Discovery of materials using“bottom-up”or“top-down”approach is of great interest in materials science.Layered materials consisting of two-dimensional(2D)building blocks provide a good platform to explore new mater...Discovery of materials using“bottom-up”or“top-down”approach is of great interest in materials science.Layered materials consisting of two-dimensional(2D)building blocks provide a good platform to explore new materials in this respect.In van der Waals(vdW)layered materials,these building blocks are charge neutral and can be isolated from their bulk phase(top-down),but usually grow on substrate.In ionic layered materials,they are charged and usually cannot exist independently but can serve as motifs to construct new materials(bottom-up).In this paper,we introduce our recently constructed databases for 2D material-substrate interface(2DMSI),and 2D charged building blocks.For 2DMSI database,we systematically build a workflow to predict appropriate substrates and their geometries at substrates,and construct the 2DMSI database.For the 2D charged building block database,1208 entries from bulk material database are identified.Information of crystal structure,valence state,source,dimension and so on is provided for each entry with a json format.We also show its application in designing and searching for new functional layered materials.The 2DMSI database,building block database,and designed layered materials are available in Science Data Bank at https://doi.org/10.57760/sciencedb.j00113.00188.展开更多
At present,there is a great demand for building materials in the market,and the market prospect of building materials is relatively considerable.Through studying the composition of river sediment and its resource util...At present,there is a great demand for building materials in the market,and the market prospect of building materials is relatively considerable.Through studying the composition of river sediment and its resource utilization in the field of building materials,this paper expounds the current domestic scholars research on river sediment in building materials,and summarizes the current problems and challenges,so as to provide a reference for the sustainable development of river sediment in the field of building materials.展开更多
We are all witnesses to the widespread use of wireless LANs (WLAN) and their easy implementation in indoor environments. Wi-Fi is the most popular technology for the WLAN. However, interference caused by building mate...We are all witnesses to the widespread use of wireless LANs (WLAN) and their easy implementation in indoor environments. Wi-Fi is the most popular technology for the WLAN. However, interference caused by building materials is a common, yet often overlooked, contributor to poor Wi-Fi performance. This interference occurs due to the nature of radio wave propagation and the characteristics of the wireless communication system. Therefore, during the implementation of these networks, one must consider the quasi-static nature of the Wi-Fi signal and its dependence on the influence of various building materials on the propagation of these waves. This paper presents the effects of building materials and structures on indoor environments for Wi-Fi 2.4 GHz and 5 GHz. To establish the interdependencies between factors influencing electric field levels, measurements were conducted in an experimental Wi-Fi network at different distances from the access point (AP). The results obtained show that the electric field strength of the Wi-Fi signal decreases depending on the distance, the building materials, and the transmitted frequency. Concrete material had the most significant impact on the strength of the electric field in Wi-Fi, while glass had a relatively minor effect on reducing it. Wi-Fi operates within the radio frequency spectrum, typically utilizing frequencies in the 2.4 GHz and 5 GHz bands. Additionally, measurements revealed that Wi-Fi signal penetration is more pronounced at lower frequencies (2.4 GHz) as opposed to the Wi-Fi signal 5 GHz. The findings can be used to address the impact of building materials and structures on indoor radio wave propagation, ultimately ensuring seamless Wi-Fi signal coverage within buildings.展开更多
With the aim of enhancing the value of local building materials, the subject of this paper is a thermophysical study of natural Chadian clay from the eastern region of Chad, “Abeche”. Samples were taken from a brick...With the aim of enhancing the value of local building materials, the subject of this paper is a thermophysical study of natural Chadian clay from the eastern region of Chad, “Abeche”. Samples were taken from a brickwork in Abeche from a depth of 1 m, then using a clay brick-making press, 4 × 5 × 8 cm3 clay test tubes were made with 2%, 4%, 6% and 8% cow dung, and a 100% clay sample was used as a control. These samples underwent thermophysical characterization using the hot-wire method with a hot-plane option, yielding results that could improve thermophysical performance. The thermal conductivity of the test sample is in the order of 0.715 to 0.420 W/m. K, at 8% for cow dung, so the addition of cow dung as a percentage in the clay matrix enabled us to obtain various satisfactory thermal parameters.展开更多
The present study focuses on the formulation of new composite consisting of plaster and raffia vinifera particle (RVP) with the purpose to reducing energy consumption. The aim of this study is to test this new compoun...The present study focuses on the formulation of new composite consisting of plaster and raffia vinifera particle (RVP) with the purpose to reducing energy consumption. The aim of this study is to test this new compound as an insulating eco-material in building in a tropical climate. The composites samples were developed by mixing plaster with raffia vinifera particles (RVP) using three different sizes (1.6 mm, 2.5 mm and 4 mm). The effects of four different RVP incorporations rates (i.e., 0wt%, 5wt%;10wt%;15wt%) on physical, thermal, mechanicals properties of the composites were investigated. In addition, the use of the raffia vinifera particles and plaster based composite material as building envelopes thermal insulation material is studied by the habitable cell thermal behavior instrumentation. The results indicate that the incorporation of raffia vinifera particle leads to improve the new composite physical, mechanical and thermal properties. And the parametric analysis reveals that the sampling rate and the size of raffia vinifera particles are the most decisive factor to impact these properties, and to decreases in the thermal conductivity which leads to an improvement to the thermal resistance and energy savings. The best improvement of plaster composite was obtained at the raffia vinifera particles size between 2.5 and 4.0 mm loading of 5wt% (C95P5R) with a good ratio of thermo-physical-mechanical properties. Additionally, the habitable cell experimental thermal behavior, with the new raffia vinifera particles and plaster-based composite as thermal insulating material for building walls, gives an average damping of 4°C and 5.8°C in the insulated house interior environment respectively for cold and hot cases compared to the outside environment and the uninsulated house interior environment. The current study highlights that this mixture gives the new composite thermal insulation properties applicable in the eco-construction of habitats in tropical environments.展开更多
