The main objective of this paper is to investigate and analyse the thermo-hydro-mechanical（THM） coupling phenomena and their influences on the repository safety.In this paper,the high-level waste（HLW） disposal con...The main objective of this paper is to investigate and analyse the thermo-hydro-mechanical（THM） coupling phenomena and their influences on the repository safety.In this paper,the high-level waste（HLW） disposal concept in drifts in clay formation with backfilled bentonite buffer is represented numerically using the CODE BRIGHT developed by the Technical University of Catalonia in Barcelona.The parameters of clay and bentonite used in the simulation are determined by laboratory and in situ experiments.The calculation results are presented to show the hydro-mechanical（HM） processes during the operation phase and the THM processes in the after-closure phase.According to the simulation results,the most probable critical processes for the disposal project have been represented and analyzed.The work also provides an input for additional development regarding the design,assessment and validation of the HLW disposal concept.展开更多
The transport of Cu(II)from aqueous solutions containing buffer media through hollow fiber supported liquid membrane(HFSLM)using di(2-ethylhexyl)phosphoric acid(D2EHPA)dissolved in kerosene as membrane phase and hydro...The transport of Cu(II)from aqueous solutions containing buffer media through hollow fiber supported liquid membrane(HFSLM)using di(2-ethylhexyl)phosphoric acid(D2EHPA)dissolved in kerosene as membrane phase and hydrochloric acid as striping phase was investigated.A set of factors were studied,including tube side velocity,shell side velocity,pH of the feed phase,Cu(II)concentration in the feed phase,buffer media concentration and D2EHPA concentration in the membrane phase.Experimental results indicate that the mass transfer coefficient increases with increasing both carrier concentration in the organic phase and flow rates on the tube side and shell side,and decreases with increasing initial Cu(II)concentration in the feed phase.With increasing pH value and acetate concentration in the feed phase,the mass transfer coefficient reaches a maximum value then decreases.The optimal operating conditions are obtained at pH value of 4.44 and 0.1 mol·L -1 acetic ion concentration in feed phase,and carrier volume fraction of around 10%in kerosene as organic phase.A mathematical model of the transport mechanism through HFSLM is developed.The modeled results agree well with the experimental ones.展开更多
[目的]确定不同越橘栽培基质适宜的施S时间和施S量。[方法]研究在设施栽培条件下CK（园土）、A（园土、草炭土1∶1）、B（草炭土）、C（园土、腐叶土1∶1）、D（草炭土、蛭石1∶1）、E（草炭土、腐叶土、蛭石、其他材料3∶3∶3∶1）6种...[目的]确定不同越橘栽培基质适宜的施S时间和施S量。[方法]研究在设施栽培条件下CK（园土）、A（园土、草炭土1∶1）、B（草炭土）、C（园土、腐叶土1∶1）、D（草炭土、蛭石1∶1）、E（草炭土、腐叶土、蛭石、其他材料3∶3∶3∶1）6种越橘栽培基质施入不同量S后pH值的变化规律。[结果]6种基质pH值的降低主要发生在施S后45 d之内,施S后75~81 d pH值基本达到相对稳定状态,以后随着时间的推移,pH值有小幅度的波动;6种基质中,基质A、B的酸缓冲性最强,基质C较强,其余基质较弱;随着施S量的增大,基质pH值降低幅度逐渐减小。[结论]该研究结果为棕壤地区越橘栽培土壤的改良和pH值调节提供了依据。展开更多
基金financed and supported by the German research institute "Gesellschaft für Anlagen-und Reaktorsicherheit (GRS) mbH"
文摘The main objective of this paper is to investigate and analyse the thermo-hydro-mechanical（THM） coupling phenomena and their influences on the repository safety.In this paper,the high-level waste（HLW） disposal concept in drifts in clay formation with backfilled bentonite buffer is represented numerically using the CODE BRIGHT developed by the Technical University of Catalonia in Barcelona.The parameters of clay and bentonite used in the simulation are determined by laboratory and in situ experiments.The calculation results are presented to show the hydro-mechanical（HM） processes during the operation phase and the THM processes in the after-closure phase.According to the simulation results,the most probable critical processes for the disposal project have been represented and analyzed.The work also provides an input for additional development regarding the design,assessment and validation of the HLW disposal concept.
基金Supported by the Program for New Century Excellent Talents in University （NCET-05-0122） the National Natural Science Foundation of China（20576008 20706003） the Ph.D.Programs Foundation of Ministry of Education of China（200800100001） The authors are grateful to Prof. Xiaolong Lii of Tianjin Polytechnic University for supplying PVDF hollow fibers.
文摘The transport of Cu(II)from aqueous solutions containing buffer media through hollow fiber supported liquid membrane(HFSLM)using di(2-ethylhexyl)phosphoric acid(D2EHPA)dissolved in kerosene as membrane phase and hydrochloric acid as striping phase was investigated.A set of factors were studied,including tube side velocity,shell side velocity,pH of the feed phase,Cu(II)concentration in the feed phase,buffer media concentration and D2EHPA concentration in the membrane phase.Experimental results indicate that the mass transfer coefficient increases with increasing both carrier concentration in the organic phase and flow rates on the tube side and shell side,and decreases with increasing initial Cu(II)concentration in the feed phase.With increasing pH value and acetate concentration in the feed phase,the mass transfer coefficient reaches a maximum value then decreases.The optimal operating conditions are obtained at pH value of 4.44 and 0.1 mol·L -1 acetic ion concentration in feed phase,and carrier volume fraction of around 10%in kerosene as organic phase.A mathematical model of the transport mechanism through HFSLM is developed.The modeled results agree well with the experimental ones.
文摘[目的]确定不同越橘栽培基质适宜的施S时间和施S量。[方法]研究在设施栽培条件下CK（园土）、A（园土、草炭土1∶1）、B（草炭土）、C（园土、腐叶土1∶1）、D（草炭土、蛭石1∶1）、E（草炭土、腐叶土、蛭石、其他材料3∶3∶3∶1）6种越橘栽培基质施入不同量S后pH值的变化规律。[结果]6种基质pH值的降低主要发生在施S后45 d之内,施S后75~81 d pH值基本达到相对稳定状态,以后随着时间的推移,pH值有小幅度的波动;6种基质中,基质A、B的酸缓冲性最强,基质C较强,其余基质较弱;随着施S量的增大,基质pH值降低幅度逐渐减小。[结论]该研究结果为棕壤地区越橘栽培土壤的改良和pH值调节提供了依据。
