One novel metal-organic framework [Cu2（L）（μ3-OH）]n（1, H3L = [1,1＇：3＇,1＇＇-terphenyl]-4,4＇＇,5＇-tricarboxylic acid） has been synthesized and characterized by single-crystal powder X-ray diffraction, IR and...One novel metal-organic framework [Cu2（L）（μ3-OH）]n（1, H3L = [1,1＇：3＇,1＇＇-terphenyl]-4,4＇＇,5＇-tricarboxylic acid） has been synthesized and characterized by single-crystal powder X-ray diffraction, IR and thermogravimetric analyses. Complex 1 crystallizes in orthorhombic crystal system, space group Pbca with a = 21.573（19）, b = 5.404（5）, c = 33.78（3） ？, C21H（12）O7Cu2, Mr = 503.39, V = 3938（6） A^3, Z = 8, Dc = 1.698 g·cm^-3, μ = 2.202 mm^-1, F（000） = 2016, 1.531〈θ〈25.009°, λ（Mo Kα） = 0.71073 A, T = 293（2） K, the final R = 0.0448 and wR = 0.1002. The structure of complex 1 is a three-dimensional（3D） framework based on infinite rod-shaped secondary building units and can be simplified as kgd topology. The gas adsorption measurements for N2, CO2, H2O, CH3OH and CH3CH2OH have been done. Fortunately, the selective sorption of CO2 over N2 was found at 195 K.展开更多
Old-age building was designed in Ziwu Town,from the aspects of energy saving,environmental protection,full use of solar energy and characteristics of the local climate.In order to meet the requirements of energy conse...Old-age building was designed in Ziwu Town,from the aspects of energy saving,environmental protection,full use of solar energy and characteristics of the local climate.In order to meet the requirements of energy conservation,environmental protection and climate adaptability of residential buildings,this paper integrates the construction and design in the prefabricated building design,at the same time,with the consideration of the possibility of expansion and removal of the nursing home,the concept of "modular unit" is put forward.Considering the climatic adaptability of the base position,the utilization of solar energy and the organization of natural ventilation should be paid attention to,also,the rammed soil construction method is added in this design,which can improve the thermal insulation performance of the building enclosure and create a comfortable indoor thermal environment both in winter and summer.In order to realize the object of industrial building construction and design,the prefabricated construction method is used,which produces impact on the surrounding environment more environmentally friendly.The building will be easily built,less restricted,and low-cost.What's more,local material and the advantages of all dry work increase the operability of the project.展开更多
Chinese unit residential buildings can be understood as a flexible urban element, and theintroduction of its concept changed the urban structure of China. In this study, starting from the constraintsof contemporary pl...Chinese unit residential buildings can be understood as a flexible urban element, and theintroduction of its concept changed the urban structure of China. In this study, starting from the constraintsof contemporary planning contexts by Chinese historical units, the categories of historical Chinese unitresidential buildings were analyzed, and how spatial order and social ties has made Chinese units becomea common framework within which collective living takes place, how does the political strategy of theChinese government creates and constructs a particular form of spatial order in each example of Chineseunit residential buildings, and the impact on the daily life of the urban population were studied. Finally,how social relations, politics, and economic strategies confront and interact within Chinese unit residentialbuildings was explored.展开更多
为探究不同反应条件对MOFs微观结构和宏观性能的影响,在不同反应条件下,以硫酸铜(CuSO_(4)·5H_(2)O)和6-(吡啶-3′-基)间苯二甲酸(H_(2)L)为材料,制备了2种金属有机框架材料(MOFs){[Cu_(2)(L)_(2)·C _(2) H _(3) N]}n(1)和{[C...为探究不同反应条件对MOFs微观结构和宏观性能的影响,在不同反应条件下,以硫酸铜(CuSO_(4)·5H_(2)O)和6-(吡啶-3′-基)间苯二甲酸(H_(2)L)为材料,制备了2种金属有机框架材料(MOFs){[Cu_(2)(L)_(2)·C _(2) H _(3) N]}n(1)和{[Cu(HL)_(2)]}n(2),并对合成的金属有机框架材料1和2进行了结构分析、TGA和FTIR表征以及对染料的吸附性能研究。单晶衍射数据分析表明:配合物1和2都属单斜晶系,P 21/c空间群。配合物1是一种基于双核轮桨次级构筑单元[Cu_(2)(COO)_(4)]构筑的三维紧密堆积化合物,配合物2由于配体部分质子化,结构中存在氢键[O_(3)—H…O_(4)],将二维层状网络结构连接成三维结构。配合物1是rtl拓扑类型的网络结构,拓扑符号为(42.610.83);配合物2是sql拓扑类型的网络结构,拓扑符号为(4^(4).6^(2))。2种配合物在相同时间间隔下对不同染料降解性能表明配合物2对水溶液中的孔雀石绿具有一定的化学吸附降解能力。展开更多
基金Supported by the Natural Science Foundation of Shandong Province(No.ZR2016BL01)the Talent Introduction Project of Dezhou University(No.320116)
文摘One novel metal-organic framework [Cu2（L）（μ3-OH）]n（1, H3L = [1,1＇：3＇,1＇＇-terphenyl]-4,4＇＇,5＇-tricarboxylic acid） has been synthesized and characterized by single-crystal powder X-ray diffraction, IR and thermogravimetric analyses. Complex 1 crystallizes in orthorhombic crystal system, space group Pbca with a = 21.573（19）, b = 5.404（5）, c = 33.78（3） ？, C21H（12）O7Cu2, Mr = 503.39, V = 3938（6） A^3, Z = 8, Dc = 1.698 g·cm^-3, μ = 2.202 mm^-1, F（000） = 2016, 1.531〈θ〈25.009°, λ（Mo Kα） = 0.71073 A, T = 293（2） K, the final R = 0.0448 and wR = 0.1002. The structure of complex 1 is a three-dimensional（3D） framework based on infinite rod-shaped secondary building units and can be simplified as kgd topology. The gas adsorption measurements for N2, CO2, H2O, CH3OH and CH3CH2OH have been done. Fortunately, the selective sorption of CO2 over N2 was found at 195 K.
文摘Old-age building was designed in Ziwu Town,from the aspects of energy saving,environmental protection,full use of solar energy and characteristics of the local climate.In order to meet the requirements of energy conservation,environmental protection and climate adaptability of residential buildings,this paper integrates the construction and design in the prefabricated building design,at the same time,with the consideration of the possibility of expansion and removal of the nursing home,the concept of "modular unit" is put forward.Considering the climatic adaptability of the base position,the utilization of solar energy and the organization of natural ventilation should be paid attention to,also,the rammed soil construction method is added in this design,which can improve the thermal insulation performance of the building enclosure and create a comfortable indoor thermal environment both in winter and summer.In order to realize the object of industrial building construction and design,the prefabricated construction method is used,which produces impact on the surrounding environment more environmentally friendly.The building will be easily built,less restricted,and low-cost.What's more,local material and the advantages of all dry work increase the operability of the project.
文摘Chinese unit residential buildings can be understood as a flexible urban element, and theintroduction of its concept changed the urban structure of China. In this study, starting from the constraintsof contemporary planning contexts by Chinese historical units, the categories of historical Chinese unitresidential buildings were analyzed, and how spatial order and social ties has made Chinese units becomea common framework within which collective living takes place, how does the political strategy of theChinese government creates and constructs a particular form of spatial order in each example of Chineseunit residential buildings, and the impact on the daily life of the urban population were studied. Finally,how social relations, politics, and economic strategies confront and interact within Chinese unit residentialbuildings was explored.