High-entropy materials represent a new category of high-performance materials,first proposed in 2004 and extensively investigated by researchers over the past two decades.The definition of high-entropy materials has c...High-entropy materials represent a new category of high-performance materials,first proposed in 2004 and extensively investigated by researchers over the past two decades.The definition of high-entropy materials has continuously evolved.In the last ten years,the discovery of an increasing number of high-entropy materials has led to significant advancements in their utilization in energy storage,electrocatalysis,and related domains,accompanied by a rise in techniques for fabricating high-entropy electrode materials.Recently,the research emphasis has shifted from solely improving the performance of high-entropy materials toward exploring their reaction mechanisms and adopting cleaner preparation approaches.However,the current definition of high-entropy materials remains relatively vague,and the preparation method of high-entropy materials is based on the preparation method of single metal/low-or medium-entropy materials.It should be noted that not all methods applicable to single metal/low-or medium-entropy materials can be directly applied to high-entropy materials.In this review,the definition and development of high-entropy materials are briefly reviewed.Subsequently,the classification of high-entropy electrode materials is presented,followed by a discussion of their applications in energy storage and catalysis from the perspective of synthesis methods.Finally,an evaluation of the advantages and disadvantages of various synthesis methods in the production process of different high-entropy materials is provided,along with a proposal for potential future development directions for high-entropy materials.展开更多
Depleting fossil energy sources and conventional polluting power generation pose a threat to sustainable development.Hydroelectricity generation from ubiquitous and spontaneous phase transitions between liquid and gas...Depleting fossil energy sources and conventional polluting power generation pose a threat to sustainable development.Hydroelectricity generation from ubiquitous and spontaneous phase transitions between liquid and gaseous water has been considered a promising strategy for mitigating the energy crisis.Fibrous materials with unique flexibility,processability,multifunctionality,and practicability have been widely applied for fibrous materials-based hydroelectricity generation(FHG).In this review,the power generation mechanisms,design principles,and electricity enhancement factors of FHG are first introduced.Then,the fabrication strategies and characteristics of varied constructions including 1D fiber,1D yarn,2D fabric,2D membrane,3D fibrous framework,and 3D fibrous gel are demonstrated.Afterward,the advanced functions of FHG during water harvesting,proton dissociation,ion separation,and charge accumulation processes are analyzed in detail.Moreover,the potential applications including power supply,energy storage,electrical sensor,and information expression are also discussed.Finally,some existing challenges are considered and prospects for future development are sincerely proposed.展开更多
As a mathematical analysis method,fractal analysis can be used to quantitatively describe irregular shapes with self-similar or self-affine properties.Fractal analysis has been used to characterize the shapes of metal...As a mathematical analysis method,fractal analysis can be used to quantitatively describe irregular shapes with self-similar or self-affine properties.Fractal analysis has been used to characterize the shapes of metal materials at various scales and dimensions.Conventional methods make it difficult to quantitatively describe the relationship between the regular characteristics and properties of metal material surfaces and interfaces.However,fractal analysis can be used to quantitatively describe the shape characteristics of metal materials and to establish the quantitative relationships between the shape characteristics and various properties of metal materials.From the perspective of two-dimensional planes and three-dimensional curved surfaces,this paper reviews the current research status of the fractal analysis of metal precipitate interfaces,metal grain boundary interfaces,metal-deposited film surfaces,metal fracture surfaces,metal machined surfaces,and metal wear surfaces.The relationship between the fractal dimensions and properties of metal material surfaces and interfaces is summarized.Starting from three perspectives of fractal analysis,namely,research scope,image acquisition methods,and calculation methods,this paper identifies the direction of research on fractal analysis of metal material surfaces and interfaces that need to be developed.It is believed that revealing the deep influence mechanism between the fractal dimensions and properties of metal material surfaces and interfaces will be the key research direction of the fractal analysis of metal materials in the future.展开更多
Research efforts on electromagnetic interference(EMI)shielding materials have begun to converge on green and sustainable biomass materials.These materials offer numerous advantages such as being lightweight,porous,and...Research efforts on electromagnetic interference(EMI)shielding materials have begun to converge on green and sustainable biomass materials.These materials offer numerous advantages such as being lightweight,porous,and hierarchical.Due to their porous nature,interfacial compatibility,and electrical conductivity,biomass materials hold significant potential as EMI shielding materials.Despite concerted efforts on the EMI shielding of biomass materials have been reported,this research area is still relatively new compared to traditional EMI shielding materials.In particular,a more comprehensive study and summary of the factors influencing biomass EMI shielding materials including the pore structure adjustment,preparation process,and micro-control would be valuable.The preparation methods and characteristics of wood,bamboo,cellulose and lignin in EMI shielding field are critically discussed in this paper,and similar biomass EMI materials are summarized and analyzed.The composite methods and fillers of various biomass materials were reviewed.this paper also highlights the mechanism of EMI shielding as well as existing prospects and challenges for development trends in this field.展开更多
