims to investigate a dam break in a channel with a bend in the presence of several obstacles.To accurately determine the flood zones,it is necessary to take into account many factors such as terrain,reservoir volume.Numerical modeling was used to determine the flood zone.Numerical modeling based on the Navier-Stokes equations with a turbulent k-epsilon RNG model,the Volume of Fluid(VOF)method and the PISO algorithm were used to analyze the flow in a bend channel at an angle of 10 with the obstacles.To verify the numerical model,a test on dam break in the 450 channel was conducted.The simulation results were compared with experimental data and with the numerical data of existing data.Having been convinced of the correctness of the mathematical model,the authors carried out a numerical simulation of the main problem in three versions:without barriers,with one obstacle,with two obstacles.According to the obtained numerical results,it can be noted that irregular landforms held the flow,a decrease in water level and a slower time for water emergence could be seen.Thus,the water flow without an obstacle,with one obstacle and with two obstacles showed 4.2 s,4.4 s and 4.6 s of the time of water appearance,respectively.This time shift can give a certain advantage when conducting various events to evacuate people.

Team China’s Groundbreaking Success at Paris Olympics

China’s Olympic delegation at the Paris 2024,with 404 athletes competing in 232 events across 30 sports,clinched 40 gold,27 silver,and 24 bronze medals,marking their best performance at an Olympics held abroad.The success of these athletes across various disciplines demonstrates the country’s efforts to expand its athletic prowess while also marks a new chapter for Chinese sportsmanship on the international stage.

Enhancing textile production:Smartex exhibits groundbreaking solutions

Smartex,a trailblazing leader in textile industry innovation,was proud to announce its return to ITM 2024,showcasing unparalleled advancements in quality control and production efficiency.Building on the success of previous exhibitions at ITM 2022 and ITMA Milan 2023,Smartex emerges stronger than ever,presenting its complete Smartex System tailored to transform textile manufacturing.

Coffee Break和Seminar:提升大学生创新能力的有效方法——南京农业大学生物学理科基地大学生科研训练计划的实践

大学生科研训练（Student Research Training，SRT）计划是提高大学生科研能力的重要途径之一，也是培养国家理科基地创新性人才的重要举措。为了解决在实施SRT过程中出现的老师与学生交流不足的问题，南京农业大学引入了以Coffee Break和Seminar为主体的交流模式。经过近四年的实践探索，该模式有力地完善和保障了SRT的顺利实施，大大促进了创新型人才的培养。文章对此进行了详细的阐述。

单一界化限制与BREAK类结果句式的推导

Tenny(1994)提出的单一界化限制规定一个事件最多只能被界化一次。但是,这一论断受到了BREAK类结果句式的挑战,因为这类句式包含两个界点。本文以事件结构理论为背景,从维度的视角对这一论断进行了修订和重新解释。以此为基础,本文提出了一个基于维度和影响性并将运动事件和变化事件统于一体的事件句法模型,对英汉语BREAK类结果句式的生成过程进行了推导和分析。研究表明,这个句法模型体现出了界性、动性和影响性等事件结构特征之间的相互关系,可以较好地处理BREAK类结果句式的推导。

Satellite remote sensing reveals overwhelming recovery of forest from disturbances in Asia

Forest ecosystems play key roles in mitigating human-induced climate change through enhanced carbon uptake;however,frequently occurring climate extremes and human activities have considerably threatened the stability of forests.At the same time,detailed accounts of disturbances and forest responses are not yet well quantified in Asia.This study employed the Breaks For Additive Seasonal and Trend method-an abrupt-change detection method-to analyze the Enhanced Vegetation Index time series in East Asia,South Asia,and Southeast Asia.This approach allowed us to detect forest disturbance and quantify the resilience after disturbance.Results showed that 20%of forests experienced disturbance with an increasing trend from 2000 to 2022,and Southeast Asian countries were more severely affected by disturbances.Specifically,95%of forests had robust resilience and could recover from disturbance within a few decades.The resilience of forests suffering from greater magnitude of disturbance tended to be stronger than forests with lower disturbance magnitude.In summary,this study investigated the resilience of forests across the low and middle latitudes of Asia over the past two decades.The authors found that most forests exhibited good resilience after disturbance and about two-thirds had recovered to a better state in 2022.The findings of this study underscore the complex relationship between disturbance and resilience,contributing to comprehension of forest resilience through satellite remote sensing.

WAVE TRANSFORMATION AND BREAKING OVER A RECTANGULAR STEP

An idealized numerical wave flume has been established by finite element method on the bases of Navier Stokes equations through prescribing the appropriate boundary conditions for the open boundary,incident boundary,free surface and solid boundary in this paper.The characteristics of waves propagating over a step have been investigated by this numerical model.The breaker wave height is determined depending on the kinetic criterion.The numerical model is verified by laboratory experiments,and the empirical formula for the damping of wave height due to breaking is also given by experiments.

Study on Characters of Hard Seeds of Amphicarpaea edgeworthii Benth. (Leguminosae) and Methods for Breaking Dormancy

[Objective] This study aimed to understand the characters of hard seeds of Amphicarpaea edgeworthii Benth. （Leguminosae） and explore the methods for break- ing dormancy. [Method] For both aerial and subterranean seeds of A. edgeworthii, the morphological characteristics were observed and the appropriate temperature for germination was explored. For aerial seeds of A. edgeworthii, the characters of hard seeds were studied, and concentrated sulfuric acid treatment, hot water soak treat- ment and mechanical damage treatment were compared to explore the methods for breaking seed dormancy. [Result] The aerial seeds were oblate and averaged 3.38 mm in length, 3.02 mm in width, 1.88 mm in thickness, 15.32 g in thousand grain weight, with a hard seed rate after of up to 98% natural maturation. The subter- ranean seeds were approximately oblate with a maximum diameter of 15 mm and a hundred grain weight of （50.08-58.26 g）; among all the treatments for breaking hardseededness, cutting seed coat treatment and concentrated sulfuric acid treatment for 20 minutes were the most effective methods, whereas hot water soak treatment was the least effective method; constant temperature between 20 and 30 ℃ was optimum for the germination of aerial seeds, and alternative temperature of 30/20 ℃ was most appropriate for the germination of subterranean seeds. [Conclusion] Cutting seed coat treatment and concentrated sulfuric acid treatment for 20 minutes were the most effective methods to break the hardseededness of A. edgeworthii.

增强上肢力量对提高街舞的重要性研究——breaking舞种

根据调查没有接受过或者自发进行上肢力量锻炼的人群中有95%以上认为breaking中的难度动作很难完成,其难度动作中较为基础简单的动作都完成的很吃力,但是经过上肢力量锻炼的人群中有87%以上认为breaking中的难度动作相对比较容易,自己练习起来比较容易,控制能力明显比没有经过锻炼的人群要强很多,能正确地发力。

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Railway Traffic Sets Record China’s railway network saw a record-breaking number of trips in the first 11 months of 2024,backed by stable economic recovery and a revitalised tourism industry.