Rechargeable magnesium batteries(RMBs)have been considered a promising“post lithium-ion battery”system to meet the rapidly increasing demand of the emerging electric vehicle and grid energy storage market.However,th...Rechargeable magnesium batteries(RMBs)have been considered a promising“post lithium-ion battery”system to meet the rapidly increasing demand of the emerging electric vehicle and grid energy storage market.However,the sluggish diffusion kinetics of bivalent Mg^(2+)in the host material,related to the strong Coulomb effect between Mg^(2+)and host anion lattices,hinders their further development toward practical applications.Defect engineering,regarded as an effective strategy to break through the slow migration puzzle,has been validated in various cathode materials for RMBs.In this review,we first thoroughly understand the intrinsic mechanism of Mg^(2+)diffusion in cathode materials,from which the key factors affecting ion diffusion are further presented.Then,the positive effects of purposely introduced defects,including vacancy and doping,and the corresponding strategies for introducing various defects are discussed.The applications of defect engineering in cathode materials for RMBs with advanced electrochemical properties are also summarized.Finally,the existing challenges and future perspectives of defect engineering in cathode materials for the overall high-performance RMBs are described.展开更多
Na_(3)V_(2)(PO_(4))_(3)(NVP)has garnered great attentions as a prospective cathode material for sodium-ion batteries(SIBs)by virtue of its decent theoretical capacity,superior ion conductivity and high structural stab...Na_(3)V_(2)(PO_(4))_(3)(NVP)has garnered great attentions as a prospective cathode material for sodium-ion batteries(SIBs)by virtue of its decent theoretical capacity,superior ion conductivity and high structural stability.However,the inherently poor electronic conductivity and sluggish sodium-ion diffusion kinetics of NVP material give rise to inferior rate performance and unsatisfactory energy density,which strictly confine its further application in SIBs.Thus,it is of significance to boost the sodium storage performance of NVP cathode material.Up to now,many methods have been developed to optimize the electrochemical performance of NVP cathode material.In this review,the latest advances in optimization strategies for improving the electrochemical performance of NVP cathode material are well summarized and discussed,including carbon coating or modification,foreign-ion doping or substitution and nanostructure and morphology design.The foreign-ion doping or substitution is highlighted,involving Na,V,and PO_(4)^(3−)sites,which include single-site doping,multiple-site doping,single-ion doping,multiple-ion doping and so on.Furthermore,the challenges and prospects of high-performance NVP cathode material are also put forward.It is believed that this review can provide a useful reference for designing and developing high-performance NVP cathode material toward the large-scale application in SIBs.展开更多
Due to the high cost of environment-friendly materials and limited funds for the new countryside construction,it is the principal contradiction in the application of environment-friendly materials to satisfy the deman...Due to the high cost of environment-friendly materials and limited funds for the new countryside construction,it is the principal contradiction in the application of environment-friendly materials to satisfy the demands of both environment protection and cost reduction.The authors proposed that the influence ranking of these materials on environment should be clarified first to settle this contradiction,that is,to choose energy-conserving and environment-friendly materials within the limit of expenditure.By comparing the energy consumption,shock resistance,economic efficiency and social acceptability of wall materials,the influence ranking was given as below:hollow concrete block < lime-sand brick < baked chamotte brick;by analyzing the advantages and disadvantages of floor and roof concrete materials,as well as attentions for reducing negative impacts,the order of their influence was given as below:precast concrete trough plate < precast hollow strength concrete plate < cast-in-place concrete plate < cast-in-place brick-concrete plate;suitable materials for door and window frameworks were concluded,the influence order of wall and floor decoration materials on environment was given as:bare walls without plastering < walls of stable soil plastering < walls of cement-water plastering < walls of lime plastering;concrete for the overall decoration < parquet floor < tile floor < terrazzo floor;and 7 heat retardation materials were suggested for the construction of new countryside.展开更多
In this paper,the photocatalytic activity of industrial titanium dioxide(TiO2)based nacreous pigments was researched as functional building materials for photocatalytic NO remove.Three industrial TiO2 based nacreous p...In this paper,the photocatalytic activity of industrial titanium dioxide(TiO2)based nacreous pigments was researched as functional building materials for photocatalytic NO remove.Three industrial TiO2 based nacreous pigments were selected to estimate the photocatalytic activity for NO remove.This study is a good proof that pearlescent pigments can eliminate NO,and its performance is positively correlated with its titanium dioxide content.And this research will widen the application of nacreous pigments in functional building materials,and provide a new way to eliminate in door nitric oxide pollution.展开更多
The composite phase change material(PCM) consisting of phase change paraffin(PCP) and polymethyl methacrylate(PMMA) was prepared as a novel type of shape-stabilized PCM for building energy conservation through the met...The composite phase change material(PCM) consisting of phase change paraffin(PCP) and polymethyl methacrylate(PMMA) was prepared as a novel type of shape-stabilized PCM for building energy conservation through the method of bulk polymerization. The chemical structure, morphology, phase change temperature and enthalpy, and mechanical properties of the composite PCM were studied to evaluate the encapsulation effect of PMMA on PCP and determine the optimal composition proportion. FTIR and SEM results revealed that PCP was physically immobilized in the PMMA so that its leakage from the composite was prevented. Based on the thermo-physical and mechanical properties investigations, the optimal mass fraction of PCP in the composite was determined as 70%. The phase change temperature of the composite was close to that of PCP, and its latent heat was equivalent to the calculated value according to the mass fraction of PCP in the composite. For estimating the usability in practical engineering, thermal stability, reliability and temperature regulation performance of the composite were also researched by TG analysis, thermal cycling treatments and heating-cooling test. The results indicated that PCP/PMMA composite PCM behaved good thermal stability depending on the PMMA protection and its latent heat degraded little after 500 thermal cycling. Temperature regulation performance of the composite before and after thermal cycling was both noticeable due to its latent heat absorption and release in the temperature variation processes. The PCP/PMMA phase change plate was fabricated and applied as thermal insulator in miniature concrete box to estimate its temperature regulation effect under the simulated environmental condition. It can be concluded that this kind of PCP/PMMA shape-stabilized PCM with the advantages of no leakage, suitable phase change temperature and enthalpy, good thermal stability and reliability, and effective temperature regulation performance have much potential for thermal energy storage in building energy conservation.展开更多
A new approach is provided to resolve the large-scale applications of coal tar pitch. Carbon foams with uniform pore size are prepared at the foaming pressure of normal pressure using coal tar pitch as raw materials. ...A new approach is provided to resolve the large-scale applications of coal tar pitch. Carbon foams with uniform pore size are prepared at the foaming pressure of normal pressure using coal tar pitch as raw materials. The physical and chemical performance of high softening point pitch(HSPP) can be regulated by vacuumizing owing to the cooperation of vacuumizing and polycondensation. Results indicate that the optimum softening point and weight ratio of quinoline insoluble are about 292℃ and 65.7%, respectively. And the optimum viscosity of HSPP during the foaming process is distributed in the range of 1000-10000 Pa·s. The resultant carbon foam exhibits excellent performance, such as uniform pore structure, high compressive strength(4.7 MPa), low thermal conductivity(0.07 W·m^(-1) ·K^(-1)), specially, it cannot be fired under the high temperature of 1200 ℃.Thus, this kind of carbon foam is a potential candidate for thermal insulation material applied in energy saving building.展开更多
This work focused on characterizing and improving the thermal behavior of metal sheet roofing.To decrease the heat transfer from the roof into a building,we investigated the efficiency of four types of phase change ma...This work focused on characterizing and improving the thermal behavior of metal sheet roofing.To decrease the heat transfer from the roof into a building,we investigated the efficiency of four types of phase change materials,with different melting points:PCMІ,PCM II,PCM III and PCM IV,when used in conjunction with a sheet metal roof.The exterior metal roofing surface temperature was held constant at 50℃,60℃,70℃and 80℃,using a thermal source(halogen lights)for 360 min to investigate and compare the thermal performance of the metal sheet roofing with and without phase change materials for each condition.The thermal behaviors of the phase change materials were analyzed by differential scanning calorimeter(DSC).The results showed the melting points of PCMІ,PCM II,PCM III and PCM IV were around 45℃,50℃,55℃and 59℃,respectively.The integration of PCM IV into the metal roofing sheet increased the thermal performance by reducing the room temperature up to 2.8%,1.4%,1.0%and 0.7%when compared with the normal metal roof sheet,at the controlled temperatures of 50℃,60℃,70℃and 80℃,respectively.The thermal absorption of the phase change materials also caused a time delay in the model room reaching a steady temperature.The integration of phase change materials with metal roofing sheets resulted in better thermal performance and conservation of electrical energy by reducing the demand for cooling.展开更多
To use fly ash and coal waste effectively, the current technologies for reprocessing and recycling these wastes into eco-building materials were reviewed, such as utilizing fly ash as the component of fly ash cement a...To use fly ash and coal waste effectively, the current technologies for reprocessing and recycling these wastes into eco-building materials were reviewed, such as utilizing fly ash as the component of fly ash cement and low heat cement after the processes of separation, removal of carbon remains and fine comminution, calcining coal waste into kaolin and meta-kaolin with suspension technology, and preparing clinkerless alkali-activated geopolymer materials with fly ash and meta-kaolin.展开更多
The necessity and difficulties of waste building material utilization in comprehensive land consolidation are put forward by analyzing the source,quantity and harm of waste building materials.Combined with the practic...The necessity and difficulties of waste building material utilization in comprehensive land consolidation are put forward by analyzing the source,quantity and harm of waste building materials.Combined with the practice of Shanghai,the mechanism and pattern of waste building materials recycling are explored,in order to provide the reference for recycling of waste building materials and efficient promotion of land consolidation.展开更多
Natural radioactivity radionuclides in building materials, such as^(226)Ra,^(232)Th and^(40)K, cause indoor exposure due to their gamma-rays. In this research, in a standard dwelling room(5.0 m 9 4.0 m 9 2.8 m), with ...Natural radioactivity radionuclides in building materials, such as^(226)Ra,^(232)Th and^(40)K, cause indoor exposure due to their gamma-rays. In this research, in a standard dwelling room(5.0 m 9 4.0 m 9 2.8 m), with the floor covered by various granite stones, was set up to simulate the dose rates from the radionuclides using MCNP4 C code. Using samples of granite building products in Iran, activities of the^(226)Ra,^(232)Th and^(40)K were measured at 3.8–94.2, 6.5–172.2 and 556.9–1529.2 Bq kg^(-1),respectively. The simulated dose rates were26.31–184.36 n Gy h^(-1), while the measured dose rates were 27.70–204.17 n Gy h^(-1). With the results in good agreement, the simulation is suitable for any kind of dwelling places.展开更多
The radioactivity concentrations of 226Ra, 232Th and 40K in 24 samples of natural and manufactured building materials commonly used in Bangladesh were measured using HPGe gamma ray spectrometer. The results in the pre...The radioactivity concentrations of 226Ra, 232Th and 40K in 24 samples of natural and manufactured building materials commonly used in Bangladesh were measured using HPGe gamma ray spectrometer. The results in the present study were compared with the world average and also with the reported data available in literature. The radium equivalent activity, the absorbed dose rate, annual effective dose, external and internal hazard indices, gamma index, alpha index, annual gonadal dose equivalent and excess lifetime cancer risk were also evaluated to assess the potential radiation hazards associated with these building materials. All samples under investigation were found to be within the recommended safety limit and do not pose any significant radiation hazards. This study can be used as a reference for more extensive studies of the same subject in future.展开更多
基金Project supported by the National Natural Science Foundation of China(Grant Nos.61888102,52272172,and 52102193)the Major Program of the National Natural Science Foundation of China(Grant No.92163206)+2 种基金the National Key Research and Development Program of China(Grant Nos.2021YFA1201501 and 2022YFA1204100)the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDB30000000)the Fundamental Research Funds for the Central Universities.
文摘Discovery of materials using“bottom-up”or“top-down”approach is of great interest in materials science.Layered materials consisting of two-dimensional(2D)building blocks provide a good platform to explore new materials in this respect.In van der Waals(vdW)layered materials,these building blocks are charge neutral and can be isolated from their bulk phase(top-down),but usually grow on substrate.In ionic layered materials,they are charged and usually cannot exist independently but can serve as motifs to construct new materials(bottom-up).In this paper,we introduce our recently constructed databases for 2D material-substrate interface(2DMSI),and 2D charged building blocks.For 2DMSI database,we systematically build a workflow to predict appropriate substrates and their geometries at substrates,and construct the 2DMSI database.For the 2D charged building block database,1208 entries from bulk material database are identified.Information of crystal structure,valence state,source,dimension and so on is provided for each entry with a json format.We also show its application in designing and searching for new functional layered materials.The 2DMSI database,building block database,and designed layered materials are available in Science Data Bank at https://doi.org/10.57760/sciencedb.j00113.00188.
基金Supported by Undergraduate Training Program for Innovation and Entrepreneurship of Jiangxi Provincial Department of Education(S202310846004&S202310846007).
文摘At present,there is a great demand for building materials in the market,and the market prospect of building materials is relatively considerable.Through studying the composition of river sediment and its resource utilization in the field of building materials,this paper expounds the current domestic scholars research on river sediment in building materials,and summarizes the current problems and challenges,so as to provide a reference for the sustainable development of river sediment in the field of building materials.
文摘We are all witnesses to the widespread use of wireless LANs (WLAN) and their easy implementation in indoor environments. Wi-Fi is the most popular technology for the WLAN. However, interference caused by building materials is a common, yet often overlooked, contributor to poor Wi-Fi performance. This interference occurs due to the nature of radio wave propagation and the characteristics of the wireless communication system. Therefore, during the implementation of these networks, one must consider the quasi-static nature of the Wi-Fi signal and its dependence on the influence of various building materials on the propagation of these waves. This paper presents the effects of building materials and structures on indoor environments for Wi-Fi 2.4 GHz and 5 GHz. To establish the interdependencies between factors influencing electric field levels, measurements were conducted in an experimental Wi-Fi network at different distances from the access point (AP). The results obtained show that the electric field strength of the Wi-Fi signal decreases depending on the distance, the building materials, and the transmitted frequency. Concrete material had the most significant impact on the strength of the electric field in Wi-Fi, while glass had a relatively minor effect on reducing it. Wi-Fi operates within the radio frequency spectrum, typically utilizing frequencies in the 2.4 GHz and 5 GHz bands. Additionally, measurements revealed that Wi-Fi signal penetration is more pronounced at lower frequencies (2.4 GHz) as opposed to the Wi-Fi signal 5 GHz. The findings can be used to address the impact of building materials and structures on indoor radio wave propagation, ultimately ensuring seamless Wi-Fi signal coverage within buildings.
文摘With the aim of enhancing the value of local building materials, the subject of this paper is a thermophysical study of natural Chadian clay from the eastern region of Chad, “Abeche”. Samples were taken from a brickwork in Abeche from a depth of 1 m, then using a clay brick-making press, 4 × 5 × 8 cm3 clay test tubes were made with 2%, 4%, 6% and 8% cow dung, and a 100% clay sample was used as a control. These samples underwent thermophysical characterization using the hot-wire method with a hot-plane option, yielding results that could improve thermophysical performance. The thermal conductivity of the test sample is in the order of 0.715 to 0.420 W/m. K, at 8% for cow dung, so the addition of cow dung as a percentage in the clay matrix enabled us to obtain various satisfactory thermal parameters.
文摘The present study focuses on the formulation of new composite consisting of plaster and raffia vinifera particle (RVP) with the purpose to reducing energy consumption. The aim of this study is to test this new compound as an insulating eco-material in building in a tropical climate. The composites samples were developed by mixing plaster with raffia vinifera particles (RVP) using three different sizes (1.6 mm, 2.5 mm and 4 mm). The effects of four different RVP incorporations rates (i.e., 0wt%, 5wt%;10wt%;15wt%) on physical, thermal, mechanicals properties of the composites were investigated. In addition, the use of the raffia vinifera particles and plaster based composite material as building envelopes thermal insulation material is studied by the habitable cell thermal behavior instrumentation. The results indicate that the incorporation of raffia vinifera particle leads to improve the new composite physical, mechanical and thermal properties. And the parametric analysis reveals that the sampling rate and the size of raffia vinifera particles are the most decisive factor to impact these properties, and to decreases in the thermal conductivity which leads to an improvement to the thermal resistance and energy savings. The best improvement of plaster composite was obtained at the raffia vinifera particles size between 2.5 and 4.0 mm loading of 5wt% (C95P5R) with a good ratio of thermo-physical-mechanical properties. Additionally, the habitable cell experimental thermal behavior, with the new raffia vinifera particles and plaster-based composite as thermal insulating material for building walls, gives an average damping of 4°C and 5.8°C in the insulated house interior environment respectively for cold and hot cases compared to the outside environment and the uninsulated house interior environment. The current study highlights that this mixture gives the new composite thermal insulation properties applicable in the eco-construction of habitats in tropical environments.
基金supported by the National Natural Science Foundation of China(22378431,52004338,51622406,21673298)Hunan Provincial Natural Science Foundation(2023JJ40210,2022JJ20075)+3 种基金the Science and Technology Innovation Program of Hunan Province(2023RC3259)the Key R&D plan of Hunan Province(2024JK2096)Scientifc Research Fund of Hunan Provincial Education Department(23B0699)Central South University Innovation-Driven Research Programme(2023CXQD008).
文摘High-entropy materials represent a new category of high-performance materials,first proposed in 2004 and extensively investigated by researchers over the past two decades.The definition of high-entropy materials has continuously evolved.In the last ten years,the discovery of an increasing number of high-entropy materials has led to significant advancements in their utilization in energy storage,electrocatalysis,and related domains,accompanied by a rise in techniques for fabricating high-entropy electrode materials.Recently,the research emphasis has shifted from solely improving the performance of high-entropy materials toward exploring their reaction mechanisms and adopting cleaner preparation approaches.However,the current definition of high-entropy materials remains relatively vague,and the preparation method of high-entropy materials is based on the preparation method of single metal/low-or medium-entropy materials.It should be noted that not all methods applicable to single metal/low-or medium-entropy materials can be directly applied to high-entropy materials.In this review,the definition and development of high-entropy materials are briefly reviewed.Subsequently,the classification of high-entropy electrode materials is presented,followed by a discussion of their applications in energy storage and catalysis from the perspective of synthesis methods.Finally,an evaluation of the advantages and disadvantages of various synthesis methods in the production process of different high-entropy materials is provided,along with a proposal for potential future development directions for high-entropy materials.
基金funding support from the National Key Research and Development Program of China(No.2022YFB3805800)the National Natural Science Foundation of China(52173059)+1 种基金The Major Basic Research Project of the Natural Science Foundation of the Jiangsu Higher Education Institutions(21KJA540002)Jiangsu Funding Program for Excellent Postdoctoral Talent(2022ZB555).
文摘Depleting fossil energy sources and conventional polluting power generation pose a threat to sustainable development.Hydroelectricity generation from ubiquitous and spontaneous phase transitions between liquid and gaseous water has been considered a promising strategy for mitigating the energy crisis.Fibrous materials with unique flexibility,processability,multifunctionality,and practicability have been widely applied for fibrous materials-based hydroelectricity generation(FHG).In this review,the power generation mechanisms,design principles,and electricity enhancement factors of FHG are first introduced.Then,the fabrication strategies and characteristics of varied constructions including 1D fiber,1D yarn,2D fabric,2D membrane,3D fibrous framework,and 3D fibrous gel are demonstrated.Afterward,the advanced functions of FHG during water harvesting,proton dissociation,ion separation,and charge accumulation processes are analyzed in detail.Moreover,the potential applications including power supply,energy storage,electrical sensor,and information expression are also discussed.Finally,some existing challenges are considered and prospects for future development are sincerely proposed.
基金financially supported by the National Key R&D Program of China(No.2022YFE0121300)the National Natural Science Foundation of China(No.52374376)the Introduction Plan for High-end Foreign Experts(No.G2023105001L)。
文摘As a mathematical analysis method,fractal analysis can be used to quantitatively describe irregular shapes with self-similar or self-affine properties.Fractal analysis has been used to characterize the shapes of metal materials at various scales and dimensions.Conventional methods make it difficult to quantitatively describe the relationship between the regular characteristics and properties of metal material surfaces and interfaces.However,fractal analysis can be used to quantitatively describe the shape characteristics of metal materials and to establish the quantitative relationships between the shape characteristics and various properties of metal materials.From the perspective of two-dimensional planes and three-dimensional curved surfaces,this paper reviews the current research status of the fractal analysis of metal precipitate interfaces,metal grain boundary interfaces,metal-deposited film surfaces,metal fracture surfaces,metal machined surfaces,and metal wear surfaces.The relationship between the fractal dimensions and properties of metal material surfaces and interfaces is summarized.Starting from three perspectives of fractal analysis,namely,research scope,image acquisition methods,and calculation methods,this paper identifies the direction of research on fractal analysis of metal material surfaces and interfaces that need to be developed.It is believed that revealing the deep influence mechanism between the fractal dimensions and properties of metal material surfaces and interfaces will be the key research direction of the fractal analysis of metal materials in the future.
基金National Natural Science Foundation of China(32201491)Young Elite Scientists Sponsorship Program by CAST(2023QNRC001)The authors extend their appreciation to the Deanship of Scientific Research at Northern Border University,Arar,KSA for funding this research work through the project number“NBU-FPEJ-2024-1101-02”.
文摘Research efforts on electromagnetic interference(EMI)shielding materials have begun to converge on green and sustainable biomass materials.These materials offer numerous advantages such as being lightweight,porous,and hierarchical.Due to their porous nature,interfacial compatibility,and electrical conductivity,biomass materials hold significant potential as EMI shielding materials.Despite concerted efforts on the EMI shielding of biomass materials have been reported,this research area is still relatively new compared to traditional EMI shielding materials.In particular,a more comprehensive study and summary of the factors influencing biomass EMI shielding materials including the pore structure adjustment,preparation process,and micro-control would be valuable.The preparation methods and characteristics of wood,bamboo,cellulose and lignin in EMI shielding field are critically discussed in this paper,and similar biomass EMI materials are summarized and analyzed.The composite methods and fillers of various biomass materials were reviewed.this paper also highlights the mechanism of EMI shielding as well as existing prospects and challenges for development trends in this field.
基金support of the National Natural Science Foundation of China(Grant No.22225801,22178217 and 22308216)supported by the Fundamental Research Funds for the Central Universities,conducted at Tongji University.
文摘Rechargeable magnesium batteries(RMBs)have been considered a promising“post lithium-ion battery”system to meet the rapidly increasing demand of the emerging electric vehicle and grid energy storage market.However,the sluggish diffusion kinetics of bivalent Mg^(2+)in the host material,related to the strong Coulomb effect between Mg^(2+)and host anion lattices,hinders their further development toward practical applications.Defect engineering,regarded as an effective strategy to break through the slow migration puzzle,has been validated in various cathode materials for RMBs.In this review,we first thoroughly understand the intrinsic mechanism of Mg^(2+)diffusion in cathode materials,from which the key factors affecting ion diffusion are further presented.Then,the positive effects of purposely introduced defects,including vacancy and doping,and the corresponding strategies for introducing various defects are discussed.The applications of defect engineering in cathode materials for RMBs with advanced electrochemical properties are also summarized.Finally,the existing challenges and future perspectives of defect engineering in cathode materials for the overall high-performance RMBs are described.
基金partly supported by the National Natural Science Foundation of China(Grant No.52272225).
文摘Na_(3)V_(2)(PO_(4))_(3)(NVP)has garnered great attentions as a prospective cathode material for sodium-ion batteries(SIBs)by virtue of its decent theoretical capacity,superior ion conductivity and high structural stability.However,the inherently poor electronic conductivity and sluggish sodium-ion diffusion kinetics of NVP material give rise to inferior rate performance and unsatisfactory energy density,which strictly confine its further application in SIBs.Thus,it is of significance to boost the sodium storage performance of NVP cathode material.Up to now,many methods have been developed to optimize the electrochemical performance of NVP cathode material.In this review,the latest advances in optimization strategies for improving the electrochemical performance of NVP cathode material are well summarized and discussed,including carbon coating or modification,foreign-ion doping or substitution and nanostructure and morphology design.The foreign-ion doping or substitution is highlighted,involving Na,V,and PO_(4)^(3−)sites,which include single-site doping,multiple-site doping,single-ion doping,multiple-ion doping and so on.Furthermore,the challenges and prospects of high-performance NVP cathode material are also put forward.It is believed that this review can provide a useful reference for designing and developing high-performance NVP cathode material toward the large-scale application in SIBs.
基金Supported by National Soft Science Foundation(2008GXS5D128)Scientific and Technological Foundation of Talents(DB07012)~~
文摘Due to the high cost of environment-friendly materials and limited funds for the new countryside construction,it is the principal contradiction in the application of environment-friendly materials to satisfy the demands of both environment protection and cost reduction.The authors proposed that the influence ranking of these materials on environment should be clarified first to settle this contradiction,that is,to choose energy-conserving and environment-friendly materials within the limit of expenditure.By comparing the energy consumption,shock resistance,economic efficiency and social acceptability of wall materials,the influence ranking was given as below:hollow concrete block < lime-sand brick < baked chamotte brick;by analyzing the advantages and disadvantages of floor and roof concrete materials,as well as attentions for reducing negative impacts,the order of their influence was given as below:precast concrete trough plate < precast hollow strength concrete plate < cast-in-place concrete plate < cast-in-place brick-concrete plate;suitable materials for door and window frameworks were concluded,the influence order of wall and floor decoration materials on environment was given as:bare walls without plastering < walls of stable soil plastering < walls of cement-water plastering < walls of lime plastering;concrete for the overall decoration < parquet floor < tile floor < terrazzo floor;and 7 heat retardation materials were suggested for the construction of new countryside.
基金supported by the National Natural Science Foundation of China(51872147)the 111 Project(D20015)the Program for Innovative Research Team of Science and Technology in the Universities of Henan Province(19IRTSTHN025)。
文摘In this paper,the photocatalytic activity of industrial titanium dioxide(TiO2)based nacreous pigments was researched as functional building materials for photocatalytic NO remove.Three industrial TiO2 based nacreous pigments were selected to estimate the photocatalytic activity for NO remove.This study is a good proof that pearlescent pigments can eliminate NO,and its performance is positively correlated with its titanium dioxide content.And this research will widen the application of nacreous pigments in functional building materials,and provide a new way to eliminate in door nitric oxide pollution.
基金Funded by National Natural Science Foundation of China(No.51308275)Natural Science Foundation of Liaoning Province(No.SY2016004)Science Foundation for Young Scientists of Liaoning Educational Committee(No.JQL201915403).
文摘The composite phase change material(PCM) consisting of phase change paraffin(PCP) and polymethyl methacrylate(PMMA) was prepared as a novel type of shape-stabilized PCM for building energy conservation through the method of bulk polymerization. The chemical structure, morphology, phase change temperature and enthalpy, and mechanical properties of the composite PCM were studied to evaluate the encapsulation effect of PMMA on PCP and determine the optimal composition proportion. FTIR and SEM results revealed that PCP was physically immobilized in the PMMA so that its leakage from the composite was prevented. Based on the thermo-physical and mechanical properties investigations, the optimal mass fraction of PCP in the composite was determined as 70%. The phase change temperature of the composite was close to that of PCP, and its latent heat was equivalent to the calculated value according to the mass fraction of PCP in the composite. For estimating the usability in practical engineering, thermal stability, reliability and temperature regulation performance of the composite were also researched by TG analysis, thermal cycling treatments and heating-cooling test. The results indicated that PCP/PMMA composite PCM behaved good thermal stability depending on the PMMA protection and its latent heat degraded little after 500 thermal cycling. Temperature regulation performance of the composite before and after thermal cycling was both noticeable due to its latent heat absorption and release in the temperature variation processes. The PCP/PMMA phase change plate was fabricated and applied as thermal insulator in miniature concrete box to estimate its temperature regulation effect under the simulated environmental condition. It can be concluded that this kind of PCP/PMMA shape-stabilized PCM with the advantages of no leakage, suitable phase change temperature and enthalpy, good thermal stability and reliability, and effective temperature regulation performance have much potential for thermal energy storage in building energy conservation.
基金Supported by the National Natural Science Foundation of China(51472086,51002051)CAS Key Laboratory of Carbon Materials(No KLCMKFJJ1703)
文摘A new approach is provided to resolve the large-scale applications of coal tar pitch. Carbon foams with uniform pore size are prepared at the foaming pressure of normal pressure using coal tar pitch as raw materials. The physical and chemical performance of high softening point pitch(HSPP) can be regulated by vacuumizing owing to the cooperation of vacuumizing and polycondensation. Results indicate that the optimum softening point and weight ratio of quinoline insoluble are about 292℃ and 65.7%, respectively. And the optimum viscosity of HSPP during the foaming process is distributed in the range of 1000-10000 Pa·s. The resultant carbon foam exhibits excellent performance, such as uniform pore structure, high compressive strength(4.7 MPa), low thermal conductivity(0.07 W·m^(-1) ·K^(-1)), specially, it cannot be fired under the high temperature of 1200 ℃.Thus, this kind of carbon foam is a potential candidate for thermal insulation material applied in energy saving building.
基金The authors would like to thank the Thailand Science Research and Innovation(TSRI),Faculty of Science,Naresuan University for providing financial support to this research work,and our research center.
文摘This work focused on characterizing and improving the thermal behavior of metal sheet roofing.To decrease the heat transfer from the roof into a building,we investigated the efficiency of four types of phase change materials,with different melting points:PCMІ,PCM II,PCM III and PCM IV,when used in conjunction with a sheet metal roof.The exterior metal roofing surface temperature was held constant at 50℃,60℃,70℃and 80℃,using a thermal source(halogen lights)for 360 min to investigate and compare the thermal performance of the metal sheet roofing with and without phase change materials for each condition.The thermal behaviors of the phase change materials were analyzed by differential scanning calorimeter(DSC).The results showed the melting points of PCMІ,PCM II,PCM III and PCM IV were around 45℃,50℃,55℃and 59℃,respectively.The integration of PCM IV into the metal roofing sheet increased the thermal performance by reducing the room temperature up to 2.8%,1.4%,1.0%and 0.7%when compared with the normal metal roof sheet,at the controlled temperatures of 50℃,60℃,70℃and 80℃,respectively.The thermal absorption of the phase change materials also caused a time delay in the model room reaching a steady temperature.The integration of phase change materials with metal roofing sheets resulted in better thermal performance and conservation of electrical energy by reducing the demand for cooling.
基金Funded by the Sciences and Technology Bureau of Yulin City (No. 2006YL100-06)
文摘To use fly ash and coal waste effectively, the current technologies for reprocessing and recycling these wastes into eco-building materials were reviewed, such as utilizing fly ash as the component of fly ash cement and low heat cement after the processes of separation, removal of carbon remains and fine comminution, calcining coal waste into kaolin and meta-kaolin with suspension technology, and preparing clinkerless alkali-activated geopolymer materials with fly ash and meta-kaolin.
基金Sponsored by Social Development Project of “Science and Technology Innovation Action Plan” of Shanghai Science and Technology Commission in 2019 (19DZ1203400)。
文摘The necessity and difficulties of waste building material utilization in comprehensive land consolidation are put forward by analyzing the source,quantity and harm of waste building materials.Combined with the practice of Shanghai,the mechanism and pattern of waste building materials recycling are explored,in order to provide the reference for recycling of waste building materials and efficient promotion of land consolidation.
文摘Natural radioactivity radionuclides in building materials, such as^(226)Ra,^(232)Th and^(40)K, cause indoor exposure due to their gamma-rays. In this research, in a standard dwelling room(5.0 m 9 4.0 m 9 2.8 m), with the floor covered by various granite stones, was set up to simulate the dose rates from the radionuclides using MCNP4 C code. Using samples of granite building products in Iran, activities of the^(226)Ra,^(232)Th and^(40)K were measured at 3.8–94.2, 6.5–172.2 and 556.9–1529.2 Bq kg^(-1),respectively. The simulated dose rates were26.31–184.36 n Gy h^(-1), while the measured dose rates were 27.70–204.17 n Gy h^(-1). With the results in good agreement, the simulation is suitable for any kind of dwelling places.
文摘The radioactivity concentrations of 226Ra, 232Th and 40K in 24 samples of natural and manufactured building materials commonly used in Bangladesh were measured using HPGe gamma ray spectrometer. The results in the present study were compared with the world average and also with the reported data available in literature. The radium equivalent activity, the absorbed dose rate, annual effective dose, external and internal hazard indices, gamma index, alpha index, annual gonadal dose equivalent and excess lifetime cancer risk were also evaluated to assess the potential radiation hazards associated with these building materials. All samples under investigation were found to be within the recommended safety limit and do not pose any significant radiation hazards. This study can be used as a reference for more extensive studies of the same subject in future.